R E A C T I O N S O F p-B L O C K E L E M E N T S

by A. K .Panda, PGT (Chem) ,KV NO-3 BBSR

1(a)# Cu + 8 HNO3(Dil. )  Cu(NO3)2 + 2NO +4 H2O

1(b)# Cu + 4 HNO3( conc.) Cu(NO3)2 + 2NO2 +2H2O

2(a)# 2NaOH (cold and dilute) + Cl2  NaCl +NaOCl +H2O

2(b)# 6NaOH (hot and conc.) + 3Cl2  5NaCl +NaClO3 +H2O

3(a)# 8NH3 (excess) + 3 Cl2  6NH4Cl + N2

3(b)# NH3 + Cl2 ( excess)  NCl3 (explosive ) + 3 HCl

4(a)# PCl3 + H2O  H3PO3 + 3 HCl

4(b)# PCl5 + H2O  POCl3 + 2 HCl
└> + H2O H3PO4 + 3 HCl

5(a)# F2 + H2O  HF + O2
5(b)# X2(g) + H2O(l)  HX(aq) + HOX (aq) ] 1/3 ClF + H2O  HF + H—O—Cl
 X2(Hydrated) ] 2/3

6(a) # 2XeF2 (s) + 2H2O(l) 2Xe (g) + 4 HF(aq) + O2(g)

6(b) # 6XeF4 + 12 H2O  4Xe + 2Xe03 + 24 HF + 3 O2
[Hydrolysis of XeF4 and XeF6 with water gives Xe03.]

7(a)# # C + 2H2SO4 (Conc.)  CO2 + 2 SO2 +2H2O

7(b)# # Cu + 2H2SO4 (Conc.) CuSO4 + SO2 +2H2O

8(a)# # 4 H3PO3  3 H3PO4 + PH3

8(b)# (NH4)2Cr2O7 —(Heat ) - N2 + Cr2O3 +H2O
8(c)# HNO2 --(Heat)  HNO3 + H2O + 2NO
8(d)# PCl5 + Heat  PCl3 + Cl2

9(a)# Cu + 2H2SO4 (Conc.) CuSO4 + SO2 +2H2O

9(b)# Cu + 4 HNO3( conc.) Cu(NO3)2 + 2NO2 +2H2O

10(a)# XeF6 + 3 H2O  XeO3 + 6 HF

10(b)# XeF6 + H2O  XeOF4 + 2 HF [Partial hydrolysis of XeF6 gives oxyfluorides, XeOF4 and XeO2F2]
10(c)# XeF6 + 2 H2O  XeO2F2 + 4HF

11(a)# XeF2 + PF5 [XeF]+ [PF6]– ;

11(b)# XeF4 + SbF5 [XeF3]+ [SbF6]–
11(c)# XeF6 + MF M+ [XeF7]– (M = Na, K, Rb or Cs)

12(a)# Ca3P2 + 6H2O  3 Ca(OH)2 + 2 PH3

12(b)# P4 + 3NaOH + 3 H2O  PH3 + 3 NaH2PO2
13(a)# 2 Fe3+ + SO2 + 2H2O  2 Fe2+ + SO4 2ˉ + 4 H+
13(b)# 5 SO2 + 2 MnO4 ˉ + 2 H2O  5 SO4 2ˉ + 4 H+ + 2 Mn2+

14(a)# P4 + 8 SOCl2  4 PCl3 +4 SO2 + 2 S2Cl2

14(c)# P4 + SO2Cl2  4 PCl5 + 10 SO2

15(a)# 3CuSO4 +2PH3  Cu3P2 + 3 H2SO4

15(b)# 3HgCl2 +2 PH3  Hg3P2 + 6 HCl

16(a)# Cu2+ (aq) + 4 NH3(aq) [Cu(NH3)4]2+(aq)

(blue) (deep blue)
16(b)# AgCl (s) + 2 NH3(aq) [Ag(NH3)2] Cl (aq) {colourless soluble complex}

17(a)# NH4Cl(aq) + NaNO2 (aq)  N2(g) +2H2O (l) + NaCl (aq)

