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Original article

Textile Research Journal


2019, Vol. 89(15) 3048–3055

Strain sensing fabric integrated ! The Author(s) 2018


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with carbon nanotube yarn for DOI: 10.1177/0040517518807441
journals.sagepub.com/home/trj
wearable applications

Wei Liu1 , Ningjuan Liu1, Yang Gao2, Shuang Wang1,


Qiong Cheng1 and Fujun Xu2

Abstract
Textiles, as a desired platform for wearable smart technology, can be integrated with smart elements in the hierarchical
levels of the fabric structure. In this study, a new way to make strain sensing fabric was developed by embedding a single
strain sensing carbon nanotube (CNT)-based yarn into the woven structure. To overcome the abrasion during insertion,
the yarn was coated with poly(vinyl alcohol) (PVA) to achieve higher mechanical performance. The gauge factor of the
yarn was improved from 0.91 to 1.64. The sensing properties of CNT/PVA yarn integrated strain sensing fabric showed a
gauge factor of over 1.1, a degree of linearity of more than 97% and good stability and repeatability during cyclic loading.
Fabric with different integrated yarn lengths, patterns and output connections has also been investigated. The results
showed that the yarn length and bend over section had a great influence on the strain sensing properties of the fabric.
Furthermore, the fabric strain sensor exhibited a quick and precise response to the finger motion detection, demon-
strating potential in wearable electronics.

Keywords
wearable electronics, strain sensor, carbon nanotube yarn, electric mechanical properties

Flexible strain sensors are a promising prospect for contact resistance change.8 Conductive materials, such
applications in wearable electronics.1,2 Compared with as polypyrrole,9 poly (3,4-ethylenedioxythiophene):
rigid and brittle strain sensors, they can withstand poly(styrenesulfonate) (PE-DOT:PSS)10 and reduced
larger deformation during stretching, torsion or com- graphene oxide11,12 have been coated on the fabric dir-
pressing and provide comfortable contact with human ectly for preparation of flexible strain sensors.
skin. Textiles, as a platform, have been shown to be an However, their electrical durability under abrasion
effective way to obtain flexible strain sensors, with inte- and washing should be considered for practical appli-
grating sensing elements into different levels of the hier- cations. Knitting or weaving conductive fiber or yarns
archy structure, including the fiber, yarn and fabric.3–5 into strain sensing fabrics is another way that can facili-
However, to exploit the development of wearable tate the sensor with the preferred structure and proper-
devices, the sensors should be able to support the ties. For example, Hong et al.13 fabricated conductive
deformations of the textile simultaneously, without
affecting the original textile characteristics, such as soft-
ness, breathable and draping properties.6,7 To respond 1
School of Fashion Engineering, Shanghai University of Engineering
to these specifications, the sensing element is required Science, China
2
to be imperceptible to human beings and compatible to College of Textiles, Donghua University, China
the structure of the textile.
Corresponding author:
The textile strain sensor can be made by applying Wei Liu, School of Fashion Engineering, Shanghai University of
conductive coating or introducing conductive fibers or Engineering Science, Shanghai 201620, China.
yarns, by which the strain sensing can be induced by Email: wliu@sues.edu.cn
Liu et al. 3049

