Example 9.

3
k(1)t/Xae = -ln(1-Xa/Xae)
k(1) =Xae -ln(1-Xa/Xae)/t
Xa 0.581
T(c) 65
t(min) 1
R 8.314
at 65 338 at 25
Xae 0.89
now now
(𝑘1(338))/(𝑘1(298)
k1(338)
)=
0.941513365387312
(𝐾10𝑒^(−𝐸1/𝑅(338)))/(𝐾10𝑒^(−𝐸1/𝑅(298)) )
now

(𝑘1(338))/𝑘1(298) =
𝑒^(−𝐸1/𝑅(338))/𝑒^(−𝐸1/𝑅(2
98))
(𝑘1(338))/(𝑘1(298))= 𝑒^(−𝐸1/𝑅(338) +□(64&𝐸1/(𝑅(298))))

after taking log

1/R(338)
2.3252298547 E1(-1/R338+1/R298) 1/R(298)
(-1/R(338)+1/R(298)
now 〖𝐾 1(338)=𝐾(10)𝑒 〗 ^(−𝐸1/𝑅(338))
E1 48679.8110240744
now as (𝐾1(338))/(𝐾(10)) 〖 =
𝑒 〗 ^(−𝐸1/𝑅(338))

taking log
similarly
lnK1(338) - lnk(10) = -E1/R(338) lnK1(298) - lnK(10) = E1/R(298)

lnK1(338) + E1/R(338) = lnk(10) lnK1(298) + E1/R(298) = lnK(10)

 lnk(10) 17.2626956823088
K(10) 31411847.3013586

now

k1 = K(10)exp(-E1/RT) now from rate equation

x(a) = k1Ca0 + r/k1+k2(ca0)

k1 = exp(17.34 - E1/RT)
also x(a) = k1+r/k1+k2
K=k1/k2
now
K = exp(75300/RT - 24.7)
and
K2 = exp(17.34 - E1/RT)/exp(75300/RT - 24.7)

k2 = exp(42.04 - 124200/RT)
 r T© T(K) k1 k2 x(a)
13 10 283 0.0350978329123 0.0000215 371.16571737
13 20 293 0.0711129617549 0.000130364027 183.47140337
Xa 0.6 13 30 303 0.1375229210955 0.000701352031 95.044977441
T(c) 25 13 40 313 0.254976061747 0.003388591776 51.303364764
t(min) 10 13 50 323 0.4550106943046 0.014850612072 28.636132645
13 60 333 0.7842190020793 0.059556258545 16.336363064
298 13 70 343 1.309386753605 0.220261927874 9.3546883849
Xae 0.993 13 80 353 2.1236595459293 0.756431282532 5.2511050681
13 90 363 3.3537498276076 2.427041538565 2.8289811536
13 100 373 5.1681595039092
x(a) 7.315383024031 1.4553688957
k1(298) 0.0920432605
400

350

300

250

200

150

100

50

0
0.0003558552 283 293 303 313 323 333 343 353 363 373

0.000403621
4.776579E-05

1(298) - lnK(10) = E1/R(298)

1(298) + E1/R(298) = lnK(10)

 lnk(10) 17.262695682
k(10) 3.14E+07

now from rate equation

x(a) = k1Ca0 + r/k1+k2(ca0)

x(a) = k1+r/k1+k2
353 363 373
 Example 9.2
K calculation
ΔG(298) -14130 C(R) = C(A) temperature(K)
ΔH(298) -75300 278
R 8.314 288
T 298 298
308
lnK(298) 5.7031642 318
K(298) 299.81458 328
338
K =K(298)exp(-ΔH(298)/RT--ΔH(298)/R/298) 368
K = exp(75300/RT - 24.7)

and
Xae = K/(K+1)
 1.2

1
K Xae
2641.708 0.999622
852.3176 0.998828 0.8
296.6813 0.996641
110.596 0.991039 0.6
43.86737 0.977712
18.40905
8.132711 0.948478
0.890503 0.4
0.915254 0.477876
0.2

0
278 288 298 308 318 328 338 3
328 338 368