17(b)# (NH4)2Cr2O7+Heat N2 + 4H2O + Cr2O3
17(c)# Ba(N3)2  Ba + N2

18(a)# PCl3 + H2O  H3PO3 + 3 HCl

18(b)# PCl5 + H2O  POCl3 + 2 HCl
└> + H2O H3PO4 + 3 HCl

19(a)# C2 H5 OH + PCl5 C2 H 5Cl + POCl3 + HCl

19(a)# CH 3COOH + PCl5 CH3 COCl + POCl3 +HCl

20(a)# 2Ag (Finely divided )+ PCl5 2AgCl + PCl3

20(b)# Sn(Finely divided ) + 2PCl5  SnCl4 + 2PCl3

21(a)# NCl3 + H2O  NH3 + 3 HOCl

21(b)# PCl3 + H2O  H3PO3 + 3 HCl

22(a)# 2FeSO4 + H2SO4 + Cl2 → Fe2(SO4)3 + 2HCl

22(b)# Na2SO3 + Cl2 + H2O → Na2SO4 + 2HCl
22(c)# SO2 + 2H2O + Cl2 → H2SO4 + 2HCl

23(a)# Cl2+F2 [437K]→2ClF;

(equal volume)
23(b)# Cl2 + 3F2 (excess) [573K ]→2ClF3 ;

24(a)# I2 +3Cl2 [437K]→2ICl3;

24(b)# I2 +Cl2 (equimolar)→2ICl

25(a)# Br2 + 3F2 →2BrF3

(Diluted with water)
25(b)# Br2 + 5F2 →2BrF5
(excess)

26(a)# 2 Na2S2O3 + I2  Na2S4O6 + 2 NaI

26(a)# Na2S2O3 + 4 Cl2 +5 H2O  2 NaHSO4 + 8 HCl
 R E A C T I O N S O F p-B L O C K E L E M E N T S
by A. K .Panda, PGT (Chem)
,KV NO-3 BBSR
Balance and Complete the following :-
(1) Cl2 + NaOH (hot and conc.)  (2) F2 + H2O 

(3) XeF2 + PF5  (4) XeF6 + NaF 

(5) Au + Aqua Regia  (6) Cu + Conc.HNO3 

(7) C12H22O11 + Conc.H2SO4  (8) SO2 + MnO4ˉ + H + 

(9) PbS + O3  (10) CH3COOH + PCl5 

(11) Ca3P2 +H2O  (12) I2 + conc. HNO3 

(13) Cu + Dil. HNO3  (14) Cu + Conc.H2SO4 

(15) Ca(OH)2 +Cl2  (16) NaCl + MnO2 + H2SO4 

(17) HgCl2 + PH3 (18) U + ClF3 

(19) XeF4 + H2O  (20) XeF6 + H2O 

(21) KMnO4 + HCl  (22) KI (aq) + H2O(l) + O3 (g) 

(23) CuSO4 + NH3  (24) PCl5 + H2O(excess) 

(25) (NH4)2Cr2O7 --(heat) (26) P4 + NaOH +H2O 

(27) Al2O3 + NaOH + H2O  (28) HCl + O2 + CuCl2(Catalyst)

(29) XeF2 (s) + H2O (l)  (30) NH3 + Cl2 (excess) 

(31) Fe3+ + SO2 + 2H2O  (32) Br2 + KI 

(33) Cl2 + H2O  (34) NaOH + SO2 
(35) SO2 + MnO4ˉ + H+  (36) Fe + HCl 
(37) Cl2(g) + NaI(aq)  (38) Na2S2O3 + I2 
(39) Na2S2O3 + Cl2 + H2O  (40) ClF + H2O 
(41) XeF4 + O2F2  (42) Cl2 + NaOH (cold and
dil.) 
(43) NH3 (excess) + Cl2  (44) SO2 + V2O5 
(45) H3PO3 + Heat  (46) SF4 + H2O 
(47) Al2O3 + HCl + H2O  (48) HNO3 + P4O10 
(49) NH4NO3 + Heat  (50) AgCl + NH3 
(51) NaN3 + Heat  (52) Ag + PCl5 
(53) PCl3 + H2O  (54) Zn + dil. HNO3 