0 Electrolyte Solutions rola nial nde hat he ie ican eS Sti Moma Conceptual Problems uot uz ews ues us aus ins rw he eine tal nein ath ange ae) tpt, ce ea ‘in nd) kel sng ofan ess eines. (6) Ironing Farms th ning oe The mn eral aon ped ot clo (aig at te i eg nel mae he a ig (2nd Wy iit pie omen Cit ny flan of CT det? ‘eda Seta 10, hs he ibs naif sion of Ha an Ca an fel eb ez rene 12152) 2h) — ay) CT wh an eae princi tye ete 80) Sat) Sn a= oye Gi comes fC (a) come tn nda ‘Wy wea alee ng te Daye kl iting ow ns es th one? Acyclic aad he Deneck ining ae ey oe case then loss rt wang ssa a tly chen sna oi tat ‘eben ee bw ihe mea nls el potential of so cited te cel pot fh aon ‘neon puedo he te edn p= Pe = Bl onthe che ptt ease ht way? Hosa Ing, ad 290+ Exreing therein in tems fe an ns hoc pst es paper “ao a of sd nti of sre enn pcs renee Wh hs ‘ier tise wih te tw erm? ‘hie ted ce ft sto (8) =D Alig alte nos a tedipcscn ee inet pole rion ps bce se a beta ‘Th Tasting tis mnann thor wesee aes be pny nly rc I epee (Gott osha eee tetany hw alae 179 Co Penn180 ows us us quot own, ous eon unis (Chapter 10 Eletoiyte Solutions Wy stot ese to mere acy coe oN a)? Is impose cre scion of ue Naa) a ae. cour ay gud ea aion ‘hats daly sea ode wl sy af ic ese iy poste ome a ne hry ee ty cfc fr ete oh i tr smth slant ‘he isa speses in ela sons tae #wverl fom fe Be domi nection with ‘oleate Comb nts None inrat wis mack eke tm spec pat The ‘nivel ofthe leet dcr tenchon we x ely be eloped, iy dnt ance int ol enh inh ns whe te Debye kl low a edo nse in hevbiey ore mays sa Inthe, a7 decrement 7) The enc petal be ety ao b= cone ver viseaing le nth has ncn shy, Phys, acing! el ted ‘Seige epson ete ech site ee ate es ee liga alin iain age sn ‘.001m NaCl and 001m KB wil beth nese sodaon of HORE (ting ost he same tS taf, he sun cen o Debye Hise) lm CaCl, wl ree dition oe he lon onsite ing ing co ow dn sting nat ih? Asa aes off oe seh, <1 and fe sldty eres 7 cee Wh once ‘eimunin platy, vows nr ‘iy ot prec oe ne ail om ye ses CEE AC FOE he Brn ‘The active cv hah on zaps fe set lian wil at veh ne ait athe cn ed rads Beer esc be ote seg the oes tune whe en ef charge) ae es tof cay rata the om noe Wy do evisos a Kal bv oon toner seins freee ction tan rations in ‘ih esate ei oe mcg? “Tht se ome theese nets eve asa lon ae eng tin, whee he cirespcig etn Tr et els hia Sot ge Wy teva fr be dotcom fr arin he atin hl ate hn kw? ter moles emily aud he jo edd oe hn te nthe a ene ft sce feces eee cate on Ths hey we ere sae un Deo ad cunt pon Be ete a dares nT they te ew fle seagate ld ea es, ‘Yat cn you cnet etn betes ns alc fc an oni tly oe oc preter hos? ‘Oval repubive inraston mst moth cpa or my tne ate eats ewes de (robe solmemd ho opie 620 ert(Chapter 10 Eletolye