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MO e Notes
MO e Notes
MODULE 1
PARTICLE TECHNOLOGY
INTRODUCTION: A liquid does not have a definite shape; it takes the shape of its
container. whereas every solid particle has a specific shape of its own. Thus, whenever we
handle any system involving solid particles, which we encounter quite often in chemical
process industries, for defining the system, first we have to specify the size and shape of the
particle involved and if mixture is present, then side distribution, this task however is not an
easy one. Solids in general are more difficult to handle than liquid and gases. In processing
solid appear in variety of forms- angular pieces, continuous sheets, finely divided powder
etc. They may be hard or abrasive, tough and rubbery, soft or fragile, dusty, cohesive, free
flowing or sticky. Whatever forms they are found to occur, has to be manipulated and if
possible their handling characteristics.
Solid particles are characterized by their size, shape and density. For regular particles like
sphere, cube the size and shape are easily specified, but for irregular particles the term size
and shape are to be defined. The particle Technology deals with the properties, characteristics
behaviour and application of particles.
Particle Size and Shape: If a particle confirms to the standard configuration which we are
familiar with such as spherical, cubicle, cylindrical etc then its size can be easily specified.
For example, the size of a spherical particle is nothing but its diameter, and a cubicle particle,
the length of its sides. However, many of the particles commonly encountered in industries
do not confirm to any of these standard configurations. We can call them in general irregular
particles, the question arises to define the shape and size of irregular particles.
During early stage of development of particle technology, number authors proposed empirical
definition particle size, for example Martin (1931) define the size of an irregular particle as
the length of the line bisecting the maximum cross section area of the particle. Similarly
Feret(1929) define particle size as a distance between the two most extreme points on the
particle surface. The limitation of such definitions obvious, for instance, if the distance
between farthest edge on the particle surface remains the same but rest of its configuration
changes, then its feret's diameter shall remain unaltered. obviously, such definition cannot
describe the actual size or shape of an irregular particle.
It was in the later year, the latest system of defining particle size by comparing with standard
configuration (normally comparing with spherical particle) got developed. Thus, we will
utilize what is called "equivalent size are equivalent diameter" of an irregular particle, which
can be broadly defined as the size of a spherical particle having the same controlling
characteristics as the particle under consideration. Naturally to apply this definition, we must
first specify what is this" controlling characteristics". This depends on the system and the
process in which the particles is involved, for example a catalyst particle, the surface area is
the most controlling parameter, therefore for defining the size of a catalyst particle, we can
use the surface diameter (ds) which will be thus be defined as the diameter of a spherical
particle having the same surface area as the particle under consideration. If Sp is the surface
area of the particle then Sp=π ds 3
Sp
or ds=
√ π
For the gravitational free settling velocity of a particle in a liquid is very much controlled by
the mass of the particle( or for a given density, is volume), we can therefore define the
particle size of such a case by the volume diameter (dv) which is once again defined as the
diameter of a spherical particle having the same volume as a particle under consideration.
1
π 3 6 Vp
Thus, if Vp is the volume of a particle then Vp= dv
6
or dv = ( )
π
3
The dynamics of a gas bubble in a liquid or that of liquid drops in a liquid or gas depends not
only on the bubble or drop volume but also on the inter-facial tension at the gas liquid or
liquid interface. Thus both the volume as well as the surface area of the bubble or drops are
controlling parameters, hence, in such a case the bubble size or drop size is defined using
the volume- surface diameter or more commonly called Sauter diameter (dvs).This is
accordingly defined as the diameter of a spherical particle having the same specific
surface( surface area per unit volume) the particle( bubble or drop) under consideration.
πd vs 2 6 6
Specific Surface = Sp= π = or dvs= where Sp is specific surface
d vs 3 dvs Sp
6
of particle.
once the controlling characteristics is specified, we can define the size of any irregular particle
using the above methodology. another popularly employed definition of a particle size is the
screen size or screen average size (davg), this in fact is the aperture size office standard screen to
which the particle just passes or more correctly The arithmetic average of the aperture size of two
successive standard screens, one of which lets the particle pass through where as other retains it
dn+dn+1
davg=
2
Once we have defined the particle size, now let us see how the particle shape can be defined.
again, the exact shape of a irregular particle is difficult to specify. one of the methods of
defining particle shape is by using the term" Sphericity"(ɸ). it is defined as" the ratio of
surface area of a spherical particle having the same volume at the particle to the surface area
of the particle". since the diameter of a spherical particle having the same volume as the
particle is dv. ɸ is independent of particle size.
