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Coatings For Elevated Temperature Service in Process Facilities
Coatings For Elevated Temperature Service in Process Facilities
for Elevated
Temperature
S e rvice in
P rocess Facilities
Heated surfaces on stacks, boilers, and similar equipment require
the highest levels of coating technology to withstand
corrosive fumes, cyclic heating operations, thermal expansion,
and atmospheric weathering.
by E. Bud Senkowski, P.E.,
KTA-Tator, Inc.
F
or many operating power generating survey of the formulation technology found
facilities, chemical plants, and in contemporary coating products for ele-
refineries, the painting of heated sur- vated temperature, and outlines surface
faces represents one of the most problem- preparation requirements to ensure accept-
atic and challenging applications for the able coating service life. Also included are
coatings engineer. Heated surfaces found design and material alternatives to liquid
on stacks, breaching, boilers, heat exchang- coatings for protecting heated surfaces.
ers, reactors, stills, crackers, furnaces, and
engine exhaust manifolds have traditionally
required the highest levels of applied
coating technology to achieve successful
Determining Operating
coating installations (Fig. 1). Once installed,
Conditions
the coatings may be subjected to the rigors The most important step in the successful
of corrosive fumes, cyclic heating opera- use of protective coatings at elevated tem-
tions, thermal expansion, and atmospheric peratures is the correct determination of
weathering. Each of these factors can con- the nominal temperature level that the
tribute to the incipient failure of the elevat- equipment or structure will be subject to
ed temperature coating system. during operation. Temperature data taken
The consequences of a less-than-opti- from active recording devices is the most
mal coating selection and installation can reliable basis for determining the tempera-
include elevated maintenance costs ture range during both normal operation
throughout the life of the facility, along and transients. In the absence of instrumen-
with expensive downtime for repairs of the tally recorded data, contact thermometers
substrate. This article presents a generic or infrared pyrometers can be used to de-
44 / Journal of Protective Coatings & Linings Copyright ©1997, Technology Publishing Company
Coatings for High Heat Service
termine point readings on the heated sur- temperatures in atmospheric exposure un-
faces. When direct temperature data are dergo accelerated oxidation, scaling, and
difficult to obtain, data derived from pro- pack rusting that rapidly deteriorate the
cess and equipment diagrams or equipment substrate. The failure to adequately protect
data sheets may be used as a guide to esti- these surfaces can result in costly metal
mating operating temperatures. Plant pro- cleaning and repair operations.
cess engineers may
also be sources for Wet or Dry Heat
temperature data, but Moisture and other
the estimates should chemical vapors can
always be subject to have an adverse effect
review for accuracy. on the performance
In the absence of hard of a coating system
data, process plant operating at elevated
personnel may overes- temperatures. All
timate temperature coatings are perme-
levels in the interest of able to the movement
conservatism. Unfortu- of vapors through
nately, this process their matrix. In the
can impose unreason- case of coatings ex-
able constraints in the posed to boiling liq-
selection of high tem- uids, an elevated oxy-
perature coatings, gen concentration at
forcing the coating the vapor/liquid inter-
specifier or engineer face can place addi-
to eliminate some nor- tional stress upon an
mally acceptable ma- attached coating. In
terials. many cases, wet heat
can cause blistering
Steady or Cyclic and adhesion loss of
Temperature an attached coating,
The rate at which heat Fig. 1 - High heat coatings are whereas the same
needed on hot surfaces on boilers,
flows into or through level of dry heat will
heat exchangers, and other operating
a substrate can affect equipment in power plants have no effect. In
the performance of an almost every case,
attached coating. The steady state tempera- there is a reduction in temperature toler-
ture represents an important design point ance when coatings are exposed to wet
for coating specification. It effectively char- heat. Heated surfaces that are allowed to
acterizes the mean level of temperature at cycle between ambient and some elevated
which the coating will be expected to per- temperature and that are exposed to the
form. However, where the temperature cy- atmosphere can undergo accelerated
cles through a range of values, then the ex- corrosion through contact with oxygen
pansion and contraction of the coating and condensed moisture. In these applica-
system, its substrate, and any structural tions, functional inhibitors must be present
joints over which the coating has been in the coating formulation to prevent sub-
placed will impose additional stress on the strate corrosion during periods of equip-
coating. Low alloy steels subjected to cyclic ment downtime.
