Nirmal Academy for Science Education CHEMISTRY ¢.- IIT-JEE ‘J NIRMAL SINGH CLASSES fr IIT-JEE Mains - Advanced NIRMAL SINGH CLASSES www.nirmalsinghchemistry.com Live Online Interactive Classes Download the app from play store--Nirmal Singh Classes Nirmal Academy for Science Education (NASE) 117/N/S5S Raniganj, Kakadeo, Near Om Chauraha, Kanpur Contact Number : 9889655556 , 745891009122102020 Assignment #01 Ranker’s Batch Qi Q2 Q3 Q4 Q5 Q6 ORGANIC CHEMISTRY (Topic : ALKYL HALIDE) (JEE-Mains & Advanced 2022) 1 More than On T Which are possible products in following, sear) moist Ag,0 cH > CH, OH CHOW CH “ OXSton ®) a © QC © Syl & Sy2 isnot favourable in (A)H,C=CH-Cl_— (B) Ph-CH,-Cl (C) Ph-Cl (D) H,C=CH-CH,-Cl Syl & 8,2 product are same in (excluding stereoisomer) 1 wT ' oy oO (D) Ph-CH-CH-CH, ra cl -H; Cl HH Which of the following statements is /are true? (A) CH,-CH,-CH,- will react more readily than (CH,), CHI for $2 (B) CH;-CH,-CH,-C! will react more readily than CH,-CH,~CH,-Br for S,2 reaction, (©) CH,-CH,-CH,-CH,-Br will react more readily than (CH,),C-CH,-Br forS,2 reactions (D) CH,-O-C,H,-CH,Br will react more readily than NO,-CH,-CH,Br for S,2reaction A solution of (R)-2-iodobutane, (ai] =~15.9° in acetone is treated with radioactive iodied, until 1.0% of iodobutane contain radioactive iodine, the specific rotation of recovered iodobutane is found to be ~15.58°, which statement is correct about above information, (A) Ithas optical purity 96% (B) % of R in solution is 99% (©)Racemic mixture is 2% (D) Final solution is dextrorotatory Inwhich of the following case configuration about chiral C* is retained: Me Me (A) H— on St, HBr, (B) H—+— 0p 822, —SHONe_, D Me Me (© n— on 20s, 08 oy Hon eo D Et Nirmal Academy for Science Education (NASE) 117/N/555 Raniganj, Kakadeo, Near Om Chauraha, Kanpur Contact Number : 9889655556 , 7458910091Q7 Qs Q9 Q0 Qui Qi2 Q13 Which of the following will react with ACOAg (A)R-NH, (B)R-OTs (RA, (D)R-Br Consider the given reaction CH, | H-C-OTs Ww cH cHCH-CN | C,H, (S) ‘his, which of following statements are correct for above reaction. (A) Product formation takes place due to the breaking of O-Ts (B) Thereactionis $5 (©) Thereactionis S, (D) Configuration of product is (R) Benzoyl chloride is less reactive than acetyl chloride for nucleophilic acyl substitution reaction because ° I) (A) —C— group of benzoy! chloride is in conjugation with benzene ring. This makes benzoyl chloride ‘more stable than acetylchloride. (B) CH, group of acetyl chloride make C-Cl bond stronger due to the #1 effect. (C)C,H- group of benzoyl chloride make CCl bond weaker due to +R effect. (D) Carbonyl carbon in benzoyl chloride is less electron deficient than acetyl chloride S,2reaction will be negligible in A a eG of Rate of S,.2 depends on (A) Conc of Nucleophile (B) Conc of substrate (C)Nature of leaving group (D) Nature of solvent Correct statement(s) for the product(s) of following reaction. CH, = CH=CH, ~ Ph Saye (A) Four different products are formed (B) Two optically active products are formed (©) The optically active compound formed here can also be made by the reaction of HCI (D) The reaction path is free radical substitution. Inthe given pair in which pair the first compound is