Petroleum Assessment of Berkine-Ghadames Basin, Southern Tunisia

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Petroleum assessment of Berkine–Ghadames Basin, southern Tunisia

Article  in  AAPG Bulletin · March 2016


DOI: 10.1306/01141612083

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Petroleum assessment of AUTHORS

Berkine–Ghadames Basin, Mohamed Naceur Aissaoui ~ Repsol


Mauritania, Ilot M-N°61, Nouakchott,
Mauritania; naissaoui@repsol.com
southern Tunisia Mohamed Naceur Aissaoui is an explorationist.
His interests include geophysical and geological
Mohamed Naceur Aissaoui, Mourad Bédir, and interpretation, seismic processing, and regional
Hakim Gabtni hydrocarbon prospectivity. He received his
diploma of engineer in geophysics from the
Algerian Petroleum Institute in 1977. The same
year, he joined Eni, an Italian hydrocarbon
ABSTRACT company, and in 2006 he left Eni and integrated
Hydrocarbon exploration in the Berkine–Ghadames Basin in the new venture team of the Repsol Spanish
hydrocarbon company. He is presently the
southern Tunisia has generally followed global economic trends. In
country manager of Repsol in Mauritania.
recent years, improvements in seismic data acquisition combined
with experience gained in log interpretation in low-resistivity res- Mourad Bédir ~ Georesource
ervoirs have resulted in oil and gas discoveries in the Upper Silurian Laboratory, Centre of Water Research and
Acacus Formation, enriching the hydrocarbon potential of the Technology, Borj Cederia, Technopark, B.P.
Berkine–Ghadames Basin in southern Tunisia. Presently, the Tu- 273, Soliman 8020, Tunisia; bedmour@
yahoo.fr
nisian daily oil production is approximately 43,000 bbl, about half of
which comes from the fields located in southern Tunisia and is Mourad Bédir is a doctor/professor, researcher,
produced from the Acacus Formation. The Berkine–Ghadames Basin and lecturer in geosciences at Georesource
Laboratory at the Centre of Water Research and
is an intracratonic basin formed during the Pan-African Orogeny. It
Technology of Borj Cedria Technopark. He
covers an area of approximately 350,000 km2 (135,135 mi2) and earned his master’s degree in 1985, his Ph.D.
extends into Algeria, Libya, and Tunisia. The sedimentary section in 1988, and state doctorate in geology/
within the basin ranges from Cambrian to present and is approx- geophysics in 1995 from the University of Tunis
imately 7000 m (23,000 ft) thick in the depocenter. The basin has El Manar. He was head of the Georesource
experienced several tectonic events, which have modified its ar- Laboratory from 1998 to 2006 and general
chitecture and affected the petroleum systems and hydrocarbon director of the Centre of Water Research and
pathways. In this study, the main elements of the petroleum geology Technology from 2005 to 2011. He specializes in
petroleum and hydrogeology basin exploration
systems are described. With the geochemical modeling results, the
and reservoir seismic sequence stratigraphy,
petroleum potential, hydrocarbon generation, expulsion time, and wire-line logging, and seismic tectonics of
quantity of hydrocarbon are assessed. The main petroleum systems carbonate and siliciclastic deposits. He has
are also defined. They are represented by the Silurian Tannezuft hot conducted several research and development
shale source rock with Ordovician Djeffara and Silurian Acacus programs and consulting. He is the author of
reservoirs, by Silurian Tannezuft hot shale with Kirchaou reservoirs, several international publications and a
and by the Devonian Aouinette Ouinine Formation Member III reviewer in international journals.
source rock with Kirchaou reservoirs. The hydrocarbon traps in the Hakim Gabtni ~ Georesource Laboratory,
area are mainly structural types. The study describes and emphasizes Centre of Water Research and Technology,
the hydrocarbon migration pathway mechanism from source rocks Borj Cederia, Technopark, B.P. 273, Soliman
to traps. To predict and derisk future drilling locations, fairway 8020, Tunisia; gabtni_hakim@yahoo.ca
maps are generated for the three plays: Ordovician, Silurian, and Hakim Gabtni is senior geophysicist scientist
and associate professor at the Centre of Water
Research and Technology (Tunisia). He earned
a B.S. degree in geology/geophysics in 2000,
Copyright ©2016. The American Association of Petroleum Geologists. All rights reserved.
master’s degree in 2002, Ph.D. in 2006, and
Manuscript received May 18, 2012; provisional acceptance July 11, 2012; revised manuscript received
December 12, 2014; revised manuscript provisional acceptance April 20, 2015; 2nd revised manuscript
HDR in 2012 from Tunis El Manar University.
received October 12, 2015; final acceptance January 14, 2016. His interests include gravity and aeromagnetic
DOI:10.1306/01141612083

AAPG Bulletin, v. 100, no. 3 (March 2016), pp. 445–476 445


investigations of sedimentary basins, integrated Triassic. Although the paper focuses on southern Tunisia, an attempt
potential geophysical techniques, and is made to introduce Libyan and Algerian knowledge to evaluate the
petroleum seismic for three-dimensional basin in a regional context.
modeling of complex geological features and
application of microgravity, seismic refraction,
and electrical resistivity tomography for near- INTRODUCTION: EXPLORATION IN THE
surface geology. He is the author of several
BERKINE–GHADAMES BASIN
papers in international journals.
The first exploration phase in southern Tunisia’s Berkine–
ACKNOWLEDGMENTS Ghadames Basin (Klett, 2000) began in the late 1950s. The
We extend our gratitude to the reviewers, drilling of the well El Borma-1 (EB-1; Figure 1) in 1964 led to
without whom this paper would not have the first discovery in the area within the Middle–Upper Triassic
been completed. We are grateful to D. A. Kirchaou Formation sandstone. The giant El Borma field to date
Pivnik, F. Plants, and S. D. Harker. Thanks has produced more than 1 billion bbl of oil and is currently pro-
are extended to colleagues in Repsol, ducing approximately 5500 bbl/day of oil.
who provided useful suggestions and Following the success at El Borma, a second exploration phase
recommendations, with special thanks to
started in 1976 in the neighboring areas targeting the Triassic
A. Chambers, A. Vayssaire, B. Black, and
H. Abdallah. Thanks are also due to Repsol
sandstone reservoirs. This effort resulted in the discovery of sev-
for permission to publish this paper. eral medium- to small-sized fields such as Makhrouga (1980; 70
million bbl of oil in place; Figure 1).
Encouraged by the exploration success in the Upper Silurian
EDITOR’S NOTE
Acacus Formation in Libya and Algeria, Eni Tunisia (formerly
Color versions of Figures 1–2, 4–15, 17–24, AGIP) was awarded the Jenein exploration block located in the
26–39, and 41 can be seen in the online study area. This started the third exploration phase. In 1996,
version of this paper. Eni re-entered the Oued Zar-1 well (OZ-1; Figure 1) and tested
the Upper Silurian Acacus reservoirs (Aissaoui et al., 1996).
The well flowed approximately 2500 bbl/day of 42° API oil
from two intervals. This was the first commercial discovery in
the Acacus Formation in Tunisia.
During the last 10 yr, several oil and gas discoveries in the
Acacus Formation enriched the hydrocarbon potential of Tunisia
and established the Acacus Formation as a primary petroleum
objective in Berkine–Ghadames Basin in southern Tunisia.
Presently, the Acacus Formation is producing oil and gas
from many fields in southern Tunisia with a cumulative daily
production of approximately 25,000 bbl of oil equivalent.
The present study is based on a large database including
70 wells, 3200 km (1990 mi) of two-dimensional (2-D) interpreted
seismic lines, and maps.

REGIONAL SETTING AND BASIN EVOLUTION

The Berkine–Ghadames Basin is one of many intracratonic basins of


the North African Saharan platform; it is a large sag basin encom-
passing more than 350,000 km2 (135,136 mi2) (Montgomery,
1994; Gauthier et al., 1995; Echikh, 1998; Klett, 2000; Dardour
et al., 2004; Holt et al., 2010). The basin is bounded to the north by
the Telemzane arch, to the east by the East Margin structure
running parallel to the Hun Graben, and to the west by the Amguid

446 Petroleum Assessment of Southern Tunisia


Figure 1. Southern Tunisia lo-
cation map. CEM-1 = Chaabet El
Mediouni-1; CS-1 = Chouech Es
Saida-1; DH-1 = Debech-1; EB-1 =
El Borma-1; EBNE-1 = El Borma
Nord Est-1; EBP-1 = El Borma
Profond-1; EC-1 = Echouech-1;
EC-2 = Echouech-2; HZ-1 =
Hamadet Zamah-1; LA-1 = Larich-
1; LA-2 = Larich-2; MG-1 =
Michiguig-1; OK-1 = Oued
Krebzab-1; OZ-1 = Oued Zar-1;
RA1-Bis = Rmel Abiod 1-Bis;
RR-1 = Rhourde Rezala-1.

