AF663A

Assigmenj1
Ans. i . given YHo=O YcHa 0.2, Yoa =07

Xi=? M Wmiy
ASSume a bumis o LooM H2= logm
CHa 2o
02- 7

Change Mass to Mole

Smole
Ha JULIN Ma
Mooeulare Mars 2g/moX
12Smol
CH4 20 =

6 /meX
= 2 1 moles
7o
32 8hmo

Tata Moos =
944
X= Molesa Ha
So M ucien of H Tatay Moles
o.5924
| XH2 Smees_
8.4-4- mol
=

XCMa 25 o 148
844

Xo 8
2-18
44
02592

MWi MHa+ YcHX MeHy+Yo x Moq

olX 2 +o2 X I6+O7 X32
M Wmx 258 3/mal
Ans.1.Ci) Roation a CA;OH lith ain

b(o +cH>0 + dN
C2AcOH+ a (+376 N,)

C'2=b
6 - 2C C=3
H
O +20 =26+C
a-3
N 3.76X 2a = 2d

d 28
Se aun fm Juadion

C2 MsoH + 3(0+ 3 75N) 2C02 +3H0+ I128M

4-6 K 332Kg+376X14H)
4-11-84k

(AF)sHo 4-1184
4-6

= 895
1(iii) ET gasReat man -Squane Vekocity, is
3AT
Vyms M

ho R 8 3144 JK mo/
at T: 3ooK. , Fon Co2
MCo2 44}/ml=44XIlo Kg/mol

3x9314+ X 3oo
Vms 44 Xlo

Vsms I3-94M\s
ms 412/38 ms

a T 6ooK, Fon CO2

Vgms 3x93144 X600

44 Xtor3

VmsS 83-21 mls

i ) Methone (CH) a Mon-lintanmakecul
in CH4 5
Tcata mo. ok atans

Je Tatal no oh DoF =3N - 3 xS =IS

Total No. of DoF = IS

d) Ttanslotional DoF 3
6) Retat ionmal DOF 3

DOF= 3N-6
= 3KxS -6
c) Vibnadinal
9

Far Monoatomic galP

paikie haa Copreituy at Cont. VolumR

y 3 Ru
Whora Ru =
Rx M Moleuan aigtt ogad
speciic gad Conost
Cy3 Rx M
Cy 3 x 287-71/KgK "Fon He R-207:1
M-4
Cy 1246 26 KT/KaAK
FOn A 20g.13, M 40u
Jo Cy = 3 208 13 x 4o

y-2 O8133/Kg K
(vi) C 20
2-
Kp-(Ko
(Xo2)
2
Pa
p
(Xo2)

1.(Vii) 2 Co + 2c0,
298K, Latm, T= loook
=l, Tat =
Fini
Fon Cont. Voluma | S= SU

And Hp-Hp -Ru (NA ini-p Tad)=o O

EMh ENhi -

Ru CATi -NoTag)=o

HR=2 x (-Ilos27)
=
22 1OS4
p = 2hto, + Clooo)LTad-2961|

2-393546+ 5+360 ( Tad-298)

Hp787092 +lo8.72 Cd-298

 a(NeT-N Tad)
8 314 (3 K298 -2 Tad)

lut all thoh Valus in n,0

-2210S4 4787092 -1o8.72( Tad-298)-8314 (894-2 Ta)

S66038-1o8 72 lad+16-62 Tad t 2496S Bo

-921 Tad = - $91oo3 ES

dd6416 97K/
ad = 647K

CO+O S O2 CO2
.Cix) at T-lo 00K

AH°CT) =
Heco looo)-h o)-os hlooo)
-C3946s9) -(-12,022) - osx( )

=-394, 659 + In2, 022

DHCD -
-28 2,63 7KT/KmoR
S°Ct)=Ldaro) loo)-0:S,(ooo)
3. 8z 4-23 4. 4SO Sx 243. So7
) 62 369S KI/Kmo-k\
sx) Te 6ooK , P-20atm

ScCboo, 2) =
(6o) +Ru x6oonleoz
po

248 2
-39S 226 +8 314X600 kn
391,7/8.30 KT/Kmo
eoboop -

5C1-d)CO2+05H20+0.25 02 +1-8BN
3 o5aCO +0

Te), T 2SooK P= tatm

mix-, Smin Hmin

Cm CTP) =
EN9 (TP)
05
3(Tleo)+ S0+
O
H, o
=
o-S
at t0-25 8o2 +t85 aNa
VEE
o:S, fog,
CO KcoXI\o:5, Ho=
o =
-

7o2 +S75
250 D= 8(2Soo)
o:s -1078ai44%64
+8314x2 Soqxn
co2s0)=g , (2 Soo) 20 785
=
9.936
I064 29
- 144074-
oS )
+ 8314Xx2Soe Xn

