THERMODYNAMIC PROPERTIES OF

METHYLENE CHLORIDE
BY SESHADRI, D. N., VISWANATH, D. S. AND KULOOR, N. R.
(Departmeni of Chemical Engineering, Indian Institute of Science, Bangalore-12, India) !
1
[Received : November 5, 1966]

ABSTRACT
Thermodynamic properties of methylene chloride have been computed upto a
temperature of 750° K and a pressure of 200 atmospheres using Martin and Hou
Equation of State. The results are presented in tabular form and as an entropy-
temperature diagram.

INTRODUCTION

Methylene chloride is used as a refrigerant and hence a knowledge of its

thermodynamic properties is necessary. A detailed literature survey revealed
that the thermodynamic properties of methylene chloride are available only
upto a temperature of 423 ° K and a pressure of about 2.6 atmospheres.
In the present work, tables and a diagram of thermodynamic properties
of methylene chloride upto a temperature of 750 ° K and a pressure of 200
atmospheres are presented.

SURVEY OF EXISTING DATA

I. Critical Constants; The critical pressure and temperature of methy-

lene chloride as given by Kobe and Lynn 6 have been used for the
present
investigation.
The critical volume of methylene chloride was calculated using
Meissner's ° method, Vowel's ° method, and by extrapolating the rectilinear
diameter to the critical temperature. The critical volume calculated
by the
last method was found to be in good agreement with the critical volumes
calculated by Meissner's and Vowel's method, and hence was accepted for the
present investigation.
Thus, the critical constants used in this work are :
T, 510.0 °K
Pc r-- 60.0 atmospheres
ala 0.181 litres/mole.

