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Alderson Et Al. - 2012 - Auxetic Warp Knit Textile Structures
Alderson Et Al. - 2012 - Auxetic Warp Knit Textile Structures
solidi
physica
Phys. Status Solidi B 249, No. 7, 1322–1329 (2012) / DOI 10.1002/pssb.201084216
status
b
www.pss-b.com
basic solid state physics
Auxetic warp knit textile structures
Kim Alderson*, Andrew Alderson, Subhash Anand, Virginia Simkins, Shonali Nazare,
and Naveen Ravirala
Institute for Materials Research and Innovation, The University of Bolton, Deane Road, Bolton BL3 5AB, UK
* Corresponding author: e-mail ka1@bolton.ac.uk, Phone: þ44 (0)1204 903519, Fax: þ44 (0)1204 399074
The design, manufacturing and characterization of warp knit structure, which is known to lead to a negative Poisson’s ratio n.
textile structures with enhanced drapeability and energy Mechanical testing has confirmed that textile structures can be
absorption is reported in this paper. Four textile structures produced which are auxetic at 458 to the warp direction, with
were produced, all based on a triangular or double arrowhead n of up to 0.22 0.03.
1 Introduction Auxetic materials are those, which Auxetic polypropylene fibres have also been fabricated
have a negative Poisson’s ratio, n i.e., they expand in the lateral using a continuous partial melt spinning process [24]. The
direction when stretched longitudinally [1]. A very wide range auxetic effect here is thought to be due to a complex granular
of materials can be fabricated in auxetic form including microstructure [25] obtained by gluing together powder
polymeric and metallic foams [2–5], polymers [6–9], fibre particles i.e., by surface melting these only. The resulting
reinforced composite laminates [10–13] and honeycombs [14– structures cannot be drawn as is the usual practise to improve
17]. A further consequence of auxetic behaviour is that many mechanical properties, as this has been shown in the fibres to
mechanical properties are predicted to be enhanced such as low lead to a positive Poisson’s ratio [24]. Thus, as would be
velocity impact resistance [18], indentation [19] and shear expected, the auxetic fibres produced have modest mechan-
[20]. A new class of auxetic materials seeking to exploit these ical properties, with a tensile strength of 25 MPa and a
property enhancements is auxetic textile structures. Auxetic modulus of 1.3 GPa, which have hampered post processing.
textile structures should lead to a range of beneficial To improve the properties, the fibres were subjected to an
attributes including improved energy absorption, high annealing study [26] which not only resulted in them
volume change, wear resistance and drapeability. Potential retaining their auxeticity but also in a tensile strength at least
applications include filter fabrics, geotextiles, reinforce- 1.5 times higher than the unannealled fibres. This allowed the
ments in advanced composites for aerospace and automotive fibres to be knitted on a simple hand-knitting machine,
sectors and personal and sports protective garments such as producing a prototype fabric [27].
bulletproof vests and batting gloves [21, 22]. A different route to the production of auxetic fibres for
There are two potential approaches to producing auxetic use in textile structures is to engineer the fibres to be auxetic
textiles. The first is to knit or weave auxetic fibres into a at the molecular level [28, 29], which should produce fibres
fabric. Evans and Hook [23] produced a multifilament strong enough to post process without additional fibre
construction in which a high stiffness filament is wrapped treatments.
helically around a thicker, low stiffness filament, with The second approach to producing auxetic textiles is to
neither constituent needing to be auxetic. The overall use conventional fibres and to knit or weave these into a
construction shows auxetic behaviour upon stretching due structure, which is itself auxetic. Ugbolue et al. [30] have
to straightening of the high stiffness filament causing the reported an auxetic knit structure using polyester and Nomex
lower stiffness one to helically wrap round it. This can yarns. In their structure, the wales are knitted from open lap
be produced using existing textile machinery and examples loops using thicker lower stiffness filaments and a high
of the materials used include an aramid-nylon yarn. stiffness filament is inlaid around aramid loops as underlaps.
Applications being investigated for these multifilaments They report that their fillet warp knit fabrics are auxetic
include as protective blast curtains. especially at the first stage of stretching, with values of
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1324 K. Alderson et al.: Auxetic warp knit textile structures
Figure 4 (a) Stitch pattern used for fabric 3 and (b) knitted fabric 3
produced from the stitch pattern.