Solutions 181 21016 Why ete ingey 7, <1 aha lin ce eases? ‘The acy cots es hoe Bsus he charge o an ety wes he chen peal ‘ctl ne ompered wi an sloping soa mle Tr ears bcm he ‘tars nur act wi eaten, lowe the ee AI Mh concensus Baws at ‘ote ome Inger, oar hence (QUIT Vader wat condos ds > archer sean? QUIK How dyer fran nin lube chnge he nat wee coms re? iors bce eshte sl moe ly bound re sarin. (Q1I9 How dynes fran nin slong the cage ins cnt ais? ede cae te ation ele mre ily oun Gr he in wth he gree hp {@1020 tke come e fo ins NACI te pt pas, Why os hres sr etal in at ‘coc ltr Wy dos os ponents mC Dion ake pls ely bn water Done teeny gun og ematon ef te shat hl oer hau heey seo ces enon SL Teds exer ia CC oe CCl nt anne hea emt eb of ing ly Bend chee Numerical Problems P1OL Cae AS etherecon BuO) a) 2K) + BAC) + 2KND C9) ag = (850,91 ap) 2 SC) 5 = 1217 = 961K" ma = 255656 acter! ‘P12 Cet AS fr te eto AgNO) + KC > ALCL) + NOS. Ssh = (AECL) ~ Sa" at) SCF a) 10 Ung te Dayal Kaking Ie ake th vale of 7) 47.2310 ato of Nae, = 75cm sn of Cl aed) a225 410m slat 0 CaPO, Asse ent disosaon, (Nae Fate eve alone ome) 1 =opemming oor matt = 000 ae! n tay =-tunee | fo FE sits =o ari 201 Rn it182 Chapter 10 Eleeroiyte Solutions seen, eB dina em) 7so mag 2 +25) = Bona na OTS = 03519 tM ns =Linad oh 1 (Sms te" 22) 00a aes ime oP = area AR 048 eae (184 Clo toni int0m han ef CAN 0 NA ONESO, OA, CoO ah een ves 2S ears tea? NOH eke nd = (G0TS0(00750) (watts? m= 007300 © meso, =r sed =(00710)0078) (noth? m= 00730 A ek es sf = o0729y0.0730%3}' (noth 'm, =<0.71 mig FIOS A wes cd asa discon ost of K, = 2500 (0) Cael de feito fo 008 ‘So oi ie Debye He Heng ew.) Cake edge of Senin fo 88 ‘Sho fis cid ale 200m 9 KC Bom he Debye Hel eiing owing eatin ‘tl hase consti inthe second deci pace.) Reet the culstion (sng the sn ‘ou fr KC Tae 103s the th Dee Heeling eae he hen ect tet? Do you scl epee ee elon a ose) al 0? (0) A wesc daca acdig ote illo sii etn. Haan) = Han +a(Chapter 10 Eletolye Solutions 183 Brose he doce a neal ce Xs ed potion ee atop crmtinThe mt f ee spc don Hn wt at 4 eye Meg ‘This cnr has two akon. We sabe fr wig ak ate od. We fn eae that 1, =tand soe rm Wess ae ofm wate 7, sig va, aoa We ‘Poth per ela tet cms m=37h0% mall! ‘hein senghad 7 wegen by 2) =m = 00073 mag ley, = “Larose ETS ~ 02046 naar Wewsetis rao 7 weskutte anew wleeatm m1 rd 6201 Rn tn ne184 (Chapter 10 Electrolyte Solutions When 7, = 0781, n= 445x107 mag? "Ths a efit pode nde alae he dere of ncn be sous me re aa (©) Werte ete We dees of dsucabe ae he Hig aw ad et te cease ke ‘eng petal ye sl dosti 20 matte Sc ly = “LIT OH =-a56 fm 533510 maa ‘We nen ck th inl onetaon hen proce tog te dscon of he ai in eon who 7. = 0392 1 = oz00motig' +212) = 0255 moth yg = 117 f= 05900 w= 