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ϕ2 P2

V́ i 1
TECNOLÓGICO NACIONAL DE MÉXICO
Instituto Tecnológico de Toluca
∫ d ( lnϕ )=∫
ϕ1 P1
( RT P
− dP)
FISICOQUÍMICA II ln P= ( −∆R H )( T1 )+( ∆RH T1 ) b

Alumnos: Saúl Garduño Benítez


B
Darío Mergruen Uribe log P °= A−
t +C

Actividad: Ejercicio de cinética química


( ∂∂ TP ) ( ∂∂VT ) ( ∂V
V P ∂P)
=−1
T

The gaseous phase decomposition of ethylene oxide produces ethane and carbon monoxide at 414.4 °C. The
following data were obtained:

Time (min) Pressure (mmHg)


0 116.510
5 122.560
7 125.720
9 128.740
12 133.230
18 141.370
Determine:

A) The reaction rate equation


B) The reaction order and the reaction rate coefficient
C) The half-life time of the ethylene oxide
D) The molar conversion after one hour

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