Atomic Structure

ABOUT EDUCATORS

DR. SHARAD KOTHARI

• MSc., PhD, NET, JRF
• 18 year experience of IIT JEE in Organic Chemistry
• Ex. Senior Faculty of Vibrant Academy, Kota and Bansal Classes, Kota

PIYUSH MAHESHWARI
• BE (Hons.)
• 11 year experience of IIT JEE in InorganicChemistry
• Author of 'Super Problems in Inorganic Chemistry',
• Ex. HOD Bansal Classes, Kota
• Ex. Senior Faculty of Vibrant Academy, Kota and Allen Career Institute, Kota

BRIJESH JINDAL
• BTech Jaipur MNIT
• 11 year experience of IIT JEE in Physical Chemistry
• Ex. Senior Faculty of Vibrant Academy, Kota, Allen Career Institute, Kota and Bansal
Classes, Kota
 ATOMIC STRUCTURE

EXERCISE-1 (Subjective Questions)

r ts
r t s
EARLIER MODELS OF ATOM
pe
ethrough a potential difference of 2 × 10 volt fallsyonEaxsilver foil. The
Q.1 An alpha particle after passingp
isx47. Calculate (i) the K.E. of the alpha-particle at thettime
6

r of falling on the foil.

(ii) K.E. of the r–y
atomic number of silverE i s
stsilver to which the particle reaches. hem
–14
particle at a distance of 5 × 10 m from the nucleus, (iii) the shortest distance from
the nucleusiof

h e m C
Q.2
CA 7
beam of some kind of particle of velocity 2 × 10 m/s is scattered by a gold (z = 79) foil. Find specific
charge of this particle (charge / mass) if the distance of closest approach is 7.9 × 10–14 m.

Q.3
ts r ts
With what velocity should an -particle travel towards the nucleus of a copper atom so as to arrive at a

A photon having  = 800 Åp

er
distance 10–13 meter from the nucleus of the copper atom?
p e
Q.4
[Given : E = 1240E
x causes the ionization of a nitrogen atom. Give the I.E. perymoleEofxnitrogen in KJ.
tr y eV-nm, 1eV = 96.43 kJ/mol]
s t r
i svelocity should an particle travel towards the nucleusmofia Cu atom so as to arrive at a
Q.5
m
With what
e h e
ChELECTROMAGNETIC WAVES, LIGHT & PLANCKS
13

C QUANTUM THEORY
distance 10 m .

Q.6 A certain dye absorbs 4700 Å and fluoresces at 5080 Å these being wavelengths of maximum absorption

r ts s
that under given conditions 47% of the absorbed energy is emitted. Calculate the ratio of the no. of
t
e r
xp e
quanta emitted to the number absorbed.

y to form HBr in presence of light is initiated by the photox

EH and(freeBrradicals) p
Q.7
s tr
The reaction between 2 2

r y E decomposition
of Br into free

m
2
192.86 KJ/mole.
Br atoms by absorption of light. The bond
t
i What is the longest wavelength of the photon that wouldisinitiate the reaction.
dissociation energy of Br is 2

h e : E = 1240 eVnm]
[Given
e m
Q.8 C h 0.01 moles of HI are decomposed.
C The quantum yield for decomposition of HI is 0.2. In an experiment
Find the number of photons absorbed.
number of molecules decomposed
[Given : Quantum yield = number of photons subjected ]
r ts
p e radiation that would cause photo dissociation of chlorine molecule if the
Q.9
E x
Calculate the wavelength of the
r t s
t r y
Cl- Cl bond energy is 241 KJ/mol.
p e
is
Q.10 The dissociation
m
energy of H is 430.53 KJ/mol. If H is exposed to radiant
y E x
energy of wavelength
e r
2 2
253.7
h
nm, what % of radiant energy will be converted into K.E.

C The eyes of certain member of the reptile family pass a single visual i t
s to the brain when the visual
Q.11
receptors are struck by photons of wavelength 132.6 nm . Ifh emenergy of 3 10 J is required to
signal
14

Cmust strike the receptor.

a total
trip the signal, what is the minimum number of photons that

Page # 1
 ATOMIC STRUCTURE

Q.12 Find the number of photons of radiation of frequency 5 × 1013 s–1 that must be absorbed in order to melt
r ts
s pe
one gm ice when the latent heat of fusion of ice is 331.5 J/g.
r t x
Q.13 Suppose 1017 J of light energy is needed by the interior of the human eye to see an object. How many
e
x p y E
photons of green light ( = 550 nm) are needed to generate this minimum amount of energy.
r
r y E i s t
2
t
Q.14 O undergoes photochemical
s 1.967 eV more energy than (O) and normal dissociation
O*. If (O*)ihas
e m
dissociation into 1 normal oxygen atom (O) and more energetic oxygen
–1

h
energy of O is 498 kJ mol
, whatm
2

h e C
is the maximum wavelength effective for the photochemical dissociation of O ? 2

Q.15CA bulb emits light of  = 4500Å. The bulb is rated as 150 watt and 8 percent of the energy is emitted as
light. How many photons are emitted by the bulb per second?

tsBOHR’S MODEL r ts
x p er x pe
E
E try
Q.16 Calculate the wavelength of radiation emitted, producing a line in Lyman series, when an electron falls
ry s
st
from fourth stationary state in hydrogen atom.
i i
e m  1



hem
Ch
[Given : = 912 Å]
R 
 h 
C
Q.17 Calculate energy of electron which is moving in the orbit that has its radius. sixteen times the radius of first
Bohr orbit for H–atom.

r t s
[Given : E1,H = 2.176 × 10–18 J/atom]
ts
p e e r
E x
Q.18 The wavelength of a certain line in the Paschen series in 1094.4 nm of H-atom. What is the
x p
value of n high
for this line.
r y E
i stof the Balmer H line is 6565 Å. Calculate the wavelength ofisHtr, liney of same hydrogen
e m
Q.19 Wavelength 
m 

C hlike atom.
h e
Q.20 Calculate the Rydberg constant R if He ions are known to C
+ have the wavelength difference between the
first (of the longest wavelength) lines of Balmer and Lyman series equal to 133.7nm.

