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Multichannel Analyzers: Wallace A. Ross
Multichannel Analyzers: Wallace A. Ross
MULTICHANNEL ANALYZERS
Wallace A. Ross
Hewlett-Packard
Santa Clara, California
9.1. INTRODUCTION
The multichannel analyzer is an important, perhaps the universal,
instrument for nuclear chemistry. It can measure complex relationships
among radioisotopes, such as relative energy, activity (Sect. 3.2), half-life
(Sect. 3.10), abundance (natural isotopic composition), etc., and can present
the relationships to the chemist in a variety of ways, depending upon his
needs. The measurement results can be displayed as curves on an oscilloscope
or recorder, printed as numbers on a digital printer or typewriter, stored on
and retrieved from a variety of storage media such as paper or magnetic tape,
manipulated arithmetically by an internal calculator, or transferred to a
computer for data reduction and report generation (Sect. 12.6.2). Despite this
power and versatility, it is an instrument which can be used and understood
with little training. For these reasons, multichannel analyzers are found in
nearly all nuclear chemistry laboratories and are used for both routine
chemical analysis and fundamental research.
In this chapter some of the applications for multichannel analyzers
will be explored. The hardware will be described to provide an understanding
of how multichannel analyzers work and to aid the reader in applying them
to his particular measurement needs. Finally, important specifications,
their value to the user, and the current state of the art of commercially
available multichannel analyzers will be discussed. New techniques that are
still in the experimental or development state are not within the scope of this
chapter.
263
9.2. APPLICATIONS
Multichannel analyzers have been used since the 1940s. Their earliest
application was as pulse-height analyzers used to measure particle energies
via the energy spectrum. This is still the primary application, although a
number of others have become important.
Fig. 9-2. A high-resolution complex )I-ray spectrum of fission products from a nuclear reactor.
Only a portion of the complete energy range is shown.
Interference between the peaks is possible. In addition, each y-ray will give
rise to a Compton scatter spectrum (see Sect. 1.6.1.2) and these contribute a
background spectrum which can obscure low count-rate photopeaks.
Figure 9-2 shows what might be measured. As the spectra become more
complex, specialized techniques using calculators or computers are necessary
to interpret them (Sect. 12.8).
advancing channels, each channel will record fewer counts than the preceding
one. The result will be a decay curve from which the half-lives of the measured
isotopes may be determined.
SOURCE
-1-
ABSORBER
LINEAR
AMPLIFIER
ADDRESS· VE LOCITV
SYCHRONIZATION SIGNAL
••••
.111111
-••
•
MULTICHANNEL
AHALYUM
PULSE nU,IN
I ICC
VELOCITY,cm/uc
.. 0..8
CHANNEL NUMBER
/["""-------,
III CRT DISPLAY
AND ANALOG
I Y OUTPUT
X OUTPUT
OUTPUTS
I Z OUTPUT
I
I
I INPUT/OUTPUT II
I
I DIGITAL
I SERIAL
OUTPUT
MCS
INPUT I INPUT / SERIAL
H--,r-I...J....;~ OUTPUT INPUT
~ I CIRCUITS I PARALLEL
MCS
L _______I OUTPUT
when doing pulse-height analysis. Again, using the example above, a 750-m V
pulse would cause channel number 750 to be addressed and incremented by
one.
There are two important types of ADCs available today for multi-
channel analyzers. The most common is the so-called ramp type, or
Wilkinson ADC (8), after the inventor. * In this type ADC, the voltage
stored on a capacitor is "run down" to 0 V by removing a constant current
from the capacitor. This results in a voltage ramp (Fig. 9-9a); hence the name
ramp-type ADC. During the voltage run down, a constant frequency clock
is gated into a scaler. When the run down reaches 0 V, the scaler is gated off
and the number stored in the scaler is a measure of the run-down time, and
hence the initial capacitor voltage or pulse height.
The other common ADC type is known by the name "successive
approximation." The principle of this type ADC is as follows (Fig. 9-6).
Assume the ADC range is 0 to 10 V. As a first approximation, the unknown
*In addition to the references used in the text, there is a vast amount of literature concerning
multichannel analyzers. References 6-13 are a selection of books and papers for the reader who
wishes to research the subject further. References 8-10 provide historical perspective on MCA
development. The others deal in more depth than this chapter with some specific aspects of
the subject, and themselves contain bibliographies including more of the literature.
Multichannel Analyzers 269
10.00 _
f COMPARISON
VOLTAGE
8.7~ -
e.1 2~ _ 8 VOLT
INPUT
7.eI2~ _
7.~0 -
6.25 _
5.00 _
3.75 _
2.50 _
1.25 _
o _
I 100 I ____ _
BINARY CODE TIME
13"10 6117 611~ 60"12 6122 6123 6238 6366 6"191 62~9 6"128
13~1l 6~1~ 6~37 6603 6682 6936 701"1 7389 8276 II "12"1 22666
1360 ~443" 12391~ 22"1291 312068 323"11"1 2~1324 14b061 68"12"1 267~4 10887
1370 600~ 4~81 3939 3861 3696 3896 31 17 38"17 38"13 3701
1380 3717
Fig. 9-7. Teletype printout of multichannel-analyzer data. Data are the photopeak of the 137CS
peak from Fig. 9-1.
·"'.1"'"
Fig. 9-8b. Sampled voltage analysis front-panel settings on HP 54018 multichannel analyzer.
274 Chapter 9
TRIGGER
LEVEL . . . . A. I NPUT PULSE
BASELINE f::=::~-:
LEADING
EDGE
TRIGGER SLOPE OF DISC HARGE
STRETCHER
CAPACITOR
VOLTAGE
ADDRESS
SCALER
GATE
a) CLOCK
ADC
DONE
+----r~---------~----~n-
CLOSE
INPUT GATE OPE N:t:=l...
