Professional Documents
Culture Documents
Chapter 3 MSW Disposal & Resources Recovery
Chapter 3 MSW Disposal & Resources Recovery
Incineration
Landfill
Sustainability of Landfills
4
Is a Landfill an Open Dump?
5
Is a Landfill an Open Dump?
6
The Dump
Impacts from Dumps
Landfill Gas
Rainwater
Odor, Dust, Noise
Polluted Surface
Water Surface Water
Leachate
Large enough to accommodate the SW needs of the area it serves (lifetime, 10 yrs, ...)
Compatible with the local SW management programs
Site must protect public health, safety, welfare, & environment
Minimize adverse impacts on surrounding area
Minimize adverse impacts on property value
Minimize impacts on traffic flow
Minimize potential for fire, spill, accidents
e.g. outside the 100 year flood plain
Far from airports (birds) - jet airports, other airports
Provide emergency response plan including notification, evacuation, & containment
procedures
Sanitary MSW Landfill Site selection
Land availability
Haul distance
Impact on SW management program
Soil conditions and topography
Geological conditions - unstable areas, seismic activity
Hydrologic conditions (surface and ground water)
Climatic conditions (rainfall and wind)
Environmental and ecological conditions
Public input and concerns
Potential use after closure
Characteristics of Landfill
1. Solid waste is placed in a suitably selected and prepared (lined) landfill site in a carefully
prescribed manner.
3. Wastes covered daily with soil, geo membranes, or other cover materials to
prevent lightweight wastes, dust, and odors from escaping and to discourage
vermin.
• At the end of each days operation a 150-300 mm of layer of cover material is placed over the
completed landfill.
• A completed lift, including the cover material is called a cell
Canyon/depression method
2. Chemical.
• Involve landfill material and biological conversion product.
2. Physical.
• Involve the gases and leachate.
8.3.4 Reactions - biological
• Biotransformation of organics into landfill gases and„liquids.
• Starting with aerobic, then followed by anaerobic processes.
• Occur aerobically for short period after deposition of solid
waste until the present of oxygen depleted.
• Main gas produce is CO2 during aerobic decomposition. Aerobic
process produces CO2 and H2O„.
• Once the O2 depleted, decomposition become anaerobicand
the organic matter is converted to CO2, CH4, NH3 andH2S.
8.3.4 Reactions - chemical
• Important chemical reaction occur:
1. Dissolution and suspension of material and biological product
in the liquid percolating through the waste.
2. Evaporation and vaporization of chemical compound and water
into the evolving landfill gas.
3. Sorption of organic compound into landfill material.
4. Dehalogenation and decomposition of organic.
5. Oxidation- reduction of metal.
6. Solubility of metal salts.
• Other than reaction occur between the waste, there also
reaction between organic compound and clay liner (affect the
structure and permeability).
8.3.4 Reactions - physical
Double liner
Example
• The lateral movement of gases produced in a landfill Can be controlled by installing vents made of
materials that are more permeable than surrounding soil.
• The spacing of vents depends on width of waste cells but usually varies from 18 to 60 m.
Outlet for Gas venting system
1) Physical transformation
2) Chemical transformation
3) Biological transformation
Physical Transformations
• The principal physical transformations that may occur in the
operation of solid waste management systems include:
– component separation
– mechanical volume reduction
– mechanical size reduction
1. Combustion (Incinerator)
Thermal processing with excess amounts of air.
Key products are N2, CO2, H2O, O2, Ash, and
Heat is generated (exothermic reactions)
Used for waste to energy plants
Chemical Transformations
2. Pyrolysis
Thermal processing in complete absence of oxygen (low temperature).
Endothermic reactions (heat is sucked by the reaction)
Organic fraction transforms into H2, CH4, CO2, trace gases, tar
3. Gasification
Thermal processing with less amount of air (high temperature).
Partial combustion of carbonaceous fuel to generate combustible fuel
gas rich in CO, H2, saturated hydrocarbons (CH4)
Internal combustion engine can be used to burn the combustible fuel
gas to generate energy
Energy Recovery from the Combustion of
Municipal Solid Waste (MSW)
– These plants can vary in size and can process between 25 and 3,000 tons per day depending on
their size and demand.
– All waste received at the facility is shredded into small pieces and fed into the incinerator. Steam
produced in the incinerator's boiler can be used to generate electricity or to heat nearby buildings.
– The residual ash and unburnable materials, representing about 10-20 percent of the original
volume of waste, are taken to a landfill for disposal.