π dv 2
ɸ= area of sphere having the same volume of particle / area of particle =
Sp
let Ss-surface area of sphere (having equal volume of particle), Vp-volume of particle
or(volume of sphere) Dp-dia of particle
Ss π Dp2 6
= = 6 Vp
consider Vp π Dp 3
Dp therefore Ss=
Dp
6
Ss 6 Vp 6 Vp
ɸ= = =
But Vp Dp SpDp
Sp
It must be noted that since sphericity compare the surface area of the particle to that of the
equivalent spherical particle, it defines only the particle shape and is independent of particle
size. Sphericity of a spherical particle is obviously 1.0. The sphericity office cubicle particle
of side' a' can be determined as follows.
volume of a cube is equal to a x a x a=a3=Vp
from above equation volume diameter of a cubical particle
6 Vp 13 6 a 13
dv = ( ) ( )
π
=
π
=1.24 a
Every mineral has a given Crystallographic structure, thus a given shape or configuration and
therefore specific sphericity.
the reciprocal of sphericity is commonly called shape factor or more precisely called
1
surface shape factor thus λs=
ɸ
Another shape factor, designated as volume shape factor (λv) is sometimes used for
calculating the volume of an irregular particle. we know that the volume of a spherical
particle is proportional to the cube of its diameter. If we assume same is true for irregular
particle as well then Vp α d 3avg or Vp= λv d 3avg where λv is the propensity constant is called
π
“volume shape factor”. Its value is for spherical particle. However, in strict sense λv is not
6
constant (though designate as shape factor) but is a function of the particle size. for a number of
cases is variation with particle size is not very large average value of λv could be used for
number of process calculation.
Particle Size: Diameter is specified for any equidimensional particle, particles that are not
equidimensional ie. that are long in one direction than in other are often characterized by" second
largest major dimension". for n if needle like particle the diameter refers to the thickness of
particle not the length. Expression of particle size
Particle units
Course Inch,mm, mesh
Fine Screen size(aperture size)
Very fine Micrometer,nanometer
Ultra fine Surface area/unit mass
Mixture of particles: In earlier discussion, we have considered the case of a single particle
only. however, in actual industrial practice we normally come across mixture of particles of
different sizes, in such a case, the mixture can be separated into number of fractions, each
fraction consisting of particles of given size.
in a sample of uniform particle of dia. 'Dp', the total volume of the particle is m/(ρ p), where
m is the mass of a sample and (ρ p) is the density of the particle. Since the volume of one
particle is(Vp) the total number of particle in a sample is N.
m
There fore N= . If Sp is the surface area of one particle then the total surface area of
ρ p Dp
6 Vp 6 Vp
the mixture is =NSp, we know that ɸ= or Sp=
SpDp ɸ Dp
m 6Vp 6m
Surface area = NSp = A = =
ρ p Dp ɸ Dp ɸ DpSp
To apply above equation to mixture of particles having various size and dimensions, the
mixture is sorted into fractions, each of constant density and approximately constant size.
Each fraction is then weighed , individual particle in it can be content or measured by
microscopic method. The above equation can be applied to each fraction and then result is
added.
Specific surface area of a mixture: If particle density( ρp) and its sphericity ɸ are known,
the surface area of a particle in each fraction can calculated by using the above equation
6m m
Surface area A = If M is the total mass then =x is the weight
ɸ DpSp M
6 xi
fraction of that individual fraction then A = where Dpi is the average dia. Of
ɸρ pDpi
particle of ith fraction and the result of all fractions are added to give total surface area “Aw”
if ɸ and ρ premains constant then
6 xa 6 xb −∓6 xn
Aw= + +…−
ɸρ pDpa ɸρ pDpb ɸρ pDpn
n
6 xi
Therefore Aw= ∑ by differentia analysis
ɸρ p i=1 Dpi
where i - is individual increments
xi-mass fraction in a given increment
n -number of increments
Dpi-Average particle size (dia.)(Arithmetic average of smallest and largest particle dia.in an
increment)
1
6 xi
Similarly Aw= ∫ by cumulative analysis
ɸρ p 0 Dpi
The integration may be conducted by graphical method. The area per unit mass of sample
then Aw is called specific surface area.