614679
o2
X n I 88
314 X2Soo +I3120IE
N t 8
 h.C2So o) -

2 So oSu2 So o)

hu969) +CrHan(2 Soo 298)-2 Seo s 2So

399 + S39SX2262 -2So o x 276.
4 6
252,
-

824 641I K3/kmol

h sa)2Soo Sh, (2Soo)

h28) 2 + Soo) (2 Soo 296)-2Soo
-

, (2 5ou)
2 6o.o92
O+36 645 X 2202 -2Soox
= S6953 7.71 K5/Kme

co 702 457.5
Sco2 10642 99.936
Shoo 824 6411 14407064 = 839048.164

-614 679
N - S695 3771+13120.9g -S 56416 73
otd 0
0SX 8 (o2 + 0 uo+18 6X N,
O

05x tog4 299.936 + 0-5X639048-164

+l:88x556416-73
qmix=1997737502 K
 Hmia(TP) N0 CT)
5h(T)to:s(1-a) haltD4 0.Shy,T)+o25 1,D
+-88 hN(T)

h s 2 5 -2 71,602 K3/Kmo

hca C2Soo) = -35 SoS K3/Kmo

(2Soo= 78,346KI/KmoR
hu2 Soo)=- 168122 o4
K7/Kmu

hN.(25oo) 6 4 0 1 4
342 kT/Kmo

So Fan d =o

Hmiy o+O 5 x-27,6o2) +,0 5x-16812204)

84o61
.02
+ 0 + - 8 8x 64o14 342
120339. 39. 44

= - 99.51S.o5 KJ /Kmo 20440o +63

Forn =O
400. 463
e5K-3SSos)+5 2o4-
Hmixo 45X-271,602) +0
+02SxFE746

Hmuiy= 90197 S63 K T/Kml

Fa o2
mup oX(-3SSoS)+ o.4 X(-27162)+ o oSx78 346
+204400,463

96126 463 K TiKmal

Fa d0.3
HTx
HT =
1SX(-3SSo + +035X(-271602) +o.075X 70 346
+204400.4+63
10988 96 3K TMl.
 Fon d= g.4

+0-1X 7E 346 + 20o 44oo.4633

2X-3So s) + 0 3x (-271602)
H o

Hni l2 365 3 463KT/kme

Fon d 0 5
+ o12SX 78 346+204
400 4/3
0:2SY-27162
25X-3SSoS +
H o
= 13741 696R/mod.

Fcen o6 467
+ 615 K763 +6 +
4400.
20
+o 2X-271502)
Hmy 0:7x -3.SSoS
ISu9o. 46 1m.

Fond-o 7 0440 0-9%7

1SX-27/6o 2
+O1 7S K 78346 +2
o3SX-3SSoS + O
pmi
= 16494 3. 963 K} K

X 7 8 3 4 6 + 2 0 4 4 00.4
67
o IX 271602 +0 2 =

SSoS
Hd e . 4 K-7
203107. 463 KI]Kml
=

Fan d o9
X 27/50 2 to 22s X B746 +2o4 400 467
Hy o4SX-7 SSof-o oS

=1942 4 6.21 K/m

Fon d= 9400 46?
0.SX-3SsoS
+0. 2SX 78346 t20
Hmiy=)
=206234.463 KT/Kmul
CEA
a Rauibriwm,
T-2 Sook,
P- Lakm =

-24 9722 KT/Ra

min pa, = ,8866 K3 /Kg K

mdbn) p, -255.18

o03699
 TEMPERATURE AND PRESSURE

CASE

REACTANT MOLES ENERGY TEMP

FUEL Co 50.0000000
KD/KG-0
0.000
FUEL 50.e000e00 e.000
OXIDANT Air L00.e0000e0 .000 0.000

O/F 4.68515AFUEL= 17.840735 R,EQ.RATIO= 1.6OO00 PH, EQ. RATI0- 1.80e0e

THERHODYNANIC PROPERTIES

BA 1.0132
T, K 500.0e
RHO, KG/CU 1.3819-1
K/KG
KI/KG 5.18
-988.39
, wsK) 24972.2
K 3 / (KG6) (*) .8868

M,(1/n) 28.350
(dLv/dLP)t 00883
(dLV/dLT)p
CP3(KG) (K)
2554
GAAS
3.3500
1.1420
SON VEL,M/SEC 915.1

MASS FRACTIOS
 0 SKmo Co +O«S KmoX H2
HPm

CogL ) T loooK,
CO2,H20, N2

Cp(lo0= 54 3(o kT/ kno -K

(tooo) = 4-1 71s KI/ KmoS-K

Ce,
=32. 762 KT/Kmo9-K
, loo)

ACP (looo) =
CC02)-9 do)
20
-

(1o-9(loe)
- C l oo

Kp(T=apA
RyT
Cloo lo64299 936
Ho(lo vo)824A

to2 -614,679
M - SS641673

7024S7s

AG
 8296¥
4 2 9 9 : 9 8 2

AG= lo6 +7024S 7.S

76.SS7
l0 00 3 12032
657
=
AGO
1-1000376S7
Iooo e
G314 X
kpCT)
=
e'

k p ( T ) = . 8 0 4 t o

=|
b y CEA T u t

300K,
T o o R ,

tuct
P-latm
whe
Tenad 278K

X c o o o 0 8 9

Xco
Kp 179