5.calculation of Entropy Change of A System

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Calculation of Entropy change of a system

 ΔSSystem = SProducts – SReactants
Q:Calculate
2Ca(s) + O2(g)  2CaO(s)
Given,
[SO Ca = 41.40 J mol-1K-1]
[SO O2 = 205 J mol-1K-1]
[SO CaO = 39.70 J mol-1K-1]

 ΔS  = 2CaO – ( 2Ca + O2 )


System

= 2*39.70 – ( 2*41.40 + 205 )


= -208.4 J mol-1K-1

**The entropy is negative for this system because 2moles


of solid is reacting with 1mol of oxygen gas which are
more disordered to form CaO(s) which is more ordered**

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