Q.21
to n = 2 of He+ spectrum.
r ts
What transition in the hydrogen spectrum would have the same wavelength as the Balmer transition, n=4

x pe when electrons of 1.0 g atom of hydrogen undergo transition givingts

E
Q.22 Calculate the total energy emitted
y energy in the visible region of its atomic spectrum. e r the

[Given : Estr= 2.176 × 10 ] p

spectral line of lowest
i –18

E x
m y radiations (radiations
1(H)

Q.23 H-eatom is exposed to electromagnetic radiation of 1028 Å and gives out induced
tr
h i
C emitted when e returns to ground state).Calculate  of inducederadiations.s
–

h m
Q.24 The electron energy in hydrogen atom is given by
C
En 
 21.7 10 12
ergs.
Calculate the energy required
n2
Page # 2
 ATOMIC STRUCTURE

ts
to remove an e completely from n = 2 orbit . What is the largest wavelength in cm of light that can be
r
used to cause this transition.
e r t s pe
xn=2 returns to
Q.25 Calculate the wavelengthx inp E
y erg/atom.
the orbit n=1. They E tr
angstrom of photon that is emitted when an e in Bohr
i s
orbit

i tr ionization potential of the ground state of hydrogen atom is 2.17×10 11

m of electron in this orbit.

san orbit of hydrogen atom is 0.85 nm. Calculatehtheevelocity
e m
Q.26 The radius
h
of
C
Q.27CThe velocity of e in a certain Bohr orbit of the hydrogen atom bears the ratio 1:275 to the velocity of


light. What is the quantum no. "n" of the orbit and the wave no. of the radiation emitted for the transition
from the quatum state (n+1) to the ground state.

ts r ts
Q.28
er pe
A doubly ionised lithium atom is hydrogen like with atomic number z = 3. Find the wavelength of the

x p x
E r yE
radiation required to excite the electron in Li2+ from the first to the third Bohr orbit.

r=y912 Å] t
1
[Given :
i st i s
m
RH

Q.29 he m h e
C result in the emission of Xrays with
C atomic number a transition from n=2 to n=1 energy level would
Estimate the difference in energy between I and II Bohr Orbit for a hydrogen atom. At what minimum

= 3.0 × 108 m? Which hydrogen like species does this atomic number correspond to.

Q.30
ts
Calculate the wave number for the shortest wavelength transition in the Balmer series of atomic hydrogen.
r ts
e
[Given : RH = 1.097 × 107 m–]
r
p to radiations. The study of spectra indicates that 27% of thepeatoms are
x
Eand 15% of atoms in 2nd energy level and the rest in groundE x
in 3rd energy r
t y
Q.31 1.8 g hydrogen atoms are excited
y
21.7 × 10is erg. Calculate 
level
12
i s t r state. If I.P. of H is

e m m
(ii) hTotal energy evolved when all the atoms return to ground state. e
(i) No. of atoms present in III & II energy level.

Q.32
C Ch
The energy of an excited H-atom is –3.4 eV. Calculate angular momentum of e– in the given orbit .

Q.33 The vapours of Hg absorb some electrons accelerated by a potential diff. of 4.5 volt as a result of which

ts
light is emitted. If the full energy of single incident e is supposed to be converted into light emitted by
r
e
single Hg atom, find the wave no. of the light.
p
E x r tsan e
makes when itrisy e
Q.34 If the average life time –8
of an excited state of H atom is of order 10 sec, estimate how many orbits –

t
ithes frequency of e in the first Bohr orbit in a H-atom.
in the state n = 2 and before it suffers a transition to n =1 state.
x p
e m r y E
t
–

h
Q.35 Calculate

C A single electron orbits around a stationary nucleus of charge +Zeem

Q.36
is
where Z is atomic number and ‘e’ is

from the second Bohr orbit to the third Bohr orbit. Find C
the magnitude of the electric charge. The hydrogen like species h required 47.2 eV to excite the electron

Page # 3
 ATOMIC STRUCTURE

(i) the value of Z and give the hydrogen like species formed.
r ts
s pe
(ii) the kinetic energy and potential energy of the electron in the first Bohr orbit.

r t
ephoton corresponding to a first line of the LymanyE x The photon
p
xfrom a stationary H atom in ground state. What is thetvelocity
r of photoelectron.
E
+
Q.37 A stationary He ion emitted a series.

t r y
liberated a photoelectron
i s
i s
Q.38 A sample of H-atoms containing all the atoms in some excited statee
m
h the light source, atoms de-excite to
e
 and
m C
is irradiated with light of wavelength

h state with emission of radiations. The emission spectrum thus obtained consists of ten spectral
atoms get re-excited to further higher orbit. On removing
Cground
lines corresponding to ten different wavelengths. Out of the ten spectral lines, seven lines have wavelength

ts r ts
smaller than the incident  while only two of them have wavelengths longer than the incident wavelength.

er
Determine the orbit number in which electrons were present initially.

x p x pe
y E r y E
Q.39

st i s t
A proton captures a free electron whose K.E. is zero & forms a hydrogen atom of lowest energy-level
r
(n = 1). If a photon is emitted in this process, what will be the wavelength of radiation? In which region

m i e m
of electromagnetic spectrum, will this radiation fall? (Ionisation potential of hydrogen = 13.6 volt,

h e h = 6.6 × 10–34K/s, C = 3.0 × 108 m/s)

C h
C
Q.40 The ionisation energy of the hydrogen atom is given to be 13.6 eV. A photon falls on a hydrogen atom
which is initially in the ground state and excites it to the (n = 4)state.
(a) show this transition in the energy-level diagram &

r t s
(b) calculate the wavelength of the photon.
t s
Q.41 The angular momentum ofp
e r
the wavenumber inE
x an electron in a Bohr's orbit of H-atom is 3.1652×10 kg-mx/sec.pefalls
–34 2 Calculate

t r y E
terms of Rydberg constant (R) of the spectral line emitted when an electron
y
from

i s
this level to the ground state.[Use h = 6.626 × 10 Js] –34

s tr
Q.42 Ine mBohr's model, for unielectronic species following symbols are m usedi
ChrU  e "z"
the
n,z
th
Radius of n orbit with atomic number "z"
 Potential energy of electron in n orbit with atomic
n,z
th
C h
number
Kn,z  Kinetic energy of electron in nth orbit with atomic number "z"
vn,z  Velocity of electron in nth orbit with atomic number "z"
Tn,z  Time period of revolution of electron in nth orbit with atomic number "z"

t
Calculate z in all cases.
r s
pe
(i) U1, 2 : K1,z = – 8 : 1 (ii) r1,z : r2, 1 = 1 : 8
(iii)
E x
v1, z : v3, 1 = 9 : 1 (iv) T1, 2 : T2, z = 9 : 32
r ts
y pe
Represent your answer as abcd, where a, b, c and d represent number from 0 to 9. a, b, c and d
tr
is x
represents the value of "z" in parts (i), (ii) ,(iii) & (iv). Suppose your answer is 1, 2, 3 & 4 then

e m
the same must be filled in OMR sheet as1234.00.
r E
y and 298K to the first
Q.43 h
C excited state of atomic hydrogen. The energy for the dissociationem is
Calculate the energy required to excite one litre of hydrogen gas at 1 atm t
pressure
–1
of H – H is 436 KJ mol .