El Biod high. To the south, the Berkine–Ghadames During the Silurian and Devonian the same re-
Basin is separated from the Murzuk and Illizi basins by gional uplift elements of the Cambro–Ordovician
the Gargaf and Ahara highs, respectively (Figure 2). were active, and limited sedimentation characterized
On a regional scale, the Paleozoic cycle is well these areas (Figure 4).
developed in southern Tunisia, Algeria, and western During the Carboniferous, the Hercynian orog-
Libya. It follows the pan-African Precambrian– eny dramatically affected the Berkine–Ghadames
Cambrian orogeny (600 Ma) (Boudjema, 1987; Basin. Compressional movements and associated
Gauthier et al., 1995, 2003; Craig et al., 2008), which uplift occurred (Gabtni et al., 2006, 2012; Dhaoui
is interpreted as a regional east–west compression et al., 2014). All the preexisting highs were re-
resulting from collision between the West Africa activated and remained as positive features. The
stable craton and a mobile zone farther east, which is Paleozoic sediments in southern Tunisia were pro-
considered to be an active margin. gressively truncated from south to north (Figure 5).
This cycle is made of three major shortening During the Mesozoic, the opening of the Tethys
phases (Taconic, Caledonian, and Hercynian compres- and North Atlantic oceans was associated with ex-
sions) separated by extensional phases (Cambrian, tensional faulting and subsidence as recognized in
Silurian, and Permian) (Guiraud and Bosworth, 1999; central Africa (Guiraud, 1998) and in the Atlassic
Guiraud et al., 2005; Gabtni et al., 2006). Tunisian margin (Bédir et al., 1992, 2001; Bédir,
The basin’s history is dominated by the tectonic 1995; Bouaziz et al., 2002; Melki et al., 2012).
activity of the structural elements outlined above, Stratigraphic thickness variations of the Triassic across
which were active from the Cambro–Ordovician faults have been identified (Figure 6). Hydrocarbons
until the Cretaceous. An orogenic phase (Austrian) are trapped against faults within the Middle–Upper
accompanied by erosion at the end of the Early Triassic sandstone levels (e.g., Bir Rebaa, Hassi Berkine
Cretaceous produced, or at least accentuated, the fields, and others located out of the study area in the
characteristics of some structures (Bishop, 1975). Algerian sector of the basin).
Figure 3 shows reduction in thickness of the Cambrian In the Tunisian North African margin, two
interval over the Atchan and Ahara structural ele- compressional events followed the Triassic rifting
ments that bound the Berkine–Ghadames Basin. (Bédir et al., 2000; Soussi, 2002; Azaı̈ez et al., 2007;

Aissaoui et al. 447


Figure 2. Saharan platform
structural domains at present
time.

Tanfous Amri et al., 2008). The Austrian event at the elements of the petroleum system of southern Tunisia
end of the Early Cretaceous (Aptian–Albian) (Bédir, and tries to guide future exploration in the area.
1995; Zouaghi and Bédir, 2005; Zouaghi, 2008) and
the Pyrenean–Alpine and Atlassic orogenies in the Reservoirs
Late Cretaceous–Pleogene have been distinguished
(Bouaziz et al., 2002; Khomsi et al., 2006, 2009). Several reservoirs have been defined in the Mesozoic
In the Berkine–Ghadames Basin, the compres- and the Paleozoic clastic sequences in southern Tu-
sional events are expressed by intense folding, trans- nisia (Figures 8, 9). These include the Middle–Upper
pression, and structural inversion generally along the Triassic fluviodeltaic sandstone Kirchaou Formation,
older trends (e.g., El Borma fault trend along which is the Devonian Tadrart braided river deposits, the
located El Borma field; Figure 7). Ouan Kasa and Tahara deltaic deposits, the Upper
Silurian deltaic deposits of the Acacus Formation, and
the Upper Ordovician fluvial to marine sandstones of
PETROLEUM GEOLOGY OF SOUTH TUNISIA
the Djeffara Formation.
A detailed reservoir description is, however, out of
The petroleum geology of the Berkine–Ghadames
the scope of this paper, and emphasis will be placed only
Basin in the Libyan sector has been discussed in sev-
on the main proven hydrocarbon-bearing reservoirs in
eral publications (Echikh, 1998; Abugares, 2000; Klett,
southern Tunisia, which are the Ordovician Djeffara, the
2000; Sikander, 2000; Yahi et al., 2001; Craig et al.,
Silurian Acacus, and the Triassic Kirchaou Formations.
2008; Galeazzi et al., 2010). Operating companies
have carried out extensive work, but unfortunately,
few publications are available in the Tunisian sector Upper Ordovician Djeffara Reservoir
(Ghenima, 1995; Aissaoui et al., 1996; Acheche et al., The Djeffara Formation was deposited after the
2001). The present paper describes the principal Taconian event (Late Ordovician). The formation

448 Petroleum Assessment of Southern Tunisia


Figure 3. Cambrian isopach
map, showing the old structural
elements of Atchan, Thiemboka,
and Ahara areas. Thickness is
expressed in meters.

is distinguishable from the underlying deposits of only fractured, extremely compact fine-grained
Bir Ben Tartar Formation by its significantly lower sandstones without depositional structures. By
gamma-ray values. Presently, the only core available analogy to what has been observed in Algeria
in the Djeffara is in the well AMIC-1 (Figure 1). (upper part of Grés Oued Saret), this formation is
However, the 1 m (3 ft) cored is not useful for likely an accumulation of storm deposit layers
sedimentological purposes, because it contains (Soua, 2013).

Figure 4. Regional schematic


cross section showing the activity
of the Ahara and Atchan highs dur-
ing the Early to Middle Devonian.
ACH-1 = Acheb-1; BRN-1 = Bir
Rebaa Nord-1; EB-133 = El Borma-
133; ET-1 = Erg Tiouline-1; Fm. =
Formation; HAD-1 = Haiadh-1;
IRLS-1 = Iralene Sud-1; MDB-1 =
Mederba-1; OT-1 = Oued Tissit-1;
OZ-1 = Oued Zar-1.

Aissaoui et al. 449


Figure 5. North–south struc-
tural cross section showing the
Hercynian effect on the Paleozoic
series in southern Tunisia.
ADM-1 = Adam-1; EM-1 =
Est Makhrouga-1; L. = Lower;
MG-1 = Michiguig-1; M. =
Middle; OZ-1 = Oued Zar-1;
TE-1 = Tebour-1; U. = Upper.

The petrophysical characteristics of the Djeffara could be the equivalent of the Kasbah Leguine For-
Formation are in general poor. Average porosity is mation present in the study area (Soua, 2013).
low, ranging between 5% and 10% with permeability Average thickness of the Hamra Formation
between 0.01 to 70 md. ranges from 20 to 50 m (66 to 164 ft). Gas and
On the northern edge of the Telemzane arch, condensate and oil are being produced within this
north of the Saharan platform (out of the study area), formation at Franig, Baguel, Tarfa, and Sabria fields
the Ordovician reservoir is composed mainly of located in the northern margin of the Saharan
quartzitic sandstone of the Hamra Formation, which Platform, outside the study area.

Figure 6. Two-dimensional
seismic line in the Algerian sector
of the Berkine–Ghadames Basin
showing the Mesozoic exten-
sional phase. H. Unconformity =
Hercynian unconformity.

450 Petroleum Assessment of Southern Tunisia


Figure 7. Seismic line showing
the structural inversion along the
El Borma fault during Late Cre-
taceous. Hercyn. Unc. = Hercy-
nian unconformity.

In 1979, the well Sabria West-1 tested 900 phase (Silurian to Middle Devonian) was responsible
BOPD of 40° API oil from the Hamra Formation. The for facies variations within the Acacus Formation,
well El Franig-1 flowed, from the same reservoir, gas passing from sand deposited in a mouth bar area to
and condensate with average rates of 6.4 MMCFGD thin bedded alternating sandstone and shale de-
and 980 BCPD, respectively. posited in a shelf area (Figure 10). The maximum
In the study area (Figure 1), the well Larich-2 thickness of 900 m (2953 ft) is reached in the
(LA-2) tested gas from the Djeffara reservoir at a daily northwestern part of the study area. Toward the
rate of 2.3 MMCF, and the well Oued Zar-1 (OZ-1) north, the Hercynian orogeny has eroded progressively
flowed oil at a daily rate of 680 bbl. the Acacus Formation (Figure 11).
However, because of its significant depth (>4000 m The hydrocarbon potential of the Upper Silurian
[13,125 ft] in the well OZ-1), its poor petrophysical sandstone was re-evaluated in 1990 in southern
characteristics, and its limited petroleum potential in Tunisia, following new log interpretation in low-
the study area, the Djeffara Formation is considered resistivity reservoirs (Figure 12).
as a marginal reservoir. The average porosity of the Acacus reservoirs
ranges from 10% to 28%. However, even if the overall
porosity is good, permeability is commonly adversely
Upper Silurian Acacus Reservoirs affected by authigenic mineralogy, specifically the
The Acacus Formation is Upper Ludlovian to Pridolian abundance of iron-rich chloritic clays (Arduini et al.,
in age. It conformably overlies the Tannezuft shale 2000).
and is unconformably overlain by the sandstone of The Acacus Formation contains multiple reser-
the Lower Devonian Tadrart Formation (Aissaoui voir levels associated with intercalated shale seals.
et al., 1996). The Acacus Formation comprises Based on log interpretation, the Acacus Formation is
sandstone layers separated by shaly interbeds with subdivided into three members: A, B, and C, with
a progradational trend from south–southeast to the C Member being the youngest. Each member is
north–northwest (Arduini et al., 2000). Tectonic subdivided into several reservoir levels (Figure 13).
activity that affected the region during the Caledonian The uppermost A1 level of the A Member constitutes

Aissaoui et al. 451


Figure 8. Southern Tunisia Mesozoic
general stratigraphy. FM = Formation;
HERCYN. UNC. = Hercynian unconformity;
QUAT = Quaternary.

