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Study on Compatibility of Thermoplastic Polyurethane
Elastomer/Nylon 6 Blend
Author: WangTao
Tutor: ChenKeJuan
School: South China University of Technology
Course: Mechanical Design and Theory
Keywords: Blend and modify compatibility TPU PA6
CLC: TQ325.14
Type: Master's thesis
Year: 2011
Downloads: 266
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Abstract

Preparing the structure and synthesis of novel high performance plastic alloy by using
modification of polymer blend has become the main trend of domestic and foreign researches. In
this paper, thermoplastic polyurethane elastomer(TPU) as the substrate adding nylon 6(PA6)
prepared TPU/PA6 blend alloy. This blend alloy retained the characteris of TPU, and also has
good tensile properties and antistatic performance by adding electrical carbon black. It reduces
the costs and expands the use of TPU.The compatibility between the polymers is the focus in
the study of polymer blends modified plastics. The properties of the blend modified plastic are
reflected form the compatibility. Therefore, solving the problem of compatibility between
polymers is the key problem in polymer modification. In this paper, we study on the key problem
of compatibility in polymer modification. Then we identified research program to improve
blending modification TPU/PA6 alloy compatibility.Based on the analysis of polymer modification
process, the basic principle of polymer compatibility, introducing improved Huggins-Flory theory
model, looking for the various influence factors of compatibility of TPU/PA6 blend alloy, and
comprehensive comparison of judgment method of compatibility of polymer and improving
compatibilizing method, then the compatibility condition of polymer was derived, and found that
selection of appropriate compatibilizer and ratio is the key to prepare comprehensive
performance TPU/PA6 alloy. It improved the compatibility of TPU/PA6 alloy by adding the
self-synthesized compatibilizer EVA-g-MAH.In this paper, we also comprehensive comparison of
the performance impact on the blend by adding different compatible agents and its dosage.
First, the data was obtained from experiments by selecting several groups of formula. Eventually
get a better compatibilizer and proportion for preparation TPU/PA6 alloy by the data analysis
and theoretical analysis and experimental summary. Test results prove that we prepared
integrated performance TPU/PA6 alloy.Analogy method was used to contrast and analyze the
compatibilization effect of the self-synthesized compatibilizer and those sold in the market such
as HDPE-g-MAH、POE-g-MAH、PP-g-MAH. Experiment compared the effect of the mechanical
properties, morphology and crystal properties on the blend alloy. Based on analyzing and
summarizing of the compatibilizer effects on the compatibilize of the TPU/PA6 alloy, the best
methods to improve the properties of TPU/PA6 blend alloy was obtained. We also improved the
antistatic properties of the blend alloy by adding 5% conductive black carbon. It makes the
project has value and practical significance for industrial applications.
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Study on Compatibility of Thermoplastic Polyurethane Elastomer/Nyl... http://www.dissertationtopic.net/doc/143775

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CLC: > Industrial Technology > Chemical Industry > Synthetic resins and plastics industry >
Polymer resin and plastic > Polyolefin plastic > Polypropylene
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