EJERCICIO 2

BALANCE DE MATERIA:

ENTRADA-SALIDA= ACUMULACION

ENTRADA- SALUDA= 0

N A r |r S−N Ar |r+ ∆ r S=0

N Ar |r r−N Ar |r +∆ r r
=0
∆r

d
dr
( r N Ar ) =0

APLICANDO LA LEY DE FICK

d XA
N A r=c D AB ( )
dr
+ X A ( N Ar + N Br )

−c D AB d X A
N A r=
1− X Ar dr( )
SUSTITUYENDO LA ECUACION:

d c D AB d X A
dr (
−r
1−X Ar dr ( ))
=0

CONSIDERANDO c D AB CONSTANTES:

d r d XA
(
dr 1−X Ar dr
=0( ))
INTEGRANDO:
 r d XA
( ( ))
1−X Ar dr
=C 1

d XA C1
( 1−X Ar
=
r )
dr

INTEGRANDO:

1
ln =C 1lnr +C 2
1−X Ar

CONDICIONES LIMITE :

CL1: r=R1 ; XA=XA1

CL2: r=R2 ; XA=XA2

1
ln =C 1 lnR 1+C 2
1−X Ar 1

1
ln =C 1 lnR 2+C 2
1−X Ar 2

RESOLVIENDO EL SISTEMA DE ECUACIONES:

1−X Ar 2 R1
ln
1−X Ar 1
=C 1 ln
R2 ( )
( 1−X Ar 2 )

C 1=
ln
[ ( 1−X Ar 1 ) ]
ln ( RR 12 )
( 1− X Ar 2 )
C 2=ln
1
1−X Ar 1
−ln
[
( 1− X Ar 1 ) ]( lnR 1
ln
R1
( )
R2 )
SUSTITUYENDO EN LA ECUACION GENERAL:
 ( 1−X Ar 2 )
( 1− X Ar 1 )
ln
[ ( 1−X Ar 1 ) ]
ln
[ ( 1− X A r )
=ln
] r
R1 ( ) ln ( RR 12 )

APLICANDO CAMBIO DE VARIABLE:

( 1−X Ar 2)
ln
[ ( 1−X Ar 1) ] =∅
R1
ln( )
R2

( 1− X Ar 1 ) ∅
ln
[ ( 1− X Ar ) ]
=ln
R
r
1 ( )

( 1−X Ar 1 ) ∅

[ ( 1−X Ar )
=
](
r
R1 )

VELOCIDAD:

W Ar =2 π rL N Ar

−c D AB d X A
N Ar =
1−X Ar dr ( )
DESPEJANDO XA:

1 X Ar r ∅
− =
1−X Ar 1 1−X Ar 1 R 1 ( )
 − X Ar r ∅ 1
=
1−X Ar 1 R 1 ( )
−
1−X Ar 1

d X Ar −∅ −(∅ +1)
−1
1−X Ar 1 dr ( )= −∅ r
R

d X Ar (1−X Ar 1)∅ −(∅+1 )

( )dr
=
R
−∅
r

−c D AB (1−X Ar 1)∅ −(∅ +1)

N Ar = r
1−X Ar R
−∅

( 1−X Ar 1) r−∅ −1
N Ar =−c D AB ∅r
1−X Ar R 1

( 1−X Ar 2 )

N Ar =
−c D AB
ln
[ ( 1− X Ar 1 ) ]
r
ln ( RR 12 )
( 1− X Ar 2 )

W Ar =2 πrL
c D AB
ln
[ ( 1− X Ar 1 ) ]
r
ln ( RR 12 )