452 Petroleum Assessment of Southern Tunisia


Figure 9. Southern Tunisia
Paleozoic general stratigraphy.
AOI = Aouinette Ouinine For-
mation Member I; AOII =
Aouinette Ouinine Formation
Member II; AOIII = Aouinette
Ouinine Formation Member III;
AOIV = Aouinette Ouinine For-
mation Member IV; HERCYN.
UNC. = Hercynian unconformity;
MISSISSIP. = Mississippian;
PENNSYLV. = Pennsylvanian.

Aissaoui et al. 453


Figure 10. Cored Acacus A1 and A3 levels.

the main oil-producing reservoir of many fields in the Middle–Upper Triassic Kirchaou Reservoirs
study area. About 40% of the production in the study The petroleum exploration history of the Middle–
area comes from the A1 level. Upper Triassic Kirchaou Formation in the North
Since 2000, the Acacus reservoirs have proven to African Saharan platform began in Algeria with the
be more prolific oil producers than the Ordovician discovery of the giant Hassi Rmel gas field in 1956.
and Triassic reservoirs. Between 2000 and 2014, The Kirchaou Formation was subsequently con-
about 30 discoveries in southern Tunisia have been firmed as a main petroleum target in southern
made in the Acacus reservoirs. Tunisia by the discovery of El Borma oil field in

Figure 11. Thickness map of


the Upper Silurian Acacus For-
mation. CEM-1 = Chaabet El
Mediouni-1; CS-1 = Chouech Es
Saida-1; EB-1 = El Borma-1;
EC-1 = Echouech-1; GD-1 =
Garet Dawed-1; LA-1 = Larich-1;
MG-1 = Michiguig-1; NKL-1 =
Nakhil-1; OZ-1 = Oued Zar-1;
RTM-1 = Ritma-1; SN-1 =
Sanrhar-1.

454 Petroleum Assessment of Southern Tunisia


Figure 12. Logs in oil well in
southern Tunisia showing low
resistivity reading in the Acacus A
oil zones. FM. = Formation;
OFA = optical fluid analyzer.

1964 and Larich and Makhrouga oil fields in 1980 inherited from the Hercynian paleotopography com-
(Figure 1). bined with a still active fault system and effusive vol-
The Kirchaou Formation is of Ladinian to Carnian canism in some places in the basin (Boudjema, 1987).
age and unconformably overlies the deformed Paleozoic In Tunisia, the formation is subdivided into two
section above the Hercynian unconformity. The for- main sequences called argilo-Gréseux and Gréseux.
mation shows complex sedimentology and geometry The two sequences are interpreted as the cyclic

Figure 13. Geosection over


an unnamed field in southern
Tunisia, oil and gas bearing in the
Acacus Formation.

Aissaoui et al. 455


Figure 14. Thickness map of the Middle–Upper Triassic Kirchaou Formation. BZ = Bir Zobbes; DB = Dhehibat; DEK = Dekamis; DH =
Debech; EBN = El Borma Nord; EC = Echouech; FM = Formation; HR = Hadjer; KE = Keskessa Est; LD = Lessoud; MR = Makhrouga; OS =
Oued Siah Sraia; OZ-1 = Oued Zar-1; PDG = Djebel Grouz; PGA = Pekten Guelb Ahmar; RH = Rhezine; SAN = Sidi Aoun; SB = Garet ben
Sabeur; SN = Sanrhar; TR = Tiaret; TT = Bir Ben Tartar.

superimposition of low-sinuosity sandy channeled the north along the Matmata high. Its thickness in-
systems, passing laterally and upward to flood plain creases generally from west to east and can reach
siltstones and mudstones with occasional dolomite 265 m (870 ft) in the basin area (Figure 14).
layers. Systems of northeast–southwest relative highs Further subdivision of the Kirchaou Formation
and troughs guided the main fluvial pathways (Ben has been defined in the El Borma field to better de-
Yagoub, 1998). The formation thins and shales out to lineate the reservoir quality and productivity. From

Figure 15. El Borma field


structural cross section. Fm. =
Formation; OWC = oil water
contact.

456 Petroleum Assessment of Southern Tunisia


the top to the base, the formation is composed of five Traps
sandstone levels labeled A, B, C, D, and E (Acheche
et al., 2001). Together the five levels reach a total In the Tunisian sector of Berkine–Ghadames Basin, most
thickness of 125 m (410 ft) in some wells in El Borma traps in the Paleozoic and Mesozoic section are low-
field, and the cumulative hydrocarbon net pay in relief anticlinal structures. Most of the structural closures
the five levels reaches 52 m (170 ft) in the field were initiated in Hercynian times and continued to grow
(Figure 15). The A level is considered as the main with time until Late Cretaceous–Early Cenozoic.
reservoir. The formation has excellent reservoir In the Algerian sector, hydrocarbon is found in
properties; its average porosity ranges from 15% to some faulted blocks along the El Borma fault trend.
22%, and permeability can reach 1 d.
Source Rocks
Seal Rocks
The hot shale of the Lower Silurian Tannezuft For-
Among the petroleum system components, the na- mation and the hot shale of the Upper Devonian
ture of the sealing rocks in the Berkine–Ghadames Aouinette Ouinine Formation Member III (AOIII)
Basin is the least studied and understood. The seal of are defined as the principal source rocks within the
the Djeffara Formation is the thick shale section of the Tunisian sector of the Berkine–Ghadames Basin.
base of Lower Silurian. The Acacus reservoirs are To evaluate the source rock properties, the
sealed by interbedded shales; however, no capillarity available data from wells were collected, and the
pressure study has been performed to determine the intervals of the Lower Silurian and the Upper Devo-
hydrocarbon column that can be held by the inter- nian Formations were carefully studied. The data in-
calations of shale within the formations. The over- clude total organic carbon (TOC) and Rock-Eval.
lying shale and anhydrite of the Upper Triassic The maturity level reached by the sediments was
provide an excellent regional seal of the Kirchaou defined mainly using optical data, vitrinite reflectance
Formation reservoirs. data (Ro), and hydrogen index (HI; expressed in

Figure 16. Regional trend of transformation ratio (TR) versus depth according to Tissot–Espitalié formula. HI = hydrogen index; TOC =
total organic carbon.

Aissaoui et al. 457


milligrams of hydrocarbon per gram of TOC). The 0.6%–0.8%, and the onset of gas generation is typically
Tmax, which is the maximum rate of hydrocarbon associated with values of 1.1%–1.3%. However, these
generation occurs in a kerogen sample during pyrolysis generation windows vary between source rocks with
analysis, was used only to outline the regional trend different kerogen types (vitrinite is typically abundant
because of the difficulty in evaluating the evolution of in type III kerogen-rich source rocks); therefore, a con-
the organic matter mainly of type II. The Ro value version to transformation ratio (TR) is applied to create
represents the highest temperature that the source rock a kerogen-specific maturity parameter. Typically, vi-
has experienced. It is a key element for identifying trinite reflectance data are presented in units of % Ro, the
the maximum temperature history of sediments in measured percentage of reflected light from a sample
sedimentary basins. This means that with a suitable that is immersed in oil (% Ro = % reflectance in oil).
calibration, Ro can be used as an indicator of maturity The depletion of HI with maturity was evaluated
in hydrocarbon source rocks. Generally, the onset of regionally, and the reached maturity was computed
oil generation is correlated with a reflectance of as TR (according to the Tissot-Espitalié (1975)

Figure 17. Southern Tunisia


Hercynian subcrop map.

458 Petroleum Assessment of Southern Tunisia


method). The regional relation of TR versus depth

Abbreviations: E = early mature; HI = hydrogen index; L = late mature; n.m. = not measurable; P = peak oil generation; Ro = vitrinite reflectance data; S2 = hydrocarbons generated by pyrolysis; SPI = source potential index; TOC = total
Source Rock Properties:

II, EP
II, EP
is shown in Figure 16. The original TOC values were

II, P

II, L
Potential, Kerogen,
computed (according to Peters, 1986) for all available

Very good, Type


Very good, Type
Very good, Type

Very good, Type


Good, Type II, P
Maturity
wells.
The interpretation of kerogen type for each
source rock (in terms of original hydrogen index HI)
was done also using cross plots of pyrolysis. A graph of
hydrocarbons generated by pyrolysis (S2, measured in
milligrams of hydrocarbon per gram of rock) versus

0.91–1.00

0.65–0.77
Ro, %

n.m.
n.m
n.m TOC content of the rock (in percent weight [wt. %])
was performed (Langford and Valleron, 1990). The
slope of the regression line gives an average hydrogen
t/m2 tons/ft2

0.04

0.07
0.11
0.02
0.01
SPI,

index (100S2/TOC) (Peters et al., 2006; Yalçin Erik


et al., 2006; Nazir et al., 2011).
The quantitative evaluation of the source rocks
SPI,

0.4

0.7
1.1
0.2
0.1

potential was given by the source potential index (SPI).


