Lecture 7 Landfill Gas and Operations PDF

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CHE 191-1: SOLID WASTE MANAGEMENT

LECTURE 7:
Landfill Gas and Operations
LECTURE 7: LANDFILL GAS AND OPERATIONS

Landfill Gas
LECTURE 7: LANDFILL GAS AND OPERATIONS

Learning Objectives

1. Explain the importance of capturing landfill gas, and describe


the methods for controlling gaseous emissions

2. Discuss the various methods of capturing and utilizing landfill


gas
LECTURE 7: LANDFILL GAS AND OPERATIONS

Predicting Gas Production

 It is essential to estimate the volume and composition of gas


produced from an operating or closed landfill.

 The following are the parameters needed to estimate gas


production:
 Gas yield per unit weight of waste
 Lag time prior to gas production
 Shape of the gas production curve
 Duration of gas production
LECTURE 7: LANDFILL GAS AND OPERATIONS

Ball park estimates

 In theory, biological decomposition of 1 ton of MSW produces


442 m3 of landfill gas containing 55% CH4 and a heat value of
19,730 kJ/m3.

 Because of the non-biodegradable fraction of the waste, the


actual average methane yield is 100 m3/MT.
LECTURE 7: LANDFILL GAS AND OPERATIONS

Gas control

 Landfill gas may vent naturally or be directed to the


atmosphere by engineered controls which may be categorized
as either:

 Passive systems

 Active systems
LECTURE 7: LANDFILL GAS AND OPERATIONS

Passive gas control systems

 Rely on natural pressure and convection to vent landfill gas

 May be:
 High permeability
 Low permeability techniques
LECTURE 7: LANDFILL GAS AND OPERATIONS

Passive high permeability systems

 Incorporate pathways such as trenches, vent walls, or


perforated pipe vents surrounded by coarse material to vent
landfill gas to the surface.
LECTURE 7: LANDFILL GAS AND OPERATIONS

Passive low permeability systems

 Low permeability systems block lateral migration via barriers


such as synthetic membranes and clayey soils.
LECTURE 7: LANDFILL GAS AND OPERATIONS

Active systems

 Active gas control systems employ some mechanical means to


remove landfill gas and consist of either

 Positive pressure (air injection)

 Negative pressure (extraction)


LECTURE 7: LANDFILL GAS AND OPERATIONS

Potential problems in as recovery systems

1. The extraction must be completed in a difficult environment


(differential settlement, pipe failure thru sag development, failure
at the condensate outlets)
LECTURE 7: LANDFILL GAS AND OPERATIONS

Potential problems in as recovery systems

2. Condensate blockage in header pipes.

3. The extraction system must balance where the gas is being


pumped from, in accordance with the spatial variability in the
gas generation rates.

4. Existence of substantial water makes extraction very


difficult.
LECTURE 7: LANDFILL GAS AND OPERATIONS

Potential problems in as recovery systems

5. Air can intrude because of suction pressures thru the landfill


surface.

6. Breaks in collection lines allow air intrusion, causing


deterioration
LECTURE 7: LANDFILL GAS AND OPERATIONS

Landfill gas pre-processing

1. Condensate removal

2. Particulate removal

3. Dehydration of the gas

4. Carbon dioxide removal

5. Hydrogen sulfide removal

6. Nitrogen removal
LECTURE 7: LANDFILL GAS AND OPERATIONS

Options for landfill gas utilization

1. Incineration – combustion as-extracted

2. Low BTU gas – process removes only free moisture,


unrefined or raw

3. Medium BTU gas – compression, removal of moisture and


heavy-end HCs
LECTURE 7: LANDFILL GAS AND OPERATIONS

Options for landfill gas utilization

4. High BTU gas – requires removal of all moisture, trace


gases and CO2.

5. High BTU gas/ CO2 recovery – Same as high BTU gas but
incorporates CO2 recovery.

6. Chemical products – cleanup processes involve conversion


of landfill gas (LFG) into chemical fractions such as methanol.
LECTURE 7: LANDFILL GAS AND OPERATIONS

Incineration

 Incineration of landfill gas is a control measure intended to


limit the gas migration from a landfill site and to mitigate
landfill gas odors that are a result of emissions to the
atmosphere.