more reactive than second to $2 reaction. wOr-o Grae oA a Nirmal Academy for Science Education (NASE) 117/N/555 Raniganj, Kakadeo, Near Om Chauraha, Kanpur Contact Number : 9889655556 , 7458910091Qi4 Quis Q16 Qi7 Qs Quis ‘A gem dichloride is formed in the reaction : (A) CH,CHO and PCI, (B) CH,COCH, and PCI, (C) CH, = CH, and Cl, (D) CH, = CHCl and HCI Incorrect about alky! halides is /are: (A) Tertiary alkyl halides undergo 8,,2 substitutions (B) Alkyl iodides on exposure to sunlight gradually darken (C\Alky| chlorides do not give beilstein test (D) nucleophilic substitution is most difficult in alkyl iodides Which ofthe following statement is/are correct ? (A) Carbonyl compounds of the general structure CH, ~C—R givea positive iodoform test II oO (B)All secondary aleohols give iodoform reaction (C)Alkanols of the structure CH,CH(OH)—R (where R =H, alkyl or aryl) give iodoform reaction, (D) The only aldehyde giving iodoform reaction is acetaldehyde. Match List I with List II and select the correct answer from the codes given below: Column I Column It (A) CH,-0-80,CH, + CH,8 () CH,-CH,-PH, (8) CH,-CH,-1+PH, @) CH,-O-C,H, (© HC=@Na+CH,-CH,-Br @) CH,-O-CH, © cHy-cl+cH-8 (4) CH=C-CH,-CH, Match List with List I forgiven §, reaction & select the correct answer from the codes given below Z-CH,Br+ CH, 0” —>Z-CH,-OCH, + BP List-1 List-II (relative reactivity) (ay @)0.1 (B)CH,- Q3 (C) CH= ®l A. © Scar 100 cH Inwhich product formation takes place according to Hoftimann’s rule ae 4 38 (A) CH,CH, -CH-CH, "SR (B) CH,CH, ~CH-CH, aa Br be chy (© cncrt,-cHN—cn, bu, (D) CH,CH,CH-CH, bu, CH CHy °S(CH,), Nirmal Academy for Science Edueation (NASE) 117/N/555 Raniganj, Kakadeo, Near Om Chauraha, Kanpur Contact Number : 9889655556 , 7458910091Q.20 Which of following will give syn-elimination (A) CH,CH,CH,-OCOCH, (B) CH,CH,CH-CH, & CH, (© CH,CH,CH, -0-C-s-CH, ©) cucu,cu,N-8 § du 3 Q.21 Which of following are correct for given reaction @ 4 N- Su oN oY (A) Major product of reaction is a (B) Majorproductis, \ A (C) Thereaction is thermal elimination reaction (D) The reaction is E, reaction Q.22 Which alkyl halide undergo E, elimination ; : Oy 4y~ ® Ay © 2 el L~f v8 ¢ Q.23 Match the List] (reaction) with List Il (reaction intermediate) and select the correct answer using the codes given below the Lists. List 1 List (A) CF,-CHCI, —aeKow/a_, CR, = CCl, (1) Transition state onl ¥ 2 2 2 ly ie @) CHy-C-OH 5 CH, -C=CH, 2) — Carbocation I CH, CH, (© CH,-CH,-Br —22%°H_, CH=CH. (3) Carbanion Iy-CHy a y=CH, . Br | (D) CH,—C-CH, _*80H/4 cy CocH, (4) Freeradical t | CH, CH. 3 Nirmal Academy for Science Education (NASE) 117/N/555 Raniganj, Kakadeo, Near Om Chauraha, Kanpur Contact Number : 9889655556 , 7458910091Q.24 Match the List with List Il and select the correct answer using the codes given below the Lists. List List IT (A)EICB (1) 3°Amine oxide (B) Saytzeffalkene as major product (2) Xamhate Gy I (EZ (@) CH,-CH, -CH-CH, (D)Ei (4) CgHs-CH, -CH-CH, .25 Match the foll | 2 teh Raman Column Il F OCH; Hy CHO cH,CH, 6 — one (EI 3 cH,0 Br a L BCH, THycriar CHS, (QR cHcIt,00 © 7 cy as (R)Eleb 0. oO @) Nirmal Academy for Science Education (NASE) 117/N/555 Raniganj, Kakadeo, Near Om Chauraha, Kanpur Contact Number : 9889655556 , 7458910091