The SPI is defined as the maximum quantity of hydro-
min–max

819–838

817–822
822–824

811–822
826–831
Tmax, °F,

carbons (in tons) that can be generated within a column


of source rock under a square meter surface area.
With the help of a modeling exercise the original
min–max
Tmax, °C,

439–440
441–444
437–448
433–439
436–439

SPI values were estimated, and the quantity of ex-


pelled hydrocarbons was evaluated.
To evaluate the reactivity of the organic matter,
an experimental evaluation of kinetic parameters of
Number % mg/g mg/g

239
203
193
364
285
HI,

five samples selected from the Devonian hot shale


Table 1. Hot Shale of the Tannezuft Formation: Average Geochemical Characteristics

sequences of the wells RR-1, CS-1, and EC-2 was


5.78 21.06
4.94 14.10
1.82 4.26
1.28 2.61
4.50 8.70
Thickness, Thickness, Sample TOC, S2,

performed. Results will be shown and discussed in the


next section.

Hot Shale of the Lower Silurian Tannezuft Formation


Located at the bottom of the Lower Silurian se-
3
4
3
4
4

quence, the organic-rich hot shale was deposited


during the eustatic sea level high stand (Soua,
65.5
65.5
65.5
65.5
65.5

2014). The section with its graptolite fauna in-


ft

dicates a cold postglacial climate (Abugares, 2000).


The hot shale is widespread in the Tunisian and
Algerian sectors of the Berkine–Ghadames Basin.
20
20
20
20
20
m

In the Libyan sector, it appears to be relatively


thin or absent over some paleohighs such as the
13,658–13,724

11,732–11,798
12,352–12,418
10,240–10,305

southern area separating the Berkine–Ghadame


9203–9269
Interval, ft

Basin from the Murzuk Basin (Echikh, 1998).


The Silurian hot shale is also well established
over the Arabian Gulf (Rub Al Khali area in Saudi
Arabia) (Milner, 1998; Abu-Ali et al., 1999;
2805–2825
4163–4183

3576–3596
3765–3785
3121–3141
Interval, m

Pollastro, 2003; Abu-Ali and Littke, 2005). Car-


bon isotopes correlate hydrocarbons found in Saudi
organic carbon.

Arabia within the Devonian, Carboniferous, and


AMIC-1

Permian reservoirs to the Lower Silurian hot shale


Wells

OZ-1
RA-1
BZ-1
EB-1

Qusaiba Formation (Abu-Ali et al., 2005).

Aissaoui et al. 459


The Silurian hot shale is the origin of 80%–90% Espitalié et al. (1985), Peters (1986), and
of Paleozoic-sourced hydrocarbons in North Af- Langford and Valleron (1990) recommend that the
rica and was also a major factor in petroleum rock with S2 greater than 5 and 10 mg HC/g rock be
generation on the Arabian Peninsula (Lüning et al., considered as having good and very good source rock
2000). potential. The graph of S2 versus TOC (Figure 18)
The thickness of the hot shale in the Berkine– shows that about half of the analyzed samples in
Ghadames Basin reaches 100 m (328 ft) in the southern Tunisia have good petroleum potential,
deepest part of the Algerian sector (Kaced and whereas most of the Libyan samples have very good
Arab, 2012). Toward the north of the study potential.
area, along the Telemzane arch, the Silurian hot All the data cited above indicate that the hot
shale is truncated by the Hercynian unconformity shale of the Tannezuft Formation is a good source
(Figure 17). rock over the whole study area.
In all the studied wells (Table 1), the Silurian
hot shale contains good quality source rock. The Hot Shale of the Upper Devonian Aouinette Ouinine
average TOC content ranges between 1.28% and Formation Member III
5.78%. During the Frasnian, organic-rich shales were de-
Based on the interpretation of the graph of posited across much of North Africa, most notably in
S2 versus TOC, the source rock is characterized by a parts of Morocco, Algeria, southern Tunisia, western
type II oil prone kerogen and an original HI of about Libya, and the Western Desert of Egypt. They are
500 mg hydrocarbons (HC)/g TOC (Figure 18). estimated to be the origin of approximately 10% of
According to the Ro % and Tmax data (Table 1), all Paleozoic-sourced hydrocarbons in North Af-
this sequence has reached the oil generation peak; in rica. In wireline logs, the Frasnian hot shales are
particular, high maturity values were measured in the marked by high gamma-ray values, commonly in
well EB-1 (Ro % = 0.91–1.0). excess of 300–400 API (Lüning et al., 2003).

Figure 18. Cross plot of hy-


drocarbons generated by py-
rolysis (S2) versus total organic
carbon (TOC) of the hot shale of
the Tannezuft Formation sam-
ples. AMIC1 = Amic-1; BZ-1 = Bir
Zobbes-1; EB-1 = El Borma-1;
HI = hydrogen index; OZ-1 =
Oued Zar1; RA-1Bis = Rmel El
Abiod-1Bis.

460 Petroleum Assessment of Southern Tunisia


The AOIII Member of the Aouinette Ouinine

Abbreviations: E = early mature; HI = hydrogen index; L = late mature; n.m. = not measurable; P = peak oil generation; Ro = vitrinite reflectance data; S2 = hydrocarbons generated by pyrolysis; SPI = source potential index; TOC = total
Source Rock Properties: Potential,
Formation is Frasnian. It is only present in the

II, EP

II, IE
II, E
II, E
southern part of the study area. It is truncated by the

Kerogen, Maturity
Hercynian unconformity to the north (Figure 17). Its

Very good, Type


Very good, Type
Very good, Type

Very good, Type


Fair, Type III, E
thickness in the study area ranges from 30 to 306 m
(98 to 1004 ft), all of which is organic rich.
In all the studied wells (Table 2), the AOIII
contains very good quality source rock (except for the
well MG-1; Figure 1). The average TOC content
ranges between 0.56% and 2.69%.
t/m2 tons/ft2 Ro, %

n.m.
n.m.
n.m.
n.m.
n.m.
Five samples from the hot shale sequence of the
wells RR-1, CS-1, and EC-2 were evaluated for re-
activity of the organic matter. The kinetic parameters
0.90
0.60
0.94
0.07
0.63
SPI,

are summarized in terms of activation energy and


frequency factor (Table 3). The results indicate
SPI,

9.4
0.7
6.3

a type II source rock. The predicted geological


9
6

temperatures for the oil generation from the


min–max

819–828
815–820
810–820
806–813
797–811
Tmax, °F,

selected samples are in the range of 100°C–150°C


(212°F–302°F), indicating a homogeneous lateral
distribution of organic matter in the source rock.
The interpretation of the graph of S2 versus
min–max
Tmax, °C,

437–442
435–438
432–438
430–434
425–433

TOC indicates the AOIII source rock is charac-


terized by a type II oil-prone kerogen and an
Table 2. Hot Shale of the Aouinet Ouinine Member III: Average Geochemical Characteristics

original HI of approximately 600 mg HC/g TOC


% mg/g mg/g

426
367
393
198
383

(0.6 lb HC/lb TOC) (Figure 19). In addition, the


HI,

graph shows that almost all of the analyzed samples


2.38 8.86

0.56 1.17
2.26 8.83
2.69 11.77

3.10 13.87

in southern Tunisia have a good petroleum po-


TOC, S2,

tential (S2 > 5 mg HC/g rock [S2 > 0.005 lb HC/lb


rock]).
All the data cited above indicate that the hot
shale of the Upper Devonian AOIII, where present,
Number
Sample

14

10

11
9

is a good source rock.

Geochemical Modeling
Thickness, Thickness,

1004
889
886
735
942
ft

To understand the history of hydrocarbon charge


during the evolution of the Berkine–Ghadames Basin,
one-dimensional petroleum system modeling was
306
271
270
224
287
m

performed to provide a picture of hydrocarbon gen-


eration, expulsion, migration, and preservation, both
9459–10,463
9495–10,384

in time and in space from the source rocks into the


Interval, ft

8186–9072
6954–7199
7743–8685

reservoir.
The modeling was performed to assess petroleum
potential, thermal maturity, hydrocarbon generation
2883–3189
2894–3165
2495–2765
1970–2194
2360–2647
Wells Interval, m

history, and quantity of expelled hydrocarbons in


selected points within a sedimentary basin.
organic carbon.

The work integrated the geological model with


the thermal and kinetic models and was calibrated to
MG-1
HZ-1
CS-1
EC-2

RR-1

experimental data.

Aissaoui et al. 461


Table 3. Summary of Kinetic Parameters on Five Samples from the Devonian Hot Shale Sequences

Well, Depth
CS-1, 2315 m CS-1, 2608 m EC-2, 3100 m RR-1, 2528 m RR-1, 2580 m
(7595 ft) (8557 ft) (10,171 ft) (8294 ft) (8465 ft)
E (Cal/mol) (Fraction %) (Fraction %) (Fraction %) (Fraction %) (Fraction %)

38.00 0.10 0.00 0.00 0.00 0.06


39.00 0.07 0.00 0.00 0.06 0.03
40.00 0.00 0.05 0.00 0.00 0.10
41.00 0.00 0.04 0.00 0.12 0.00
42.00 1.01 0.04 0.00 0.10 0.14
43.00 0.81 0.08 0.00 0.16 0.05
44.00 1.37 0.03 0.25 22.00 0.26
45.00 0.70 0.15 0.34 0.15 0.00
46.00 1.28 0.00 0.00 0.37 0.68
47.00 0.65 0.14 0.00 0.51 0.12
48.00 1.64 0.30 0.00 0.00 0.00
49.00 0.50 0.00 0.00 1.02 0.00
50.00 2.78 0.00 0.00 0.00 0.00
51.00 0.13 0.00 0.00 0.00 15.24
52.00 5.56 0.00 82.08 13.00 22.33
53.00 0.00 0.00 0.00 20.60 43.98
54.00 52.36 0.00 14.21 33.90 2.10
55.00 8.91 0.00 2.37 14.52 11.90
56.00 17.89 62.22 0.00 6.06 0.90
57.00 0.43 2.16 0.00 5.54 1.42
58.00 1.83 22.09 0.75 0.82 0.00
59.00 0.71 0.00 0.00 1.24 0.18
60.00 0.00 6.76 0.00 0.08 0.15
61.00 0.00 1.09 0.00 0.00 0.00
62.00 1.27 0.00 0.00 0.00 0.38
63.00 4.86 0.00 1.54
Frequency factor (1/sec) 4.384 · 1015 2.079 · 1015 8.990 · 1015 4.090 · 1015 1.710 · 1015

See Figure 1 for well location.