Figure 3 (a) Stitch pattern used for fabric 2 and (b) knitted fabric 2
Table 3 Guide bar settings and fibres used for fabric 3.
produced from the stitch pattern.
bar setting fibre
x (warp direction)
1
2
Moveable
crosshead
Video-
CCD extensometry
camera software
Load
cell
Width
Force Length
Extension PC2
PC1
Figure 5 (a) Stitch pattern used for fabric 4, (b) loop diagram for
fabric 4 and (c) knitted fabric 4 produced from the stitch pattern.
Figure 7 (online colour at: www.pss-b.com) Schematic of the
videoextensometry set-up.
Table 4 Guide bar settings and fibres used for fabric 4.
bar setting fibre
marks on the fabric along the length and width. Thus, from
front 2-0/2-4 (1 in–1 out) 480dtex Dorlastan V500 the axial and transverse length data gathered during the test,
2 2-4/0-2 (1 in–1 out) 480dtex Dorlastan V500 the axial and transverse strains can be calculated. Transverse
3 0-0/4-4/8-8/4-4 mono-filament PES width data is collected for ten sections along the length of
0.25 mm the sample, enabling the individual width section data to be
4 2-0/2-2/2-4/2-2 mono-filament PES generated as well as an average width data set. Data from the
(1 in–1 out) 0.15 mm middle 4 of the ten width sections was used in all data
analysis in order to minimize edge effects nearest to the
testing machine grips. Load-extension data for each test was
3 Experimental characterization methods The also captured.
fabrics were heat set and characterized using combined
mechanical testing and videoextensometry. Test samples 4 Results In order to show how the data from the
(15 cm long by 5 cm wide) were cut along and perpendicular videoextensometer are used to produce the Poisson’s ratios,
to the warp direction and also at 458 to the warp direction, one example of tests performed on fabric 1 will be worked
all the directions as shown in Fig. 6. through. Figure 8 shows the width and length data for fabric 1
Tests were performed up to 10% loading strain and were when subjected to tensile loading along the x or warp
repeated several times per sample. Figure 7 shows a direction. There is one length curve (indicated by the thicker
schematic of the MESSPHYSIK ME 46 videoextensometer line) and ten width curves, corresponding to all ten of the
and tensile testing machine, which were used to measure the individual transverse sections. It can be seen that as the fabric
axial and transverse strains to ascertain the Poisson’s ratio. is stretched, the width decreases, indicating a conventional
The videoextensometer camera captures the image of the material with a positive Poisson’s ratio.
sample and the software operates directly as a strain meter by In order to calculate values of the Poisson’s ratio, the
detecting the relative change in distance between fiducial width and length data were converted to transverse and axial
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1326 K. Alderson et al.: Auxetic warp knit textile structures
15.9 19.78
Table 8 Poisson’s ratio values for fabric 4.
15.8 19.76
nxy nyx n12 n21
width 1
0.1 0.06 0.23 0.05 0.22 0.03 0.13 0.02
width 2
15.7 19.74 width 3
Length(mm)
width 4
Width(mm)
width 5
15.6 19.72 width 6
width 7 very low (near zero) values of n are produced in two of the
width 8
width 9
orientations.
15.5 19.7
width 10 Following the same analysis method, Table 6 shows the
length
15.4 19.68
Poisson’s ratio values obtained for fabric 2 in all four key
orientations. Once again, the fabric is conventional, with
15.3 19.66
near zero values of n in two of the orientations.
0 2000 4000 6000 8000 10000 12000 14000 16000 The results for fabric 3 are shown in Table 7. This fabric
Time(msec) sample can be seen to show auxetic behaviour in the n21
Figure 8 Plot of length and width variations against time for fabric1 direction, with n21 ¼ 0.13 0.04 and near zero behaviour
tested in the warp (x) direction. in n12, with n12 ¼ 0.02 0.02.
A more detailed analysis is reported here for fabric 4,
with Fig. 9a–d showing the length and average width against
true strains, respectively, using time in each of the four orientations, with the average width
coming from each of the four central widths of the fabric.
l
e1 ¼ ln (1) It can be clearly seen that the fabric shows conventional
l0 behaviour for the first two graphs, when tested in the x- and y-
where e1 is the true strain and l and l0 are the length and directions but has auxetic behaviour when tested at 458 and
original length, respectively. þ458. Figure 10a–d shows graphs for the four orientations
Since the Poisson’s ratio, nij, is defined as of average widthwise strain against lengthwise strain
calculated as above, with the gradient of these graphs giving
ej
nij ¼ (2) the Poisson’s ratio values as shown in Eq. (2).