ultra-high molecular weight polyethylene (UHMWP)/ Experimental details


polyaniline (PANI) composite yarn into a cylindrical
plain weft-knitted fabric. The gauge factor of the
Preparation of strain sensing CNT composite yarn
fabric changed from 7.38 to 15.47 with different densi- Aerogel spun CNT yarns with diameter of 40–45 mm
ties. For knitted fabric, electrical resistance change were provided by the Suzhou Institute of Nano-Tech
resulted from a close or distant contact of the adjacent and Nano-Bionics (Suzhou China). PVA 1799 with a
fiber or yarns during the extension, which was caused polymerization degree of 1700 and alcoholysis degree
by the deformation of the loop structure.14 Similarly, of 99% was bought from Sinopharm Chemical Reagent
the strain sensor can also be designed into a warp- Co., Ltd. PVA solution (5% concentrated) was pre-
knitted or woven structure by utilizing the conductive pared by dissolving PVA in a solvent containing
polymer yarns.15,16 For fabricating the free-standing equal volumes of deionized water and ethanol. The
strain sensing fabric, the conductive fibers or yarns CNT yarn was immersed in the PVA solution for
should be scalable and achieve suitable electrical and 30 min and passed through a quilting pin to remove
mechanical properties, which has limited the develop- the excess solution. After drying the yarn at room tem-
ment of the one-piece all-in-one wearable strain sensing perature for 24 h, the strain sensing CNT composites
textile.17,18 yarn can be obtained.
To target the positions of measurement, strain sen-
sing fabric can also be obtained by incorporating the Fabrication and characterization of the strain
yarn strain sensors into the textile structure.19 The sen-
sensing fabric
sing feature of fibers or yarns can be achieved by coat-
ing of intrinsically or extrinsically conductive polymers, As shown in Figure 1, single CNT/PVA yarn of a cer-
usually by immersing the yarns into a solution of con- tain length was integrated into the plain structured
ductive polymer or non-conductive polymer with con- cotton fabric in the interlacing warp direction by
ductive fillers.20–22 There are some other ways to make hand sewing. Two copper wires were connected into
the strain sensing yarn. For example, carbon nanotube the two ends of the integrated yarn by using silver
(CNT) yarn (fiber) made by twisting of the axially paste. Epoxy glue was further applied on the two
aligned CNT assembly also exhibits a piezoresistive ends to ensure a tight and stable connection. To inves-
effect23,24 and can be further improved by incorporat- tigate the influence of the embedding shape on the elec-
ing with polymer.25,26 However, strain sensing fabrics tro-mechanical property of the fabric, yarns with
based on the yarn strain sensors are seldom reported. different lengths of 1, 3 and 5 cm and output connec-
Recently, Eom et al.27 integrated in situ polymerized tions were integrated into the fabric separately.
PEDOT/PS strain sensing fiber into a woven fabric A KEYSIGHT 34461A multimeter was used to test
by using a mechanical sewing machine. The gauge the electrical resistance of the integrated yarn by the
factor of the textile strain sensor was higher than two-probe method. The electrical resistance data was
0.76. Yet, the sensing yarn was attached on the surface output simultaneously during the stretching of a
of the fabric, which might cause low abrasion 60 mm  200 mm substrate fabric with a strain rate of
resistance.
In this paper, we report a flexible strain sensor by
embedding poly(vinyl alcohol) (PVA)-coated CNT
yarn into the woven structure. Among many types of
CNT yarns, aerogel spun CNT yarn has great advan-
tages due to its good electrical properties and high effi-
ciency during production.28 PVA was carefully chosen
as a coating polymer because it has good compatibility
with CNT yarns.26 The coated yarn possesses a strain
gauge factor of 1.64 and it is quite flexible with a strain
at break of 20%. After integration, the textile strain
sensor exhibited a strain gauge factor higher than 1
and good stability. Meanwhile, the sensing properties
of fabric embedded with different patterns and output
connections were investigated under cyclic loading.
Furthermore, the strain sensing fabric was attached to
a finger to monitor the finger bending motion, and
it demonstrated potential application in wearable Figure 1. Schematic view of the carbon nanotube (CNT)/
electronics. poly(vinyl alcohol) (PVA) yarn integrated fabric strain sensor.
3050 Textile Research Journal 89(15)

4.8 mm/min. The micro structural observations of CNT Figure 2(b), as the yarn was covered by polymer with a
yarns and CNT/PVA yarns were conducted with a field densified structure. It also demonstrated an improved
emission scanning electron microscope (FESEM, mechanical performance over the original CNT yarn.
Hitachi S4800, 5 kV). The tensile strength and modulus increased from 228 to
341 MPa and 7.3 to 15 GPa, respectively. Although the
failure strain of the PVA-coated CNT yarn was lowered
Results and discussion from 30% to slightly over 20%, it could still meet the
requirements as a sensor for detecting hand gestures or
Physical properties of CNT yarn and PVA/CNT yarn body posture.29,30 The high strain of CNT yarn resulted
The CNT yarn had a rough surface with whisker CNTs from the rearrangement of CNT alignment during ten-
and micro cracks along the twisting angle direction sile loading. As the PVA combined with CNT in the
(Figure 2(a)). This morphology of the yarn was coated yarn, a dense film structure was obtained, which
formed during the process of spinning CNT yarn via inhibited CNT rearrangement.
the one-step floating catalyst chemical vapor deposition Both CNT yarn and CNT/PVA yarn are elec-
(CVD) method. To improve the properties of CNT trically conductive with resistivity of 70  10 and
yarn, a layer of PVA coating was applied on the cir- 150  10
/cm, respectively. During tensile loading,
cumference of the yarn. After coating by 5% concen- the electrical resistance of both yarns changed linearly
trate PVA solution, the coated CNT yarn shrank with a due to the increased intrinsic resistance of individual
diameter of 35–42 mm and showed a smooth surface in CNTs.26,31 As shown in Figure 2(d), the resistance