With the data (stratigraphy, lithology, and tec- The present thermal regime was defined by
tonic evolution) provided by the available wells, a computing the present heat flow value (expressed in
regional geological model of the Berkine–Ghadames heat flow unit [HFU]) in the wells from the available
Basin and its evolution was defined. The two main bottom hole temperatures (Figure 22). The average
sedimentary cycles, Paleozoic and Mesozoic, are heat flow values of 1.2–1.4 HFU (Figure 23) are in
separated by the Hercynian unconformity, which agreement with a long stable geological setting. The
marks an important erosive event whose effect on the increase of the heat flow in the northern area of the
wells was estimated. The burial history of the basin study can be related to the presence of a shallower
was reconstructed using the backstripping tech- basement. The maturity parameters (Figure 24) were
nique. The burial history plots for the well PDG-2 also considered. All these data are key points to re-
(Figure 20) and well LD-1 (Figure 21) show depth construct the thermal history.
versus geologic time for all the geological formations The thermal history diagram (Figure 25) shows
penetrated by the wells. an increase of the thermal regime from 1.0 to 1.4

462 Petroleum Assessment of Southern Tunisia


Figure 19. Cross plot of hy-
drocarbons generated by pyrolysis
(S2) versus total organic carbon
(TOC) of the hot shale of the
Aouinette Ouinine Formation
Member III (AOIII) samples. CS-1 =
Chouech Es Saida-1; EC-2 =
Echouech-2; HI = hydrogen index;
HZ-1 = Hamadet Zamah-1;
MG-1 = Michiguig-1; RR-1 =
Rhourde Rezala-1.

HFU, which could be explained by the Triassic rifting. (0.6 lb HC/lb TOC), and original SPI = 10–11 t
From the Triassic until the present time the thermal HC/m2 (1–1.12 tons HC/ft2).
regime is assumed to be constant. Maturity maps (expressed as TR) and expelled
hydrocarbons maps have been prepared for both
Hydrocarbon Maturity, Generation, and source rocks at present time and at specific key
Expulsion moments in the past.
Hydrocarbon expulsion occurred depending on the
The model, calibrated to the well results, was applied amount of generated hydrocarbons, the porosity of the
on selected points, and evolution of maturity and rock, and the compaction effects. To evaluate the ex-
timing of hydrocarbon generation and expulsion were pulsion with the Rock-Eval data, a cross plot of depth
simulated for the Lower Silurian Tannezuft For- versus S1/TOC was used (Figure 26), where S1 rep-
mation hot shale and the Devonian Aouinette resents how many milligrams of free hydrocarbons
Ouinine Formation Member III source rocks, using can be thermally distilled out of 1 g of sample of source
the following mean values obtained from the ex- rock (McCarthy et al., 2011). The ratio S1/TOC is the
perimental data: Lower Silurian Tannezuft For- indication of the expulsion of the hydrocarbon. An
mation hot shale values are kerogen type II, original increase of the ratio means that the generated hydro-
TOC = 5%, original HI = 500 mg HC/g TOC (0.5 lb carbon remains in the source rock, and no expulsion
HC/lb TOC), and original SPI = 2 t HC/m2 (0.2 tons occurs. On the contrary, when the ratio decreases,
HC/ft2), and Upper Devonian Aouinette Ouinine the expulsion of the hydrocarbon occurs. In this case
Formation Member III values are kerogen type II, study, the S1/TOC ratio is decreasing at approximately
original TOC = 3%, original HI = 600 mg HC/g TOC 3200–3400 m (10,500–11,155 ft) depth (Figure 26).

Aissaoui et al. 463


Figure 20. Burial history plot for the well PDG-2. BBT/K. Leguine = Bir Ben Tartar/Kasbah Leguine; LD1 = Lessoud-1.

The basin modeling gave the following results (Eocene) hydrocarbon potential values ranging from
for the two studied source rocks. 0.1 to 2.1 t HC/m2 rock (0.01 to 0.21 tons HC/ft2
The Lower Silurian Tannezuft Formation hot shale rock) (Figure 28).
source rock reached a good level of maturity (TR > 0.1, The Upper Devonian AOIII source rock, as
minimum value to consider a source rock as mature). previously described, has a very interesting petroleum
Moving from north to south within the study area, the potential even if its presence is limited in the southern
maturity level becomes higher. Its present-day maturity part of the study area.
in southern Tunisia ranges from mature for oil in the At present time, its maturity is ranging from a
north to overmature or gas generating in the south TR = 0.1 (very close to the expulsion) to TR = 0.8,
(Figure 27). able to expel hydrocarbons over a large part of the
In the study area, the hydrocarbon expulsion oc- southern part of the study area (Figure 29). The
curred mainly in the Mesozoic and Cenozoic ages. In expulsion process, which occurred at approximately
the deepest part of the Berkine–Ghadames Basin (in 3200–3400 m (10,500–11,155 ft) in depth, started in
the Algerian sector out of the study area), a Pa- the Late Cretaceous (ca. 100 Ma) and continued until
leozoic phase of expulsion could be recognized. the Eocene (36 Ma). After the Eocene the expulsion
During Cretaceous up to Eocene (36 Ma), hy- process was negligible.
drocarbon expulsion occurred. The lack or reduction The quantity of hydrocarbon expelled from
of sedimentation is the main cause for the inter- the source rock suggests at 36 Ma (Eocene age),
ruption of expulsion after the Eocene. hydrocarbon potential values ranging from 0.1 to
The quantity of hydrocarbon expelled from the 2.5 t HC/m2 rock (0.01 to 0.25 tons HC/ft2 rock)
source rock was considerable and suggests at 36 Ma (Figure 30).

464 Petroleum Assessment of Southern Tunisia


Figure 21. Burial history plot for the well LD-1. A. Ouinine = Aouinette Ouinine; C. Intercalaire = Continental Intercalaire; PDG2 = Djebel Grouz-2.

Petroleum Systems and Hydrocarbon (Figures 33, 34) and Devonian Aouinette Ouinine
Migration Pathways Member III with Kirchaou reservoirs (Figures 33, 35).
Note that although the Paleozoic reservoirs hold
Definition of the Petroleum Systems hydrocarbons generated by a single source rock (i.e.,
The definition of the petroleum systems in southern Tannezuft hot shale), the hydrocarbon accumulations
Tunisia has been achieved through the analysis of within the Kirchaou Formation reservoirs were sourced
the geological framework and the results of the by the two source rocks (i.e., Silurian and Devonian).
geochemical analyses performed on the source rocks
and the available oil samples (Figure 31). Hydrocarbon Migration Pathways
The stratigraphic relations between the source and
the reservoir rocks allow us to define two petroleum Migration into Paleozoic Reservoirs
systems, which can be recognized in the Paleozoic Most of the hydrocarbon generated by the Silurian
sequences in the Tunisian sector of the Berkine– hot shale was migrated downward into the un-
Ghadames Basin: Silurian Tannezuft hot shale with derlying Ordovician sandstone. Although the
Upper Ordovician Djeffara reservoirs and Silurian Silurian–Ordovician petroleum system is con-
Tannezuft hot shale with Acacus reservoirs (Figures sidered valid, the Ordovician reservoirs have
32, 33). In addition, deposition during the Triassic of been poorly explored in southern Tunisia be-
the Kirchaou reservoirs above the Hercynian erosional cause of their significant depth (3500–5000 m
surface allowed for two additional petroleum systems: [11,483–16,404 ft]) and poor petrophysical char-
Silurian Tannezuft hot shale with Kirchaou reservoirs acteristics. In addition, many gas and condensate

Aissaoui et al. 465


Figure 23. Heat flow at present time expressed in heat flow unit
(HFU). BZ-1 = Bir Zobbes-1; CS-1 = Chouech Es Saida-1; EC-2 =
Echouech-2; GD-1 = Garet Dawed-1; HZ-1 = Hamadet Zamah-1;
LA-1 = Larich-1; OZ-1 = Oued Zar-1; RA-1Bis = Rmel Abiod-1; RR-1 =
Figure 22. Temperature and vitrinite reflectance calibration
Rhourde Rezala-1.
example in wells Echouech-2 (EC-2) and Laric-1 (LA-1).

discoveries have been uneconomic as demonstrated


by the wells Larich-1 (LA-1), El Borma Deep-1
(EBP-1), and Chaabet El Madiouni-1 (CEM-1)
(Figure 32).
Part of the hydrocarbon expelled from the Si-
lurian hot shale migrated into the Acacus reservoirs
and accumulated in the Oued Zar (OZ), Hammouda
(HMD), Adam (ADM), Hawa (HWA), Nour (NOUR),
Warda (WRD), Ahlem (AHL), Sourour (SOR), and Figure 24. Regional maturity trend in wells RR-1 and EC-2. TR =
other fields (Figure 32). transformation ratio.
The migration mechanism of hydrocarbon from
the hot shale into the Acacus reservoirs is, however,
not well understood. Migration may have occurred
vertically along fault zones and fractures or vertically
through the silty shale of the Tannezuft Formation.