Ch
Page # 4
 ATOMIC STRUCTURE

r ts
s pe
PHOTOELECTRIC EFFECT

e r t x
[Given : N = 6 × 10 ] x
p
Q.44 Calculate the threshold frequency
E 1
of metal if the binding energy is 198.9 KJ mol of electron.
r y
A

r E
23
t
y energy per mole when threshold wavelengthmofisphoton is 240 nm.
i
Q.45 Calculate the t
s= 20 × 10 , N = 6 × 10 ]
binding
e
e m
[Given : hc –26 23

C h
h
A

Q.46CA metal was irriadated by light of frequency 3.25 × 10 s . The photoelectron produced had its KE,
15 1

2 times the KE of the photoelectron which was produced when the same metal was irradiated with a
light of frequency 2.0 ×1015 s1. What is work function.[Given :NA = 6 × 1023]

ts r ts
Q.47
er pe
U.V. light of wavelength 800 Å & 700 Å falls on hydrogen atoms in their ground state & liberates

x p x
y E emitted from tungsten surface is 3.06 eV. What voltagetrwould E
electrons with kinetic energy 1.8 eV and 4 eV respectively. Calculate planck’s constant.
y be required to
Q.48 The K.E. of anrelectron
st to rest.
bring theielectron i s
e m h e m
Q.49 h C
C made
A light source of 320 watt emit monochromatic light of wavelength 6200 Å. If all emitted photons are
to strike on metal plate of work function equal to 1.8 eV and quantum yield is 25% then photocurrent
observe is

Q.50
r ts s
What will be the KE of photoelectron ejected by a metal upon irradiation with electromagnetic radiation
t
e r
xp
of wavelength equal to that of the last line in Lyman series of He+ ion?
I.P. of metal = 3.8 eV.

yE x pe
str ryE
Q.51

mi i s t
When light of frequency 3.2 × 1016 Hz is used to irradiate a metal surface the maximum kinetic energy
of the emitted photoelectron is 3/4 of the energy of irradiating photon then the threshold frequency of the
e m
Ch e
metal would be :

Ch
DE BROGLIE DUAL NATURE

Q.52 In a hydrogen atom, in transition of electron a photon of energy 2.55 eV is emitted, then calculate
change in wavelength of the electron.

r ts
Q.53
e
What is de-Broglie wavelength of a He-atom in a container at 300 K.(Use Uavg)
p
E x r ts
t r y
Q.54 Through what potential difference must an electron pass to have a wavelength of 500 Å.
p e
m is potential a proton beam be subjected to give its protons a wavelength
Q.55 To what effective
E x of 1 ×10 m.
y difference = 100 KV.
10

Q.56 h
e
What is de Broglie wavelength associated with an e accelerated throughs
i t r
C
– potential

h m
e (mass 6 × 10 Kg) orbiting around
24

C
Q.57 Calculate the de-broglie wavelength associated with motion of earth
6
the sun at a speed of 3 × 10 m/s.

Page # 5
 ATOMIC STRUCTURE
Q.58 What should be the velocity of an electron so that its momentum becomes equal to that of a photon of
wavelength 5200Å.
r ts
r ts
e applied between the plates, to accelerateytheEprotons, pe
x such that,
p
x300 nm?
Q.59 What should be the potential difference,
r
y E
they have a wavelength of
i s t
i strHEISENBERG’S UNCERTAINTY PRINCIPLE h e m
e m C
Chproton is accelerated to one- tenth of the velocity of light. If its velocity can be measured with a
Q.60 A
precision + 1%. What must be its uncertainty in position.

Q.61
ts r ts
A base ball of mass 200 g is moving with velocity 30 × 102 cm/s. If we can locate the base ball with an

r pe
error equal in magnitude to the  of the light used (5000 Å), how will the uncertainty in momentum be

p e
compared with the total momentum of base ball.
x
E x yE
Q.62
r y tr
An electron has a speed of 40 m/s, accurate up to 99.99%. What is the uncertainty in locating its
s
i st
position.
i
m wavelength. The minimum
e m h e
Chpercent error in its measurement of velocity under this circumstance
C will be approximately
Q.63 The uncertainty in the location of circulating electron is equal to its de-Broglie

SCHRODINGER EQUATION / APPLICATION OF QUANTUM NUMBER

Q.64
r ts t
Mr. Santa has to decode a number "ABCDEF" where each alphabet is represented by a single digit.
s
e
p (r – 5k r + 6k )
Suppose an orbital whose radial wave function is represented as
e r
 =x p
r y Einformation given about each alphabet then write down the answers
(r) k 1 ·e  r / k 2 2
3
2
3
E xin the form of
stfor above orbital.
From the following
i tr y
m
"ABCDEF",
e i s
hInfo A = Value of n where "n" is principal quantum number
h e m
C Info C =Azimuthal quantum number of subshell to orbital belongs
Info B = No. of angular nodes
C
Info D = No. of subshells having energy between (n + 5)s to (n + 5)p where n is principal quantum
number
Info E = Orbital angular momentum of given orbital.

t s
Info F = Radial distance of the spherical node which is farthest from the nucleus
r
(Assuming : k3= 1)
p e
E x r ts
t r y 1
Q.65 Calculate the distance of spherical nodes for '3s' orbital from nucleus?
p e
is R = 9 3a (6 – 6  +  ) e x
 2r
E


m where  =
y
2 2

e
3/ 2

r na 0
3s

h t
0

C The difference between orbital angular momentum of a 2s and ae3dmelectron

Q.66 is is
Ch
Page # 6
 ATOMIC STRUCTURE

1  1 
3/ 2

 r 
r   2 
r ts
s pe
 2  e a 0 
Q.67
t
The wave function of 2s electron is given by :  2s 
r
e between r and a .
 