117
•
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coat as •• 0 0 .-..*1 0 CM
Co•Es t) 0 6-••••? 't-.,M u ri0 pi C:- t-i .t a T
ral_r0 Psa 0 tai
00 > 4) as
cti 0 .414-1 0 ••••■I CI cti pi CZ iP r~ 0 r., . 4::: tti V
4.a 6e.4
•••■• • 'sm. 0 z ea
pa MI .0 u s 4-a
fii e.s• 03 a 1.4
°4 1/4.4 4me
a. idor
46) /all CZ 4,
0i) Cd at CZ ,C;4 0 •*gm it
C t 000 Cli) V vb14 °
a ,.. ...... v h. 4.4 is* 0
4.-1 0 .7-i 1:, a
n:, +j; 71 P c 0 u h. o w
e 1.4
- -- 01 .-in ca. o = co o u
0 Ca a 04ciu; oN (Ts 0 c u
il Las a; ac ci
, ...,
CI as
0
..-• tu 00 0 . g•ss U Oa u a C Ist..), E p cij r
••sai 'lir ps cs 4•.•
Cs 1.4
••= 64 g -14 CI 14 ai ••••• lij .::: 0 in cu 4)
in > 4-• 1.- it) .. 4001 EU 44. it 0 in
• = 1..-1
_, 4.. co gn Ili Q Pr U 0 •13 ger-, ° • ?'
co v., a
1:4 U 0 = go
4 1■I ... u
0
*a cr..
0
CI
St
4I
a)
ce•1 a
cci 0 l's
64 U CA =
u c.)
1•4 W) cn
12. ,1:4
-64 0 5
?-%c013
ets.
. • em
cvl P 0 C 0
0 • r•
ISOI
0 tal 'd'a I-1 01) • is it) N
Al
a PIN
4.-• p
(1 Cr6
•.13
cl 0 >, szl 10 ..c4
ti v
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..... ... CA. ° V JD
= CI
4.-1 PCi
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t)
tiO . . a 2 M N • is 4-•
g 1.a 0 .174 44 0 t3 C1 0 14"= 4c-,#3 C4Z2
a 0, at 5... 0 01) fy 0 -0 4-0
fa u u W. .2 4)4)
0 cia) Q a ~4 C "pi
1-1 E cl al ta
> 0 .-• 0 04
I-, Cs ":" .=
clii <LI ••••■ it • PCu ril
• .... 5. al 7:3 IC 1.4 C
il ° 0
+a C
Cti e rns
C3 . 1;1
CZ I-, VI tomi • ..1 II g re c - 5" V"
cd ei....
%b. ,.= u L. N t" ..=
1.) .as
0 0 4-a I-4 n I g(i)eM 11.1 4 a ' E Z cl ra 4-c;
10 , ems 0
XI Sal C CC im• +a t`t
pic 0 al "Zt 0 •••• > lbe ~ = •••1 U la t) et gbal
p,.,4 61 CI
.,., u I) 1..
0 0 I., 0 p 4. ... PO 11■3 twi
ti 0 CIO Z.)4 0 ~ 13
.$1■0 v 71 Ci
7, 1-4 L- ' 0 c a cz"= Q. 4.61 ri)
-a .0 -0 (Ire 1Z; ci) 41)
VI
E
cn cr
in E..„ x t% ta v
cn bi
d pwab ta. 0 pc3 > a U -^, U..•I 4) N ± 1
A a = 0 QV i'm" 1.6 ••••-
••• Cl 0 Cs s
co la s■ill
Wt 0 )•• sits 10 Tao e4 I ~4 I
rA
bp ren cr, ,,.., c c C 0 .11:
u eh 6 45) cn
(4 \O 4.0 42 •••• 4sd
en ett Ca ..0 •••• ct 0 1.1" CIO a E+4
'no %in r4 g-• OG ert 0 C. 0 X C)
to, X IC 03 0 CI .0 M ' Cl) • la ...,
..° C.) t) ". ••••• CD Cu)
0,0E-4 u 1°4 I." ,Cri Cc rt., " 0 •-• I-4 On a 44-'
.4 cA ••4) 00 C4 et ° 7, CI
0 0 ~4 ~4
u >. i... to) .0 u era
d
1.-
g a) en ns• (41 \O 0 a)
U) t•-we 4.) 0.) 1/4..)
4" PC, c....' '-
-'0
1... „ C(400
= 4) •-•-i .... 0 t2 7P,
40 i..$ +a a
s.• ci
ta +
et
X
p or, . .C1 + On oci re 4-' >-, 0 0 1/40 1.4 ...a ca, ....a 4;.4 ° t)> 0 ki ON .4D ikr
i "ts rt) • ;31 {2 ril
d. • :•1.
Cid 1••
••••• 0 Ce.•
to 0
v 04 CA
E" E•ft4 re; cri ci, t's CJI Cl a tu .72 . 0 co) v 0 pC
.4t ° C ti NI
P. cl u - -----, Nr 4.) Ea = ei c.) .-.4 GI . en (.3 rNI
ea 4) M 1:3 t) wit -1:1 t..- C= I-1 0 01) %a 44 ID u .0 1- v) wri-
4 I 1 cn 1 Z f-• L, 03 al u . rw 4a 4-6
0
0 4.) '13 €.) 0 Q. ; t o
ce; I 06
at > CC ea 4 1734 + 1”-1 QM u ', M r= ;:::, a • .... e , 4 a "0 = Pa" 4.0 0 CA MI N r i ..c Ne
i.m. 0 ~ o ... u) •-- cci Cr
4.1 ...NA cc ci .... • ... ..... ea
0 t... g 1 11 I til I.-4 I= a tati
wo E 0 I) •0 0 Ir. ttl 'la cfj in
4sa 4) M 1-4 I I1
.0 0 ....1 ,... et Iv ...., ce-1 0 U
Ira Cie) 1.4 U 6_, 0 p., ..a. *a ' :4 4) a 4 ' ••Z
1 cd 0
0 0 ree, 0 "0 p 4:t "um; 0 ...
693 1-4 a o 4-• * ctl.
u Cle
w ..:-.. Cr4-1. ch , ,_ 0 to.-
'‘•••%
40 0 El +7 2) -T, 0 CI ..:: ra cti ri
- -be-%
cz 0 0
: • • Do ti Do or3 P. 03 "
"
C3
p. 4.4
13 14 4, 0
4•0/ . a
ti)
.13 0.0
CI > t
U
is:
0
Z tu c 42
u ,~I
o 03 =
a4 tu
0
km. t 1..1 0 ct cl 0 n 47.4 viz)
CIN sal ."
u "0 .0 u -*-4
tp P•., cti 1.- a) in
04 = N ch 0 0 "-' evit; 1~11
I-1 ro2 re% a lea. Cr IS tiMi n ta f„j > .0
a
an
Car
)■ ••4 00 4■4
=
tri Oa a-... p 4 -- .ct a - LI 1 9 cc 41 1
(144 fp_ a
‘.. >-• .4 •0
•••
ICJ • • .1.4
c
C) CI 0
P.
4) .0 U *ear 4-a
ni w
eN 0-• 0 'Ell :Zs. (13 0 = t fel
0
CA en > 0 .0 W3 ba4 •
n•P 1..1 can
1.--
a■•0 eti cha 1.4 •C r4
Ct Tui trI
tm) 'ICJ en .C1 Ct • ••• t el) +a
tat -10 (;) •-.. im la
4.)Eta 4-4 V > • 0-:
CI tt (1) 5
= ..... as t ret p limb 11) Z CI 8 7-•
t., u ek!:', 0
° `4-
0
f,..a la) L e
CLa
. ,..
E "9, 2. te, sin o°en
_ a cr m44 Cn
k 4 ea l's
ts, = Pi I) 10 10 -P
s t-2, czta t _. es
C4. • •-• 00 6 .1 4ma 4) t) t) t al •- ■ y 4-.1
th iza p ••-• ...a fli ,-.11 I; r" 124 o VI 0 0 Cd
ta e 4sla
ct ;64 e st ....... s-4 7; co'V V
ci el 4)
E a a to)
4 9..1 V) 0 0 en ON t.) erg 0 ,big 4) iz 4) •-•
a) 0 u V ..,
0 %Tr CI 4) 9 0 0 4... 0 1...
X 4.) ..-. sic;
el 6. al 4) 4-cta I •C Ce) 0 XI ;5 C) - 4 a 4 1- w..: les
• .4.-* = c in isi itri
413‘ E 'aSki
- CI
M oi 43 en I-I e 447, 11-1 IN-1 ai :30 il
in c., s
u .4 . :4 0 pi duOs
CI 4) C:14
in t) tim4 0 iml CL te.". Z.J. el 0 as ---1
0 4) Ill is CV 0 CI) 0 di E
00
~II
4) 0 0
fli nii, ej •CI .c fl u 4-I a.
cc iu ,a.
0 °
..0 Lif
0
. CI 1) .szl eld :Z. cP-1 c..• rp, 0
u "0 .0 tt \--, 4.4
11■1 eCt Voi MI 0 [-, 0 aC 0 4..• 0 ci 1"•4
_ 4-44:11 ilml V+ cli
 TEMPERATURE ° K
o 0
te; o
u et
us