 Active gas collection system is used without energy


recovery
LECTURE 7: LANDFILL GAS AND OPERATIONS

Low BTU gas

 Use as a heating fuel

 Uses for a steam boiler to generate electricity

 For cement kilns or other heat-demanding industries


LECTURE 7: LANDFILL GAS AND OPERATIONS

Medium BTU gas

 Has half the heating content of natural gas

 Sale to industry/utility

 Steam production

 Power generation

 Internal combustion engines

 Gas turbines
LECTURE 7: LANDFILL GAS AND OPERATIONS

High BTU gas

 Sale to natural gas pipelines

 Possible use in vehicles

 CO2 recovery
LECTURE 7: LANDFILL GAS AND OPERATIONS

Landfill gas conversion to power

1. Reciprocating engine (0.7-3 MW per unit)

2. Gas turbines (0.7-3 MW per unit)

3. Steam turbines

4. Combined cycle
Reciprocating engines

 Experience has shown that contaminants in landfill gas can


produce rapid engine wear sufficient to cause engine failure
for operating times as little as 10 to 30 days.

 Engine corrosion can be reduced by dehydrating the gas


with a refrigerated dryer.
LECTURE 7: LANDFILL GAS AND OPERATIONS

Gas turbines

 Inherently more resistant to corrosive effects from landfill gas


because of the high temperature alloys used.

 Lower emissions

 Has a dual oil system to prevent shutdown

 Simpler to operate

 Higher operating cost


 Lower energy efficiency (15-25%)
LECTURE 7: LANDFILL GAS AND OPERATIONS

Steam turbines

 Large-scale, long term power generation project

 Generation capacity in excess of 10 MW

 Fuel to power conversion efficiency of 24%


LECTURE 7: LANDFILL GAS AND OPERATIONS

Combined cycle

 Utilizes both steam and gas turbines

 Conversion efficiency of over 35% can be achieved by


recovering waste heat
LECTURE 7: LANDFILL GAS AND OPERATIONS

High BTU and CO2 recovery

 Production alternatives:

 Physical processes where CO2 is removed by dissolution in


water

 Chemical removal by bonding between solvent and CO2

 Adsorption of a thin layer of molecules to the surface of solids


such as activated carbon

 Membrane removal
LECTURE 7: LANDFILL GAS AND OPERATIONS

Complete conversion of biodegradable organic waste

1 1 1
𝐶𝐻𝑎 𝑂𝑏 𝑁𝑐 + 4 − 𝑎 − 2𝑏 + 3𝑐 𝐻2 𝑂 → 4 − 𝑎 + 2𝑏 + 3𝑐 𝐶𝑂2 + 4 + 𝑎 − 2𝑏 − 3𝑐 𝐶𝐻4 + 𝑐𝑁𝐻3
4 8 8
LECTURE 7: LANDFILL GAS AND OPERATIONS

Problem Set: Gas Potential

 Calculate the gas potential in m3/ton of waste received for a


waste having the following chemical formula. Assume that the
waste is 79.5% organic and 50% of the organic mass is
biodegradable.

 MSW Chemical Composition 𝐶60 𝐻94 𝑂38 𝑁1


LECTURE 7: LANDFILL GAS AND OPERATIONS

Problem Set: Gas Potential

1. Normalize mole H, O and N to C

𝐶60𝐻94𝑂38𝑁 → 𝐶𝐻1.56𝑂0.633𝑁0.0167
2. Each mole of degradable MSW produces:

1 1
4 + 𝑎 − 2𝑏 − 3𝑐 𝐶𝐻4 = 4 + 1.56 − 2(0.63) − 3(0.0166 𝐶𝐻4 = 0.53
8 8
3. 1 ton =1000 kg
Assume MSW is 79.5% organic, 50% of which degrades:

1 𝑘𝑔 𝑀𝑆𝑊 0.795 𝑘𝑔 𝑜𝑟𝑔𝑎𝑛𝑖𝑐 0.5 𝑘𝑔 𝑑𝑒𝑔𝑟𝑎𝑑𝑎𝑏𝑙𝑒 𝑘𝑔 𝑑𝑒𝑔𝑟𝑎𝑑𝑎𝑏𝑙𝑒


1000𝑥 𝑥 = 397.5
1 𝑡𝑜𝑛 𝑀𝑆𝑊 𝑘𝑔 𝑀𝑆𝑊 𝑘𝑔 𝑜𝑟𝑔𝑎𝑛𝑖𝑐 𝑡𝑜𝑛 𝑀𝑆𝑊
LECTURE 7: LANDFILL GAS AND OPERATIONS

Problem Set: Gas Potential


𝑔
4. MW of MSW = 23.9
𝑚𝑜𝑙𝑒
𝑔
387,500
𝑡𝑜𝑛 = 16,631 𝑚𝑜𝑙𝑒 𝑀𝑆𝑊
𝑔 𝑡𝑜𝑛 𝑀𝑆𝑊
23.9
𝑚𝑜𝑙𝑒
𝑚𝑜𝑙𝑒 𝑀𝑆𝑊 𝑚𝑜𝑙𝑒 𝐶𝐻4 𝑚𝑜𝑙𝑒 𝐶𝐻4
5. 16,631 𝑥 0.531 = 8,831
𝑡𝑜𝑛 𝑀𝑆𝑊 𝑚𝑜𝑙𝑒 𝑀𝑆𝑊 𝑡𝑜𝑛 𝑀𝑆𝑊

𝐿
6. At STP, 22.4
𝑚𝑜𝑙𝑒 𝑔𝑎𝑠

𝐿 𝑚𝑜𝑙𝑒 𝐶𝐻4 𝒎𝟑
22.4 𝑥 8,831 = 𝟏𝟗𝟕, 𝟗𝟏𝟓 𝑳 𝒐𝒓 𝟏𝟗𝟖
𝑚𝑜𝑙𝑒 𝑔𝑎𝑠 𝑡𝑜𝑛 𝑀𝑆𝑊 𝒕𝒐𝒏 𝑴𝑺𝑾
LECTURE 7: LANDFILL GAS AND OPERATIONS

Landfill Operation
LECTURE 7: LANDFILL GAS AND OPERATIONS

Learning Objectives

1. Explain the importance of proper filling sequences and cover


application
2.Identify alternative cover materials for landfills
3.Describe the use of daily cover, intermediate cover and final cover
4.Identify practices for vector control in landfill operations
5.Identify the advantages and disadvantages of biological control
6.Give example of biological control applicable to landfill operations
7.Discuss the dangers posed by landfill gas.
8.Identify the potentially harmful landfill gasses
LECTURE 7: LANDFILL GAS AND OPERATIONS

Filling Sequences

 After weighing waste is brought to working face of the


landfill

 Waste is deposited in a cell and covered with soil or


similar material (e.g. compost and shredded tires)

 Filling sequence is established at the time of landfill


design and permitting
LECTURE 7: LANDFILL GAS AND OPERATIONS

Compaction and Covering

 It is the cornerstones of a sanitary landfill operations, and


assist in reducing short-term environmental and social
impacts of the landfill sites
LECTURE 7: LANDFILL GAS AND OPERATIONS

Benefits of Compaction

1. Windblown litter is reduced, as loose materials are contained


2. Access to the waste by vermin, flies and birds is reduced if
the waste body is sufficiently dense
3. Increased in air space
4. A compact waste body encourages runoff rather than the
infiltration of incident rainwater, minimizing leachate generation
5. Spontaneous combustion is minimized, through reduction in
available oxygen
6. The waste body is trafficable by waste transport vehicles and
site plant.
LECTURE 7: LANDFILL GAS AND OPERATIONS

Advantages of covering the waste body at the end of each day

1. Windblown litter is reduced, as loose materials are covered.

2. Access to the waste by vermin, flies and birds is minimized.

3. A surface is provided for on-site traffic.

4. Compacted cover material encourages runoff rather than the


infiltration of incident rainwater, minimizing leachate generation.

