UNIVERSITY OF ENGINE

CHEM

SUBMITTED TO

SUBMITTED BY

PROBLEM 3.38(P)
Chlorine at 90°C where P=33.08 bar.
Then find molar values of volume of satu
The RK equation for vapour and vapour like roots is give

𝒁=𝟏+𝜷−𝒒𝜷((𝒁−𝜷)/((𝒁+∈𝜷

𝜷=𝜴_(𝑷_𝒓 )/𝑻_𝒓 𝒒=𝝍𝜶(𝑻_𝒓 )/(

𝜶(𝑻_𝒓 )=𝑻_𝒓^(−𝟏/𝟐) 𝒛=𝑷𝒗/𝑹𝑻

Symbol Values
z ?
V ?
T 363.15
P 33.08
R 83.14
Ω 0.08664
ψ 0.42748
 ε 0
σ 1
Pc 77.1
Tc 417
Pr 0.42905317769
Tr 0.87086331
β 0.04268542134
α(Tr) 1.07158099621
q 6.0711962
R 83.14

Iteration X Z=1+β-qβ (z-β)/(z

1 0.724976267 0.7249762671133
100 0.724976267

Unkonowns Units
z 0.724976267 no
v 661.6896743 cm^3/mol

for liquid and liquid like roots

The equation is givenby

z=β+(z+Єβ)(z+σβ)(1+β-z/qβ)

Symbol Values
z ?
V ?
T 363.15
P 33.08
R 83.14
Ω 0.08664
ψ 0.42748
ε 0
σ 1
 Pc 77.1
Tc 417
Pr 0.42905317769
Tr 0.87086331
β 0.04268542134
α(Tr) 1.07158099621
q 6.0711962
R 83.14

Iteration X
1 0.04268542134
100
Unknowns Values

z
v

Generalized correlations

For molar volume of liquids

Rackett's equation is given by

Symbol Values Units

V ? cm^3mol^-1
Vc 124 cm^3mol^-1
Zc 0.265 no
Tr 0.87086331 no

V=Vc*Zc^(1-Tr)^2/7
V= 59.16324795 cm^3mol^-1
 For vapours and vapours lik

Pitzer correlation is given by

and

Where
B°=0.083-0.422/Tr^1.6

B¹=0.139-0.172/Tr^4.2

Symbol values
z ?
T 363
P 33.08
Tc 417
Pc 77.1
Tr 0.8705035971
Pr 0.4290531777
B° -0.443840968
B¹ -0.168958399
w 0.069
B -0.455499097
R 83.14

Column1 Column2 Column3

Unknowns required values
z=1+BPr/Tr
z 0.77549394
V=ZRT/P
V 707.505062
Symbol Values
z ?
V ?
T 363.15
P 33.08
R 83.14
Ω 0.08664
ψ 0.42748
ε 0
σ 1
Pc 77.1
Tc 417
Pr 0.42905317769
Tr 0.87086331
β 0.04268542134
α(Tr) 1.07158099621
q 6.0711962
R 83.14

IT X
1 0.04268542134
100
NIVERSITY OF ENGINEERING AND TECHNOLOGY,LAHORE

CHEMICAL DEPARTMENT

SIR HUMAYUN WALI

HAFIZ AHMAD RAZA (2017-CH-78)

where P=33.08 bar.

values of volume of saturated laquid and saturated vapours.
pour like roots is given by

𝜷((𝒁−𝜷)/((𝒁+∈𝜷)(𝒁+𝝈𝜷)))

𝒒=𝝍𝜶(𝑻_𝒓 )/(𝜴𝑻_𝒓 )

𝒛=𝑷𝒗/𝑹𝑻

Units
no
cm^3 mol^-1
K
bar
cm^3 bar k^-1 mol^-1
no
no
 no
no
bar
K
no
no
no
no
no
cm^3 bar k^-1 mol^-1

Z=1+β-qβ (z-β)/(z+εβ)(z+σβ)
0.724976267113373

+β-z/qβ)

Units
no
cm^3 mol^-1
K
bar
cm^3 bar k^-1 mol^-1
no
no
no
no
 bar
K
no
no
no
no
no
cm^3 bar k^-1 mol^-1

Units

no
cm^3mol^-1

ations

V=Vc*Zc^(1-Tr)^2/7
rs and vapours like roots

Z=1+BP/RT=1+BPr/Tr

B=B°+wB'

2/Tr^1.6

units
no
k
bar
k
bar
no
no
no
no
no
CM^3mol^-1
cm^3barK^-1mol^-1

Column4 Column5 Column6

uired values Units

no

cm^3mol^-1
 Units
no
cm^3 mol^-1
K
bar
cm^3 bar k^-1 mol^-1
no
no
no
no
bar
K
no
no
no
no
no
cm^3 bar k^-1 mol^-1