Table 1
Thermal Resistance: Silicone Resin Formulations*
Temperature Range
Silicone Content
Resin System Pigment (percent) Fahrenheit Celsius
are used. These coatings also display high Silicone resins are blended in increas-
levels of corrosion resistance. ing amounts with other hydrocarbon resins
to impart heat resistance to a coating
Moisture-Curing Polyurethanes binder. Alkyd, acrylic, and phenolic resins
Another class of resins with moderate heat- are blended with moderate additions (15
resistant properties is the moisture-curing percent to 25 percent) of silicone resin to
urethanes. They are single package formu- produce improvements in heat resistance
lations that cure by the reaction of atmo- that add approximately 100 F to 150 F (38
spheric moisture with residual isocyanate C to 66 C) to the sustained heat operating
groups, in either aromatic or aliphatic range of the coating system. Through the
urethane resin bases. These resins have addition of proportionately greater amounts
been represented to withstand elevated of silicone resins (50 percent to 90 percent)
temperatures in the range of 220 F to 325 F and heat-resistant pigments, the operating
(104 C to 163 C). With some commercial range of the coating formulations can be
products, discoloration may occur at the extended to approximately 450 F to 700 F
upper limit of this range. While moisture- (232 C to 371 C).
cured urethanes are formulated with col- The higher temperature formulations
ored, aluminum, and zinc pigments, the are color-limited because they incorporate
temperature tolerance of the urethane carbon-based and metallic pigments. At the
binder will be the limiting factor in elevat- highest levels of thermal performance, for-
ed temperature service. mulations utilizing 100 percent silicone
resins with ceramic pigments can survive
Silicone Resins sustained operation in the 800 F to 1,200 F
Because of a high degree of cross-linking (427 C to 649 C) temperature range. Finzel1
with multi-functional silane groups, silicone has classified the many silicone resin-based
polymers exhibit excellent thermal stability formulations available for industrial use.
and a very strong resistance to oxidation. Table 1 summarizes the thermal resistance
These properties make silicone resins, as a of different silicone resin formulations.
class, one of the most heat-resistant, and
widely-used binder systems for elevated Silicate Resins
temperature service. Silicone resin systems Inorganic zinc-rich coatings are principally
often require heat rather than ambient cure. used as extremely effective corrosion-resis-
48 / Journal of Protective Coatings & Linings Copyright ©1997, Technology Publishing Company
Coatings for High Heat Service
tant materials. However, as a binder class, tance. The materials are reported to with-
the inorganic, silicate-based resins used in stand dry heat service temperatures in
these coating formulations also exhibit ex- the range of 1,000 F to 2,000 F (538 C to
cellent resistance to elevated temperatures. 1,093 C). They cure at ambient tempera-
The alkyl silicates, which cure through the tures and require no extended heat cure
incorporation of atmospheric moisture, or prior to service.
the alkali silicates, which cure by elimina-
tion of water, are robust binders in zinc-
rich systems. They perform well because
Pigment Type
the inorganic constituents of the systems
behave as refractory-like materials, exhibit- Pigments That Impart Color
ing melting points in the 1,400 F to 1,600 F Pigments selected for elevated temperature
range (760 C to 871 C). use frequently have better overall tempera-
In practice, it is actually the zinc ture resistance than the binders with which
metal pigment, with a melting point of ap- they are blended. Pigments utilized in high
proximately 790 F (421 C), that is the limit- temperature coatings are generally inorgan-
ing factor in the high temperature perfor- ic (mineral-based) or metallic. In the case
mance of inorganic, zinc-rich systems. of the mineral-based pigments, materials
Coating manufacturers list the service tem- like clay, fumed silica, mica, and ceramic
perature of these materials at 750 F to 790 particles will have melting or decomposi-
F (399 C to 421 C), with intermittent opera- tion points that are significantly higher than
tion to 1,000 F (538 C). the resins with which they are blended.
