CHEMISTRY

SINGLE CORRECT TYPE

Q.1 Consider the following conversion and calculate the net energy change for the following conversion:
NaCl  s   H2O  Na  aq   Cl   aq 
Given are the magnitudes of different energies:
LE of NaCl = x kJ/mol
HE of Na+ = y kJ/mol
HE of Cl- = z kJ/mol
(A)  x  y  z  kJ/mol (B)  x  y  z  kJ/mol

(C)  x  y  z  kJ/mol (D)  x  y  z  kJ/mol

Q.2 Select the correct order :

(A) Na3 N > Mg3 N2 > AlN  Latticeenergy 

(B) Na   g  < Mg2  g  < Al3  g  Ionic radius 

(C) Li  aq  > Na   aq  > K  aq  Hydrated ion radius 

(D) F  aq  > Cl  aq  > I  aq  Ionic mobility 

Q.3 Iodine molecules are held in the solid lattice by ……………

(A) London forces (B) dipole-dipole interactions
(C) covalent bonds (D) coulombic force

Q.4 Which of the following is arranged order of increasing boiling point :

(A) H2O  CCl4  CS2  CO2 (B) CO2  CS2  CCl4  H2O

(C) CS2  H2O  CO2  CCl4 (D) CCl4  H2O  CO2  CS2

Q.5 Select the correct reason for given statement “Flouride of Al is ionic while chloride of Al is
covalent”
(A) IEof Alin AlF3 >AlCl3 (B) EA of Flourine > Chlorine

(C) Lattice energy of AlF3  AlCl3 (D) EA of Flourine < Chlorine

Q.6 Which of the following has largest bond angle?

 (A) PH3 (B) PF3 (C) NF3 (D) NH3

Q.7 Which of the following bond has max % s character :

(A) Sb – H bond in SbH3 (B) N – H bond in NH3
(C) H – Te bond in H2 Te (D) All have equal%S – Character.

MULTIPLE TYPE
Q.8 Select the correct statement(s)
(A) The total no. of 3c-2e bonds in the dimer of AlCl3 is 2
(B) MgCl2 is linear while SnCl2 is angular
(C) Cl2>F2 (Bond energy)
(D) HI>HBr>HCl>HF (order of acidity)

Q.9 Which of the following combination of bond pair (b.p.) and lone pair (l.p.) give same shape?
(i) 3 b.p. + 1 l.p. (ii) 2 b.p. + 2 l.p. (iii) 2 b.p. + 1 l.p. (iv) 2 b.p. + 0 l.p.
(v) 3 b.p. + 2 l.p. (vi) 2 b.p. + 3 l.p.
(A) (ii) and (iii) (B) (iv) and (v) (C) (iv) and (vi) (D) (iii) and (vi)

Q.10 Which of the following species fails to exist ?

(A) H4S (B) PH5 (C) H6S (D) NH5

1 2 3 11 21 31 41

Q.11 F2 C  C  C F2 F2 C  C  C  C F2
'X ' 'Y '
(A) Dipole moment of Y is zero
(B) Y is a planar molecule
(C) In C-1 in X has C – F bonds in yz plane then the  nodal plane between C-1 and C-2 bond will
be yz plane, formed by sideways overlapping of px orbitals
(D) If C – F bonds of C – 11 in Y are in xy plane then C – F bond of C – 41 in it are in yz plane.

Q.12 Consider the following atomic orbitals :

 Which of the following statement(s) is/are correct regarding given orbital?
(A) It is a gerade atomic orbital
(B) It has zero nodal plane
(C) Circular electron density is present in „XY‟ plane
(D) Opposite lobes of orbital have same sign of wave function  ψ 

Q.13 Which of the following species is/are superoctet molecule?

(A) AlF3 (B) SiCl4 (C) XeF2 (D) ICl3

Q.14 Which of the following orbital(s) cannot form δ -bond?

(A) d x2  y2  orbital (B) d xy  orbital (C) d z2  orbital (D) Px  orbital

INTEGER TYPE
Q.15 The total no. of Non-axial d-orbitals which are used by the central atom for it‟s hybridization in the
following molecules is X. Find x + 1.
XeF2 , SF6 , PF3 , TeCl4 , PH3 , H2 S , NF3 , PCl3 F2 , ClF3 , PCl6

MATRIX TYPE
Q.16 Match the Columns :
Column - I Column – II

Molecular orbital formed has 1

(A) (P)
Nodal plane

Molecular orbital formed 2 Nodal

(B) (Q)
planes

Molecular orbital formed is HOMO

(C) (R)
of O2

Molecular orbital forms is HOMO

(D) (S)
of C2.

Molecular orbital formed has 0

(T)
nodal plane.
Q.17 Answer the following questions:
(P) The number of p  d bonds in S3O9

(Q) Find bond order in NO+

(R) The number of vacant hybrid orbitals which participate in the formation of 3-centre 2 electron
bonds i.e., banana bonds in diborane structure.
(S) The number of intramolecular H-bonds formed in a molecule of chloral hydrate.

(P) (Q) (R) (S)