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Indoor Light Harvesting Using Dye Sensitized Solar Cell: Abstract
Indoor Light Harvesting Using Dye Sensitized Solar Cell: Abstract
Abstract—Solar power has assumed a vital and established role perform in low lighting condition, and low cost fabrication
in the present day’s clean energy economy. Ever since silicon process.
solar cells developed, the prime focus has always been to harness Most of the energy harvesting systems developed is for
the outdoor sunlight. The indoor light, though of lesser intensity outdoor applications where the sunlight is plenty. Intelligent
than its outdoor counterpart, has the potential to power on WSN systems need to operate reliably for several years
devices such as wireless sensor nodes (WSN) that work in the low without the need for battery replacement, because frequent
power range. Harnessing electrical power from indoor lighting battery replacement many be infeasible and expensive. In
environment with very low luminance level is relatively anew and
relatively weaker light conditions, conventional light
challenging concept. The limitation of the existing silicon solar
harvesting systems that are designed for strong light irradiance
cells to perform efficiently under the indoor lighting condition
restricts its deployment. The Dye Sensitized Solar Cell (DSSC), show very low efficiency.
also known as the next generation solar cell, with its better The concept of harnessing energy from dual indoor energy
conversion efficiency can work effectively in low lighting sources, i.e., thermal energy from machine heat and ambient
conditions such as cloudy skies and indirect sunlight. In addition, light from artificial lighting is proposed in [1]. A low input
it has the capability to absorb light from various light sources voltage power management circuit system, using an
that are usually used to illuminate indoor rooms. The WSN amorphous silicon photovoltaic cell as an energy harvester,
systems are conventionally battery powered. The power storage driving a wireless sensor load is explained in [2]. A detailed
capabilities of DSSCs could eliminate the additional need for a comparison and experimental study of six distinct solar cell
battery and thus reduces the number of batteries deposited into technologies for ambient light energy harvesting under a
environment.The paper intends to carry out an experimental regulated light intensity of 330lux which is in tune with
study on DSSC and its potential application as an energy normal office illumination is stated in [3]. The characteristics
harvester. and properties of mono and polycrystalline silicon, amorphous
Keyword- Dye sensitized solar cell, indoor light, WSN
silicon (a-Si), DSSC, Gallium Arsenide (GaAs), pervoskite
I. INTRODUCTION solar cells are summarized in Table III of [3]. Both GaAs and
DSSC exhibit an efficiency of about 28% whereas a-Si and
Conventional silicon cells demand extremely-high purity
pervoskite cells have efficiencies around 15.59% and 20.4%,
silicon (the purity is usually of the level 99.999%) and the
respectively. The results obtained show that gallium arsenide
cells are typically made via energy-exhaustive crystal growth
GaAs and DSSCs exhibit similar performances in indoor
and vapor deposition methods. A large quantity of light
condition. An experimental investigation in [4] on III-V solar
absorbing material is used in silicon solar cell fabrication and
cells, i.e., GaAs and Gallium Indium Phosphide (GaInP)
this adds to the cost of production. Silicon solar cells are
material, revealed their capability to perform better than
outperformed by dye-sensitized solar cells (DSSC) which have
amorphous silicon (a-Si) and DSSC under low-level
wider acceptance angles and better absorption capacity for
illumination. However, taking into consideration the material
diffused sunlight and fluorescent light. In a sharp contrast to
and manufacturing cost, DSSC is the ideal option for
the conventional systems where the semiconductor undertakes
powering an autonomous wireless sensor node. A
both the task of light absorption and charge carrier transport, a
methodology for a photovoltaic harvester with maximum
DSSC performs the two functions separately. Light is captured
power point tracking for self-powered WSN is described in
by a sensitizer, which is secured to the surface of a
[5]. It focuses on boosting the harvester’s efficiency in
semiconductor. The absorption capability of the cell can be
transmitting energy from the solar module to the energy
tuned to different wavelength ranges making it possible to
storing device. The model discussed in [5] foresees the
broaden the wavelengths of light it absorbs efficiently. The
instantaneous power collected by the panel thereby assisting in
charge separation occurs at the interface by means of a
the harvester design and optimization procedure. Compared to
photo induced electron infusion from the dye into the
the silicon counterpart, the DSSCs have better conversion
conduction band of the solid. DSSC has been gaining
efficiency in low light conditions. As explained in [6], it is due
considerable attention because of its simplicity, ability to
to the low charge transfer resistance under low irradiance
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2018 International CET Conference on Control, Communication, and Computing (IC4) | July 05 – 07, 2018 | Trivandrum
condition. The effect of DSSC configuration on useable output is in parallel with the rectifying diode. An inductive
power, provided through low-power step-up DC-DC recombination passage on account of charge-transfer current
converters, is outlined in [8]. A better utilization of physical is incorporated in the circuit, consisting of a recombination
area, as explained in [8], enhanced the converter’s power resistance (Rrec) in series with an inductor (L). The charge-
efficiency by more than 6%, allowing a broader range of transfer resistance and interfacial capacitance at the anode and
wireless sensors to be powered by DSSC and possibly electrolyte/cathode interface are characterized by Re and Ce,
increasing the performance of existing DSSC powered sensors and Rce and Cce, respectively. The Nernst diffusion associated
as well. with the carrier transport by ions within the electrolyte is
denoted by the Warburg impedance (W). The series resistance
II. ENERGY HARVESTING SYSTEM component, RS, represents the contact and bulk resistive losses
A. Solar Cell Structure prevalent in a DSSC, such as, the sheet resistance of the
filmed TCO glass.