4 2  a 0  
x
a0 
If it has a node at r = r , findp E
E
0
x relation 0 0
t r y
t r y of orbital angular momentum of an e that occupies
i s1s, 2s , 2p , 3d , 3p.
s m
Q.68 Calculate magnitude –

m i e
hWork out electronic configuration of
e C
Ch
Q.69 A compound of Vanadium has magnetic moment of 1.73 BM.
Vanadium ion in the compound.

ts r ts
x p er x pe
E
stryE
i s try
mi em
e h
Ch C

r ts ts
e r
E xp x pe
ry yE
i st i s tr
em m
Ch Ch
e

r ts
xpe ts
yE r
is tr x pe
em ryE
C h i s t
hem
C
Page # 7
 ATOMIC STRUCTURE

EXERCISE-2 (Objective Questions)

r ts
t s pe
(I) FILL IN THE BLANKS :
(i)
e r x
Radiation of  = 155 nm was irradiated on Li (work function = 5 eV) plate. The stopping potential
p
(in eV) is __________.
x r y E
Increasing orderrofy
E i s t
(ii)
i t
s Na , Fe , Co , Cr m
magnetic moment among the following species is ________.
e
h
+ +3 2+ +2

e m
h is ________. C
CH-atom is
(iii) If in the hydrogen atom P.E. at chosen to be 13.6 eV then st
the ratio of T.E. to K.E. for 1 orbit of

(iv) The light radiations with discrete quantities of energy are called ______.

ts r ts
(v)
er pe
Assume that the potential energy of a hydrogen atom in its ground state is zero. Then its energy in the first
x p x
excited state will be__________.

y E r y E
t r i s t
Single correct is
(II) OBJECTIVE TYPE:

e m h e m
Q.1
C hThe distance of closest approach of an -particle projected towards
What will be the distance of closest approach, when the momentum
a nucleus with momentum p is r.
C projected -particle is 2p?
of
r r
(A) 2r (B) 4r (C) (D)
2 4

r ts ts
Q.2
e
The energy of electron is maximum at
r
(A) Nucleus
E xp (B) Ground state
x pe
r y
(C) First excited state (D) Infinite distance from the nucleus
E
t level would allow the hydrogen atom to absorb a photon buttrnotyto emit a photon
Q.3 i s
Which electronic
i s1s
e m
(A) 3s (B) 2p (C) 2s
m (D)
h
Q.4C Orbital angular momentum associated with 2p - electron is : h
e
2h
C h h
(A) (B) 0 (C) 6 (D)
 2 2

Q.5
r t s
The angular momentum of an electron in a certain orbit of Li+2 ion is 3.15 × 10–34 (in SI units). What will

x pe
be the potential energy of electron in that orbit ?
ts
(A) –13.6 eV

r E (B) –27.2 eV (C) + 13.6eV

ynumber is not related with Schrodinger equation
(D) –53.4 eV
er
Q.6
is
Which quantum t (D) SpinE
x p
e m
(A) Principal
h
(B) Azimuthal (C) Magnetic
tr y
C ofTheLishortest i s in the Paschen series
em
Q.7 wavelength of He atom in Balmer series is x, then longest wavelength
+2

h
is

(A)
36 x
5
(B)
16 x
7
(C) C 9x
5
(D)
5x
9

Page # 8
 ATOMIC STRUCTURE
Q.8 An electron, a proton and an alpha particle have kinetic energies of 16E, 4E and E respectively. What is
the qualitative order of their de Broglie wavelengths?
r ts
(A) e > p = 
r ts
(B) p =  > e (C) p > e >  (D)  < e » p
e of 1 and 2 lines of Lyman series in H–likeyatom xto difference in pe
x p E
st5.5r: 1
Q.9 The ratio of difference in wavelengths st nd

wavelength for 2nd andE

(A) 2.5 : 1 try (B) 3.5 : 1
rd
3 lines of same series is:
i
i s (C) 4.5 : 1
e m (D)

h electrons fall to lower energy states.

e m C
h is the difference in energy between two levels if a transition between them gives rise to 0.5 Å X-
Q.10 X-rays are emitted as the electrons deep within atoms having many
CWhat
ray?
(A) 24.8 eV (B) 24.8 KeV (C) 24.8 MeV (D) none of these

ts r ts
Q.11
(A) R/3
x (B) 9R er
If radius of second stationary orbit (in Bohr's atom) is R. Then radius of third orbit will be
p (C) R/9
x
(D) 2.25R pe
y E emitted when an electron jumps from state A to C istr3000 E
y Å and it is 6000 Å
r
Q.12 Wavelength of radiations
i s i s emitted when an electron
t jumps from state B to state C. Wavelength of the radiations
when the electron

e m
jumps from state A to B will be
h e m
C h(A) 6000 Å (B) 3000 Å
C
(C) 4000 Å (D) 2000 Å

Q.13 The ratio of wave length of photon corresponding to the -line of Lyman series in H-atom and -line of
Balmer series in He+ is
(A) 1 : 1
r t
(B) 1 : 2
s (C) 1 : 4 (D) 3 : 16
ts
Q.14 Three energy levels P, Q, p
e
R of a certain atom are such that E < E < E . If  ,  and  aree r
length of radiationE
x P
x p
Q the wave
R 1 2 3

relationship tr y E
corresponding to transition R  Q ; Q  P and R P respectively.
y
The correct

i s between  ,  and  is
1 2 3

i s t r
e m 1 1 1
m 2 1 1
h(A)  +  =    (C)  =  
e  
C Ch
1 2 3(B)  3 1  2 3 (D) 1 2  3 1  2

Q.15  
The value of (n2 + n1) and n 22  n12 for He+ ion in atomic spectrum are 4 and 8 respectively. The
wavelength of emitted photon when electron jump from n2 to n1 is
32
r ts 9 9 32
(A) R
9 H
p e
(B) R
32 H
(C) (D)
32 R H 9RH

E x r ts
t r yreturns to ground level, are
Q.16 Number of possible spectral lines which may be emitted in bracket series in H atom, if
p e
electrons present

m is
th
in 9 excited level
(D) 5 yE
x
h e
(A) 21 (B) 6 (C) 45
s tr
i in its position is:
C (A)
Q.17
(C) 2.64 × 10 e m
m
A mosquito of 2 mg is moving with a speed of (20  0.1) m/sec. Uncertainty
2.64 × 10 m –29
(B) 2.64 × 10 m –28