5. The spread of site fires can be minimized, if any, as the waste


body is not continuous.
LECTURE 7: LANDFILL GAS AND OPERATIONS

Landfilling Techniques/Method

1. Face Tipping Method


 In this method the wastes are tipped out and then
compacted into a bench

2. Onion skin method


 Has similarities to face tipping, but with toe of the face
extending at a much shallower gradient
LECTURE 7: LANDFILL GAS AND OPERATIONS

Cover materials

 “Traditional” Cover

 Are typically composed of subsoils and other excavation


wastes or construction industry wastes such as bricks and
crushed broken concrete
LECTURE 7: LANDFILL GAS AND OPERATIONS

Cover materials

 Alternatives to “Traditional” Cover Materials

 Heavy duty, reusable plastic sheets


 Non-reusable plastic films
 Geotextiles
 Fiber matting
 Foams
 Shredded wood/green waste
 Composted waste
LECTURE 7: LANDFILL GAS AND OPERATIONS

Cover materials

 Alternatives to “Traditional” Cover Materials

 Fly ash and bottom ash from utilities and municipal waste
incinerators
 Sewage sludge
 Foundry sands
 Yard waste (lawn clippings, leaves and tree branches)
 Construction and demolition debris
 Shredded automobile tires
 Slurry products
LECTURE 7: LANDFILL GAS AND OPERATIONS

Cover materials

1. Daily Cover

 Serves as an essential function on all landfills accepting


municipal and other biodegradable wastes.

 Improves the appearance of working areas and decreases the


possibility of windblown debris

 It also reduces the access to the waste by birds, insects and


vermin and diminishes odors and fire rick
LECTURE 7: LANDFILL GAS AND OPERATIONS

Cover materials

2. Intermediate Cover

 Used when filled surfaces are likely to be left for a period of


weeks or months before additional lifts to waste are to be
added

 Reduces rainfall infiltration while binds the deposited wastes


down and hence reduces litter.
LECTURE 7: LANDFILL GAS AND OPERATIONS

Cover materials

3. Pre-Final Cover (Temporary Capping)

 Low permeability materials over the filled area

 To avoid long term effects of settlement due to decomposition


of a proportion of the landfilled materials into landfill gas and
leachate
LECTURE 7: LANDFILL GAS AND OPERATIONS

Cover materials

4. Final Cover (Final Capping)

 Final landform until significant settlement has ceased

 It should not have slopes to cause heavy and rapid run-off that
may cause erosion and affects the integrity of the covering in
the long run.
LECTURE 7: LANDFILL GAS AND OPERATIONS

Disease Vector Control


1. Reducing the area of the working face

2. Increasing the thickness of the daily cover

3. Changing cover type, i.e. the material less permeable to air and
water

4. Application of repellants, insecticides, and rodenticides

5.Composting of organic wastes prior to disposal

6.Use of predators for control of insects, birds, and animal populations


LECTURE 7: LANDFILL GAS AND OPERATIONS

Disease Vector Control


7. Frequently placing an adequate quantity of compacted soil over
the wastes or by chemical means

8. Maintaining the smallest possible working face

9. Prevent the accumulation of stagnant water on the site

10. Properly grading the surface, by filling depressions and


placing cover soils over waste materials

11. Regular inspection of burrows, droppings and other signs of


the presence of rats, mice and birds
LECTURE 7: LANDFILL GAS AND OPERATIONS

Biological Control of Pests


1. Parasitoids such as wasp and parasitic chalcid provide
continuous controls the population of house flies and blown
flies

2. Flies does not developed resistance unlike in chemical

3. Cost of biological were fraction of what they would have been


for chemical control

4. Reduced used pf insecticides allowed populations of naturally


occurring parasites and predators to build up
LECTURE 7: LANDFILL GAS AND OPERATIONS

Control of Explosive Gases


1. Contributes to local smog

2. Cause unpleasant odors

3. Will trigger complaints to neighbors

4. Methane is highly combustible

5. Accumulation of methane may results in fire and explosions

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