– The ash created from the combustion process is collected from beneath and through a air
Pollution control system above so to prevent air pollutants from escaping.
Modular Systems
– Modular Systems burn unprocessed, mixed MSW. They differ from mass burn facilities in that they
are much smaller and are portable. They can be moved from site to site.
– Modular incinerator units are usually prefabricated units with small to medium capacities of
between 5 and 120 tons of solid waste per day.
– Due to their small capacity, modular incinerators are generally used in smaller communities or for
commercial and industrial operations.
– The majority of modular units produce steam as the sole energy product.
• The principle organisms involved in the biological transformation of organic waste are
bacteria, fungi, yeasts and actinomycetes.
• Biological Processes (used for the conversion of the organic fraction of MSW)
(1) Aerobic composting
(2) Anaerobic Digestion
(3) High-solid anaerobic Digestion
Biological Transformations
1. Aerobic Composting
•Decomposition of organic fraction of waste in presence of oxygen
• The rate of degradation is a function of these key factors: organic fraction in
waste, temperature, moisture content, and available nutrients
• Key reaction products include: resistant organic matter (containing lignin),
CO2, H2O, NH3, sulfates, and Heat
2. Anaerobic Digestion
• Decomposition of organic fraction of waste in absence of oxygen (an-aerobic)
• Key reaction products include: resistant organic matter, CH4 and CO2, H2S,
NH3, sulfates, and Heat
• Odor issues due to formation of methane
• CH4 and CO2 equally constitute about 99% of total gas production
• Resistant organic matter is a sludge with relatively high water content. Hence,
needs dewatering before disposal or transportation.
Biological Process of Composting: Aerobic
Aerobic Decomposition: is the process where organic matter is digested by
microorganisms under aerobic conditions resulting in a rise in temperature and the
formation of carbon dioxide and water in addition to humus-rich compost.
(1) Mesophilic - slightly rotted material exists, in which mainly bacterial degradation of
easily degradable substances takes place (~40oC)
(2) Thermophilic - fresh compost is produced where further degradation of easily
degradable materials as well as degradation of cellulose, (55oC–65oC)
(3) Cooling phase - Finished compost. A decrease in microbial activity and temperature
occur in this phase.
(4) Maturation phase - Matured compost. Very low microbial activity with further
formation of humid substances and stabilization take place.
Composting
It is an aerobic, biological process which uses naturally occurring microorganisms to convert biodegradable
organic matter into a humus-like product
• Onsite Composting
• Vermicomposting
• Aerated (Turned) Windrow Composting
• Aerated Static Pile Composting
• In-Vessel Composting
Onsite Composting
• Organizations that are going to compost small amounts of wasted food can compost
onsite.
• Composting can significantly reduce the amount of wasted food that is thrown away.
• Yard trimmings and small quantities of food scraps can be composted onsite.
• Animal products and large quantities of food scraps are not appropriate for onsite
composting.
Vermicomposting
• Red worms in bins feed on food scraps, yard
trimmings, and other organic matter to create
compost.
• The worms break down this material into high quality
compost called castings. Worm bins are easy to
construct and are also available for purchase.
• One pound of mature worms (approximately 800-
1,000 worms) can eat up to half a pound of organic
material per day.
• The bins can be sized to match the volume of food
scraps that will be turned into castings.
• It typically takes three to four months to produce
usable castings. The castings can be used as potting
soil.
Aerated (Turned) Windrow Composting
• Aerated or turned windrow composting is suited for large
volumes such as that generated by entire communities and
collected by local governments, and high volume food-
processing businesses (e.g., restaurants, cafeterias, packing
plants).
• This type of composting involves forming organic waste into
rows of long piles called “windrows” and aerating them
periodically by either manually or mechanically turning the
piles. The ideal pile height is between four and eight feet
with a width of 14 to 16 feet. This size pile is large enough to
generate enough heat and maintain temperatures. It is small
enough to allow oxygen flow to the windrow's core.
• Large volumes of diverse wastes such as yard trimmings,
grease, liquids, and animal byproducts (such as fish and
poultry wastes) can be composted through this method.
Aerated Static Pile Composting
• Aerated static pile composting produces compost
relatively quickly (within three to six months).
• It is suitable for a relatively homogenous mix of
organic waste and work well for larger quantity
generators of yard trimmings and compostable
municipal solid waste (e.g., food scraps, paper
products), such as local governments, landscapers, or
farms. This method, however, does not work well for
composting animal byproducts or grease from food
processing industries.
