INSTITUT PERTANIAN BOGOR Name

PROGRAM PENDIDIKAN NIM

KOMPETENSI UMUM Group
CHEMISTRY MIDTERM Signature
ODD SEMESTER, 2018/2019
Date: Friday, 26 October 2018
Time: 120 minutes

“STUDENTS INVOLVED IN CHEATING WILL RECEIVE A FAILING GRADE FOR THIS TEST"

T-F-S: Cross T if the statement is true, info is false, or S if the statement is not always true or false.
1. T — F — S A hypothesis is a consistent explanation of a set of observations.
2. T — F — S A limiting reagent is an agent that is completely consumed in a reaction.
3. T — F — S A covalent bond is a bond formed from the same atoms.
4. T — F — S Gas condensation is an example of a deviatlon from an ideal gas.
5. T — F — S A change from one phase to another phase results in the release of energy.
6. T — F — S IM of NaOH is the same as the concentration of lm of NaOH.
7. T — F — S The freezing point of salt water is lower than that of pure water.
8. T — F — S Thermal energy is the energy available by virtue of an object’s position.
9. T — F — S A reaction will proceed spontaneously when AH, AS, and AG all have negative
values.
10. T — F —
The reaction CH3COOH (pq) + HzO(¿) N CH3COO ,) + H 0+ ,2) is a
S
homogeneous equilibrium.
Multiple Choice 15. The correct coefficients to balance the
Put an x for the correct answer on the provided following equation consecutively is. ......
answer sheet! Cu + HNO3 Cu(NO )2 + NO + HzO
11. Which of the following substances is not a A. 1, 2, 4, 3, 1 D. 3, 6, 3, 3, 3
pure substance? B. 2, 4, 5, 2, 1 E. 2, 6, 2, 3, 3
A. Fe C. H2O ) E. NAOH C. 3, 8, 3, 2, 4
B. He (g) D. NkCl (s) (aq)
16. For the following reaction:
12. A plece of iron with mass of 0.6 g with CH OH Ot D C 2 + HCO
volume of 0.12 mL will have density of When this reaction is balanced 1 mol of CO2
g/mL formed will correspond with....
A. 0.5 B. 2 C. 4 D. S E. 6 A. 2 mol of CH OH
B. 3 mol Of 0 2
13. The following process is considered as a C. 1 mol of CH3OH
physlcal change.... D. 0.5 mol of 0 2
A. Exploding firework D. water electrolysis E. 1.5 mol of 2
B. Rusting iron E. Electroplating
C. Melting iron 17. As much as 29 g of an organic compound
(CyHy) Was burned to give 88 g of COz and
14. The ratio between neutrons and protons in 2 U 45 g of HCO. The empirical formula of this
is....
A. 0.39 C. 1.59 E. 2.59 compound
B. 0.63 D. 1.63 is... C. CzHb E. C 4H 10
A. CH4 D. C3H
B. CtHt io
18. 5 g CaCO3 is reacted with 1 L HCl 1 M 24. The compound which is in a gas phase at a
according to the following equation: temperature of 25 °C and a pressure of 1 atm
C@CO3 p) + 2HCl O CaCl2 (aq) + H@O$qq) “ is. . .
CO 2(g) A. H Ot CCHP E. HN 3
The limiting reagent is B. NH4 D LiF
A. CaCO3 C. CaC 2 E. CO
B. HCl D. H2O 25. A factor that causes a molecule to have high
viscosity is...
19. Fluoride acid is made through the following A. A high boiling point
reaction: B. A high melting point
CaF2 * H2SO4 CaSO4 + 2HF C. A strong dispersion force
In an experiment where sulfuric acid is in D. A weak dispersion force
excess, 97.5 g of CaF produces 47 g of HF. E. A strong intermolecular force
The percent yield of this experiment is...
A. 98% C. 96% E. 94% 26. If a light bulb filled with argon at 1.20 atm
B. 97% D. 95% and 18 °C is heated to 85 °C at constant
volume, then the final pressure of argon
20. The correct Lewis symbol for elements in inside the light bulb is
group VA is: A. 1.48 atm C. 0.25 atm E. 7.08 atm
A C E B. 0.98 atm D. 5.77 atm

B D 27. The fusion curve in the following picture is

shown by...
21. The bond that is formed between Ca and Cl
in
CñC z is....
A. An ionic bond because there is a shared
electron
B A covalent bond because there is a shared
electron A. Line 1—4 D. Point 3
C An ionic bond because the Ca atom B. Line 2-4 E. Point 4
donates its electron to the Cl atom C. Line 3—4
D. A covalent bond because the Ca atom
donates its electron to the Cl atom
E. A polar covalent bond because Ca 1s an 28. The solute in a solder solution is
electropositive atom and Cl is an A. Sn C. Pb E. Cr
electronegative atom B. Ag D. Zn