Migration into Triassic Reservoirs


Part of the hydrocarbon expelled from the Silurian
hot shale migrated into the Kirchaou reservoirs Figure 25. Thermal history diagram. HFU = heat flow unit.

466 Petroleum Assessment of Southern Tunisia


Figure 26. Cross plot of depth
versus milligrams of free hydro-
carbons that can be thermally
distilled out of 1 g of sample of
source rock/total organic carbon
(S1/TOC). CS-1 = Chouech es
Saida-1; EC-2 = Echouech-2;
HZ-1 = Hamadet Zamah-1;
LA-1 = Larich-1; MG-1 =
Michiguig-1; OK-1 = Oued
Krebzab-1; RR-1 = Rhourde
Rezala-1.

Figure 28. Lower Silurian hot shale Tannezuft Formation


Source rock. Expelled hydrocarbon at 36 Ma. CS-1 = Chouech Es
Figure 27. Present-day maturity of Lower Silurian hot shale Saida-1; EB-1 = El Borma-1; EC-2 = Echouech-2; HMD-1 =
Tannezuft Formation source rock. BZ-1 = Bir Zobbes-1; EB-1 = El Hammouda-1; HZ-1 = Hamadet Zamah-1; LA-1 = Larich-1; OZ-1 =
Borma-1; OZ-1 = Oued Zar-1; RA1-Bis = Rmel Abiod 1-Bis. Oued Zar-1; RA1-Bis = Rmel Abiod 1-Bis.

Aissaoui et al. 467


The Devonian hydrocarbon migrated into the
Kirchaou Formation from Ouan Kasa and Tahara
carrier beds depending on their respective subcrop
relationships, following a secondary migration path
(Figures 33, 35).

Hydrocarbon Exploration Plays in Southern


Tunisia

The three main exploration plays in the study area are


in order of importance the Silurian, the Triassic, and
the Ordovician.

Silurian Play
This play has been proven in southern Tunisia and
is so far the primary and least risky exploration
target. As previously discussed, the Silurian Acacus

Figure 29. Present-day maturity of Upper Devonian Aoui-


nette Ouinine Formation Member III (AOIII) source rock.
CS-1 = Chouech Es Saida-1; EC-2 = Echouech-2; HZ-1 =
Hamadet Zamah-1.

from the Ordovician carrier beds, which subcrop


the Hercynian unconformity. It then migrated
southeastward and accumulated in El Borma (EB),
Debech (DH), Sanrhar (SN), Djebel Grouz (PDG),
Hammouda South East (HMD-SE), and Makhrouga
(MR) fields (Figures 33, 34).
Most of the hydrocarbon generated by the
Devonian AOIII source rock was expelled into the
underlying Ouan Kasa and the overlying Tahara
reservoirs, which act as carriers, whereas a minor part
was expelled directly into the Triassic Kirchaou
Formation (Figure 33). Nevertheless, accumulation in
the above mentioned Paleozoic reservoirs is very rare
in southern Tunisia. The Ouan Kasa reservoir is oil
bearing in just one field in Tunisia, Ech-Chouech-1
(EC-1; Figure 1), whereas hydrocarbon has never Figure 30. Upper Devonian Aouinette Ouinine Formation
been found in the Tahara reservoirs, probably be- Member III (AOIII). Expelled hydrocarbon at 36 Ma. CS-1 = Chouech
cause of the lack of traps and/or lack of seal. Es Saida-1; EC-2 = Echouech-2; HZ-1 = Hamadet Zamah-1.

468 Petroleum Assessment of Southern Tunisia


Figure 31. Reservoirs and
source rocks of the analyzed
hydrocarbons. CS-1 = Chouech
Es Saida-1; DH-1 = Debech-1;
EB-1 = El Borma-1; EBNE-1 =
El Borma Nord Est-1; EC-1 =
Echouech-1; Fm. = Formation;
HMD-1 = Hammouda-1; LA-1 =
Larich-1; MR-1 = Makhrouga-1;
OZ-1 = Oued Zar-1; PDG-1 =
Djebel Grouz-1; SN-1 = Sanrhar-
1; ZTE-1 = Zemlet Taiara-1.

Formation reservoirs were sourced by the Silurian hot several unsuccessful wells drilled in the area. We
shale. The trapping mechanism is provided by gentle note that not all of the successful wells are located
four-way dip closures (Figure 36), and the main risk is on evident structural closures (i.e., the well LA-1
associated with trap definition. In southern Tunisia, could have been drilled in a stratigraphic trap), but
from 1957 to present, approximately 58 exploratory all dry wells seem to be out of closure. In addition,
wells have been drilled targeting the Silurian Acacus in southern Tunisia, at least two different source
play. Of these, 14 wells were drilled off structure and rocks may charge the Triassic reservoirs. Thus, only
were dry; 8 wells had oil shows; and 36 wells, drilled
from 1997 to 2008, were classified as commercial
discoveries (i.e., HMD, ADM, HWA, NOUR, OZ,
WRD, and others; Figure 32). The commercial rate of
success is 62% (Figure 37).
The size of the producing fields ranges from 3
to 15 km2 (1.2 to 5.8 mi2), and the largest field
discovered in southern Tunisia in the Acacus
reservoir has 300 million bbl of oil in place and
recoverable reserves of approximately 100 million
bbl of oil.
Any four-way dip closure at the Acacus level
is associated with a very high chance of success.
However, we consider that the central–eastern part of
the study area is the most prospective sector for the
quality of the source, the reservoir, and the sealing
rocks and the relatively shallow depth of the Acacus
Formation ranging from 2250 to 3250 m (7382 to
10,663 ft) below sea level (Figure 38).
Figure 32. Lower Silurian–Paleozoic petroleum systems.
ADM = Adam; AHL = Ahlem; CEM-1 = Chaabet El Mediouni-1;
Triassic Play EBP-1 = El Borma Profond-1; HMD = Hammouda; HWA =
The Middle–Upper Triassic Kirchaou Formation Hawa; LA-1 = Larich-1; OZ = Oued Zar; SOR = Sorour; WRD =
is considered as a secondary play because of the Warda.

Aissaoui et al. 469


Figure 33. Southern Tunisia:
Kirchaou, Acacus, and Djeffara
hydrocarbon charging model.

prospects located along the Devonian or Silurian oil success of 27% (Figure 39). The main reasons for the
migration pathways can have a good chance to be failures are the difficulty in interpreting low-relief
charged (Figures 34, 35). structures using 2-D seismic lines, artifacts caused
Eighty-five new field wildcat wells have been by the static correction problems (Figure 40), and lack
drilled in the study area, all of which penetrated the of reflectivity on top of the Triassic reservoir. Taking
Triassic, although only 45 targeted the Kirchaou into account all those factors, a play map exploration
reservoir sandstone. Out of 45, 12 were successful risk is tentatively presented for the Kirchaou Play
and productive wells, giving a commercial rate of (Figure 41).

Figure 34. Lower Silurian–Kichaou petroleum system. Figure 35. Devonian–Kichaou petroleum system. AOI &
DH = Debech; EB = El Borma; Fm. = Formation; HMD-SE = II = Aouinette Ouinine Formation Members I and II; AOIII & IV =
Hammouda-Sud Est; MR = Makhrouga; PDG = Djebel Grouz; Aouinette Ouinine Formation Members III and IV; Fm. =
SN = Sanrhar. Formation.

470 Petroleum Assessment of Southern Tunisia


Figure 36. Generally low relief anticlines at Djeffara level are conformable with the shallower Tannezuft and Acacus levels. Fm. =
Formation; Hercyn. Unc. = Hercynian unconformity.

We consider that the northern part of the study local tectonism may enhance the permeability via
area is the most prospective sector (except where the fracturing the reservoir, thus increasing the pro-
source rock is absent) for the quality of the source, the duction rate. In addition, the Djeffara reservoir has
reservoir, and the sealing rocks. more chance of receiving hydrocarbon charge because
it is directly below the Silurian hot shale source rock.
Ordovician Play In Murzuk and Illizi basins, the Upper Ordovician
The Ordovician Djeffara reservoir is considered is a widespread and prolific reservoir. In these areas,
a secondary and high-risk play because of its the Upper Ordovician is interpreted as progradational
poor reservoir characteristics (mean porosity 5% and paleovalley infill deposited following a major glacial
mean permeability of 0.2 md), its significant depth, incision (Smart, 2000; Le Heron et al., 2004).
and the nature of hydrocarbon trapped (mainly gas in In the study area, 10 wells have penetrated the
wells CEM-1, OZ-1, and EBP-1; Figure 1). However, Ordovician: 6 of these encountered gas. However,

Figure 37. Silurian Acacus


play result.

Aissaoui et al. 471


Figure 38. Silurian Acacus exploration play risk. HC = hydrocarbons; S. R. = source rock.