C h –34
(D) 2.64 × 10 m –31

Page # 9
 ATOMIC STRUCTURE
Q.18 The wavelength associated with a golf weighing 200g and moving at a speed of 5m/h is of the order
(A) 10–10m (B) 10–20m (C) 10–30m (D) 10–40m
r t s
t
Q.19 The longest wavelength of He inrPaschen
s series is "m", then shortest wavelength of BexpinePaschen
series is (in terms of m): p
e +

y E
+3

E x tr
5
tr y 64 53
i s 7
(A) m
36
i s (B)
7
m (C)
8
m

h em (D) m
64

h m
eis uncertainity in location of a photon of wavelength 5000Å
C if wavelength is known to an accuracy
Cof(A)1 7.96
Q.20 What
pm?
–14
× 10 m (B) 0.02 m (C) 3.9 ×10 m–8 (D) none

Q.21
ts r ts
Approximate De-Broglie wavelength ratio of  particle with respect to proton is, if both are accelerated

er
through same potential difference :

x p x pe
(D) 8 E
1
E y
1
(A)
8
tr y (B)
2
(C) 2

i s tr
i s
Q.22 Electromagnetic radiations having  = 310 Å are subjected m
e m h e to a metal sheet having work

Ch(A) 0, no emission will occur (B) 2.18 ×C

function = 12.8 eV. What will be the velocity of photoelectrons with maximum Kinetic Energy..
10 m/s 6

(C) 2.18 2 × 106 m/s (D) 8.72 × 106 m/s

Q.23
r ts ts
Assuming Heisenberg Uncertainity Principle to be true what could be the minimum uncertainty in de-broglie
e r
xp pe
wavelength of a moving electron accelerated by Potential Difference of 6 V whose uncertainty in position
7
r y E E x
yÅ
is n.m.
22
i st (B) 6 Å r
(D) t0.3125
i s
Q.24 h
e m
(A) 6.25 Å (C) 0.625 Å

m
When an excited hydrogen atom returned to its ground state, someevisible
h
C with other quanta. Which of the following transitions must have quanta were observed along
C occurred?(D) 4  1
(A) 2  1 (B) 3  1 (C) 3  1

Q.25 A photon of 300 nm is absorbed by a gas and then re-emits two photons. One re-emitted photon has

ts
wavelength 496 nm, the wavelength of second re-emitted photon is :
r
(A) 759
p e
(B) 857 (C) 957 (D) 657

E x r ts
y
Q.26 Which has the highest specific charge?
(A) Na
tr
+ (B) Mg +2 (C) Al 3+ (D) Si 4+
p e
m isto Bohr's atomic theory, which of the following relations is/are incorrect?
y E x
e
Q.27 According
h i s tr
C (A) Kinetic energy of electron  z2

em
h
n2

C number  z
(B) The product of velocity of electron and the principal quantum 2

Page # 10
 ATOMIC STRUCTURE

(C) Frequency of revolution of the electron in an orbit 

z2
r ts
s pe
n3
r t
e on the electron  x
p
z3
(D) Coulombic force of attraction
n4
r E
y of energy so that it
xin energy level with energy 'X' was provided withtexcess
r y E s
energy level with energy Y. If it can emit 6 wavelengthsioriginated from all possible
Q.28 A mono electronic species

i
jumps to higher t m is correct:
s these group levels, then which of the followingherelation
h e
(Here
m
transition between
n is the principal quantum number of energy level X)C :
C(A) X/Y = (n – 1) 2 (B) X/Y = 1 + 3/n
(C) (X / Y) = 1+3/n (D) X/Y = n/6

ts r ts
er pe
Q.29 The transition from the state n = 4 to n = 3 in a He+ ion results in ultraviolet radiation. Infrared radia-

x p
tion will be obtained in the transition from :
E x
ryE
(A) n = 2  n = 1 (B) n = 3  n = 2 (C) n = 4  n = 2
tr y (D) n = 5  n = 4

t
smomentum of an electron of H - atom is proportional to : is
i
Q.30 The angular
m e m 1
h e 1
C h
C
(A) r 2 (B) (C) r (D)
r r

Q.31 Wavelength of the de-Broglie wave of an electron revolving in the sixth orbit of the hydrogen atom is :

r s
(r0 is the Bohr's radius = 0.529 Å)
t t s
(A) r0
p e
(B) 12r0 (C) 6r0 (D) 24r0
r
eis given
Q.32 Graph between kineticx p
r y Eon a metal plate during photoelectric experiment :
energy of photoelectron KE
x
Vs frequency(v) of an incident photon
(max)
E
st
when light is incident
i tr y
e m i s
h em
C KE(max) (Joule)
0
Ch
v1

r ts v

pe
Wavelength of light corresponding to frequency v1 is 200 nm. If monochromatic light of wavelength

x
100 nm is incident on metal plate then K.E.(max) of ejected photoelectron is :
E r ts
(A) 1 × 10–27 J
tr y (B) 9.9 × 10–17 J (C) 9.9 × 10–19 J (D) 1 × 10–22 J
pe
Q.33
mis E x
The energy of an electron in the first Bohr orbit of H atom is  13.6 eV . The possible energy value(s) of
y
he the excited state(s) for electrons in Bohr orbits of hydrogen is/are :
i s tr
C (A)  3.4 eV (B)  4.2 eV (C)  6.8 eV
em
(D) + 6.8 eV

Q.34 The number of nodal planes in a px orbital is:

(A) one (B) two (C) threeC
h (D) zero

Page # 11
 ATOMIC STRUCTURE
Q.35 The quantum numbers +1/2 and –1/2 for the electron spin represent:
(A) rotation of the electron in clockwise and anticlockwise direction respectively.
r ts
e r ts
(B) rotation of the electron in anticlockwise and clockwise direction respectively.
x pe
x p
(C) magnetic moment of the electron pointing up and down respectively.
(D) two quantum mechanical spin states which have no classical analogue.
r y E
r E
y , which established the nuclear model of atom,mused
i t
s a beam of :–
i t
s which impinged on a metal foil and get absorbed.
Q.36 Rutherfords experiment
e
 -m
(A)  - particles,
(B)e C h
h rays, which impinged on a metal foil and ejected electron.
C(D) Helium nuclie, which impinged on a metal foil and got scattered.
(C) Helium atoms, which impinged on a metal foil and got scattered.