rn 3
z a
• .1
q ID
0
I 13
-Ca
• 0
-ri o
00
' >
- c
0
73
— cm
ill 91
U) °
-..„....
0
X)
>
3 o
3
0
r
rn
0
x o -

•
• .je it
 Thermodynamic Properties of Methylene Chloride 119
The maximum and average absolute deviations were found to be 0.46% and
0.15% respectively. Equation [21 has been used for the present investigation.

5. Heat Capacity of the Saturated Liquid : The heat capacity of saturated

liquid has been presented by Dzung t . These data have been utilized in
checking the internal consistency of the tabulated results.

6. Latent Heat of Vaporization:

The heats of vaporization of methylene
chloride have been presented by Dzung 3. These data were fitted to an
equation of the form :
[3]
with n-r-- 0.41 and AO = 9.062.
The maximum and average absolute deviations of calculated values of
heats of vaporization, in the range of available data were found to be 0.1% and
0.04% respectively. For this work, Equation [31 has been accepted for the
calculation of latent heats of vaporization.

CALCULATION OF THERMODYNAMIC PROPERTIES

For the calculation of thermodynamic properties, Martin and Hou
Equation of State,
RT A2 # B2T + C2e- KT1 Tc As+B37 4- C3e -ICTITe
P
/1„) (V— + (R- Boy

A4 B5T 4- C se – KTITc £41

(V B0) 4 ( 1 BO) '
with K= 5.475 has been used. a

The constants in Equation [41 evaluated following the procedures

outlined the authors' are :
130 = 3.307556 x 1(1 2
A2— — 16.355163
B2 Pa 1.1851555 x 10 -2
C2 333.17645
Ca

