SAFETY DATA SHEET (SDS)

Name of chemical : Ralli Hand Sanitizer

1. PRODUCT IDENTIFICATION / COMPANY ADDRESS

Trade Name Ralli Hand Common Name Sanitizer Synonyms Hand

Sanitizer sanitizer
Company Name / Address / Rallis India Ltd.
Phone / Fax 23rd Floor, Lodha Excelus,
New Cuffe Parade, Off Eastern Freeway,
Wadala, Mumbai 400037.

Emergency contact -Mr. Alok Chandra.- 022-67761674

Chemical Name Mixture of ethyl alcohol, Hydrogen peroxide and glycerin

2. HAZARD IDENTIFICATION

Hazard Classification Flammable Liquids - Category 2

Serious Eye Damage/Irritation - Category 2A

LABEL ELEMENTS HAZARD PICTOGRAMS.

GHS02 GHS07

Signal word Danger

HAZARD STATEMENT H225 Highly flammable liquid and vapour. H319

Causes serious eye irritation.
Rallis India Limited SDS – (Hand Sanitizer )

PRECAUTIONARY P102 Keep out of reach of children.

STATEMENT P103 Read label before use.
P210 Keep away from heat/sparks/open flames/hot
surfaces. No smoking.
P233 Keep container tightly closed.
P243 Take precautionary measures against static
discharge.
P101 If medical advice is needed, have product
container or label at hand.
P305+P351+P338 IF IN EYES: Rinse cautiously with
water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P337+P313 If eye irritation persists: Get medical
advice/attention.

3. COMPOSITION / INFORMATION AND INGREDIENTS

Structural Mixture of Chemical Family Alcohol

Formula C2H5OH. H2O2 Molecular weight NA
CAS No NA Molecular NA
Formula
Name Product identifier % GHS-US classification

Ethyl Alcohol 64-17-5

75-80%
Eye irritant 2A
Acute toxicity - Oral Category 4
Acute toxicity - Inhalation
(Vapors) Category 4 Skin
Hydrogen
corrosion/irritation Category 1
peroxide 7722-84-1 0.01
Sub-category B Serious eye
damage/eye irritation Category
1 Specific target organ toxicity
(single exposure) Category 3

Water 7732-18-5 20-25 % Non Hazardous

4. FIRST AID MEASURE

Ingestion If swallowed, DO NOT induce vomiting. Get medical attention if symptoms

occur. Rinse mouth thoroughly with water.
Inhalation If inhaled, remove to fresh air. Get medical attention if symptoms occur.
Eyes In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. If easy to do, remove contact lens, if worn. Get medical attention.
Skin Wash with water and soap as a precaution. Get medical attention if
symptoms occur.

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Rallis India Limited SDS – (Hand Sanitizer )

Antidote No specific antidote.

Most important Causes serious eye irritation.
symptoms/
effects, acute
and or delayed
Indication of First Aid responders should pay attention to self-protection, and use the
immediate recommended personal protective equipment when the potential for
medical attention exposure exists.
and special
treatment needed

5. FIRE FIGHTING MEASURES

Fire extinguishing media
Hazardous decomposition
products
Special firefighting
procedure
Precaution to Fire Fighters
Water spray Alcohol-resistant foam Dry chemical ,Carbon dioxide
(CO2)
Carbon oxides
Do not use a solid water stream as it may scatter and spread fire.
Flash back possible over considerable distance. Exposure to
combustion products may be a hazard to health Unsuitable
extinguishing media- High volume water jet
In the event of fire, wear self-contained breathing apparatus. Use
personal protective equipment.

6. ACCIDENTAL RELEASE MEASURES

Personal precaution Remove all sources of ignition. Use personal protective equipment.
Follow safe handling advice and personal protective equipment
recommendations.
Precautions for the Discharge into the environment must be avoided. Prevent further
environment leakage or spillage if safe to do so. Prevent spreading over a wide area
(e.g. by containment or oil barriers). Retain and dispose of contaminated
wash water. Local authorities should be advised if significant spillages
cannot be contained.
Clean up method Non-sparking tools should be used. Soak up with inert absorbent
material. Suppress (knock down) gases/vapors/mists with a water spray
jet. For large spills, provide diking or other appropriate containment to
keep material from spreading. If diked material can be pumped, store
recovered material in appropriate container. Clean up remaining
materials from spill with suitable absorbent. Local or national regulations
may apply to releases and disposal of this material, as well as those
materials and items employed in the cleanup of releases. You will need
to determine which regulations are applicable. Sections 13 and 15 of this
SDS provide information regarding certain local or national
requirements.