Q.37
ts r ts
An atom has a mass of 0.02 kg & uncertainity in its velocity is 9.218 × 10–6 m/s then uncertainity in

r pe
position is : (h = 6.626 × 10–34 J - s)
(A) 2.86 × 10–28 m
p e
(B) 2.86 × 10–32 cm (C) 1.5 × 10–27 m
x
(D) 3.9 ×10–10 m

Q.38 Energy of H–atomE

x
in the ground state is –13.6 eV , Hence energy in the secondy E
(A) –6.8 eVt r y i tr excited state is –
s(D) –4.3 eV
i s (B) –3.4 eV (C) –1.51 eV
muncertainty in velocity (ms ) is
e m in position of a particle of 25 g in space is 10 m.he
Ch(Planck’s constant h = 6.6 × 10 Js) C
Q.39 Uncertainity –5 Hence –1
–34

(A) 2.1 × 10–28 (B) 2.1 × 10–34 (C) 0.5 × 10–34 (D) 5.0 × 20–24

Q.40
ts
In Bohr series of lines of hydrogen spectrum, third line from the red end corresponds to where one of the
r ts
e
following inter-orbit jumps of electron for Bohr orbits in an atom of hydrogen.
r
(A) 4  1
E xp (B) 2  5 (C) 3  2
x
(D) 5  2
pe
ry yE
i st i s tr
em m
Ch Ch
e

r ts
xpe ts
yE r
is tr x pe
em ryE
C h i s t
hem
C
Page # 12
 ATOMIC STRUCTURE
Comprehension
Paragraph for question nos. 41 to 43
r ts
e r ts pe
The French physicist Louis de Broglie in 1924 postulated that matter, like radiation, should exhibit a dual
x
p E
behaviour. He proposed the following relationship between the wavelength  of a material particle, its

E x try
linear momentum p and planck constant h.

tr y h h i s
i s  = =
em
Ch
p mv
em
Ch
The de Broglie relation implies that the wavelength of a particle should decreases as its velocity increases.
It also implies that for a given velocity heavier particles should have shorter wavelength than lighter
particles. The waves associated with particles in motion are called matter waves or de Broglie waves.
These waves differ from the electromagnetic waves as they
(i) have lower velocities

ts r ts
r pe
(ii) have no electrical and magnetic fields and
(iii)
p e
are not emitted by the particle under consideration.
x
x E
The experimental confirmation of the de Broglie relation was obtained when Davisson and Germer, in
E y
y tr
1927, observed that a beam of electrons is diffracted by a nickel crystal. As diffraction is a characteristic
r sproperties of an electron or
st considered the limits of how precisely we can measure i
property of waves, hence the beam of electron behaves as a wave, as proposed by de Broglie.
i m
e m
Werner Heisenberg
h e
Chwe can measure both position and momentum. The more C
other microscopic particle like electron. He determined that there is a fundamental limit of how closely
accurately we measure the momentum of a
particle, the less accurately we can determine its position. The converse is also true. This is summed up
in what we now call the "Heisenberg uncertainty principle: It is impossible to determine simultaneously

r s
and precisely both the momentum and position of a particle. The product of uncertainty in the position,
t ts
e h
r
xp
x and the uncertainty in the momentum (mv) must be greater than or equal to
pe
. i.e.
4

r y E x (mv) 
h
E x
i st
4
t r y
e m i s
Q.41 The correct order of wavelength of Hydrogen (1H1), Deuterium (1H2) and Tritium (1H3) moving with

h
same kinetic energy is
(A) H > D > T (B) H = D = T (C) H < D < T
h e m (D) H < D > T
C
Q.42 The transition, so that the de-Broglie wavelength of electron C +
becomes 3 times of its initial value in He ion
will be
(A) 2  5 (B) 3  2 (C) 2  6 (D) 1  2

Q.43
r ts
If the uncertainty in velocity & position is same, then the uncertainty in momentum will be
hm
xpe h h 1 h
ts
(A)
yE (B) m (C) (D)
r
tr pe
4 4 4m m 4

mis yE x
he i s tr
C em
C h
Page # 13
 ATOMIC STRUCTURE
Paragraph for question nos. 44 to 47

r ts
The only electron in the hydrogen atom resides under ordinary conditions on the first orbit. When energy

er ts pe
is supplied, the electron moves to higher energy orbit depending on the amount of energy absorbed.
x
p E
When this electron returns to any of the lower orbits, it emits energy. Lyman series is formed when the

E x try
electron returns to the lowest orbit while Balmer series is formed when the electron returns to second

try i s
orbit. Similarly, Paschen, Brackett and Pfund series are formed when electron returns to the third, fourth

i s
and fifth orbits from higher energy orbits respectively.
em
m Ch
Maximum number of lines produced when an electron jumps from nth level to ground level is equal
e
Ctoh . For example, in the case of n = 4 , number of lines produced is 6. (4  3, 4  2, 4  1,
n (n  1)
2
3  2 , 3  1, 2  1). When an electron returns from n2 to n1 state, the number of lines in the spectrum
will be equal to

ts r ts
r pe
(n 2  n1 )(n 2  n1  1)

p e 2
x E , then the
x from energy level having energy E to energy level havingE
E in terms of energy of photon as:
If the electron comes back
y energy
r y 2

s t r 1

st
difference may be expressed
i m i
m e
hc
e E – E = E ,  =
h
ChSince
2 1 E
C thus each transition from one energy
h and c are constants, E corresponds to definite energy;
level to another will produce a light of definite wavelength. This is actually observed as a line in the
spectrum of hydrogen atom.

r ts  1 1 
Wave number of line is given by the formula   R  2  2  .
ts
e n 
r
xp pe
 1 n2 

y E
where R is a Rydberg's constant ( R = 1.1 × 107 m–1)
r E x
i s t emitted corresponding to transition n = 3 to n = 1 is [htr=y6 ×10 J-sec.]
i sNone of these
Q.44 The energy photon –34

(A) m
h e 1.76 ×10 J –18 (B) 1.98 ×10 J –18 (C) 1.76 ×10 J
e m
–17
(D)

C In a collection of H-atom, electrons make transition fromC5 hexcited state to 2nd excited state then
Q.45 th

maximum number of different types of photons observed are

(A) 3 (B) 4 (C) 6 (D) 15
st nd
Q.46 The difference in the wavelength of the 1 line of Lyman series and 2 line of Balmer series in a hydrogen
atom is
r t s
(A)
9
p e
(B)
4
(C)
88
(D) None
2R
E x R 15R
r ts
t r yof electromagnetic radiation emitted during the transition of electron inpbetween
e
Lis ion whose principal quantum numbers sum is 4 and difference is 2 is x
levels of i
Q.47 The wave number two

e m
2+

r y E
C h(A) 3.5 R (B) 4 R (C) 8 R i s t
(D) R
8

em
9

C h
Page # 14
 ATOMIC STRUCTURE

Paragraph for question nos. 48 to 50

r ts
er ts pe
The wave numbers of the spectral lines of Lyman Series may be calculated using the equation given
x
x p r yE
below as derived by Niels Bohr for an atom or ion free from electron-electron repulsion.