43 a 2.1346826
113 a — 1 . 4 1 263 0 x 10 -3
C3 —I 54.635205
A 4 _ 0.11580094
B5 a 7.3944412 x 10 -6
C3 -- 0 1 707260
 4..b cu wo 0 p-. 1----1 f_
".1 "0 "0 rii-ml rare
00
in wci 0
t," WO C C
r's•
i...I
C co
Ci $-4 to 0 Cl, isai L...1
• 1.4 dn
0
imm+1
CZ: 03 4rs a
*ICI crii rt -a t...
4) 0 PP. tu A C
u. a ° Za: 1... ›,
a 1-• o ..= ID ti "
.... ..-1 01 -a' c,)
C. ..... 1- v CA 0
aus o ...• 4-a es- 0
0
.... el V a ..c 0 t 0 gip u
....• >4) itla ---
. U ..... }•-•
6.9 CU fal; ea&
:4 t 0 > U
CO 6 6
C 4)
L.- 1 .4 I k
P o .,.., pr. 0 0 I
. 6- r-- I 10
= .0 .fas'-'
p PO 14m4 '-0 en
, IN
4 o cd :Ts ce) ti cid CA
1.- 1-• vi vic; .= .
C Mt f4a
a 1.1m1 I) (1..) • .... „ , "TZI I. 0 -b....,
1:4 0 ‘n %. ciln --..., Q. ....
re ......
„, gt o
Ck•71 '
•-• phi I. CI .
C = 0 4-.) ct v, c::: CI Ct
0 0 'L.. U,(x)
1-1 C 0 at, 0.0 cm" tli a re-i En
03 fit
-I,-.
U
0 al C = (...) el;
t..1 Li 1-. -CI
P cot) al 4) 00
......, 0 Q., I 7----, Q = • "II
c x 0 41) (1.)
....t • .
1-1" 'CI IC
a, a. ci) ••
4■10
cx,
4.4 WS 4.) as V el . 0 •1Z) .....
C..) ••••■ *4 1.4 ... 1.4 c,.7 fo 43 0
Cr.; ..." U 1.-.4 1.7N
D 1 t._,
ei m = CI
Z C 4-a CU C:4 IZ Cs ..1C3 CI4 I -fth% n
.< ... .... Pit .... et
rm It i, MI Cil al
0 9, 014. E 1k k es
•••1
. •-• - 1.- C 1 CI 4 40" I Nei re) 1 1.14
4 p, _Z
cc
• 0••1
113 0 0
r„ + elD Nt- 4
Et ' a u L 1 ict ----- bq 1 1/4.) .... .0... Q.
tel lit 4--- + c 4-1 a , cz ..----. ‘. 1
....- k ... CU se, cs s....., cn 0 0
,..G 01) gicr + V
1.1 cr cti in (1.) ‘ 1 Na C el -,, .1 %.......• pc .....1 a
tu I.'"Z -■.- Ct
a -...., , + 4 C
Lisi 0 4-' Z 11-') %Mb n lftVZI •-••
CI 1 Cri . al
= o Cti 10 CS 4. k Ct./ ccec est-r n °sr 0 da) et
tal ., -0 1;:l Vi II.)
te. = ,,Z' E ----am Il 1 "0 .....,...• ..---, k + + + I0 0.) =
AC el 0 t..... ti L. c re-3 ap 4.) Q
c: o 0 0
C1J ° 0... 1 E3/44 tem cl ■ID ----, cri:ii g it 1 F.:: V) ism et it
Z 0 ...I
im.m...1
1
1
icti CN .i.
..7
< cy - ......„.
4 0 four) nt3 I ti 12 Ei4
i..." •.- 4 e ct cl r--1 eta- . k k k
3 ta u En >. % .-..........--- .. tam c.) IS. n
CA a.) la 13
tcti .0 > (Ns 0 e -ack i I 4. 1 to
'-44 teal II = ■agel ilwai c‘i
Cq
0
%ere
Swum/ en
-----....
1 as
NI0 C,, 0 4.; tl
0 rt: 9g1 1
S
' E Cam = 043 Uod t%.1 0 . •-• "0 + 'Jr C .ercl
vs 0 o *a' t 4" Cle) *a CV (e) C.) ici li ....
En + tri N...., (.51 1 r+ Cil 1 Ilb• ■ 3
(A •• •t i:
...4 ■
= Pt CI CZ IIMIMINI
I - ---- k4
1
IS% eaffilMIS , 0
pis?
0
'St assi
Z ca 0 Q 0 4 , ta crl F.: . 0:1
•
.
tn >
ct __ a •• •
ts_ ci 4.)
■ CA.so
Aft. I vi
V k
1-• 1-4 0
•kt rt %- --..
c3
4-
es, Ng -6i •........... i
p u bd1/44
t',
aw I
0
vt 7:3
144 Ci
u es
• 0 0 = ts 0 ":3 1- ism
a -• ,
----- I i.... ,
1 -----
, 1 4..e 0 0
0 04..t =
0 0. 0 e4 rem t`Aat
'WM. ....I 4 t 'MI = V) • °'I Cq es--. E....I a1/_ei
4 s, 0 CI 1:1 CI"
.. 10•4 = 40.1 te) 0 ----■ N _i ...
0 - cr, 3 a :sc
(n >a ‘,. ,.....a =
0 74
••
St Wrad 0:1 C esgi
•••....„..
Pci \ifs--
Z, o ta). ch... .1+1 cits
A , 0 cii E ..... = th 4 el
Q .., ...... _ ..., .10 c.) o 11 ...... cr I I ...... 111 ±P + < n. . 4.-. • 6-4
414 bi) C..) nj 'se11 ge me* ...... .... •1■4 ••■4 i fia ra
1.1 10■
,.......t it wit CI f T 1 ‘,....• ....... Q
z a ta.,
`t u 0 tv .s
ria,
ia 4,
+ ...... a., 6' 0
ct writ 0 a4.4 ....... iI 0 ro
:L3
Ca v) ..0 P• t . 4-4 t3 aa. = PIC4 Cr C .. I. ft....... +
±1 4 "CI
" 'it as 0 670 WU • '` 0 el Esetag en a pa 0
ti) 0 p,. ?-.. on i cl In CI •1 Imii vg:1
0 .-- -a N 1■
ID mt
,,, a LZ ca Ti ty ta. = 4. 1.1 % se
ei--, 'I N 4 cl sod IIJ 4-4
vm• . owl DO WI) la
.... a u o t
... as IS.2 = Cli
C • ell ... Me' ÷ + + + +I ti --u.el 1•13 4.•■
c 2 ct
ten *4 r igi Cr rl
ia. ral 1/40 r.,
1h" 1=
z .-•
ttl a I c...) + 0 vs
1,■04 1 = to% CA 5 a .4-• al Nvaleve Cl
bo1
(r) eN4 = Cti =
1:4
tu v 0
0 v . .. 10 7:I I
esi •4■4 CA On C
.0 ••... Ii PC
4 .-sti ai
.m4 0 jet = C:1 C 03 CI
M. 0 it +1•0 PP`
in 0 Cl r3 f
•
 Thrrmodynconic Properties of Methylene Chloride 121

properties, the heats of formation and Berthelot's correction for entropy and
enthalpy. Using the values of entropy and enthalpy at the boiling point, the
constants of integration, Cs and CH were evaluated.
The values of entropy and enthalpy were calculated at various temp&
ratures and pressures using Equations 11 and N.

