Acids and Alkalis-Acids and Base

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Acids and Alkalis

Acidity is measured on the pH scale

 1 is a strong acid
 7 is neutral 
 14 is a strong alkali

acid + alkali  > salt + water


Naming salts:
-  the alkali gives the first half of the name e.g. sodium hydroxide forms sodium salts.
- the acid gives the second part of the name
              : hydrochloric acid gives chlorides
              : nitric acid gives nitrates
              : sulphuric acid gives sulphates
An acid is something which produces hydrogen ions in solution
Bases are the oxides and hydroxides of metals
Alkalis are soluble bases the produce hydroxide ions in solution.
Neutralisation occurs when hydrogen ions and hydroxide ions combine to form water:
H+(aq) + OH-(aq) > H2O(l)
Video link: https://youtu.be/OY_C80eGqSU

Acids and Bases


The amount of detail needed depends on exactly which part of the course you are on. Someone aiming for the higher
level of the Further Chemistry course would need all of this. Check with you specification to find out exactly what you
require.
Acids are hydrogen ion donors. When they react, they release H+ ion(s).
Bases neutralise acids. They are hydrogen ion acceptors. When they react, they accept H+ions.
Some bases are known as alkalis. They contain the OH-ion and are soluble in water.
Strong acids are totally dissociated in water. This means that for hydrochloric acid (HCl) all of the HCl molecules
break down to give H+ and Cl- ions. There is no HCl left.
Weak acids are partly dissociated in water. This means that for ethanoic acid (CH3COOH) some of the CH3COOH
molecules break down to give CH3COO- and H+ but some remain as CH3COOH. This is nothing to do with the CH3 bit
not changing, because these hydrogen are never released. The important thing is that some of the molecules
that release the hydrogen atoms that can be released as ions and some don't.
Strong and weak is different to concentrated and dilute. Concentrated means a lot of substance in only a little solvent;
dilute means lots of solvent and only a little substance.
Ethanoic acid is only ever a weak acid (because that is how ethanoic acid molecules are) but you can have it in a
dilute form (like vinegar) or in the very smelly concentrated form.
Be careful the next time someone asks you if you want coffee strong or weak. You can tell them that you cannot
change how strong it is but you might want to make it more dilute or more concentrated.
Choosing an Indicator
We use an indicator to find the volume of an acid that just reacts with a certain volume of an alkali.
We are trying to find the volumes of each required to give equal numbers of moles of H+(aq) and OH-(aq) ions.
Strong acid with strong base
Assume we have the alkali in the flask and add acid to it. To start with, the pH is high (around 14) and
stays there until just before the end-point when it falls steeply to around pH 1. Any indicator that changes
colour between these pH values will do as an indicator for this reaction.
Weak acid with strong base
Assume we have the alkali in the flask and add acid to it. To start with, the pH is high (around 14) and
stays there until just before the end-point when it falls steeply to around pH 8. After that, it slowly
decreases to around pH 3. Any indicator that changes colour between 14 and 8 will do as an indicator for
this reaction. A good example for this would be phenolphthalein (pink in pH > 10 and colourless in pH <
10).
Strong acid with weak base
Assume we have the alkali in the flask and add acid to it. To start with, the pH is fairly high (around 11)
and decreases fairly quickly towards the end-point when it falls steeply from around pH 6 to around pH 1.
After that, it stays low. Any indicator that changes colour between 6 and 1 will do as an indicator for this
reaction. A good example for this would be methyl orange (red in pH > 4 and orange in pH < 4).

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