472 Petroleum Assessment of Southern Tunisia


Figure 39. Triassic Kirchaou
play result.

oil has been recently produced in a commercial stratigraphic traps, especially in the western part of
quantity from the Ordovician in the Bir Ben Tartar the study, which is covered by sand dunes.
license located 30 km (19 mi) northeast of the study In addition, geological work has to be per-
area. formed to understand source rock and reservoir
relationships, hydrocarbon charging mechanism,
and migration pathways for specific prospects.
CONCLUSIONS AND RECOMMENDATIONS
Thematic maps, such as porosity or permeability
This paper synthesizes the Paleozoic and Triassic maps, should be generated when enough data
petroleum systems in southern Tunisia’s Berkine– are available. Detailed analysis of the old wells
Ghadames Basin and shows that the area has re- logs within the Paleozoic section, if performed,
maining hydrocarbon potential. could define new petroleum objectives. Particular
The main petroleum objectives in the study area attention should be paid to the interpretation
are clastics within the Ordovician, the Upper Silurian, of the logs recorded in the Acacus Formation
and the Middle–Upper Triassic intervals. Source because the low resistivity reading in this for-
rocks are identified in the Lower Silurian Tannezuft
mation may conceal the presence of hydrocarbon
Formation and Upper Devonian Aouinette Ouinine
accumulations. Finally, using new hydrocarbon
Formation Member III.
Geochemical modeling was performed to assess production techniques (acidization, hydraulic frac-
petroleum potential, thermal maturity, hydrocarbon turation, etc.) could increase the Ordovician res-
generation history, and quantity of expelled hydro- ervoirs’ deliverability.
carbons in the study area.
Different petroleum systems and plays have been
highlighted, and fairway maps have been tentatively
drafted. These elements are milestones for future
exploration in the area.
However, to better define the main prospective
zones and increase the chance of success, improve-
ment in seismic acquisition and processing is nec-
essary. Three-dimensional seismic coverage is essential
to map the remaining structural and stratigraphic
features.
Detailed and accurate static corrections must
be applied to the seismic volumes. Time-to-depth
conversion maps using accurate velocity fields are Figure 40. Two-dimensional seismic line in El Borma area
fundamental to identify low-relief structural and showing static correction anomalies.

Aissaoui et al. 473


Figure 41. Triassic Kirchaou exploration play risk. AOIII = Aouinette Ouinine Formation Member III; HC = hydrocarbons; S. R. = source rock.

REFERENCES CITED Acacus new play in southern Tunisia, in Proceedings of the


5th Exploration and Production Conference, Entreprise
Tunisienne d’Activites Petrolières Memoir 10, p. 1–14.
Abu-Ali, M. A., J. L. L. Rudkiewicz, J. G. McGillivray, and
Arduini, M., M. Barassi, F. Golfetto, A. Ortenzi, G. Serafini,
F. Behar, 1999, Paleozoic petroleum system of central
E. Tebaldi, E. Trincianti, and C. Visentin, 2000, Silurian-
Saudi Arabia: GeoArabia, v. 4, no. 3, p. 321–336.
Devonian sedimentary geology of the Libyan Ghadames
Abu-Ali, M. A., and R. Littke, 2005, Paleozoic petroleum
Basin: Example of an integrated approach to the Acacus
systems of Saudi Arabia: A basin modelling approach:
Formation study, in The geology of northwest Libya:
GeoArabia, v. 10, no. 3, p. 131–168. Second Symposium of Sedimentary Basins of Libya 2,
Abugares, Y., 2000, The petroleum geology of the Paleozoic p. 183–210.
clastics of the Murzuk basin, Al Atchan saddle, and the Azaı̈ez, H., M. Bédir, M. Soussi, and D. Tanfous, 2007, Seismic
southern part of the Ghadames basin, in The geology of sequence stratigraphy and platform to basin reservoir
northwest Libya: Second Symposium of Sedimentary structuring of lower Cretaceous deposits in the Sidi Aich-
Basins of Libya 2, p. 213–244. Majoura (central Tunisia): Journal of African Earth Sci-
Acheche, M. H., A. M’Rabet, H. Ghariani, A. Ouahchi, and ences, v. 48, p. 1–18, doi:10.1016/j.jafrearsci.2007.02.009.
S. L. Montgomery, 2001, Ghadames Basin, southern Bédir, M., 1995, Mécanismes géodynamiques des bassins
Tunisia: Reappraisal of Triassic reservoirs an future associés aux couloirs de coulissement de la marge atlas-
prospectivity: AAPG Bulletin, v. 85, no. 5, p. 765–780. ique de la Tunisie: Sismo-stratigraphie, sismo-structurale
Aissaoui, N., M. H. Acheche, J. Ben Yacoub, A. M’rabet, et implications pétrolières, state thesis of science, Uni-
T. Nahdi, F. Pezzino, and J. Smaoui, 1996, Silurian versité de Tunis II El Manar, Tunis, Tunisia, 420 p.

474 Petroleum Assessment of Southern Tunisia


Bédir, M., F. Zargouni, S. Tlig, and C. Bobier, 1992, Subsurface Ghadames basin boundary in southern Tunisia based on
geodynamics and petroleum geology of the transform gravity and magnetic anomalies: Journal of African Earth
margin basins in the Sahel of El Jem and Mahdia (eastern Sciences, v. 44, p. 303–313, doi:10.1016/j.jafrearsci
Tunisia): AAPG Bulletin, v. 76, no. 9, p. 1417–1442. .2005.11.021.
Bédir, M., L. Zitouni, N. Boukadi, S. Tlig, R. Alouani, and Gauthier, F. J., A. Boudjema, and R. Lounis, 1995, The
C. Bobier, 2000, Rifting, halocinèse et structuration des structural evolution of the Ghadames and lliizi basins
bassins péri-téthysiens jurassiques et Crétacé inférieur de during the Paleozoic, Mesozoic, and Cenozoic; pe-
subsurface sur la marge atlasique centre-ouest de la troleum implications (abs.): AAPG International
Tunisie (Région de Gafsa-Sidi Ali Ben Oun): Africa Conference and Exhibition, Nice, France, September
Geoscience Review, v. 7, no. 3, p. 289–306. 10–13, accessed February 18, 2016, http://www.
Bédir, M., N. Boukadi, S. Tlig, F. Ben Timzal, L. Zitouni, searchanddiscovery.com/abstracts/html/1995/intl/abstracts
R. Alouani, F. Slimane, C. Bobier, and F. Zargouni, 2001, /1214d.htm.
Subsurface Mesozoic basins in the central Atlas of Tu- Gauthier, F., R. Hedley, and S. Mckenna, 2003, The structural
nisia: Tectonics, sequence deposit distribution and hy- and tectonic evolution of the Berkine-Ghadames Basin: First
drocarbon potential: AAPG Bulletin, v. 85, no. 5, North African/Mediterranean Petroleum and Geoscience
p. 885–907. Conference, October 6–9, 2003, Tunis, Tunisia, 4 p.
Ben Yagoub, J., 1998, South Tunisia-Middle Triassic Kirchaou Galeazzi, S., O. Point, N. Haddadi, J. Mather, and D. Druesne,
Formation, in Tunisian exploration review: Schlum- 2010, Regional geology and petroleum systems of the
berger, p. 28–45. Illizi–Berkine area of the Algerian Saharan Platform:
Bishop, W. F., 1975, Geology of Tunisia and adjacent parts of An overview: Marine and Petroleum Geology, v. 27,
Algeria and Libya: AAPG Bulletin, v. 59, no. 3, p. 413–450. p. 143–178, doi:10.1016/j.marpetgeo.2008.10.002.
Bouaziz, S., E. Barrier, M. Soussi, M. M. Turki, and H. Zouari, Ghenima, R., 1995, Hydrocarbon generation and migration in
2002, Tectonic evolution of the northern African margin the Ghadames Basin: Application to the filling history of
in Tunisia from paleostress data and sedimentary record: the El Borma oil field, in Proceedings of the Seminar on
Tectonophysics, v. 357, p. 227–253, doi:10.1016/S0040- Source Rocks and Hydrocarbon Habitat in Tunisia: En-
1951(02)00370-0. treprise Tunisienne d’Activites Petrolières Memoir 9, p.
Boudjema, A., 1987, Evolution structurale du bassin pétrolier 145–182.
“Triasique” du Sahara Nord Oriental (Algerie), thèse, Guiraud, R., 1998, Mesozoic rifting and basin inversion along the
l’Université de Paris-Sud, Centre d’Orsay, Paris, 290 p. northern African Tethyan margin: An overview: Geological
Craig, J., C. Rizzi, F. Said, B. Thusu, S. Luning, A. I. Asbali, Society, London, Special Publications 1998, v. 132, no. 1,
and C. Hamblett, 2008, Structural styles and pro- p. 217–229, doi:10.1144/GSL.SP.1998.132.01.13.
spectivity in the Precambrian and Palaeozoic hydro- Guiraud, R., and W. Bosworth, 1999, Phanerozoic geodynamic
carbon systems of North Africa: Journal of the Geology of evolution of northeastern Africa and the northwestern
East Libya, v. 4, p. 51–122. Arabian platform: Tectonophysics, v. 315, no. 1–4,
Dardour, A. M., D. R. D. Boote, and A. W. Baird, 2004, p. 73–104, doi:10.1016/S0040-1951(99)00293-0.
Stratigraphic controls on Paleozoic petroleum systems, Guiraud, R., W. Bosworth, J. Thierry, and A. Delplanque,
Ghadames Basin, Libya: Journal of Petroleum Geology, 2005, Phanerozoic geological evolution of northern and
v. 27, no. 2, p. 141–162, doi:10.1111/j.1747-5457.2004. central Africa: An overview: Journal of African Earth
tb00050.x. Sciences, v. 43, no. 1–3, p. 83–143, doi:10.1016
Dhaoui, M., H. Gabtni, C. Jallouli, A. Jleilia, K. Mickus, and /j.jafrearsci.2005.07.017.
M. M. Turki, 2014, Gravity analysis of the Precambrian Holt, P., M. Allen, J. Van Hunen, and H. Bjornseth, 2010,
basement topography associated with the northern Lithospheric cooling and thickening as a basin forming
boundary of Ghadames Basin (southern Tunisia): Journal mechanism: Tectonophysics, v. 495, p. 184–194, doi:
of Applied Geophysics, v. 111, p. 299–311, doi:10.1016 10.1016/j.tecto.2010.09.014.
/j.jappgeo.2014.10.014. Kaced, M., and M. Arab, 2012, The potential of shale gas plays in
Echikh, K., 1998, Geology and hydrocarbon occurrences in Algeria: World Gas Conference, Kuala Lumpur, Malaysia,
the Ghadames Basin, Algeria, Tunisia, Libya, in Petro- June 4–8, 2013, v. 1, p. 49–53.
leum geology of North Africa: Geological Society, Lon- Klett, T. R., 2000, Total petroleum systems of the Triassic/
don, Special Publications 1998, v. 132, p. 109–130. Ghadames Province, Algeria, Tunisia and Libya—The
Espitalié, J., G. Deroo, and F. Marquis, 1985, La pyrolyse Tannezuft-Oued Mya, Tannezuft-Melrhir and Tannezuft-
Rock-Eval et ses applications: Revue de l’Institut Français Ghadames: US Geological Survey Bulletin 2202-C, 118 p.
du Pétrole, v. 40, p. 563–579, 755–784. Khomsi, S., M. Bédir, M. Soussi, M. G. Ben Jemia, and K. Ben
Gabtni, H., C. Jallouli, K. Mickus, M. M. Turki, M. Jaffal, and Ismail, 2006, Mise en evidence des compressions Eocène
P. Keating, 2012, Basement structure of southern Tunisia as moyen et supérieur en Tunisie orientale: Comptes
determined from the analysis of gravity data: Implications Rendus de l’Académie des Sciences, Géosciences, v. 338,
for petroleum exploration: Petroleum Geoscience, v. 18, p. 41–49.
p. 143–152, doi:10.1144/1354-079311-050. Khomsi, S., M. G. Ben Jemia, D. Frizon De Lamotte,
Gabtni, H., C. Jallouli, K. Mickus, H. Zouari, and M. M. Turki, C. Maherssi, O. Echihi, and R. Mezni, 2009, An overview
2006, The location and nature of the Telemzan High - of the Late Cretaceous–Eocene positive inversions and

