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Improving Corrosion Inhibition
Improving Corrosion Inhibition
Improving
corrosion inhibition
Eric N. Freeman, P.E.,
T.D. Williamson, Inc.,
Tulsa, Oklahoma
Recently developed “spray pig” helps offshore operators gauge the success of their
corrosion inhibitor applications.
T
op-of-line corrosion (TLC) is an through the vertical drop that results when J. Waterhouse. This system has been co-
inherent problem in high carbon sending batch treatment from a platform developed with Pruett by TDW engineers
dioxide, wet and multiphase gas down into a subsea line. Tyler Lloyd and Robert Strong. As embod-
gathering or gas transmission pipelines due In response to both the TLC phenome- ied by TDW’s V-Jet Corrosion Inhibitor Pig
to the difficulties of adequately delivering non and the realization that batch treat- and the recent Semi-Smart V-Jet (with data-
corrosion inhibitors to the uppermost area ment is not always effective in combating logger) version, spray pig technology relies
of the inner pipe wall. Subsea pipelines can corrosion, many pipeline operators have on a series of nozzles mounted on the front
be especially susceptible to TLC and thus sought out other chemical treatment of a pig to disperse chemical inhibitor
are at high risk for premature failure if cor- options, such as the patented V-Jet “spray (introduced into the line in conjunction
rosion develops; offshore lines in Southeast pig” technology developed by Rick D. with the pig) onto the “hard to reach”
Asia have, in some instances, suffered from Pruett and others of T.D. Williamson, Inc. upper regions of the inner pipe wall.
serious TLC-induced degradation. Millions (TDW), with assistance and support from
of dollars have already gone into repairing Yves Gunaltun and his former team at Total Spray pig primer
or even replacing subsea lines compro- (France). Ongoing developments of this Though the use of spray nozzles to dis-
mised by corrosion. Regardless of the line tool have included incorporation of a data- perse inhibitor upward is innovative, part
location, unchecked corrosion can easily logging system, the brainchild of Pruett’s of what makes the V-Jet pig attractive is its
cause large-scale production losses. Should initiated at the request of consultant Robert basis in two simple, standard pigging con-
through-wall failure occur, environmental
damage could be severe.
Until recently, the standard response to
the threat of line corrosion was batch treat-
ment using a solid chemical slug or col-
umn held between two batching pigs. The
goal was to keep the chemical intact and
contacting all surfaces of the inner pipe –
including the upper wall – long enough to
deposit a corrosion-deterring protective
film. In many cases, batch treatment can
still be a viable option. However, when you
factor in manpower and equipment
requirements, chemical expense and pro-
duction loss, batch treatment is not cheap.
Even more worrisome for some operators
is the fact that inline inspections have
shown that, in many instances, batch treat-
ment is not effective in offshore lines. One
reason for this is that it is very difficult to
maintain the integrity of a chemical slug T.D. Williamson’s Semi-Smart V-Jet Pig just prior to an offshore run in Southeast Asia.
Data acquisition
To eliminate this gap and provide more
immediate feedback on the performance of
a spray pig in any given application, engi-
neers at TDW have developed a “Semi-
Smart V-Jet Pig,” so named for its incorpo-
ration of some, but not all, existing inline
inspection technologies into the body of
the pig itself as an on-board datalogger. It
is, essentially, a spray pig with a brain.
when using the spray pig as a batching pig run(s). To gauge effectiveness, it is neces- Capable of operating under normal spray
in front, especially, it is not necessary to sary to know if inhibitor fluid is being suc- pig conditions, this pig is equipped to col-
have a solid slug of inhibitor fluid between cessfully delivered to the desired pipe sur- lect a variety of information during every
the pigs. Rather, a “bow-wave” effect will face and at the desired film thickness. run. This includes data on differential pres-
tend to keep the fluid level well above the Further, there is a need to verify that this sure, which is helpful because, as previ-
suction ports at the bottom of the spray delivery is happening at the right frequency ously noted, Delta P is of key importance
head since gas flow rate (and thus, pig to maintain the chemical film intended to to achieving proper jetting action. The
speed) is generally faster than the liquid inhibit corrosion and thus preserve the semi-smart spray pig gauges pressure at
flow rate. pipe wall’s integrity. both the front and back of the pig.
Attempts to gauge effectiveness are hin- In order to be effective, a spray pig
Quality control dered by a number of variables at play in must deliver inhibitor to the top of the
In order for a spray pig run to be truly any inhibitor application program, includ- pipe. To verify that this is indeed happen-
successful, several conditions must be ing chemical performance, changes in ing, the semi-smart design also monitors
met. First and foremost, the pipeline must fluid composition and changes in operat- rotation/orientation of the pig. The data
be piggable, meaning valves are open, ing conditions (such as temperature, pres- acquired by the device offers a complete
obstructions are removed, and bend radii sure and flow rate). All of these variables three-dimensional profile of how the pig
are adequate (at least three times the pipe need to be considered when planning a moved throughout the run, including tool
diameter in most cases). Assuming these spray pig regimen and when attempting to rotation, spray nozzle orientation and port
perquisites are met, the line should also gauge a regimen’s success. For onshore orientation. Should an improper orienta-
be clean, both to prevent debris from pipelines, use of top-line corrosion tion occur, the pig’s sensors can tell
building up in front of the pig and dis- coupons and frequent, regular monitoring whether this was temporary or perma-
rupting nozzle operation and to make (perhaps monthly) is a good way to vali- nent, and where it took place in the
sure that the inhibitor fluid is actually date success. Due to the lack of access to pipeline (for example, relative to known
contacting the pipe wall (rather than sim- offshore pipelines, the best method for corrosion areas).
ply coating scale, black powder or other gauging inhibitor application effectiveness To be optimally effective, a spray pig
compounds attached to the wall). Paraffin has been through the use of inline inspec- should stay within speed limits that allow
buildup, for example, can affect a tool’s tion (ILI) tools. Though they are capable of for proper contact time between the
orientation, the amount of inhibitor-to- mapping the total length of a line and pro- inhibitor and the pipe wall. The semi-smart
wall contact, pig speed and jetting action. viding detailed information on wall defects, design includes an odometer to generate a
Finally, a corrosion inhibitor compatible these tools are costly and, therefore, infre- speed profile on the run, as well as accu-
with product and other constituents in quently run (typically bi-annually). This rate location of events recorded during the
the pipeline must be utilized. inherent time gap between when a chemi- run. It may be possible to calculate the
Assuming an adequately prepared cal treatment plan is undertaken and when minimum inhibitor contact time for spe-
pipeline and proper inhibitor and spray pig the inspection tools can map changes cre- cific pipe segments within the run and
usage, the challenge then becomes how ates a potential delay in detecting problems cross-check this with vendor suggestions.
best to gauge the effectiveness of the in inhibitor application. Contact time is generally longer than what
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