22. The group of three compounds with covalent 29. The solubility of compound X in water at 25
bonds is... °C and at a pressure of 1 atm is 35 g/L. When
A. HCI, SC , BaC 2 D. H 2 O, SO2› OF2 175 g of compound X is dissolved in 5 L of
B. HBr, NaF, Lil E. CaO, LizO, MgO water at the same temperature and pressure,
C. HIS 4› KOH, Kz$O4 then the obtained solution 1s a solution.
A. Diluted D. Unsaturated
23. The moment dipoles of NH3, HCO, SOA, B. Supersaturated E. Concentrated
HC1 are 1.46; 1.87; 1.60; 1.08, C. Saturated
consecutively. The
correct order for polarlty is
A. NH3 HCO > SO2 > 30 The molallty of a 6.58 M of ethanol
HC1 (CH CH OH) solution with density of 0.927
B. NH3 H2 < S 2 HCl
C. H2O > SO2 > NH HC1 E. H2O > HCl > NH3
D. HzO < SO2 < NH3 HCI SOA
g/mL is ....
A. 0.001 m D. 0.1 m
B. 10.54 m E. 7.10 m
C. 0.0892 m
Cause and Effect Multiple Choice.
The following problems consist of three parts, the STATEMENT, the word BECAUSE, and the REASON,
which are written consecutively.
Answer criteria.
A. If the statement is correct, the reason is correct, and both statement and reason have a cause and
effect relationship
B. If the statement is correct, the reason is correct, but both the statement and reason DO NOT have a
cause and effect relationship
C. If the statement is correct, and the reason is wrong
D. If the statement is wrong, but the reason is correct
E. If both the statement and the reason are wrong

41. MO1 is an lntenslve property 46. The size of cells in an isotonic solution will
BECAUSE remain relatively unchanged
Two substances with the same number of BECAUSE
moles contain the same number of atoms or An isotonic solution has a balanced amount
molecules of solute and solvent inside and outside of the
cells
42. The reaction coefficient of reactants and
products of a chemical equation must be The melting process of ice has a positive
entropy value
47. BECAUSE
balanced The melting of ice follows the first law of
BECAUSE thermodynamics
Chemlcal equations must obey the law of
mass conservation

43. NH3 is an example of a polar compound
BECAUSE
The arrangement of the electron pairs of NH3
is tetrahedral
44. Solid CO will not melt when it is heated at a
temperature of 80 °C and a pressure of 1 atm
BECAUSE
Liquid CO2 only forms when the pressure is
more than 5.2 atm
45. The boiling point of water is lower than the
boiling point of H2S
BECAUSE
H2S has a molecular mass bigger than that of
water.
48. The reaction of AB2 A + 2B has A// < 0
BECAUSE
In this reaction, energy is absorbed
49. The reaction of CaCO3(s) CaO ,) CO2(g)
has the value of Kp — P CO2
BECAUSE
The Kp value is not influenced by solids
50. An equilibrium reaction of CO(g) + C 2(g)
COC1 g) will have a Kc value equal to the
Kp value
BECAUSE
The An of that reaction is equal to 0
31. Based on the pictures below, the solution with 36. At an equilibrium process the following is
the lowest freezing point is.. . true. . . .
A. AG < 0 D. AG > 0
B. AG = 0 E. AH < 0
C. AH > 0

37. For the following reaction:

Note: • = mol of solute particles Ca(HCO j)2( ) CaO‹ ) 2 CO (g) + H2 (g)-
o = mol of solvent particles The equilibrium equation is ....
A. I B. II C. III D. IV E. V
N O CO 2 CaO
2 2
K =
32. Which of the following is an example of a A. Ca(HC@ 21
system that allows the movement of energy 2
[CO J [CaO
and K
mass? —— 2

A. A capped bottle D. Battery B [Ca(HCO )

B. A refrigerator E. A thermos [CaO
C. A swimming pool C K ——)Ca(HCO3 ) 2 ]
2
2.04 mol of aluminum metal with a specific D‘ K —— C P 2 J Hp O 2
heat of 0.903 J/g °C has an initial temperature \co
of 27.5 °C. If the aluminum metal receives K
—— Ca(HCO )
725 J of heat, the final temperature of the E.
metal will
be....
A. 41.8 °C 38. If the known equilibrium constant for the
D. 41.1 °C
reaction of H2 * 12 2HI is 50 at 600 K, then
B. 42.1 °C E. 421.5
C. 315 °C °C the equilibrium constant for HI ki H2 + ' 12