Figure 2. (a) Scanning electron microscopy (SEM) picture of carbon nanotube (CNT) yarn; (b) SEM picture of CNT/poly(vinyl
alcohol) (PVA) yarn; (c) Typical stress–strain curves of CNT yarn and CNT/PVA yarn; (d) Tensile strain-dependent relative resistance
change of the CNT yarn and CNT/PVA yarn.
Liu et al. 3051

change rate demonstrated a linear relationship with the the load transfer from yarn to CNT was improved.
tensile strain. The resistance change rate was calculated Therefore, when the intrinsic resistance of CNTs
by the ratio of changed resistance R to the original increased more, it resulted in higher resistance change.
resistance R0. To evaluate the correlation between the Since the yarn had a large tensile strain of 20%, it could
resistance and strain of the yarns, the gauge factor be elongated without breaking with the strain of the
(GF), as a measure of the sensitivity of the strain fabric lower than 20%. Moreover, the improved tensile
gauge, was calculated using the following equation strength, strain sensitivity and anti-abrasion property
of CNT/PVA yarn made it applicable for integrating
R=R0 into a woven structure as a sensing element.
GF ¼ ð1Þ
"
Electro-mechanical properties of single CNT/PVA
where e is the strain of the yarn. The gauge factor of the
yarn inserted in woven fabric
original CNT yarn was calculated to be 0.91, while that
of the PVA-coated CNT yarn was 1.64, which indicated Since the CNT/PVA yarn was much finer compared
an improved sensibility with strain. This was because with normal textile yarns, such as cotton or cotton
the sensing property of the yarn primarily came from blend yarns, it could be easily threaded into the
the intrinsic resistance change of the CNT during woven structure by simply tracing a single warp yarn
stretching.26,32 With PVA coating, the yarn showed or weft yarn into the interlacing space of the textile.
an increased mechanical structure, which proved that Figure 3(a) shows a schematic view of a single

Figure 3. Strain sensing properties of the strain sensing fabric: (a) schematic view of the structure of strain sensing fabric; (b) strain
sensing plain woven fabric with embedding of a single carbon nanotube (CNT)/poly(vinyl alcohol) (PVA) yarn; (c) relative resistance
change of CNT/PVA yarn and strain sensing fabric during five cyclic loadings; (d) gauge factors (GFs) of the CNT/PVA yarn and strain
sensing fabric during five cyclic loadings.
3052 Textile Research Journal 89(15)

CNT/PVA yarn inserted into the plain structure in the and linearity of the yarn and fabric are compared in
warp direction. The strain sensor fabricated by using Table 1. In fact, the resistance change of fabric resulted
cotton fabric as a platform and CNT/PVA yarn as a from the stretching of the embedding yarn, which indi-
sensing element is shown in Figure 3(b). It can be cated that the strain sensing properties of the yarn were
observed that the CNT/PVA yarn exhibited less curva- well maintained in the sensing fabric. This is because
ture in the space in between the warp and weft yarns the fine and strong PVA-coated CNT yarn has a much
than in the warp yarn and weft yarn of the fabric. stable structure, which make it resistant to abrasion
As shown in Figure 3(c), with five times cyclic load- during the stretching and releasing of the fabric.
ing of 3% strain, the fabric and CNT/PVA yarn both The stability of the sensing fabric was also investi-
demonstrated cyclic relative resistance change. After gated by up to 30 cyclic tensile loadings with strain of
the first tensile loading, the electrical resistance of the 7%. The electro-mechanical properties of the elastic
CNT/PVA-coated yarn and integrated fabric increased strain sensing fabric are shown in Figure 4. This
approximately by 2.5% and 1.9%, respectively, due to fabric can keep a very stable electro-mechanical per-
the stress relaxation and realignment of CNT and PVA formance during cyclic loading and would be durable
in the yarn.26 The gauge factor of the fabric increased for applications. The strain-dependent relative resist-
after the first cycle and became stable at around 1.1. ance change in Figure 4(b) shows that the fabric had
Moreover, the resistance response curve of the fabric an electrical response when the strain was higher than
showed good linearity of over 97%. The gauge factor 3% at the first loading cycle. After releasing, the rela-
tive resistance changes of the fabric increased by 1%
and then remained unchanged due to the adjusting of
Table 1. Gauge factor and linearity of carbon nanotube (CNT)/ the CNT-coated yarn in the fabric during stretching.
poly(vinyl alcohol) (PVA) yarn and the fabric sensor during dif- For the following cycles, the electrical response started
ferent loading cycles as the strain reached 4.5% and the gauge factor exhib-
Gauge factor Linearity (%) ited similar and stable values around 1.3. The excellent
electro-mechanical stability of the CNT/PVA yarn
Loading CNT/PVA Fabric CNT/PVA Fabric embedded fabric during 30 cyclic tensile loadings dem-
cycle yarn sensor yarn sensor onstrates that it is capable of working as a strain sen-
1st 1.06 0.64 98.1 97.2
sing fabric for wearable electronics. Compared with
other fabric sensors with stiff conductive yarns woven
2nd 1.36 0.98 99.0 98.6
or knitted into the fabric structure, fabric integrated
3rd 1.33 0.91 98.3 97.8
with sensing CNT/PVA yarn has a much lower
4th 1.27 1.01 99.1 98.7 impact on the fabric, especially its hand feeling and
5th 1.27 0.93 99.1 98.3 draping properties.