ENTROPY AND ENTHALPY OF SATURATED VAPOUR

As Martin and Hou Equation of State (Equation 4) holds good for the
saturated vapour region also, the properties of saturated vapour were calculated
in the same manner as in the superheated vapour region.

ENTROPY AND ENTHALPY OF SATURATED LIQUID

The latent heat of vaporization of methylene chloride was calculated

using Equation [31.
The entropy of vaporization A Sy, is related to the heat of vaporization,
by the relation,
Allv— TASy 191

The entropies and enthalpies of' saturated liquid were calculated using the
equations,
[10]
Si 9= Sg — A Sv
(I 1]
ani Iii =--- 1-18, — A If v

The properties of saturated and superheated methylene chloride are

presented in Tables I and 11 respectively, and in graphical form as Figure 1.

INTERNAL CONSISTENCY OF THE TABULATED RESULTS

The internal consistency of the results was checked by two methods as

outlined below. dif s TdS + Vd P may be used

The relation ,
(a) Using dH = Td S + Yd P:
to check the internal consistency of the entropy and enthalpy values.

At constant pressure, [12]

dif a- Td S

from which
Hence di! de d (TS) — Sd T, (13]
S2 e TI SI -- 2 54T
HI 1 gc T2
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 TABLE IT
Properties of Superheated Vapour
(Pressure range 0.1 to 5.0 atms.)

0.1 0.2 0.3 05 1.0 2.0 3.0 5.0

P Atms.-4-
TIC&

280.0 V 228.5 113.6

H -16374 -16386
S 68 43 67.03
300.0 V 245.1 122.1 81.02 48.19
H -16131 -16141 - 16150 - 16170
S 69 27 67.87 67.04 65.98
320.0 V 261.7 130.4 86.67 51.65 25.38
H - 15880 - 1f 888 -15896 - 15912 15954
S 70 08 68 68 67.86 66.81 65.33
341,0.0 V 278 3 138.8 92.27 55.07 27 16 13.19
H - 15621 - 15628 - 15634 - 1564 -15683 -15754
S 70.87 69.47 t)8 65 67.61 66.16 64.62
360.0 V 294.8 147.1 97.85 58 46 28.92 14.13 9.197
H - 15354 - 15360 - 15366 - 15377 - 15406 - 15466 - 15528
S 71.63 70.24 69.42 68 38 66 95 65.45 64.51
380.0 V 311.3 155.4 103.4 61.81 30.65 15.05 9.841 5 664
H -15080 -15U85 -15090 -1c100 - 15124 -15174 -15226 - 15335
S 72.37 70 98 70.17 69.13 67.71 66.24 65.33 64.10
400.0 V 327 8 163 7 108 9 65. 8 32.36 15.94 10.46 6 075
-149;2 -150J4 cta
H - 14799 - 14803 -14807 -14815 -14836 -14879
S 73.09 71.71 70 89 69.8S (8.45 66,99 66.11 64 92
420.0 V 344.2 171.9 114.5 68.52 34.06 16.82 11.07 64t8
1-1 -145U1 -14514 - 14518 - 14525 - 14543 14579 - 14616 - 1404
S 73 79 72.41 71 60 70 57 69.16 67.72 66.86 65.70
440.0 V 360 7 180.2 120.0 71.85 35.74 17.69 11.67 649
H -14215 -14218 -14221 - 14228 - 14143 - 14275 - 14307 - 14374
S 74.48 73.10 72.29 71.26 69 86 68.43 67.57 66.45
 LO*PL 9PTL, ti 9L 98'LL LTSL I co 08 S
Ott" CCU
90E11 — tall — 981 — E8Z11 — NM — , 15111 — H
SVE11 61E11 —
81'SZ ZL'OS 9101 17'691 VVSZ 9 4 805 A 00Z9
ZO - 01 1891
WEL 6817L LZ*9L 6Z4LL 01'8L Li7 . 6L S
Z9' 1 L L9'Zis
0L911" 9S911 — Z179 1 1 — VE911 — ZE911 — 0E911 — 6Z911 — H
86911 —
StIVZ LOt6t7 01 . 86 601 0'9VZ ZsZ6P A 0 009
089 6 gr91
80*ZL 16•L OE'VL 695L It9L I 5'LL 21 68 8L S
Col t
910Z1' 100ZI — 98611 — 8L611'" . 5L611 — tL611 — - ZL611 — H
Lta I
Z9 1 EZ It LV 1056 S'851 8 . LEZ 1 8' 5Lt A 0 . 08C
LEE' 6 8951
817' IL I E*ZL IL'il 60 . 5L I I 9L Z6'9L i. 0E . 8L S
EV'OL
85EZI — ItEr.1 — 5ZEZI — 911Z1 — CHU — ZIEZ1 — . WEN — H
16EZ1 —
Z I *SI 8L'IZ 5C5t IL'I6 WES! 96t i Cat A 0'095
Z66'8
LS OL OL; IL 01 . EL 6VVL 155L ZE'9L I OL'LL S
18 - 69
-
-
-
TEM — g69Z1 — 9L911 — 8S9Z1 — 6179Z 1 — 9t9Z 1 tV9Z 1 Zt911 H
5179 8 C5 PI tOs a 6041' 1188 5'LV1 Ell ZZ ; 6 .ZVP A 0 .0t5
81'69 5rOL SOIL 8IZL LWEL 68 . VL OCCL 1 80' LL s .
-
L901.I — LZO€1 a 900 .:I — L86Z1 — LL6 : 1 — L6Z1 — IL6Z1 — 696Z1 H
got 8 66'El 01'1Z EV'ZV 01 .C8 O'ZVI I'C1Z i 5 1 9Zir A 0 .0Z g
ES'89 09'69 WOG S8' I L VVEL 91*I'L LO'CL I St '9L S
66EE1 VSEEI — ZEEE I — 60EE I — 861E1 — 176ZEI — Z6IC I — 06ZE1 — H
Mitt WEI SZ*OZ LCOP 02 , 18 c9E 1 6.170Z . 001P A 000C
9819 S689 6L'69 01' IL 091L Z9' IL Wirt 18 . 5L S
LZLE1 — 9L9€!' 159E1 a LZ9E1 — i719EI — 609E1 — L09C1 — tO9E1 — H
E8CL VWZI 017'61 01'6C 6V . 8L 01E1 9961 9' E6C A 0 . 08t
91 - L9 LZ*89 Z1'69 tg'OL V61 L 96'ZL WEL cyst 'Si. S
-
'NOVI — V66E1 — 996E1 — 816E1 — tZ6E 1 - 816E1' 916fl 116c1" H
OU'L 9Z'ZI SS'81 EV . LE LUSL SuSt I t'88I F LU A 0'0917
givi
t Not
160 4-.sti2v-d
05 WE 0'1 01 co Ct Z'O
-_
".1 O'S 01 VO atirl 3.MSSaid)
romil
inocitA paingiocins jo sapiodom
('pluo3)-11 ativj
 TABLE 11
Properties of Superheated Vapour
( Pressure range 0.1 to 5.0 atms.)
____ __ _ _ _
P. Atms.-+ 0.1 0.2 0.3 0.5 10 2.0 3.0 5.0
TIC 4 _ _ _ '