34. The known data is as follows: A. 50 C. 25 E. 0.282

S(s) + 3/2 Oz (g) SOA (s) EH' 395.2 kJ B. 100 D.
2SO2 (g) * 0 2 (g) 2S 3 (s) AH = —198.2 kJ
0.141
Determine the AH of the following reactlon: 39. At a temperature of 923 °C, the reaction of
2NO@ (g) + 0 2 ( g) 2NOj g) has a Up value of
A. 1.2 kJ D. 390 kJ 56.1. The K, value of that reactlon at the
B. —197 kJ E. —296.1 same temperature is...
C.—593.4 kJ kJ A. -21.25 C. 0.15 E. 5501
B. 1.32 D. 0.57
35. If 207 g of ethanol (CzH6O) is evaporated at
its normal boiling point, at 61.3 °C, and the 40. The formation reaction of HF from hydrogen
molar enthalpy of evaporation at this and fluorine has a K value of 0.43 at a certain
temperature is temperature. If 3 mol of each species are put
28.5 kJ/mol, then the entropy for this process in a 1.5 L container, then the reactlon will
is....
A. 223.58 J/K D. 399.67 A. Have Q > A
B. 383.64 J/K J/K B. Be at equilibrium
C. 287.17 E. 157.93 J/K C. Not shift
D. Shift toward HF
J/K
E. Shift toward He and Ft
Complex Multiple Choice A. If(1), (2), and (3) are correct
Read carefully the choices numbered (1) B. If(1) and (3) are correct
through (4). Cross.’ C. If(2) and (4) are correct
D. If only (4) is correct
 E. IfALL are correct
51. Chemical and physical changes can occur
in our daily life. The following processes
that can be said to be chemical changes
is/are...
(1) A stone building becoming brittle
when exposed to air, water, or acid.
(2) The melting process of ice to water.
(3) The burning process of wood to
become charcoal.
(4) Moth balls (naphthalene balls) that
subllmate when exposed to open air.
52. The correct statement about the Rutherford
experiment is/are...
(1) It used alpha rays
(2) Lots of alpha rays were deflected
(3) It used a gold plate
(4) It is the basis of the plum pudding
atomic model
53. The organic compound propanoic acid has
the formula of CH3<H2COzH
(1) The element with the smallest percent
mass is O
(2) Its molar mass is 88 g/mol
(3) lg of propanoic acid contains more C
atoms than H and O atoms,
(4) Its empirical formula is the same as its
molecular formula
54. Based on the VSEPR theory, the
compound(s) or ion(s) with linear geometry
is/are...
(1) SO2
(2) IFz°
(3) HzO
(4) BeCl2
55. The pair(s) of molecules with their correct
molecular geometry is/are...
(1) BF3 and NH3 — trigonal planar
(2) BeC1 and C 2 — linear
(3) SO2 and H2O — linear
(4) NH3 and PCl — trigonal pyramid
56. The correct statement(s) about “the
Kinetics Molecular Theory of Gases” is/are
...
(1) Gas molecules always move in a
certain direction
(2) Gas molecules exert an attraction
or repulsive force on one another
(3) The kinetic energy of gas molecules
is inversely proportional with
temperature
(4) A gas is made up of molecules that
are separated from each other by
distances smaller than their own
dimensions
57. Strong electrolyte compound(s) is/are...
(1) HCI
(2) CH3OH
(3) NaOH
(4) CtH12O 6
58. The correct statement(s) about the
solubility of a solld compound in a solvent
is/are....
(1) The solubility of a solid compound
increases at lower temperature
(2) The solubility of a gas in liquid is
inversely proportional with the gas
pressure above the liquid
(o) A saturated solution contains the
amount of solid compound higher than
its solubility value
(4) The solubility of a gas will increase at
lower temperature
59. The First Law of Thermodynamics is
associated with....
(1) Degree of disorder
(2) The orderliness of pure crystal
(3) Direction of a spontaneous change
(4) The law of conservation of energy
60. For the reaction Nz «, ) 2NO2(g) with AH =
56.9 kJ, the amount of N2O, can be
increased by. . . .
(1) Increasing the pressure
(2) Increasing the volume
(3) Lowering the temperature
(4) increasing the concentration of N2O4
Short Fill in the Blanks
Fill the questions below with the correct short answers!
61. Elements of A and B form 4 binary compounds K, L, M, and N. The mass ratio of A combined
with 1.0000 g of B in compounds K, L, M, and N is 1:3:4:5. If the molecular formula of
compound M is A2B3, then the molecular formula of compound N is.......
62. The average atomic mass of Lithium is 6.941 amu. Lithium has two isotopes: 6Li and 7Li. The
atomic mass of Li isotope is 6.015 amu with a natural abundance of 7.42%. The atomic mass of
7
Li isotope is .......
63. Hydrogen (H) and Sulphur (S) atoms have electronegativity values of 2.1 and 2.5, respectively.
The type of bonding they will form is........
64. The intermolecular forces that occur when CC J4 1s mixed with CHP (CH 2)4CH3 is. ......
65. The deeper someone dives, the higher the solubility of gas inside the blood, which is the
application of which law?
66. Measurement of energy using a bomb calory meter is done at constant .....