Because of their heavy loading of zinc Mineral pigments can typically withstand
pigment, typically in the 80 percent to 90 temperatures in the range of 1,500 F to
percent range, inorganic zinc-rich coatings 2,000 F (816 C to 1,093 C).
exhibit a gray, matte finish. In high temper- Aluminum, zinc, and stainless
ature applications, they may be used with- steel are also used in high temperature
out a topcoat. However, where the heated coating systems. The upper limits of metal-
system may be shut down, cycled through lic pigments are principally defined by
lower temperatures, or exposed to moisture their melting points. The melting points
in the range of ambient to 200 F (93 C), the are approximately 1,220 F (660 C) for
inorganic zinc-rich coating may serve as an aluminum, 790 F (421 C) for zinc, and
anti-corrosion, high temperature primer. 2,500 F (1,371 C) for stainless steel. Due
This primer can then be topcoated with a to their high thermal conductivity, these
variety of high temperature coatings to pro- metals aid in the transfer of heat away
vide a colored topcoat. Among compatible from the coated substrate and in the
topcoats are silicone, silicone acrylic, and ability of the coating system to survive at
epoxy-based formulations. elevated temperatures.
Pigments used to impart color to high
Silicon Oxide Resins temperature coatings must be stable in the
Recent advances in coating technology in- range of intended temperature usage. With-
clude the advent of organo functional, sili- in the range of thermal-resistant coatings,
con oxide-based resins that have a substi- certain colored organic and inorganic pig-
tuted organic-cyclic structure. These ments exhibit good-to-excellent resistance
materials are capable of forming highly to heat loading in the range of 200 F to 500
cross-linked organic/inorganic polymers F (93 C to 260 C).
possessing high heat and chemical resis- Coatings utilizing some form of car-
Table 2
Coloring Pigments for High Temperature Coatings
50 / Journal of Protective Coatings & Linings Copyright ©1997, Technology Publishing Company
Coatings for High Heat Service
sponding to at least an SSPC-SP 10/NACE 2, their transfer efficiencies for extractive sam-
Near-White Blast Cleaning, for coatings pling. The works of Trimber2 and Flores3
subjected to elevated temperatures in atmo- discuss these parameters as they relate to
spheric service. such detection means as ion-sensitive,
For coatings subjected to elevated paper chromatography.
temperatures in wet heat service, the sub- Under certain conditions in operating
strate should plants, it may
be cleaned in be impossible
accordance to use abrasive
with SSPC-SP blast cleaning
5/NACE 1, to prepare the
White Metal metal surfaces
Blast Cleaning. (Fig. 2). In
Using these situa-
coatings in a tions, it may be
wet heat con- possible to em-
dition also re- ploy SSPC-SP
quires that the Fig. 2 - Abrasive blasting may not always be acceptable 11, Power Tool
in operating plants because it may interfere with
metallic sub- Cleaning to
equipment or cause safety hazards.
strate be free Bare Metal.
of soluble chemical contamination in the This cleaning method is suitable where a
form of chlorides, sulfates, and ferrous roughened, clean, bare metal surface is re-
ions. If not removed, each of these contam- quired, but where air-driven abrasive clean-
inants can precipitate the blistering of ap- ing cannot be used.