Aissaoui et al. 475


Oligo-Miocene subsidence events in the foreland of the Pollastro, R. M., 2003, Total petroleum systems of the Pa-
Tunisian Atlas: Structural style and implications for the leozoic and Jurassic, Greater Ghawar Uplift and adjoining
tectonic agenda of the Maghrebian Atlas system: Tectono- provinces of central Saudi Arabia and northern
physics, v. 475, p. 38–58, doi:10.1016/j.tecto.2009.02.027. Arabian-Persian Gulf: US Geological Survey Bulletin
Langford, F. F., and B. Valleron, 1990, Interpreting Rock-Eval 2202, 100 p.
pyrolysis data using graphs of pyrolisable hydrocarbons Sikander, A. H., 2000, Structural development geology and
versus total organic carbon: AAPG Bulletin, v. 74, no. 6, hydrocarbon potential of the Ghadames and Murzuk
p. 799–804. basins—An overview, in The geology of northwest Libya:
Le Heron, D., O. Sutcliffe, K. Bourgig, J. Craig, C. Visentin, Second Symposium of Sedimentary Basins of Libya 2,
and R. Whittington, 2004, Sedimentary architecture of p. 327–340.
Upper Ordovician tunnel valleys, Gargaf Arch, Libya: Smart, J., 2000, Seismic expressions of depositional process in
Implications for the genesis of a hydrocarbon reservoir: the Upper Ordovician succession of the Murzuk Basin:
GeoArabia, v. 9, no. 2, p. 137–160. Geological exploration in Murzuk Basin, Amsterdam,
Lüning, S., J. Craig, K. D. Loydell, and B. Fitches, 2000, Elsevier, p. 397–415.
Lowermost Silurian “hot shales” in North Africa and Soussi, M., 2002, Le Jurassique de la Tunisie atlasique:
Arabia: Regional distribution and depositional model: Stratigraphie, dynamiquesédimentaire, Paléogéographie
Earth Science Reviews, v. 49, p. 121–200. et intérêt pétrolier, 363 p.
Lüning, S., K. Adamson, and J. Craig, 2003, Frasnian organic- Soua, M., 2013, First evidence of tunnel valley-like formation
rich shales in North Africa: Regional distribution and during the late Ordovician “subgalacial” period in
depositional model: Geological Society, London, Special southern Tunisia: Influence on the Jeffara sandstone
Publications 2003, v. 207, no. 1, p. 165–184. reservoir quality: SPE Middle East Oil and Gas Show and
McCarthy, K., K. Rojas, M. Niemann, D. Palmowski, Exhibition, Manama, Bahrain, March 10–13, 2013, SPE-
K. Peters, and A. Stankiewicz, 2011, Basic petroleum 164391-MS, 21 p.
geochemistry for source rock evaluation: Oil Field Re- Soua, M., 2014, Paleozoic oil/gas shale reservoirs in
view, Summer 2011, v. 23, no. 2, 32–43. southern Tunisia: An overview: Journal of African
Melki, F., T. Zouaghi, M. Ben Chelbi, M. Bédir, and Earth Sciences, v. 100, p. 450–492, doi:10.1016/j
F. Zargouni, 2012, Role of the NE-SW Hercynian master .jafrearsci.2014.07.009.
fault systems and associated lineaments on the structuring Tanfous Amri, D., M. Soussi, M. Bédir, and H. Azaiez, 2008,
and evolution of the Mesozoic and Cenozoic basins of the Seismic sequence stratigraphy of the Jurassic of the central
Alpine Margin, northern Tunisia, in E. Sharkov, ed., Atlas, Tunisia: Journal of African Earth Sciences, v. 51, no.
Tectonics—Recent advances: Rijeka, Croatia, InTech, p. 2, p. 55–68, doi:10.1016/j.jafrearsci.2007.12.005.
131–168, doi:10.5772/50145. Tissot, B., and J. Espitalié, 1975, L’évolution thermique de la
Milner, P. A., 1998, Source rock distribution and thermal matière organique des sédiments: Applications d’une
maturity in the southern Arabian Peninsula: GeoArabia, simulation mathématique: Revue de l’Institut Français du
v. 3, no. 3, p. 339–356. Pétrole, v. 30, p. 743–778.
Montgomery, S., 1994, Ghadames Basin and surrounding Yahi, N., R. G. Schaefer, and R. Littke, 2001, Petroleum
areas: Structure in tectonics, geochemistry and field generation and accumulation in the Berkine basin, eastern
summaries: Houston, Texas, Petroleum Frontiers, 79 p. Algeria: AAPG Bulletin, v. 85, no. 8, p. 1439–1467.
Nazir, A., J. Mateen, K. Shehzad Ch., N. Mehmood, and Yalçin Erik, N., O. Ozcelik, and M. Altunsoy, 2006, Inter-
F. Arif, 2011, Shale gas potential of Lower Indus Basin, preting Rock-Eval pyrolysis data using graphs of S2 versus
Pakistan (abs.): Pittsburgh Association of Petroleum TOC Middle Triassic–Lower Jurassic units, eastern part
Geologists/SPE Annual Technical Conference, No- of SE Turkey: Journal of Petroleum Science and En-
vember 22–23, 2011, Islamabad, Pakistan, accessed gineering, v. 53, no. 1–2, p. 34–36.
February 18, 2016, http://www.searchanddiscovery Zouaghi, T., 2008, Distribution des séquences de dépôts
.com/abstracts/pdf/2012/90138papg/abstracts/ndx_ du Crétacé (Aptien-Maastrichtien) en subsurface: Rôle
ahmad04.pdf. Malaysia, June 4–8, 2013, v. 1, p. 49–53 de la déformation tectonique, l’Halocinèse et évolution
Peters, K. E., 1986, Guidelines for evaluating petroleum source géodynamique (Atlas central de la Tunisie), Ph.D.
rock using programmed pyrolysis: AAPG Bulletin, v. 70, thesis, Faculté des Sciences de Tunis, Tunis, Tunisia,
no. 3, p. 318–329. 367 p.
Peters, K. E., L. B. Magoon, K. J. Bird, Z. C. Valin, and Zouaghi, T., and M. Bédir, 2005, 2D seismic interpretation of
M. A. Keller, 2006, North Slope, Alaska: Source rock strike-slip faulting, salt tectonics, and Cretaceous un-
distribution, richness, thermal maturity, and petroleum conformities, Atlas Mountains, central Tunisia: Journal of
charge: AAPG Bulletin, v. 90, no. 2, p. 261–292, doi: African Earth Sciences, v. 43, p. 464–486, doi:10.1016
10.1306/09210505095. /j.jafrearsci.2005.09.010.

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