The structure of a dye sensitized solar cell resembles a The current-voltage terminal equation with open-circuit
sandwich framework, which includes the photoanode, voltage and short-circuit current, under static condition; can be
electrolyte and cathode. The electrodes consist of two glass expressed below as (1):
plates which has a transparent conducting oxide (TCO) q V IZ q V IZ
coating. The anode is formed by a substrate of titanium I Iph Ii exp 1 Ir exp 1
nkbTc mkbTc
dioxide (TiO2) layer coated with a dye material. The second
conducting glass is usually deposited with platinum (Pt) (1)
coating and it acts as the counter electrode. The space between
both the electrodes is filled with the electrolyte. It must have Where,
the suitable electrochemical potential in order to integrate with Iph Isc Ki Tc Tref s (2)
the semiconductor and systematically provide the charge
mobility in a cyclic manner. Z (3)
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2018 International CET Conference on Control, Communication, and Computing (IC4) | July 05 – 07, 2018 | Trivandrum
V. EXPERIMENTAL STUDY
The fabrication of a DSSC was carried out by making use
of Fluorine-doped Tin Oxide (FTO) coated transparent
conducting glass by the dimension 25mmX25mmX2.2mm.
TiO2 paste is annealed on to the glass substrate in a tubular
furnace at a temperature of 450 for about 20 to 30 minutes.
The substrate is then allowed to cool down to the room
temperature. It is essential to sensitize the electrode by making
use of a dye which can absorb as much light energy as
possible in the visible light spectrum. Fruits are a source of
natural dyes and they are capable of absorbing visible light.
This property is due to the presence of anthocyanin, a (a) (b)
compound that is responsible for the red, violet and blue Fig.9.Measurements under halogen lighting: (a) Voltage reading (b)
colors found in many fruits, flowers and leaves. Pomegranate current reading
extract was used as the dye for the experiment. The stained
electrode, as shown in Fig.7 (a) is coated with electrolyte The electrical characteristics of the cell were recorded
obtained by mixing 0.01molar iodine in 0.1molar potassium upon excitation with three different light sources, maintaining
iodide solution. The counter electrode was prepared by a constant intensity and varying the distance of the light
scribbling with the graphite pencil on the glass plate. The source from the cell. The voltage characteristics, as seen in
electrodes are assembled together (Fig.7 (b)) and the cell is Fig.10, were observed under a 12W LED lamp (40-45 lumens)
tested. and mobile phone flashlight (60-80 lumens).
400
350
300
250
200
(a) (b) 150
Fig.7. (a) Pomegranate juice absorbed on TiO2 coated conducting 100
glass substrate (b) Fabricated DSSC
50
A. Testing of the DSSC
0
The cell is tested by connecting the voltmeter leads on to
the offset portion of the assembled cell. Fig.8. (a) and (b) 1 2 3 4 5 6 7 8 9 10 11 12 13
show that, when tested in an indoor environment, under Distance (cm)
diffused lighting condition, the cell yielded a voltage of about
100mV and under fluorescent lighting condition around halogen(mV) flashlight(mV) LED(mV)
290mV was observed.
Fig.10. Plot showing the variation of voltage with respect to distance
of light source from the cell when excited by three different light
sources.
(a) (b)
Fig.8. Voltmeter reading under (a) diffused sunlight (b) fluorescent
lighting
A voltage of 253mV and current in the order of microamperes
were obtained, as demonstrated in Fig.9. (a) and (b), upon
exciting the cell by a 12V, 35W halogen tungsten lamp (430
lumens output).
Fig.11. DSSCs in series
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