ei Repeat tests were conducted a number of times on each
where i is the direction of length and j the width direction, fabric and on a number of fabrics and the overall Poisson’s
the transverse and longitudinal true strains were plotted ratio values are given in Table 8. Thus, it can be seen that on
against each other. The slope is thus nij. Best-fit lines were repeat stretching, fabric 4 retains its auxeticity with all
fitted to the data for each of the four middle sections (as Poisson’s ratio values being negative as shown by the error
noted above to remove edge effects) and an average was bars of 0.03 and 0.02 for n12 and n21, respectively, on
obtained. This was repeated for each of the four key each stretch.
conditions. As an example, when tested in the x or warp
direction, fabric 1 yielded values for the four middle 5 Discussion The knitted fabrics in this study were
sections of nxy ¼ þ0.62, þ0.45, þ0.18 and þ0.08, which designed to be auxetic in the first stage of stretching and also
when averaged equated to nxy ¼ þ0.3 0.3. The results of to be able to undergo subsequent stretching, as shown in
the analysis for fabric 1 in all four directions are shown in Table 8, unlike other auxetic fabrics reported, which are
Table 5. The results show that the fabric is conventional, but effectively one stretch only auxetic materials. The fabrics
generated are complex and it is difficult to pick out the
underlying mechanisms behind their behaviour. In order to
Table 5 Poisson’s ratio values for fabric 1.
begin to understand how the fabrics produce the auxetic
nxy nyx n12 n21 effect, a detailed optical microscopy study was undertaken.
0.3 0.3 0.04 0.07 0.02 0.03 0.1 0.1 Samples of the fabrics were fitted with locating pins to aid in
geometric parameter identification and images were taken at
0.5% and 10% loading strain for each sample and loading
Table 6 Poisson’s ratio values for fabric 2. direction considered. The micrographs contain a wealth of
information and a detailed study is underway. However, a
nxy nyx n12 n21
preliminary study has been undertaken and the following
0.26 0.06 0.08 0.04 0.04 0.04 0.18 0.03
observations have been made.
During the first stage, stretching of the fabric occurs by
stretching of the fibres of the stabilization component and by
Table 7 Poisson’s ratio values for fabric 3. rotation of the fibres of the auxetic component about their
vertices. This rotation causes the re-entrant triangles of the
nxy nyx n12 n21
auxetic component to deform towards regular triangles, thus
0.11 0.03 0.33 0.04 0.02 0.02 0.13 0.04
producing a negative Poisson’s ratio. The modulus of the
(a) 29.35
average width
108 (b) 27.5
average width
108
length length
29.3 27.4
106 106
27.3
29.25
104 104
27.2
29.2
length (mm)
length (mm)
width (mm)
width (mm)
102 102
27.1
29.15
100 27 100
29.1
26.9
98 98
29.05
26.8
29 96 96
26.7
28.95 94 26.6 94
0 100000 200000 300000 400000 500000 0 100000 200000 300000 400000 500000
time (msec) time (msec)
length (mm)
29.05
width (mm)
29
99
100
29
28.9 98
28.95
98 97
28.8 28.9
96
96 28.85 95
28.7
28.8 94
28.6 94
28.75 93
0 100000 200000 300000 400000 500000
0 100000 200000 300000 400000 500000
time (msec)
time (msec)
Figure 9 (a) Plot of length and average width against time for fabric 4 tested in the warp (x) direction. (b) Plot of length and average width
against time for fabric 4 tested perpendicular to the warp direction. (c) Plot of length and average width against time for fabric 4 tested at 458
to the warp direction. (d) Plot of length and average width against time for fabric 4 tested at þ458 to the warp direction.
material during the first phase is defined by the modulus of interaction and relative characteristics of its two components
the fibres of the stabilizing component and the resistance of i.e., auxetic and stabilizing. The changes in knit pattern from 1
the fibres of the auxetic component to the rotation. This to 4 affect these relative characteristics and, as has been clearly
resistance depends on the knit pattern, the types of fibres used shown, this leads to very different properties. A general trend
for the auxetic component and the relative properties of from the first to the fourth pattern is the increase in the modulus
the fibres of the auxetic and stabilizing components. For of the stabilizing component. Pattern 4 also introduces a lateral
example, the fibres of the auxetic component must have a interaction of the stabilizing component with the auxetic
sufficiently high modulus compared to the resistance to component, which acts to pull the centre of the re-entrant side
rotation of that fibre about its vertices, such that the shapes of of the triangle out of the triangle, causing the expansion in the
the auxetic component deform rather than stretching or lateral direction. This is believed to lead to the improved values
buckling. Likewise, the elasticity of the fibres of the of n12 ¼ 0.22 0.03 and n21 ¼ 0.13 0.02.