r
 E
y
 1
 RH  Z 2 1  2 
where n = 2, 3, 4 5….
i s t
i s t  n 
em
where
e m C h
Ch
2 2 4
2 m K e e
R  H = Rydberg constant
3
ch
me is the mass of electron but for actual calculation we will have to consider the nuclear motion and then
m will have to be replaced by reduced mass (µ) where

t s r ts
r pe
m N  me

mN  me e
ptheir usual significances.
, m = mass of nucleus
x
x
N

y
All the other symbols have
r E
yno nuclear attractive
Erequired to excite an electron from a level to the state where
The amount ofrenergy
s t by the electron is called IP of the atom. mis t
m i
force is experienced
e
e
Q.48 If electron
h
in H-atom is replaced by another hypothetical micro-particle say - which is 200 times heavier

Chthan electron, the wavelength of the 2 line of LymanCseries of H-atom will be

1
 
 
nd

9 9 1 4
(A) 1600 R
r ts
(B) 8 R (C) 150 R (D) 3R
ts
H

Q.49 If proton in the nucleusx

p e H H H

r
e but
y p
Ethe wave number of the lowest energy transition in the LymanEseriesx of the above
0
of hydrogen atom is replaced by positron ( e ) having the charge of proton
r
+1

t considering the nuclear motion will be equal to

mass that of electron,
designatedsH-atom
i tr y
e m i s
h
3
R
3
R
RH
em 3
R
C Ch
(A) (B) (C) (D)
4 H 8 H 2 2 H

Q.50 Due to inter electronic repulsion, an electron experiences less nuclear charge. It is, therefore, said that
inner electronic shells electrons shield the nucleus. The actual nuclear charge experienced by an electron
is called effective nuclear charge. If the electrons in K-shell shields the nucleus to the extent of 0.5 (say)

r ts
each. What will be the wave number of the spectral line arising out of n = 4 to n = 2 transition in Li atom?
3
(A) RH
xpe 3
(B) RH (C)
RH
(D) 8RH
ts
4
yE 8 4
r
is tr x pe
em ryE
C h i s t
hem
C
Page # 15
 ATOMIC STRUCTURE
Assertion Reason
Q.51 Statement-1: Energy emitted when an electron jump from 5  2 (energy level) is less than
r ts
er ts
when an electron jump from 2  1 in all 'H' like atom.
x pe
p E
Statement-2: The |total energy difference| between 1st & 2nd energy level is greater than that of
x try
any two energy level provided level '1' is not part of those two energy levels.
E s
try i
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.

i s m
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.
e
m Ch
(C) Statement-1 is true, statement-2 is false.
e
Ch
(D) Statement-1 is false, statement-2 is true.

Q.52 Statement-1 : Emitted radiations will fall in visible range when an electron jump from
higher level to n = 2 in Li+2 ion.
Statement-2 : Balmer series radiations belong to visible range in H-atoms.
ts r ts
r pe
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.

p e x
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.
x
(C) Statement-1 is true, statement-2 is false.
E y E
r y
(D) Statement-1 is false, statement-2 is true.
is tr
i st: Radial part of wave function of 4p and 3p are not m
h e m
Q.53 Statement-1 x
h
y
e same.
Statement-2
C (A) Statement-1depends on n & l. C
: Radial part of wave functions depends on l & m and angular part of wave function

is true, statement-2 is true and statement-2 is correct explanation for statement-1.

(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.
(C) Statement-1 is true, statement-2 is false.

r ts
(D) Statement-1 is false, statement-2 is true.
ts
e r
E xp x pe
ry yE
i st i s tr
em m
Ch Ch
e

r ts
xpe ts
yE r
is tr x pe
em ryE
C h i s t
hem
C
Page # 16
 ATOMIC STRUCTURE
More than one may be correct
Q.54 Correct statement(s) regarding 3Py orbital is/are
r ts
er ts
(A) Angular part of wave function is independent of angles ( and )
x pe
p E
x try
(B) No. of maxima when a curve is plotted between 4r2R2(r) vs r are '2'
E s
try
(C) 'xz' plane acts as nodal plane
(D) Magnetic quantum number must be '–1'
s electrons make transition from 4 excited state m i
m i he
e
Q.55 In a H-like sample
h 10 different spectral lines are observed C
thto 2 state then nd

C(A)
(B) 6 different spectral lines are observed
(C) Number of lines belonging to the Balmer series is 3.
(D) Number of lines belonging to the Paschen series is 2.

ts r ts
Q.56
er
Choose the incorrect statement(s):

x p x pe
E
(A) The order of wavelength is

yE try
Micro waves > Radio waves > IR waves > visible waves > UV waves

i str i s
(B) The order of Bohr radius is (rn : where n is orbit number for a given atom)

em
r1 < r2 < r3 < r4
em h
(C) The order of total energy is (En : where n is orbit number for a given atom)

Ch E1 > E2 > E3 > E4

C
(D) The order of velocity of electron in H, He+, Li+, Be3+ species in second Bohr orbit is
Be3+ > Li+2 > He+ > H

Q.57
r ts
If, in hydrogen atom, radius of nth Bohr orbit is rn, frequency of revolution of electron in nth orbit is fn and
ts
e r
xp
area enclosed by nth orbit is An, which of the following graphs is / are correct?

yE x pe
strrn log An
ryE
(A)
mi (B)
A1

i s t
e m
Ch e
n log n

log rn log
Ch
fn
(C) (D) f1

log n
s
log n

r t
pe
Q.58 Which is / are correct statement.
x t
(A) The difference in angular momentum associated with the electron present in consecutive orbits of
E r s
tr yh
pe
is x
H-atom is (n–1)
2

em yE
(B) Energy difference between energy levels will be changed if, P.E. at infinity assigned value other than
r
C h zero.
i s t
em
(C) Frequency of spectral line in a H-atom is in the order of (2  1) < (3  1) < (4  1)

h
(D) On moving away from the nucleus, kinetic energy of electron decreases.
C
Page # 17
 ATOMIC STRUCTURE

Q.59 If uncertainty in velocity is 6.62 × 10–2 m/s for a particle of mass of

0.05
ts
gm. Its uncertainty in position
r
s (B) 10 pe

may be
e r t x
(A) 0.5 × 10–18
p E
–18

(C) 0.8 × 10–18

E x (D) 0.5 × 10
r
–17

t y
t r y i s
i [MATRIX TYPE]
he m
scolumn II contain data on Schrondinger Wave–Mechanical
e m
Q.60 Column I &
h usualColumn C model, where symbols have

Ctheir meanings.Match the columns.