plied coating films through osmotic effects. A final area requiring specific atten-
For this reason, a pre-cleaning step, per- tion lies in the surface profile of the metal-
formed in accordance with SSPC-SP 1, Sol- lic substrate. To avoid the problem of
vent Cleaning, using steam or aqueous thermally induced coating stresses, high
media, should be completed before abra- temperature coatings are generally speci-
sive cleaning is attempted if the presence fied for application at lower film thickness
of these materials is suspected. than conventional coatings. A dry film
The decontaminated surface should, thickness (dft) range of 3 to 6 mils (75 to
at a minimum, comply to condition SC-2 of 150 micrometers) is common for these ma-
the Joint Surface Preparation Standard terials. Within this thickness range, a 1- to
SSPC-SP 12/NACE 5, Surface Preparation 2-mil (25- to 50-micrometer) surface profile
and Cleaning of Steel and Other Hard Ma- would ordinarily be appropriate. However,
terials by High- and Ultrahigh-Pressure due to the high incidence of failure among
Water Jetting Prior to Recoating. The SC-2 defective coating applications, many high
cleaned surface should have less than 7 temperature coating applications are made
µg/cm2 of chloride contamination, less than over previously corroded surfaces. After
10 µg/cm2 of soluble ferrous ions, and less cleaning, these surfaces may be pitted and
than 17 µg/cm2 of sulfate contaminants as roughened, conditions that will be prob-
verified by accurate analysis. lematic to uniform coating deposition. Care
However, it should be noted that field should be taken to both cover the existing
methods for the surface sampling of steel metal profile with the specified dft and
contaminated by soluble salts, such as avoid the accumulation of excessive coat-
swabbing or surface-cell extraction, vary in ing in substrate pits. That is, the applied
coating should conform to the surface pro- sary to accomplish a full cure. The baking
file and not fill deep pits; otherwise, undue period completes the curing by driving off
coating stress may develop upon curing residual solvents, sets the binder, and im-
and placing into service. proves its weathering characteristics.
In some situations, equipment cannot A third type of high temperature coating
be shut down for cleaning and painting, formulation utilizes single-component resin
and all work must be done directly on hot binders that hold dispersed metallic pigment,
surfaces. While this is not an ideal condition like aluminum, in suspension and facilitate
under which to carry out such operations, a the pigment transfer to the metal surface. Sim-
limited number of high temperature coatings ple oleoresinous, coumarone-indene, and
can be used successfully. These coatings are pure silicone resins are used in these formula-
generally single-component, self-priming sili- tions. As the substrate is elevated to the oper-
cone copolymer formulations that will toler- ating temperature, the binder resin is boiled
ate application to surfaces at temperatures off to allow the metallic pigment to melt and
up to 500 F (260 C). However, the hot sur- fuse to the substrate, or, in the case of the
faces must initially be cleaned in accordance higher boiling silicone resins, to create a com-
with SSPC-SP 1, Solvent Cleaning, to remove plex fusion product of resin, ceramic col-
adherent dirt, oil, and grease. Weld flux must orants, and additives. By these methods, coat-
also be removed. This operation should then ing service temperatures of 900 F to 1,500 F
be followed by abrasive blast cleaning in ac- (482 C to 816 C) are attainable.
cordance with SSPC-SP 10. The coating
should be applied before visible oxidation
forms on the hot surfaces.
Alternatives to Conventional
Liquid Coatings
Several alternatives are available for pro-
Curing Cycle Considerations
tecting hot surfaces. Although these alterna-
High temperature coatings cure by a variety tives have high installation costs, they may
of mechanisms. The curing mechanism will greatly reduce the costs of periodic mainte-
be closely tied to the binder system em- nance painting with conventional high tem-
ployed in the coating formulation. Coatings perature liquid coating systems.
that cure at ambient temperatures use
mechanisms such as oxidation, reaction Thermal Spraying
with atmospheric moisture, and chemical Metals—like stainless steel, aluminum, zinc,
curing. Coatings that cure by these mecha- 85/15 zinc/aluminum, and 90/10 alu-
nisms must reach a state of full cure before minum/alumina—have been used success-
heat is applied. fully in high temperature service to protect
Another group of high temperature metallic substrates from additional oxida-
coatings requires the application of heat to tion and corrosion. The coatings are ap-
complete the cure cycle. To fully cure, this plied directly to the metallic substrate by
class of coatings typically requires a one- to passing the coating media, in the form of a
two-hour baking period at an intermediate wire or powder, through a high energy
temperature that is 40 percent to 60 percent source consisting of a high intensity flame,
of the peak operating temperature. The plasma arc, or electric arc. As the coating
curing cycle is related to the time/tempera- materials pass through the energy zone,
ture relationships during the cycle. Higher they are heated to a molten or plastic state
temperatures will shorten the time neces- and propelled by a stream of compressed
52 / Journal of Protective Coatings & Linings Copyright ©1997, Technology Publishing Company
Coatings for High Heat Service
54 / Journal of Protective Coatings & Linings Copyright ©1997, Technology Publishing Company