CEB 2023/CDB 2033

TEST 1
May 2020 SEMESTER

COURSE : CEB 2023/CDB 2033 – CHEMICAL

ENGINEERING THERMODYNAMICS II
DATE : 14 July 2020

TIME : 4.00 PM – 5.45 PM (1 HOUR 45 MINUTES)

INSTRUCTIONS TO CANDIDATES

1. NO PLAGIARISM allowed during test. Please fill out the declaration

link for originality of work.
2. Begin EACH answer on a new page and indicate clearly answers that
are cancelled, if any.
3. The solution should be handwritten, and all solution pages should be
compiled in one file of pdf with maximum file size of 20 MB with clear
resolution (CAMSCANNER can be utilized).
4. Where applicable, show clearly detail steps taken in arriving at the
solutions and indicate all assumptions.
5. In case there is error in uploading solution through Ulearn, it can be sent
to jalal.foroozesh@utp.edu.my.
Note: There are TWELVE (12) pages in this Question Booklet including the
cover page and the Appendices.

Universiti Teknologi PETRONAS

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1. Air with the mass of 87 gram experienced mechanically reversible

processes in a closed system. The initial state is P1 and T1 (60°C). In
the first process, air is cooled at constant pressure, followed by heating
at constant volume to 4 bar and 70°C. These processes were then
replaced by an adiabatic process followed by cooling at constant
pressure to 4 bar and 70°C from initial condition of P1 and T1 (60°C).
Heat Capacity at constant pressure CP =(7⁄2)R and heat capacity at

constant volume CV =(5⁄2)R.

Last digit of student P1 Last digit of student P1
ID (bar) ID (bar)
0 1
2 3
4 1.2 5 1.4
6 7
8 9

a. Calculate the heat transferred (J), work (J), and change in internal
energy (J) for each process.
[10 marks]
b. Calculate the change in enthalpy (J) for each process.
[3 marks]
c. Sketch the processes on a single pressure-volume (P-V) diagram and
label the position of each volume and pressure.
[4 marks]
d. If the processes were irreversible with efficiency of 80%, determine
the real work (J) and heat transferred (J).
[3 marks]

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2. a. Twenty grams of carbon dioxide vapor is at T1 (350 K) and P1.

Calculate the residual enthalpy (J) by using Redlich-Kwong equation
of state.
Last digit of P1 Last digit of P1 Last digit of P1
student ID (bar) student ID (bar) student ID (bar)
0 1 2
3 4 5
90 110 130
6 7 8
9
[6 marks]
b. The twenty grams of carbon dioxide vapor in part (a) experience
changed from T1 and P1 to T2 (650 K) and P2 (105 bar). Determine
the value of ΔSig (J.K-1).
[4 marks]
c. A mixture is comprised of 40% carbon dioxide (1), and the rest is
carbon monoxide (2) at T (350 K) and P. Calculate the value of
residual entropy (J.mol-1.K-1) of mixture using Lee/Kesler correlation.
Last digit of P Last digit of P Last digit of P
student ID (bar) student ID (bar) student ID (bar)

0 1 2
3 4 5
46 37 29
6 7 8
9
[6 marks]
d. Determine the value of residual Gibbs in part (c) using Pitzer
correlation for second virial coefficient.
[4 marks]

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APPENDIX A
List of Formulas

1. Generic Cubic Equations of State:

Pr
β=Ω
Tr
ψ α(𝑇𝑟 )
q=
Ω 𝑇𝑟
𝑍−𝛽
𝑍 = 1 + 𝛽 − 𝑞𝛽
(𝑍 + 𝜀𝛽)(𝑍 + 𝜎𝛽)
1+𝛽−𝑍
𝑍 = 𝛽 + (𝑍 + 𝜀𝛽)(𝑍 + 𝜎𝛽) ( )
𝑞𝛽

