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  • -CH · -C H ·: m/z = 327 m/z = 165

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    Trisno Afandi
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    The document shows the fragmentation pattern of an imidazol derivative compound with the molecular formula C14H11N2O and m/z of 342. When subjected to electron ionization at 70 eV, it loses a methyl group (-CH3) to form a fragment with m/z of 327, and it also completely decomposes through the loss of a phenylnitrene (-C6H5NO) to form a fragment with m/z of 299. Further fragmentation includes losing a cyclohexadienyl group (-C6H6) to form a fragment with m/z of 194.

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    fragmen ms intermediet 2

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    The document shows the fragmentation pattern of an imidazol derivative compound with the molecular formula C14H11N2O and m/z of 342. When subjected to electron ionization at 70 eV, it loses a methyl group (-CH3) to form a fragment with m/z of 327, and it also completely decomposes through the loss of a phenylnitrene (-C6H5NO) to form a fragment with m/z of 299. Further fragmentation includes losing a cyclohexadienyl group (-C6H6) to form a fragment with m/z of 194.

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    24 views2 pages

    -CH · -C H ·: m/z = 327 m/z = 165

    Uploaded by

    Trisno Afandi
    The document shows the fragmentation pattern of an imidazol derivative compound with the molecular formula C14H11N2O and m/z of 342. When subjected to electron ionization at 70 eV, it loses a methyl group (-CH3) to form a fragment with m/z of 327, and it also completely decomposes through the loss of a phenylnitrene (-C6H5NO) to form a fragment with m/z of 299. Further fragmentation includes losing a cyclohexadienyl group (-C6H6) to form a fragment with m/z of 194.

    Copyright:

    © All Rights Reserved
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    of 2

    N

    OH

    H OCH3

    m/z = 342

    70 eV

    OH

    H OCH3

    m/z = 342

    -CH3· -C14H10·

    N
    N
    OH
    OH
    N
    HN

    H O
    H OCH3

    m/z = 327 m/z = 165

    -CO
    N

    OH

    N CH

    m/z = 299

    -C6H5NO

    -C8H6N
    NH

    H m/z = 77

    m/z = 194

    Gambar IV.4 Pola fragmentasi dari senyawa turunan imidazol (3)

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