67. 1 mol of gas A and 1 mol of gas B are added to a closed container with a volume of 1 L,. Those
gases then react according to the following reaction: 2A + 3B A B3. When the equilibrium
conditlon 1s reached, there is still 0.25 mol of gas B left unreacted. The value of Kc for this
reaction is .......
 18
IA VIIIA

PERIODIC TABLE 2
H 2 13 14 15 16 17 lie
i.oozo IIA IIIA IVA VA VIA VIIA 4.003

4 5 6 7 8 9 10
Li Be B C N O F Ne
6.940 9.013 1fl R2 12,011 14 008 16.000 19.60 20.183

11 12 13 14 15 16 17 18
Na Mg 3 4 5 6 7 8 9 10 11 12 Al Si P S Cl Ar
22 991 24 32 I HR IVR VB VII VII B VI HB VI HB VIIIR IB II B 26.95 28 09 TO.975 32 066 35 457 29 944

19 20 21 22 23 24 25 26 27 28 ?9 30 31 32 33 34 35 36
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
39.100 40.08 44.96 47.90 50.95 52.01 54.94 55.85 58.94 58.71 63.54 65.38 69.72 72 60 74 9 I 78.96 79.916 83.80

37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54
Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
85.48 87.63 88.92 91.22 92.91 95.95 99 101.1 l 02.91 106.4 107.58 1 l 2.41 114.87 I 18.70 121.87 127 126.91 131.30

55 56 57 72 73 74 75 76 77 75 79 80 81 82 83 84 85 86
Cs Ba •La Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
132.9 I 137.36 138.92 178.50 180.95 183.86 186.22 190.2 192.2 195.09 I 97.0 200.61 204.39 207.21 209.00 210 210 222

87 86 89 104 105 106 107 108 109

Fr Ra ‘Ac Unq Unp Unh Uns Uno Une
*23 226 2*7 257 260 263 262 265 266

*Lan4anida 58 59 60 61 62 63 64 65 66 67 68 69 70 71
Ce Pr Nd Pm Sm Eu Gd Tb Dy fIo Er Tm Yb Lu
140 13 140.92 I <^ °7 l5lL35 15 0 157 26 158 93 1 62 51 I ñ4 94 lfi7 7 1 fi8 9d 1 78 fl4 174 99

‘Aktinida 90 91 92 93 94 95 96 97 98 99 100 101 102 103

Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lw
INSTITUT PERTANIAN BOGOR 2018/2019
DIREKTORAT PROGRAM DATE: Friday, 26 OCTOBER 2018
PENDIDIKAN KOMPETENSI UMUM (PPKU) Time: 120 minutes

PPKU CEMISTRY MIDTERM ODD SEMESTER

 Name NIM Class Signature

Directions:
1. Put an X on your answer choice on the answer sheet. If you want to change the answer, put a double line on your old answer (}, and
cross your new answer.
2. Use a black/blue ballpoint to answer. It is not allowed to use pencil nor to making lots of corrections
using tip-x.
1. T F PUT AN
S X FOR THE CORRECT 6.ANSWER
T TF — F —
S S
2. T F S 7. T F S
3. T F S 8. T F S
4. T F S 9. T F S
5. T F S 10. T F S
Multiple Choice
11. A B C D E 26 A B C D E
12. A B C D E 27 A B C D E
13. A B C D E 28 A B C D E
14. A B C D E 29 A B C D E
15. A B C D E 30 A B C D E
16. A B C D E 31 A B C D E
17. A B C D E 32 A B C D E
8. A B C D E 33 A B C D E
19. A B C D E 34 A B C D E
20. A B C D E 35 A B C D E
21. A B C D E 36 A B C D E
22. A B C D E 37 A B C D E
23. A B C D E 38 A B C D E
24. A B C D E 39 A B C D E
25. A B C D E 40 A B C D E
Additional Data:
R = 0,0821 L atm/mol K = 8,314 I/mol K

PJU 1 PJU 2 Coordin,ator

2
Name/NIM:.....................................................

Cause and Effect Multiple Choice

41. A B C D E 46 A B C D E
42. A B C D E 47 A B C D E
43. A B C D E 48 A B C D E
44. A B C D E 49 A B C D E
45. A B C D E 50 A B C D E
Complex Multiple Choice
51. A B C D E 56. A B C D E
52. A B C D E 57. A B C D E
53. A B C D E 58. A B C D E
54. A B C D E 59. A B C D E
55. A B C D E 60. A B C D E

Short Fill in the Blanks

61. .........

62. ..............................................................................................................................................

63

64

65. ........

66. ..............................................................................................................................................

67. .........

Best Wishes for a Successful

Exam

Coordinator