334800? motte! Werealtem andy and erie y+ 0200 mothg =m +0200 mate =0235¢ma ny, = “LIT 1x SSE = 0508 "m= $5410? mae! rp 0201 Rn Ean me,Chapter 10 Eletolye Solutions 185 ‘This ation goods and wee ie deo sina e re ep dn 88 F106 cake amen in avy of D050 m PO, sn fr wich Be ean ay niet 048 = (222s -orcasexeas e000 -PIRT A125, te sc const rhe stn of et i Eig ince ep of Sian 150 wan [0 ir wing rs son a ‘Beane count ine sed Sal pl, Compr tse ala wi you wel en ei ‘eto a bon re Compe ora witb ep of son a he ASS =| A wed dsc ocrdg te ling equim tn, ap © Hag) +a) cee cei asa neu sels ts good pronation te tay cu Rone {as Te acy oft in apne phe upon Sacaea epee y= Yer. anl, =P ‘he cquttmegen Bose new Teg OE Thing a 0 ves. We se fr nea eve Matos We fst sme at 7. = Lan ‘ee Wee vale of oso fd ing hau elem Nerep hs cee Shae oe et e001) «8 CH,COO" Ca) + oo Crit 201 Re Eatin a186, m= 1oti<10" mate rata ta “Linc fi? =-00009 n=00s 19-2 wen = 0984 When = Les 10° metas mates 10 mag ‘Tissot comer unl toca be dap of ec, Leori0" moth" 149110? ma oy L6 Susxi0%matkg* om 203 Rene tnChapter Eletrolyt Solutions 187 $8611 mate" Whe m= 361107 matte $6110" mothe meres = 808 %=0s16 We 7 = 0916 m= 558D«10° malig 58810? mala “Ti rethas comer ny ese te dee of sce = 35810" mothe” SSEx1O? wal kg” 190% = 0.372% ascites as igo Fras ‘n= 10? walks arom 10? make op 20 es en188, Chapter 10 Electrolyte IAL rom a Ta 103 App Da Tat aa ty oe ee 020 -sofations assuming complete cisscciation of a SKC bh NaS, = Meh 2, = (0200718 = 0348 & Naso, o2mm 7, =0208 (© Meck, came 2, = (0317 (088 «18 FIN Estimate dere of cition 0.290 sition atone aK, = 0) tt ss 00 ma the ston eaves pars), Use tec abs ban ae eae cere od gh eh Deyeck ing. BC KOH ARNO, ‘Compare your resis wih ede of scan the sung 7, = 1 mcaccas, oa ft es saint Snitch one esto oa, Frm Tate 103, , = 0397 oa00mihg— ato 10 matte ~patimalig ert 620 Nr EatChapter 10 Electrolyte Soatons 189 (9 Ae, From Title 103, 7, = 0336 = 140.107 eg 1.107 ti ‘Assan, = 25507 wotig P1010 cote nt 0 fr eto BNO) KCKap > BA) + NO ay 280 0) +20") S08") = 286005) = 286} 0°) 286, = ay) = AB) 2051) Mj W674 SeD8K a+ 250012E a = 16S Ah = 0a) 0706p) 0C7 so) PGi Exe, tems, a aE) L005.) CAC, (9) NPD, wn KFA Assn ompee (9) Ui 05 a = tay (0 NapOg a, lahat stata (0 Kren: 9 = aha =a? PILIE Cl su Mana tn Rap eg he Terai Ra 16190 {Chapter 10 Flectrolyte Solutions, O15 Cae he oe erg ie slin at O75 me K,S0,, D088 m Nj, a Do a weet rsa Boost se 259 CHN Eo) + Hah 1s 5125 10° Cael the exe ops (0) 40.210 m Slatin of (CH): Ne water wing a ee ‘hectare conta nth oan deci pa) Rep i ele fr on Tht abo 00 min NNO, Dou eed ose am erate alco ht ae? ‘Wense an feratve metas expla in te scaon F103. ‘op 6201 en iChapter 10 Electrolyte Solutions 193 (CH) NILaR) + HON) CHLNHLeN + OFF on) ty <1 ms aet0 mat vena une n= "aa 110? wag ete evens, Yim crit lk voce? me! tay, = “LTB «1xMLdR107 = 0.1250 wer etait! Tedprectndnh 2 po =a & M0, 9500 0500 2,‘Asotin fhe it etn pat Jat = 9500 09114 = OSU lig" seb 05T hi on wlio Lele ae cum ng ater ertion It = 9500 0021 = 0883 malig! set VISE = 08480 m= 00229 mothe? Thedepee etna 22 0 = PIR? Dict ci a icon om of, ~ 322107, Cao idee Unie 40105 ‘cn ft) ing Dye cel ng low wigan Boe ala al fe reat ‘ia #2 int sonl eialpo () Raps tm ese seeing emesis ote ‘ease snteve mad ws xpd inthe sloa FS (Wert conse thease when 7s ger by he Dobe Hk nig In, Te ose 2 te fice gent , ny, = 1.1 OT = 02481 2) = m= G7 wake erent m and and it sv we expt 201 Rema ieChapter 10 Electrolyte Solutions 19s F ate te? 7208 in 098 Sontag! vim, 078 aha 7 = 5403107 motte ‘Tis acy end ek and wee ere of dscion be 10% = 513% o "hs dts mar at cle ing he Dee kiting hv 11023. Caalue he De shel seeing eh Vi 28 Kn 078 m sian of KPO wssancutdier* sonal ev) = MPS ox 32) = nossa a3 Om! * oa 1624 Cat da 9 O05 men of K$04 298 K. How nile ae you Bat oe ‘so lags th xp coi 3 Pa a,196, [Chapter 10 Electrolyte Solutions Fa Seud ond) Henad oma reeset xomtses) anaes Net = 02) xoa2ts ma bg! = 04eakomtg lage “Lie “117s OBES 05058 moot a(S} = o1mexoss sons St voy cn ges 186s 10:7 sow sion ea fom pd tar fr Th adteaie P1825 Cala and 4.0.19 mtn f NP, of 298K Asse compte in, Hom co. ‘et a youth yur lal os wi ogre wih experinel es? Nao, 21. = hes =he, reader 95 rosea tag -1373 3 VOTES = 1.103 nao m= CFOS = 009% ml a, =(Z5)r. = omvoxas0 = 00128 Not vey cei Figures 106 and 107 show sia devisees fom pressed tear fr > obvnelia" {71826 Cacaue te ksh fet oft soon in Pebles PID, outers For N03) 2a 3 eax 1-294 n<0orsomtns rome. rats eres so mthg!Chipter 10 Eletolye Sol 197 PIMz7 Cable the ve om 5.5107 ml salons of) KCL () CNOA) ZSO4. ADE come pe isc. @ x maton Fan 5107 wag canon, Peay sn 02 a= (55107 moth © B80 mn obim n= 510° lg PIAIR- Cte Ay Be renin NgNO.s) + KC) -> ABCA + KNO a. AECL) + ACK) # ANOS ya) ~ ACA a) = 8G} 0405 09) AT AK" ag) ~ GC" 00) Aa = 86 AGC) ~ A188) ~ BACT a9) = 188 = maKiest! e11auimd = $57 aa AU, = 0 (A) = AUT 9) AAC) 12708) ma! —S61dma +1612 an" = 6540 11420 Cle ptf slain ha 0200 le CHCOOH an 0.18 mobil in CH,COON ing he ‘vce aay Wha le wo you bv see yes sane a 7, = 7 = Tt" ,C00") mCsC001) anveiw? = LPOG) | O15 2, (0200) ‘ono 3m 179.10 130 AF pital") “Toca ffm the Dis oun, we mit cei te ae seg a te Solo. The sat atc ot ew he ope natn oe ce cs al ut ol tng ane cal ‘tom contin of 1,000 ne mayor) po Binal ons’ wom oy caste! pg 220 Pane Esa ne198 Chapter 10 Eletralyte Solutions ao 2 eae = vile feast «409 P1030 Use the Daves euton wee 7 4 100 solo KOH, Compare your ase nh he as naomi “Ts eerie le the and va of LSE, prt 0201 Rr Fine