Case I
1 𝑍 + 𝜎𝛽
𝐼= ln ( )
𝜎−𝜖 𝑍 + 𝜖𝛽
Case II
𝛽
𝐼=
𝑍 + 𝜖𝛽

𝐻𝑅 𝑑 𝑙𝑛 𝛼(𝑇𝑟 )
=𝑍−1+[ − 1] 𝑞𝐼
𝑅𝑇 𝑑 𝑙𝑛 𝑇𝑟
𝑆𝑅 𝑑 ln 𝛼(𝑇𝑟 )
= ln(𝑍 − 𝛽) + 𝑞𝐼
𝑅 𝑑 ln 𝑇𝑟

2. Change in Entropy
𝑖𝑔 𝑑𝑇 𝑑𝑃
𝑑𝑆 𝑖𝑔 = 𝐶𝑝 −𝑅
𝑇 𝑃
𝑇 𝐶 𝑖𝑔
𝑝𝑑𝑇 𝐷 𝜏+1 𝜏−1
∫ = {𝐴 + [𝐵𝑇0 + (𝐶𝑇02 + 2 2 ) ( )] ( )} ln 𝜏
𝑇0 𝑅 𝑇 𝜏 𝑇0 2 ln 𝜏

3. Generalized Correlations
𝐻𝑅 (𝐻𝑅 )0 (𝐻𝑅 )1
= +𝜔
𝑅𝑇𝑐 𝑅𝑇𝑐 𝑅𝑇𝑐
𝑆 𝑅 (𝑆 𝑅 )0 (𝑆 𝑅 )1
= +𝜔
𝑅 𝑅 𝑅
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0.422
𝐵 0 = 0.083 −
𝑇𝑟1.6
0.172
𝐵1 = 0.139 −
𝑇𝑟4.2
𝑑𝐵 0 0.675
= 2.6
𝑑𝑇𝑟 𝑇𝑟
𝑑𝐵1 0.722
= 5.2
𝑑𝑇𝑟 𝑇𝑟
𝐻𝑅 𝑑𝐵 0 𝑑𝐵1
= 𝑃𝑟 [𝐵 0 − 𝑇𝑟 + 𝜔 (𝐵1 − 𝑇𝑟 )]
𝑅𝑇𝑐 𝑑𝑇𝑟 𝑑𝑇𝑟
𝑆𝑅 𝑑𝐵 0 𝑑𝐵1
= −𝑃𝑅 ( +𝜔 )
𝑅 𝑑𝑇𝑟 𝑑𝑇𝑟

4. Adiabatic Equations at Constant Heat Capacities for Ideal Gases

𝑅⁄
𝑇2 𝑉1 𝐶𝑉
=( )
𝑇1 𝑉2
𝑅⁄
𝑇2 𝑃2 𝐶𝑃
=( )
𝑇1 𝑃1
𝐶𝑃
⁄𝐶
𝑃2 𝑉1 𝑉
=( )
𝑃1 𝑉2

5. Interpolation
𝑋2 − 𝑋 𝑋 − 𝑋1
𝑀= ( ) 𝑀1 + ( ) 𝑀2
𝑋2 − 𝑋1 𝑋2 − 𝑋1
𝑋2 − 𝑋 𝑋 − 𝑋1 𝑌2 − 𝑌
𝑀 = [( ) 𝑀1,1 + ( ) 𝑀1,2 ]
𝑋2 − 𝑋1 𝑋2 − 𝑋1 𝑌2 − 𝑌1
𝑋2 − 𝑋 𝑋 − 𝑋1 𝑌 − 𝑌1
+ [( ) 𝑀2,1 + ( ) 𝑀2,2 ]
𝑋2 − 𝑋1 𝑋2 − 𝑋1 𝑌2 − 𝑌1

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APPENDIX B
Properties of Pure Species

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APPENDIX B
Properties of Pure Species (cont’d)

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APPENDIX C
Heat Capacities of Gases in the Ideal-Gas State

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APPENDIX D
The Lee/Kesler Generalized-Correlations (Values of (HR)0/RTc)

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APPENDIX D
The Lee/Kesler Generalized-Correlations (Values of (HR)1/RTc)

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APPENDIX D
The Lee/Kesler Generalized-Correlations (Values of (SR)0/R)

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APPENDIX D
The Lee/Kesler Generalized-Correlations (Values of (SR)1/R)

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