Average particle size: The average particle size for a mixture of particles may be defined in
several ways. One average is the volume-surface mean diameter Ds is related to specific
surface Aw, and defined by the equation
6
Ds= this is called Sauter diameter dvs
ɸ ρ p Aw
n
6 xi
We know that Aw= ∑ substituting in above equation for Aw we get
ɸρ p i=1 Dpi
6 1
Ds= n n
6 xi =
ɸρp ∑ ∑ xi
ɸρ p i=1 Dpi i=1 Dpi
1
n
Volume surface mean diameter = Ds = xi
∑ Dpi
i=1
If number of particles in each fractions Ni are known instead of mass fraction Ds is given by
∑ ¿ Dpi3
the equation Ds= i=1
n
∑ ¿ Dpi2
i=1
Other
averages are some times useful. Arithmetic mean diameter Dn is used and given by
n n
∑ ¿ Dpi❑ ∑ ¿ Dpi❑
Dn= i=1 n
= i =1 Where NT is the number of particles in the entire sample.
NT
∑¿
i=1
n
The mass mean “Dw” is calculated by the equationDw=∑ xi Dpi and
i=1
1
1
[ ]
3
Dv= n
The Volume mean is found by the equation xi
∑ Dpi 3
i=1
For the samples consisting of uniform particle the average diameter will be same for all. For
the mixture containing particles of various sizes, therefore average diameter may differ
widely from one another. Length mean diameter is another type of expressing the mean
diameter of the entire mixture. "Length mean diameter " DL
n
∑ ¿ Dpi2
DL= i=1
n
∑ ¿ Dpi❑
i=1
Number of particles in a mixture: To calculate from the differential analysis, the number of
m
particles in a mixture N= is used to calculate the number of particles in each fraction
ρ p Vp
and Nw the total population in one Mass unit of a sample is obtained by summation over
all fraction. For a given particle shape, the volume of any particle is proportional to its
diameter cube Vp= λv D 3p where λv is a shape factor and assuming λvis independent of size
m xa xb −∓xn
and using N= we get Nw= + + …−
ρ p Vp λv ρ pDpa λv ρ pDpb λv ρ pDpn
n
1 xi 1
Nw= ∑ =
λv ρ p i=1 Dpi λv ρ p Dv3
3
Determination of particle size: The size of a particle or the size distribution of a mixture of
particles can be determined using a number of methods, such as screening( best applicable
for particle size above 40 microns), gravity sedimentation( for size 1- 100 microns),
centrifugal sedimentation( for size 0.005- 3 microns), elutration under Gravity ( for sizes 5-
100 Micron), under centrifugal field of sophisticated technique such as ultra-
microscopy( for size 0.005- 0.2 microns), electron microscopy (for sizes 0.005- 5 microns),
light scattering microscope(for size 0.1- 10 Micron) and x ray scattering microscope(for
sizes 0.005 - 0.05 Micron) are used when high Precision is required in the particle size
distribution. We shall confine our discussion to screening which is one of the cheapest and
easiest method of particle size analysis.
The importance of particle size analysis in industrial practice need not have to be
overemphasized. particles must be separated according to their size before using them for any
industrial operation since the process efficiency vary much depend on particle size employed.
For example, the effectiveness of a catalyst particle which dependent on their surface area
which in turn depends on their size. The hiding power of a paint pigment controlled by the
projected area of the pigment particles which again is the function of their size. The setting
rate of Portland cement and the final strength of the concrete depends substantially on the
uniform size of cement dust and the size of sand and gravel used to prepare the concrete mix.
In the combustion of solid fuel like coal, uniformity of fuel bed is very critical parameter.
Even in practice like carbonization it is absolutely necessary that and gasification it is
absolutely necessary that coal bed is composed of particles of uniform size to ascertain
satisfactory yield of quantity of products. so, screening offers to be one of the easiest and
most rapid method of particle size analysis and separation.
