Doubling Frequency Total area

concentration/ of successful under the

rate would collisions curve remains
mean double increases the same
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frequency of particles per of particles
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collisions More particles
Emp and mean collide with
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proportion of shift right activation
particles than Collide more energy
the activation frequently
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collide more per unit
frequently volume
Wider range To break
Distribution
of energies As the the bonds
shifts to the
than lower right in the temperature
increases the Particles
Greater area temperatures MBD graph must have
under curve particles have
more energy the required
because energy for
there is more a reaction Activation
particles to take
Peak (Emp) energy-
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stays at the Increasing the
same point
temperature they collide energy needed
but the curve concentration/ for particles
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the x axis is higher pressure to collide
sucessfully
because there
is no maximum Collision theory
energy for
molecules
Reactions can
Kinetics only occur
when collisions Increases the
Starts at 0 take place
because no
Maxwell rate of reaction
molecules Boltzmann by offering
have no distribution Adding a an alternative
energy Shows the catalyst route with
spread of a lower
energies that Increasing activation
molecules surface area energy
have at a Activation
particular Most probable energy is
temperature energy is Incrases lower so
the peak the rate of more particles
reactions will have Higher
that energy frequency
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have low collisions
the curve Emp Causes
energy
represents collisions to
because
the number occur more
collisions
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can slow Not the
them down. mean energy Make it smaller Activation
energy

To the right
of the Emp