Figure 4. Electro-mechanical stability of the strain sensing fabric during 30 cyclic tensile loadings: (a) load cycle-dependent relative
resistance change; (b) tensile strain-dependent relative resistance change.
Liu et al. 3053

Strain sensing fabric with different classified as serial integration (Figure 5(b)) and parallel
integration (Figure 5(c)). For the former, by increasing
integrated patterns of the inserted yarn length, the relative resistance
To monitor the deformation of the fabric in a specific changes obviously decreased. This is because the bend
area, the strain sensing CNT/PVA yarn can be inte- over section of the serial inserted yarn, along the weft
grated into the fabric with different shapes and different direction, was compressed by the adjacent weft yarn
output connections. As shown in Figure 5, CNT/PVA during the stretching along the warp direction, and
yarns with different lengths of 1, 3 and 5 cm were inte- this resulted in the degradation of strain sensitivity. In
grated into the fabric in three different ways. The fabric comparison, the CNT yarns inserted in parallel
was applied with a cyclic loading with a tensile strain of (Figures 5(c) and (f)) were electrically connected with
3%. Figure 5(a) shows the strain sensing fabric with each other by the conductive paste. These patterns
straight insertion of yarns with different lengths. By showed less variation of the resistance change rate as
increasing the yarn length from 1 to 3 and 5 cm, the there was no bend over section along the weft direction.
relative resistance change of both fabrics increased and Therefore, the total length of the inserted yarn had less
showed smooth curves (Figure 5(d)). In fact, the rela- influence on parallel output resistance.
tive resistance changes of the fabric were calculated
based on the resistance change of the inserted yarn. Monitoring of finger bending motions based on the
When a longer CNT was inserted into the woven struc-
ture, the yarn had more contact with the adjacent warp
strain sensing fabric
and weft yarns, making the inserted structure more In order to demonstrate the potential applications of
stable. Therefore, the yarn could take more uniform the strain sensing fabric for wearable devices, the fabric
loading during the tensile stretching of the fabric. was attached to the joint (Figure 6(a)) and segment
With the same insertion length of the CNT/PVA (Figure 6(b)) part of the index finger to detect the
yarns, they can also be integrated into the fabric with minor strain from bending. When the finger was bent,
rectangle patterns (Figures 5(b) and (c)). By setting the the resistance change of the fabric was recorded simul-
width of the pattern to 1 cm, the height of the rectangle taneously by the digital multimeter. As shown in Figure
pattern increased with the increasing of the yarn length. 6, with increasing the bending angel to a certain degree,
Based on the different output connections, it can be the electrical resistance of the fabric increased and then

Figure 5. Strain sensing fabrics integrated with 1, 3 and 5 cm lengths of carbon nanotube/poly(vinyl alcohol) yarn and comparison of
their electro-mechanical properties: (a) and (d) for the straight warp insertion pattern; (b) and (e) for rectangle pattern insertion with
series output connection; (c) and (f) for rectangle pattern insertion with parallel output connection.
3054 Textile Research Journal 89(15)

Figure 6. Monitoring of the finger bending motion with attaching the strain sensing fabric to the joint (a) and segment (b) part of the
index finger.

remained stable. Compared with the fabric that is fixed Funding


on the joint part of the finger, the fabric that is fixed on
The authors disclosed receipt of the following financial sup-
the segment part of the finger had less increase of resis- port for the research, authorship, and/or publication of this
tance due to there being less elongation during the article: This work was supported by the National Natural
bending. This demonstration clearly showed the feasi- Science Foundation of China (Grant No. 51503120), the
bility of the fabric sensor applied in wearable electronic Science and Technology Commission of Shanghai
structures to detect human motions. Municipality (Grant No. 14YF1409600) and the Shanghai
Education Committee (Grant No. ZZgcd14016).

Conclusions
In summary, flexible strain sensing fabrics have been ORCID iD
successfully fabricated by integrating strain sensing Wei Liu http://orcid.org/0000-0002-8811-0356
CNT/PVA composite yarn into woven fabrics. The
electro-mechanical performance of the strain sensing
fabric showed that the strain sensing properties of the References
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