stabilizing component must be sufficiently high compared It is expected that at some stage, the structure will revert
with the resistance of the fibres of the auxetic component to to a conventional structure displaying positive Poisson’s
rotation so that the stabilizing component can act to return ratios as the network expands in much the same way as is
the auxetic component to its original configuration when the seen in honeycomb and other auxetic network structures.
stress on the fabric is removed. This means that it is likely This is likely to be at strains much higher than the 10%
that the modulus of the fabric will be dominated by the assessed here since initial microscopic examinations do not
modulus of the stabilizing component. reveal that the structure is at its limits when 10% strain is
Looking now at the four stitch patterns investigated here, applied. In addition, the fabric behaves linearly elastic up to
as stated above, the behaviour of the fabrics is defined by the the 10% strain applied.
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1328 K. Alderson et al.: Auxetic warp knit textile structures
(a) (b)
0.004 0.01
0.002 0.005
0 0
0 0.02 0.04 0.06 0.08 0.1 0.12 -0.02 0 0.02 0.04 0.06 0.08 0.1 0.12
Average strain_y
Average strain_x
-0.002 -0.005
-0.004 -0.01
-0.006 -0.015
y = -0.1078x + 0.0017
y = -0.2684x + 0.0025
-0.008 -0.02
-0.01 -0.025
-0.012 -0.03
Strain_x Strain_y
(c) (d)
0.02 0.012
0.01
0.015
0.008
y = 0.1969x - 0.0008 y = 0.1299x - 0.0012
Average strain_2
Average strain_1
0.01 0.006
0.004
0.005
0.002
0
0 0 0.01 0.02 0.03 0.04 0.05 0.06 0.07 0.08 0.09 0.1
-0.02 0 0.02 0.04 0.06 0.08 0.1 0.12
-0.002
-0.005 -0.004
Strain_1 Strain_2
Figure 10 (a) Plot of transverse against longitudinal strain length for fabric 4 tested in the warp (x) direction. (b) Plot of transverse against
longitudinal strain length for fabric 4 tested perpendicular to the warp direction. (c) Plot of transverse against longitudinal strain length for
fabric 4 tested at 458 to the warp direction. (d) Plot of transverse against longitudinal strain length for fabric 4 tested at þ458 to the warp
direction.
Simple analytical models based on hinging, flexing and shows the pristine double arrowhead geometry of Fig. 1, and
stretching of the fabric components are currently being Fig. 11b shows the same geometry where the long arms
developed. It is likely that the three mechanisms need to be aligned towards the 2-axis have been rendered inactive
considered acting in a concurrent manner. Also it is (indicated by dashed lines). The array of active elements
recognized that other mechanisms may operate in the (solid lines) in Fig. 11b approximates a sheared re-entrant
fabrics. In particular, fibre translation determined by friction, hexagonal honeycomb, with ‘vertical’ (long) arms aligned
leading to slippage, is expected to occur. towards the 1-axis. The re-entrant hexagonal honeycomb
Another modification, which may need to be incorpor- displays auxetic response for loading along or perpendicular
ated into the models relates to the arms of the networks being to the direction of the ‘vertical’ arms when deformation is
fibres rather than beams. Consider, for example, the case of a predominantly by flexing or hinging of the arms. Now
tensile load applied vertically to the structure of Fig. 1. In this consider the case of the structure of Fig. 11a subject to tensile
case, the long arms of the network are placed under tension loading along the 1-axis. This loading will tend to flatten the
along their lengths, whereas the short arms are under axial adjacent cells bounded by ABCD along the y-direction,
compression. In which case the short fibre arms are likely to which will place the long arms aligned towards the 2-axis
adopt a kinked or buckled form in contrast to the combination (e.g., arm AC) to be placed under compression. In the case of
of flexed, hinged or shortened deformation determined from stiff beam elements, cell flattening is resisted. However, for
beam mechanics. The kinked/buckled fibres become inactive fibre elements, the arms aligned towards the 2-axis become
in the mechanism responsible for the effective mechanical buckled/kinked and thus are rendered inactive, leading to the
properties, which may explain why the on-axis auxetic structure of Fig. 11b and, therefore, the occurrence of auxetic
response predicted from beam theory has not been achieved behaviour for tensile loading along the 1-axis. A similar
in the fabrics investigated here. argument can also be advanced for tensile loading along the
The presence of off-axis auxetic response in fabrics 3 and 2-axis. A thorough assessment of which ribs become inactive
4 may also be attributed to the occurrence of inactive during loading is clearly now required to assess the validity
buckled/kinked fibres during mechanical loading. Figure 11a of these initial considerations.