• In aerated static pile composting, organic waste
mixed in a large pile. To aerate the pile, layers of
loosely piled bulking agents (e.g., wood chips,
shredded newspaper) are added so that air can pass
from the bottom to the top of the pile.
In-Vessel Composting
• In-vessel composting can process large amounts of waste
without taking up as much space as the windrow method and it
can accommodate virtually any type of organic waste (e.g.,
meat, animal manure, biosolids, food scraps).
• This method involves feeding organic materials into a drum,
silo, concrete-lined trench, or similar equipment.
• This allows good control of the environmental conditions such
as temperature, moisture, and airflow.
• The material is mechanically turned or mixed to make sure the
material is aerated. The size of the vessel can vary in size and
capacity.
• This method produces compost in just a few weeks. It takes a
few more weeks or months until it is ready to use because the
microbial activity needs to balance and the pile needs to cool.
Biological Process of Composting: Anaerobic
Anaerobic digestion is a degradation of organic material by bacteria in the absence of
air (anaerobic). Thereby, the organic material is transformed into biogas, a renewable
and green energy. Four stages:
•Hydrolysis
◦ Cleavage of a chemical compound through the reaction with water.
◦ Insoluble complex molecules are broken down to short sugars, fatty acids and amino
acids.
•Fermentation (Acidogenesis)
◦ Products from hydrolysis are transformed into organic acids, alcohols, carbon dioxide
(CO2), hydrogen (H) and ammonia (NH3).
•Acetogenesis
◦ Organic acids and alcohols are converted into hydrogen (H2), carbon dioxide (CO2) and
acetic acid (CH3COOH). Therefore, oxygen is consumed and anaerobic conditions are
created
•Methanogenesis
◦ Methanogenic bacteria (methanogenesis), transform the acetic acid, carbon dioxide and
hydrogen into biogas.
Be oxygen free
Not contain
Have a constant inhibiting salt
solids loading (may be heavy
rate. metals or excess
ammonia)
Have sufficient
Be of adequate
nutrients
alkalinity, 1500 to
phosphorus and
7500 mg/L
nitrogen
Anaerobic Digester
Source: HOLLIGER
1. Airtight chamber, filled with green waste (2008)
Household
floating-drum
http://www.open2.net/blo
gs/media/blogs/Biogas_pla
nt_Kerala.jpg
digesters
Source: F.
HEEB
Portable
reactors form
the Indian
NGO BIOTECH
http://images01.olx.in/ui/4/96/20
http://colli239.fts.educ.msu.edu/wp- /67509620_1-Install-biotech-
content/uploads/2009/05/biotech2007cc.jpg [Accessed: 04.06.2010] portable-biogas-plants-and-
convert-food-waste-to-biogas-
Vazhuthacaud.jpg [Accessed:
04.06.2010] 71
Examples: Large-scale digesters
http://www.klima-sucht-schutz.de/mitmachen/klima-
quiz/lexikon.html []Accessed: 04.06.2010
72
What is Biogas ?
Methane (CH4) 50 to 75 %
Carbon Dioxide (CO2) 25 to 50 %
Hydrogen (H) 5 to 10 %
Nitrogen (N2) 1 to 2 %
Hydrogen sulphide (H2S) Traces
Sources: YADAV & HESSE (1981); FAO (1996); PIPOLI (2005); GTZ (2009
Source: MUENCH (2008)
Methane is the valuable part of the biogas. Biogas that contains about 60 to 70 % of
CH4 has a calorific value of about 6 kWh/m3 what corresponds to about half an L of
diesel oil. (ISAT/GTZ 1999, Vol. I)
73
Factors Influencing Composting Process
• Nutrient Balance
• Particle Size
• Moisture Content
• Oxygen Flow
• Temperature
Design considerations for composting systems
Item Comment
Carbon to Initial C/N ratio should be 20:1 to 35:1 by weight*. The ratio
nitrogen ratio reduces during composting process because of carbon loss and
nitrogen accumulation
Air requirements Air with at least 50% oxygen remaining should reach all parts of the
composting material
Moisture content Moisture content of the composting mixture should not be > 60%
for static pile and windrow composting and not > 65% for in-vessel
composting
pH control pH should be 6 to 9; optimally 7 to 7.5
Temperature Temperature should be 50 to 55°C for the first few days and 55-
60°C for the remainder of the active composting period
Control of To kill all pathogens, temperature must be maintained between 60
pathogens and 70°C for 24 hours
Mixing and Material should be mixed or turned on a regular schedule
turning
* See table slide after next for some example C/N values (be aware that it is not so easy to measure
the C/N ratio: you will require access to a laboratory for this)