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 Rallis India Limited SDS – (Hand Sanitizer )

7. HANDLING AND STORAGE

General Do not breathe vapors or spray mist. Do not swallow. Do not get in eyes.
precaution Avoid prolonged or repeated contact with skin. Handle in accordance with
good industrial hygiene and safety practice. Non-sparking tools should be
used. Keep container tightly closed. Keep away from heat and sources of
ignition. Take precautionary measures against static discharges. Take care
to prevent spills, waste and minimize release to the environment.
Personal Do not mix with bare hand. Use gumboots, mask, hand gloves, rubber apron,
protection hood or hat.
Storage Keep in properly labeled containers. Keep tightly closed. Keep in a cool, well-
ventilated place. Store in accordance with the particular national regulations.
Keep away from heat and sources of ignition.
Incompatibilities Strong oxidizing agents Organic peroxides Flammable solids Pyrophoric
liquids Pyrophoric solids Self-heating substances and mixtures Substances
and mixtures which in contact with water emit flammable gases Explosives
Gases

8. EXPOSURE CONTROL / PERSONAL PROTECTION

Personal protection

Skin Select appropriate protective clothing based Eyes Wear the following
on chemical resistance data and an personal protective
assessment of the local exposure potential. equipment: Safety
Wear the following personal protective goggles
equipment: Flame retardant antistatic
protective clothing. Skin contact must be
avoided by using impervious protective
clothing (gloves, aprons, boots, etc).
Respiration Follow OSHA respirator regulations (29 CFR Other Ensure that eye flushing
1910.134) and use NIOSH/MSHA approved systems and safety
respirators. Protection provided by air showers are located
purifying respirators against exposure to any close to the working
hazardous chemical is limited. Use a place. When using do
positive pressure air supplied respirator if not eat, drink or smoke.
there is any potential for uncontrolled Wash contaminated
release, exposure levels are unknown clothing before re-use.
Exposure limits
1000 ppm TLV-STEL NA
TLV-TWA 1880 mg/M 3

Appropriate Minimize workplace exposure concentrations. Use only in an area

Engineering Control equipped with explosion proof exhaust ventilation. Use with local exhaust
ventilation.

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Rallis India Limited SDS – (Hand Sanitizer )

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance Clear pale Molecular Weight NA Specific 0.87 Aprox.

blue gravity
colored
liquid
Odor Alcoholic Flash Point oC 25 PH 6.5 to 8.5
Auto Ignition NA Boiling Point oC 7o Melting NA
Temp. oC @ 760 mm Hg Point oC
Vapor Press. Vapour Density NA Solubility Soluble
mPa @ 24 °C NA

LEL % NA UEL % NA % NA
Volatile
Evaporation rate NA Viscosity @ 25 oC NA

Octanol / Water Partition log Pow: -0.35 Relative density NA

Coefficient

10. STABILITY AND REACTIVITY

Chemical Stable under normal Possibility of Flammable liquid and vapor.

Stability conditions. Hazardous Vapors may form explosive
reaction mixture with air. Can react with
strong oxidizing agents.
Hazardous No hazardous Incompatible Oxidizing agents
Reactions/ decomposition products Materials
Decomposition are known.
products
Condition to Heat, flames and sparks.
avoid

11. TOXICOLOGICAL INFORMATION

Routes of Inhalation Skin contact Ingestion Eye contact

exposure
LD50 (oral / >5,000 LD50 (dermal/ >2000 LC50 (inhalation / 124.7
rats) mg/kg rats)mg/kg rats) mg/l-4 hrs

Target Organ No data available

Effects
Symptoms related to physical, chemical & No data available
toxicological characteristics

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Rallis India Limited SDS – (Hand Sanitizer )

12. ECOLOGICAL INFORMATION

Mobility in Soil No data available

Persistence and Readily biodegradable. Biodegradation: 84 % Exposure time: 20 d
degradability
Bioaccumulative
Potential NA
LC50 fish Pimephales promelas (fathead minnow, Daphnia magna (Water flea): >
1,000 mg/l
Effects on birds No data available
Effects on bees No data available

13. DISPOSAL CONSIDERATIONS

Dispose of in accordance with local regulations, Empty containers should be taken to an
approved waste handling site for recycling or disposal. Do not burn, or use a cutting torch on, the
empty drum.

14. TRANSPORT INFORMATION

UN No. 1170 IMDG No.

Shipping Name Ethanol solution, Flammable Hazard class 3
Packing group II Hazard Sub NA
class
Marine Pollutant NA Labels required Xi, F
Warning Statement Keep away from foodstuffs, children, heat/flames & destroy empty
container after use.
Packaging / Closed container
Precaution
Shipping Marking Ethanol solution, Flammable

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Rallis India Limited SDS – (Hand Sanitizer )

15. REGULATORY INFORMATION

SYMBOLS: Xi, F

PHRASES R:
R21 Harmful in contact with skin.
R22 Harmful if swallowed.
R36 Irritating to eyes.
R37 Irritating to respiratory system.
R20 Harmful by inhalation.
R25 Toxic if swallowed.

PHRASES S:
(S1/2): Keep locked up and out of the reach of children
S21: When using do not smoke
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S28: After contact with skin, wash immediately with plenty of ... (to be specified by the
manufacturer)
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection
S45: In case of accident or if you feel unwell seek medical advice immediately (show the label
where possible)

16. OTHER INFORMATION

NFPA Rating :

USE-
This is a personal care or cosmetic product that is safe for consumers and other users under
normal and reasonably foreseeable use. Cosmetics and consumer products,

The information provided in this safety data sheet is correct to the best of our
knowledge, information and belief at the data of its publication. The information given is
designed only as guidance for safe handling, use, processing, storage, transportation,
disposal and release and is not to be considered as a warranty or quality specification.
The information relates only to the specific material designated and may not be valid for
such material used in combination with other materials.
This data belongs to Rallis India Limited. All rights reserved.

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