Manganese violet

Manganese violet is the common name for ammonium

manganese(III) pyrophosphate, an inorganic compound composed of Manganese violet
ammonium (NH+4), manganese in the +3 oxidation state, and the
pyrophosphate anion (P2 O4−
7 ). It is prepared by heating a mixture of
manganese(III) oxide (Mn2 O3 ), diammonium phosphate, and
phosphoric acid. This material is a popular inorganic pigment.[1]

Contents
Chemical structure
Spectra
Use
See also
References
Names

Chemical structure Other names

ammonium manganese(III)
Two polymorphs are known, referred to as the α- and β-forms, but in pyrophosphate
each case the structures are similar. The Mn(III) centres occupy Identifiers
distorted octahedral sites, being surrounded by six oxygens provided
CAS Number 10101-66-3 (http://w
by the pyrophosphate ligands.[2]
ww.commonchemistr
y.org/ChemicalDetai
Spectra l.aspx?ref=10101-66
-3)
IR-spectra, reflectance, and fluorescence spectra can be found at
ColourLex.[3] 3D model Interactive image (ht
(JSmol)
tps://chemapps.stola
f.edu/jmol/jmol.php?
Use model=%5BN%2BH
4%5D.%5BMn%2B
Manganese violet is used in eye liner pencils, eye shadow, lipstick,
nail enamel, and oil paint.[4] 3%5D.O%3DP%28%
5BO-%5D%29%28%
5BO-%5D%29OP%2
See also 8%5BO-%5D%29%2
List of inorganic pigments 8%5BO-%5D%29%3
DO)

References ChemSpider 141372 (http://www.

chemspider.com/Ch
1. Hugo Müller, Wolfgang Müller, Manfred Wehner, Heike emical-Structure.141
Liewald "Artists' Colors" in Ullmann's Encyclopedia of 372.html)
 Industrial Chemistry 2002, Wiley-VCH, Weinheim. ECHA 100.030.221 (https://
doi:10.1002/14356007.a03_143.pub2 (https://doi.org/10.10 InfoCard echa.europa.eu/sub
02%2F14356007.a03_143.pub2) stance-information/-/
2. Yasmin Begum, Adrian J. Wright "Relating highly distorted substanceinfo/100.0
Jahn–Teller MnO6 to colouration in manganese violet
30.221)
pigments" J. Mater. Chem., 2012, vol. 22, pp. 21110–
21116. doi:10.1039/c2jm33731b (https://doi.org/10.1039% EC Number 233-257-4
2Fc2jm33731b)
PubChem 160915 (https://pubc
3. Manganese violet, at ColourLex (https://colourlex.com/proj CID
hem.ncbi.nlm.nih.go
ect/manganese-violet/)
v/compound/16091
4. "Household Products Database - Health and Safety
Information on Household Products" (https://hpd.nlm.nih.go 5)
v/cgi-bin/household/brands?tbl=chem&id=1166). UNII 72M48QQV8Q (http
hpd.nlm.nih.gov.
s://fdasis.nlm.nih.go
v/srs/srsdirect.jsp?re
gno=72M48QQV8Q)
CompTox DTXSID70889526 (h
Dashboard
ttps://comptox.epa.g
(EPA)
ov/dashboard/DTXSI
D70889526)

InChI
InChI=1S/Mn.H3N.H4O7P2/c;;1-8(2,3)7-9(4,
5)6/h;1H3;(H2,1,2,3)(H2,4,5,6)/q+3;;/p-3
Key: UHHXUPJJDHEMGX-UHFFFAOYSA-K

SMILES
[N+H4].[Mn+3].O=P([O-])([O-])OP([O-])([O-])=
O

Properties
Chemical NH4MnP2O7
formula
Molar mass 246.885
Appearance violet solid
Except where otherwise noted, data
are given for materials in their
standard state (at 25 °C [77 °F],
100 kPa).
Infobox references

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