I Column II (Type of orbital)

ts r ts
er pe
(A) (P) 4s

x p E x
stryE
i s try
mi em
e (Q) hany
Ch C of the 5p orbital
(B)

(C) (,) = K (independent of &) (R) 3s

r ts ts
(D)
e
atleast one angular node is present (S) any of the 6d orbital
r
Q.61
E xp
Column-I Column-II
x pe
(A)
r y
Electron moving in 2nd orbit in He+ ion (P) Radius of orbit in which
yE
st r
electron is moving is 0.529 Å
i
mElectron moving in 3 orbit in H-atom (Q) Total energy i t
s of electron
h e
(B) rd

(–)13.6 ×e
m is
C Ch
9eV

2.188  106
(C) Electron moving in 1st orbit in Li+2 ion (R) Velocity of electron is m/sec
3

r ts
(D)
x p2e orbit is Be
Electron moving in nd +3 ion (S) De-broglie wavelength of electron is
ts
150
Å

y E r 13.6

i st r x pe
e m ryE
C h i s t
hem
C
Page # 18
 ATOMIC STRUCTURE

ANSWER KEY r ts
6.4×10 J, 2.1×10 J, p e mr tsEXERCISE - 1 x pe
Q.1 –13
x 3.4×10 –13 Q.2 –14
y
1.39 × 10 C/kg
r E 8

E
6.3 × 10 m sec y Q.4
r Q.5 6.3 × 10is
t
Q.3
i t
6

s Q.7 6200 Å
–1
1494.66 KJ/mol
e m
m/s 6

Q.6
e
0.5080m C
Q.8 h 10
3 × 22

h
Q.9 C4.96 × 10 m –7
Q.10 8.68 % Q.11 20,000

Q.12 10 22 Q.13 28 photons Q.14 174 nm

ts r ts
Q.15 27.2 × 1018

x p
Q.16
er 972.8 Å Q.17 – 1.36 × 10–19 Joules
x pe
E
yE try
Q.18 6 Q.19 4863 Å Q.20 1.096 × 107 m–1
r
st Q.22 1.82 × 10 J/mol
Q.21 n =1, n i=2 i s
em ergs, 3.7×10 cm
1 2
5 Q.23

hem
6563 Å ; 1216 Å ; 1028 Å

Q.24 h C 1220 Å
C 5.425×10 –12 –5 Q.25

Q.26 5.44 × 105 m/s Q.27 2 ; 9.75 × 104 cm–1 Q.28 114 Å

Q.29 10.2 eV , z = 2
r ts Q.30 27425 cm–1
ts
x pe atoms, 832.50 KJ
21
Q.31 292.68×10 atoms, 162.60×10 21 Q.32 h/
per
Q.33 3.63 ×10 m ry
E Q.34 8 ×10 E x
i st
6 –1 6 Q.35
ry
6530×1012Hz
t
Q.36 340 m
e i s
m
Ch
eV , – 680 eV Q.37 3.09 × 10 cm/sec 8 Q.38 3
e
Q.39 910 Å ;U.V Q.40 973.5 Å ChR
Q.41
8
 
9
Q.42 1233.00 Q.43 97.819 KJ Q.44 5 ×1014 s–1
Q.45 500 KJ/mol Q.46 298.35 KJ/mol Q.47 6.57 ×10–34 Js
Q.48 3.06 V
r ts
Q.49 40 Amp Q.50 50.6 eV

pe
Q.51 8 × 1015 Hz Q.52 6.64 Å Q.53 0.79 Å
6.03×10–4 Volt
x
Q.54 Q.55 0.0826 Volts Q.56 3.88 pm
Q.57 3.68 × 10–65 m
E Q.58 1400 m/s Q.59 9.12 × 10–9 V
r ts
Q.60 1.05×10–13 m
tr y Q.61 1.75 × 10–29 Q.62 0.0144 m
pe
mis 93 3
yE x
93 3
Q.63
he 8 Q.64 300303 Q.65
2
tr
a0,

is ; ;
2
a0

C Q.68 0 m
e 2
h
6
h
2
h

h
Q.66 6h Q.67 r0 = 2a0 ;0;
2 2 2
Q.69 [Ar] 3d1 C
Page # 19
 ATOMIC STRUCTURE

EXERCISE - 2
r ts
ts pe
(I)
(i) 3 eV
p er
(ii) Na+, Co2+, Cr2+, Fe3+ (iii) zero
x
E
x try
(iv) photons (v) 23.8 eV
E s
(II)
i s Q.2 try e mi
m Ch
Q.1 D D Q.3 D Q.4 D Q.5 B
e
Q.6
Ch
D Q.7 B Q.8 A Q.9 B Q.10 B

Q.11 D Q.12 A Q.13 A Q.14 B Q.15 C

Bts
Q.16 B Q.17 B
r ts Q.18 C Q.19 D Q.20
eAr
Cp e x p
Q.21 A
x Q.22 Q.23 C Q.24 A
E Q.25

Q.26 D
stry EB
Q.27 Q.28 C Q.29
i sD try Q.30 C
Q.31 B m
i emA
h e Q.32 C Q.33 A
C hQ.34 Q.35 D

C
Q.36 D Q.37 A Q.38 C Q.39 A Q.40 D

Q.41 A Q.42 C Q.43 A Q.44 A Q.45 C

r t s Ats
Q.46 B Q.47 C
p e Q.48 A Q.49 B Q.50
r
e BCD
E x x p
Q.51 A
tr y
Q.52 D Q.53 C Q.54 BC
yE Q.55

s
i Q.57 AB i s tr
Q.56 AC
e m Q.58 CD Q.59 ABCD
m
Q.60 h (A) S, (B) R, (C)e
C Ch
(A) P, (B) P,Q,S, (C) P, R (D) Q, S Q.61 Q, (D) P

r ts
xpe ts
yE r
is tr x pe
em ryE
C h i s t
hem
C
Page # 20