SCREENING:
(i) A method of separating solid particles according to size alone is called screening.
(ii) Screening is an operation for separating solids on the basis of size alone.
(iii) It refers to the separation of solid materials on the basis of size using screens of
known
openings.
(iv) Screening is the separation of a mixture of solid particles of various sizes into two or
more fractions by means of a screening surface.
In screening, a mixture of solid particles of various sizes is dropped on a screening
surface/screen (a surface provided with suitable openings) which acts as a multiple go and
no-go gage. The material that passes through a given screen/screening surface is called the
undersize or minus (-) material while the material that remains on the screen/screening
surface is called the oversize or plus ( +) material.
A single screen can make a single separation of the material charged into two fractions. These
are called unsized fractions as only the upper or lower limit of the particle sizes they contain
is known and the other limit is not known. The material can be separated into sized fractions
i.e. the fractions in which both the maximum and minimum particle sizes are known, by
passing it through a series of screens of different sizes. Screening is much more commonly
adopted for dry particulate solids and occasionally for wet particulate solids.
Materials for Screens: Industrial screens are made from metal bars, woven wire cloth, silk
bolting cloth, perforated or slotted metal plates. Many varieties and types of screens are
available for different purposes but we will discuss few representative types.
Necessity of or reasons for carrying out screening operation/importance of screening
operation: The screening operation is industrially carried out in order to
(i) remove the fines from a feed material before a reduction equipment such as jaw
crusher,
ball mill or rod mill,
(ii) prevent an incompletely crushed material (oversize) from entering into another unit
operations,
(iii) produce a commercial or process-grade material to meet specific particle size limits,
(iv) remove the fines from a finished product prior to shipping.
Comparison of Ideal and Actual screens: The objective of a screen is to accept a mixture of
various sizes of grains and separate it into two fractions, namely an underflow and overflow.
The underflow is the one that is passed through the screen and the overflow is the one that is
rejected by the screen.
An ideal screen is the one which sharply separates the feed mixture in such a way that the
smallest particle in the overflow is just larger than the largest particle in the underflow. The
ideal separation defines a cut diameter Dpc (a typical particle dimension) which makes the
point of separation between the undersize and oversize fractions and is nearly equal to the
mesh opening of the screen.
Fig. 1 (a) shows the performance of an ideal screen in terms of the screen analysis of the feed.
The point 'C' in the curve is a cut point. The fraction A consists of all particles larger than cut
diameter (Dpc) while the fraction B consists of all particles smaller than cut diameter.
Working: The material to be screened is fed at the upper end and gradually moves down the
screening surface towards the lower end. In doing so, the material passes over the apertures of
gradually increasing size (as the single cylinder is provided with · perforations ranging from
the finest desired at the feed end to the coarsest at the discharge end).
If the single cylinder is provided with the screen having three different size perforations then
we get four fractions. The finest material is collected as the underflow in the compartment
near the feed end and the oversize material (coarsest) is withdrawn from the discharge end.
Such type of arrangement is usually used for smaller capacities. With this type of trornrnel,
there is a tendency of blockage of the apertures by the large material and the screen with the
finest opening being the weakest it is subjected to the largest wear.
The operating speed of a trommel is 30 to 50% of the critical speed (the critical speed is the
one at which the material is carried completely round in contact with the screening surface).
Various trommel arrangements: For separation of a given material into several size
fractions, several trommels are operated in series. The first trommel of a series may have the
coarsest perforations so that it produces the coarsest finished product which is delivered to the
next trommel and so on. In such a case, it is most convenient to place the trommels one above
the other as shown in Fig.(a).
When the first trommel of the series has the smallest perforations, the oversize material passes
to the next trommel and so on. In such a case, it is most convenient to put the screens in line,
end to end as shown in Fig.(b)
If the screening equipment of this type is put into service for finer separations then the
cylinder may be covered with a fine wire or silk cloth instead of a perforated plate or coarse
wire screen. Such an equipment is usually called a reel.
Fig. (d) shows several concentric cylinders. The innermost is the longest and has coarsest
perforations. The outer ones are successively shorter and have finer perforations.In this
arrangement, maximum load is given to the strongest screen but the construction is
complicated and expensive.