640.0 V 525.0 262.4 174 9 104.9 52.38 26.12 17.36 10.36

H -10928 - 10929 - 10930 - 10932 - 10939 - 10951 - 10963 -10988 fr.
S 80.61 79.23 78 42 77.40 76.02 74 63 73.81 72.77
V o
660.0 541.4 270.7 180.3 108.2 54 03 26.95 17.92 10.70
H -10570 -10571 -10572 -10574 -10580 -10592 -10603 -10626 ta:i
S • 81.16 79.78 78.97 77.95 76.57 75.18 74 37 73.33 i
680.0 V 557.9 :78.9 185.9 111.5 55.68 27.78 18.48 11.04
H -10207 -1O08 -10210 -10212 -10217 -10228 -10239 -10261 :IP
S 81.70 80.32 79.51 78 50 77.11 75.72 74 91 73.87 I
7G0.0 V 574.3 287.1 191.4 114.8 57.33 28.61 19.04 11.38 t
H -9841 - 9842 - 9843 -9845 -9850 -9860 - 9870 - 9891 o
S 82.23 80.85 80 04 79.03 77.65 76.26 75,44 74.41
720.0 V 590.7 295.3 196.8 118.1 58.98 29.44 19.59 11.71
11 -9470 - 947 I. -9472 -9474 -9478 -9488 -9498 -9517 c;..".
S 82.75 81.37 80 57 79_55 78.17 76.78 75.97 74.93
750.0 V et3
615.3 307.6 205.1 123.0 61.45 30.68 20.42 12.22 n
11 -8906 -8906 -8907 -8909 -8914 -8923 . - 8932 - 8950 t-
E3-
S 83.52 82.14 81.33 80.32 78.94 77.55 76.74 75.71 :I
tl:
- __ et
 . ______ ____ _
81'09 1949 9Z°99 E1L9 V6 4 89 S
91c1 — 601(1 — SS8ZI — 6S9ZI — LLVZ1 — IT
Z691 0 1169'0 OZE°1 Z60 V61 V A 0°09S
VCE9 VS S9 99°99 11 89 S
S6LEI — ZSZEI — 8Z011 — 9Z8! — H
S9Z9*0 OPZ*1 L86° t 01Z4 A 0'0K
ICZ9 LL V9 S6 - S9 S919 S
OEN — 60E1 — 0017E1 —• ZLIEI — H
d' 19175'0 SS 1 'I 6L13°I EZO 'V A 0 4 0ZS
a
S ZZ19 V619 IZ'S9 8699 S
101SI — MP! — 9LLE1 — LiCEI — II
n 99Z17 .0 Z901 99L1 ZEICE •A o005
z
a 00 19 ZV V9 Lt°99 S
Cl; SOSV1 — V911'1 — 198E1 — H
d 9SS6°J 1179°1 919E A 0°08V
I. 9819 LS°19 1750 S •
ii-
< LLOSI — L95tP1 — 90M — 1-1
z
< IEZ8*0 ZIS'I Eio°1 A 0°0917
19°Z9 LEV9 S
5- 000SI — EMI — Ft
Z91°1 'WE A 0 60117
i
S619 s
6 L0611 — H
72 966•Z A 0'01P
< SO 19 S
ELM — Ft
cAL
ISLIZ A 0•0017
t Nei
o ooz gym cram (roc 0 Oi 0'0Z 0'0i • 4--.stuily
Csullg 0 . 001 01 01)1 32= itissoid)
anochu panatpacIns Jo sa!liadoid
(ppioa)—II aThYj
•
 TABLE (concld.)
Properties of Superheated Vapour
(Pressure range 10.0 to 20( atms.)

