Nirmal Academy for Science Education

C HE MI STRY for I I T-J E E

NIRMAL SINGH
CLASSES
for IIT-JEE Mains - Advanced

NIRMAL SINGH CLASSES

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Nirmal Academy for Science Education (NASE) 117/N/555 Raniganj, Kakadeo, Near Om Chauraha, Kanpur
Contact Number : 9889655556 , 7458910091

Nirmal Academy for Science Education (NASE) 117/N/555 Raniganj, Kakadeo, Near Om Chauraha, Kanpur
Contact Number : 9889655556 , 7458910091 page no # 1
 21102020 Assignment # 07 FC Batch
ORGANIC CHEMISTRY
(Topic : GOC // Sub Topic : Basic Strength )
(for JEE-Mains & Advanced 2022)
=============================================================================================================

01. The correct sequence regarding base strength of aliphatic amines in aqueous soloution
is :
(a) R3 N > R2 NH > R NH2 > NH3 (b) R2 NH > R NH2 > R3 N > NH3 .
(c) R2 NH > R3 N > R NH2 > NH3 (d) R NH2 > R2 NH > R3 N > NH3 .

02. Decreasing order of basicity of the three isomers of nitro aniline is :

(a) p—nitroaniline > o—nitroaniline > m—nitroaniline .
(b) p—nitroaniline > m—nitroaniline >o—nitroaniline .
(c) m—nitroaniline > p—nitroaniline > o—nitroaniline .
(d) m—nitroaniline > o—nitroaniline > p—nitroaniline .

03. Strongest base is :

NH
(a) NH2 CNH2 (b) pyridine
H2 N
(c) C=O (d) Di-methylamine .
H2 N
04. Which of the following is most basic ?

(a) (b) (c) (d) NH2

NH
N N
H

05. Acetanilide is :
(a) Weaker base than Aniline (b) Stronger base than Acetamide
(c) Both are correct (d) None of these correct

06. Which of the following is the strongest Bronsted base ?

N
O
(a) NH2 (b) N—H
N
H

(c) NH2 (d) N—H .

Nirmal Academy for Science Education (NASE) 117/N/555 Raniganj, Kakadeo, Near Om Chauraha, Kanpur
Contact Number : 9889655556 , 7458910091 page no # 2
 07. Which of the following is the weakest Bronsted base ?

(a) N (b) N

O
O
(c) N (d) N .

08. Which of the following is strongest Bronsted base ?

H3 C
O
(a) N (b) N .
H
CH3 CH3
(c) O2 N— —N (d) ——N .
H H
09. For the following compounds, which is the strongest base and which is strongest acid?
O
N
O NH2 S=O
(I) (II) (III) (IV) NH2
N—H N
H
(a) II = strongest base, I = strongest acid
(b) IV = strongest base, III = strongest acid
(c) III = strongest base, IV = strongest acid
(d) II = strongest base, III = strongest acid .

10. Which of the following is weakest base ?

(a) C6H5 NH2 (b) C6H5 CH2 NH2
O

(c) C6H5 CONH2 (d) N—H

11. Which of these is the strongest base ?

Et N
(a) Et N (b)
Et N

O
_ + _ +
N —K
(c) (d) N Li .
O

Nirmal Academy for Science Education (NASE) 117/N/555 Raniganj, Kakadeo, Near Om Chauraha, Kanpur
Contact Number : 9889655556 , 7458910091 page no # 3
 (a) NH2 O

NH (b)
12. ; Basic strength order is :

CH2 —NH2
(c)

(a) a > b > c (b) b > a > c (c) c > a > b (d) c > b > a .
13. Strongest base is :

NH2 NH2 NH2 NHCOCH3

Me
(a) (b) (c) (d)
Me
14. Weakest base is :

NH2 NH2 NH2 NH2

Me
(a) (b) (c) (d) .
Me
Me

15. The pKb value is lowest for : (pKb = — log kb)

NH2 NH2 NH2 NH2

(a) (b) (c) (d) .

16. Strongest base is :

NH
H2 N
(a) (b)
O O

(c) ——NH2 (d) ——NH—— .

17. Which of the following is weakest base ?

O NH2

(a) (b) N (c) (d) .

N
N H H

Nirmal Academy for Science Education (NASE) 117/N/555 Raniganj, Kakadeo, Near Om Chauraha, Kanpur
Contact Number : 9889655556 , 7458910091 page no # 4