P. Anus. 10.0 20.0 30.0 ;. 50.0 100.0 150.0 200 0

T°K

580.0 V 4 576 2.193 1.396 0.7520 0.24/3

H - 12126 -12290 -12466 - 12858 - 14240
S 69 56 67.97 66.95 65.42 62.10 '--i
600.0 V 4.755 2.291 1.468 0 8061 0.2991 -1714-
H -11771 -1192! -12080 -12425 -13518 o
t.
S 70 16 68.60 67.60 66 15 63.33 `z
,tr.
620.0 V 4.933 2.388 1.538 O861 0.3407 0.1672
H -L1412 -1051 -11695 -12005 -12922 -14059 Fi .

S 70.75 69.21 68.23 66.84 64.31 62.00 3

0

640.0 V 5.110 2.483 1.607 0.9048 0.3767 0.2015 *b

et
H -11050 -11179 -11312 -11592 -123S8 -13309 4.-./.4
tt-
ea
S 71.32 69 80 68.84 67.49 65 15 63.19 to
660.0 V 5. 1 86 2.577 1 674 0.9510 0.4C92 0 2309 0.1488 -‘
H -1O85 -10804 -10928 -11185 -11890 -12a68 -13418 et i

S 7L88 70.37 69.43 68.12 65 92 64.18 62.70 Z-

c.c
680.0 V 5.460 2.670 1.740 0 9957 0.4392 0.:566 0 1677 fr
H -10316 - 104728 -10542 - 10179 -11515 -12093 -12786 (11

S 72.44 70.94 70 01 68.73 66 63 65 04 63 65

700.0 V 5 634 2.762 1.804 1.039 0.4674 0.2799 0..878 Si
H -.9943 - 10047 -10155 _10 1 75 -10955 -11558 -12172
S 72.98 71.49 70.57 69.31 67.30 65.81 64 54
720.0 V 5.807 2.853 1.868 1.082 0.4941 0.3015 0.2e68
H -9566 -9666 -9766 -9972 -10505 -11049 -1196
S 73.51 72.03 71.11 69.88 67.93 66 53 65 35
750.0 V 6 065 2.988 1 963 1.144 0.5322 0.3316 0.2328
H -8995 -9086 -9179 -9366 -9842 -10319 -10789
S --..2
7423 72.81 71.91 70.71 68 83 67.52 t'6 45
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izi
ai c,; .0 :1.:4) r--1 in 4-t
mt. . 0 "4 fij tij CI
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0 1,....e o 0" rty lit
ct -
aaa 1
M Ct CA L..._. w■ •• •••■
" ap W. Cci a= ett seams 00 0 en 0 co
0 1•••1 gb b
win CA 00 • •••• in
in frit CI3 0 en AT %.0
(... {A V .0*al , ry • "I
11% ...I V -0 in (1.0 a 0 0 0 0
0 0
C
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at es t•-. *0 .4 •10 c; a 6 6 6 d
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p. •,„.
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0 JD a. 4••• • -
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00 til; ?..%) ...,
0 ci, °
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0 ta.... 4.... . v....„ PI:: cn
Cl)
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. D• (n = . •-• c) g ik, •a
It 0 .2 _ Ou
tu ..... 0 <t3 °~1 % r; on 4,731 > .
v u c..) as ..... 11:3 d cr o tt ...- .r:: ...
ta )--/ 1 0 in In C° en 11■4
CZ "C-1 4
cn ri bli 74 I-I tt Ma %.-,%..."
a
L. "c3 03 t: ttC z 'gri .... 1... = --ii .1...i
4-• Lla
1 06 re": ci en cc;
m
c._ al
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li
EM cr - al u c..) i.-1 1 oo o a, 9'4 'en en
r
a 0 4-4 ••••
it3 cr Cr I cm s Iasi 0
u > simI rml
0 cc VI t•-• CO ofs
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•
C--- \CI CI
414 re. U 4.) col • .-• rj4 ri) + 4... Isom' <
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Z ei scl to + c ti
•...
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I-4
C '?
ii.S1 ;
.< .... "2 •4-1 "Ci kg 4. col C tia) "0 a
%..use rh-, CI "c3 t° i
*a -4-4 0 roN
t. • 4. et:
ti.
7. tet 4,..• o v't "t3 Tr t C
crl ....„... tilim ;1
g €4-4 rg (...)
1:3
4
ta
0 E 4"
...L-1 0 0 4-1 .... C14 'tit
.......... tu
re • g••• 74 1..t en 1 C ez
en t4 re) PPt ea =
ta; 0••• el 1+4 eu =rr
e 0 0 40 o
4.s•
Ob. at CI iiimmi C3 t3 Sa %WI 4. 0 .... - u 0 0
Z 0 bm•• it a Pt > . - - t-t -0 in In kr) tn in w-)
C44 CIII4
t t•INISI (n) en 0 c<4 V)
CI U3 741 ,. t--- t--- r--- r-- r-- ca.--
Z Cr . In 0 0 P.a.1 "0 (A 0
cd 3/4... 4;13 bal cd
rz V.4 73 :El = ■•
14 '41-4
C.)
C 0
I I 1 1 I 1 1
• ad 1•4 I fo 5
64 0
xi n •--4
0 et° cli i
, o o o o o o
4.. %Le ›:,
t > tt 4.1 tei 0 1• v.. p.i jr. en ..-.4 .--, C--. in
a • n• tu 1.-4 to • p) )• I"' .... ,.., 4c-cs•
co el en ql• in in to
al Cio) ct CO ce ist c os
› = I-I Uvizi .
C Li iu isi - .
u w vs ct 11 ...:: a' > .13
gic cao 4) >
.. ca 0 i
C) •-• .0 Iwo cs - 1/2 4a0
00
rci S
z C...) 03 4) u 0 cd 104■
til 4Z-1 0 V V
-I to u El V; fad ra
cr 0 > V V) 4•J C15 14.4 et
VI en >- 41.1 ctl 0 •-• 4-' 1-4 1st .Z8 0 CII CI
• smi III i
4..a OA cn 0 1....) 4° > 4-1 4.) U --I 0 0 000
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C " (1)n v-1
as>2.. C:i 9--4 0 0 c•
e rel le•S ... „.Ss„, 0 15 ec 4) 1.4 in 0
Tui P-I "6-4 u Tzt u
cc: MI tt CO 0 I- 4...0 1.4 esi
cl ..... hm4 0 ,s_. 41.) cm
"c3 o 0 el
Nor U.. on ...• • s4.0 (113 • omml 0
-It
co -0 ra Gn I) 4-k CA 6 c U
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 Thermodynamic Properties of Methylene Chloride 129

TABLE IV

Temp. °K Ckliterature) C/(calcuiated) %deviation

250.0 23.341 22.617 3.10

260.0 23.351 22.941 1.76
270.0 23.476 23.227 1.06

280.0 23.522 23.450 0.31

290.0 23.684 23.667 0.07

300.0 23.898 23.856 0.18

310.0 24.162 24 051 0.46

NOMENCLATURE

Constants in Equation (2)

a,b,c,d, Constants in Equation (1)

B0 1A21B2,,C2
A 3 , 133,C 3 1
A4 1 .85 C5
i Constant in Equation (4)

Heat capacity at constant pressure, calories/gram mole

°K
C F. °K
Heat capacity at constant volume, calories/gram mole
Cv
Enthalpy, calories/gram mole
Constant in Equation (3)
Ti
Pressure, atmospheres
Entropy, calories/gram mole . .K
Temperature, G K
Volume, litres/gram mole
V
Enthalpy of vaporization, calories/gram mole
Q.K
Entropy of vaporization, calories/gram mole
Heat of vaporization, calories/gram molt
Constant in Equation (3)
Ao •
 a, • ›. a
Sa
.....
le (,) ca
• :,
• c i" ..-.
7.." a
> =
0 •1-..4,
— a'
.-
4; li
'44-i
c:7; C
0 = . • Cci
1,1 — Cs4 in .
• IN • .... •:r _•
... r---
00
In
III r4 ‘1.
in .V- c', • a en V %el
ws sic thrt 0 4 / "mom NI.
■ • w in CA
te"..
•■••■'I t)
1-- 1••1
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r 4) sc cy, .
cel a u ..., was
tel Cts 06 .. kn In i-I vs
M Ina 0 les >4
1/46 tn 1... ct et • . ch in
ea 44 fi) cn el a
tio. .
n ”.4 cn 4) in -- ON
'it .1". •t) r-- wi OZ
ON
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'l
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u
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cis 4.) 0 7, .9. ;la
z tat > ••... _. bo )., .,...,
rei VJ • V)
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