LOAD
ADDRESS
REGISTER ------------------~"--
MEMORY
READ ------------------~~
MEMORY
WRITE --------------------------~
______________________
INCREMENT ~nL____
ACCUMU-
LATOR
SAMPLE
PULSE
STRETCHER
CAPACITOR
VOLTAGE
b)
ADDRESS
SCALER
GATE
CLOCK
+----ofW------~
ADC DONE
INPUT GATE
CLOSE j 1 _________ -oPEN- &:.:l..
_____________________n_
LOAD
ADDRESS
REGISTER
MEMORY
READ --------------------~~
MEMORY
WRITE ----------------------~~
INCREMENT
ACCUMU-
lATOR
-------------------------"----
Fig. 9-9. (a) Timing diagram of pulse-height analysis mode, analysis of a single input pulse.
(b) Timing diagram of sampled voltage analysis mode, analysis of a single voltage sample.
276 Chapter 9
a: a 0 0 I • 0 . : ~
.0 .0 .. c:;) c;; •
INCREMENT
~g~~:;s
----l'
,. INCREMENT MEMORY ADDRESS
CHANGES MEMORY ADDRESS TO NEXT CHANNEL
"---
/ READ COMMAND READS NEXT
MEMORY -J""1 MEMORY CHANNEL ~
READ
WRITE COMMAND WRITES ACCUMULATOR
MEMORY DATA INTO MEMORY ......11....-
WRITE
MEMORY STROBE PULSE TRANSFERS
LOAD --JI/ MEMORY CONTENTS TO ACCUMULATOR '\....-
ACCUMU-
LATOR
o 456 8 9 10 II 12
Fig. 9-11. Timing diagram of multichannel scale mode. Timing is shown for a single channel.
278 Chapter 9
Fig. 9-12. Multiparameter spectrum. An isometric view of one quarter of a 60Co coincidence
spectrum showing the two photopeaks.
9.4. CHARACTERISTICS
9.4.1. Analog-to-Digital Converter
The ADC is the single most important factor in measurement capability
of a pulse-height analyzer. It is the thing which determines both the speed
and accuracy of the measurement. The ability of an ADC to make an accurate
measurement is usually described by its differential and integral linearities
(Fig. 9-13). Differential linearity is a measure of how nearly all the channels
have the same incremental voltage width, ~ V. Typical ADCs today have
differential linearities of 1 % or better, that is, all channels are within ± 1 %
of being the same width. Integral linearity is a measure of the deviation, ~y,
of the worst-case channel position from a theoretical straight line fit to all the
channels. The ADC conversion function should be linear, but in most ADCs
280 Chapter 9
4096
'"
..J
'"Z
..
Z
:I:
U
>
x VOLTS 10
Fig. 9-13. Integral and differential linearity are a measure of the quality of the transfer function
of the ADC, channels output vs volts in.
there will be some curvature, especially at the bottom and top channels.
Typical ADCs today have integrallinearities of much better than ±0.1 % of
full scale. See also Figs. 8-3 and 8-4, and Eqs. (8-1) and (8-2).
Another important measure of an ADCs performance is the speed of
making a conversion. For a ramp-type ADC, the conversion time (or dead
time) is proportional to the number of channels and inversely proportional
to the clock frequency that is counted during rundown. ADCs are com-
mercially available today with clock rates of up to 200 MHz. This gives a
conversion time for 8192 channels of less than 50 f.1.sec. The primary benefit
offered by the successive approximation-type ADC is that it can be made to
go faster than a ramp ADC because the conversion time is proportional to
the number of bits rather than the number of channels. Successive approxi-
mation ADCs are available with conversion times ofless than 5 f.1.sec for 2048
channels (11 bits). Although the successive approximation ADC is faster than
the ramp, it is typically more complicated and requires correction circuitry
to attain the differentiallinearities which are provided directly by the ramp-
type ADC. For this reason, the ramp ADC is still much more widely used in
multichannel analyzers than the successive approximation.
Measurement resolution is a function of several characteristics of an
ADC. These include input noise, dc stability, and count-rate shift. Typical
ADCs are capable of putting at least two-thirds of the pulses from a noise-
free pulser into one channel out of 4096. Their stability is such that in a
normal operating environment in the course of a twenty-four hour measure-
ment, the drift should not be more than about ± 1 channel out of 4096.
Count-rate shifts of less than one channel between 0 and 90 % dead time are
available.
Since differential linearity is such an important specification of an ADC
in a multichannel analyzer, special hardware has been developed and is
commercially available for measuring it. It is variously referred to as a
Multichannel Analyzers 281
sliding pulser or ramp pulser.1t provides a train of pulses with controlled and
slowly changing amplitudes. This pulse train is typically obtained by chopping
a slow voltage ramp, hence the name ramp pulser. If the pulse train is
analyzed by a pulse-height analyzer with perfect differential linearity, a flat
spectrum will result (though only after a sufficient number of counts and
ramp sweeps have been made to average out statistical effects). A small
amount of study will prove that the percent deviation from flatness of this
spectrum is exactly equal to the percent differential nonlinearity of the ADC,
assuming a perfect pulser system, of course.
9.4.2. Memories
Most multichannel analyzers use ferrite core memories. This is because
they offer the best compromise for a multichannel analyzer between cost and
speed. Memory cycle times in commercially available multichannel analyzers
run from about 2 to 5 J1.sec. Speeds faster than this would not offer any
particular benefit for pulse-height analysis because the ADC conversion
times exceed this by a good margin. Multichannel-analyzer memories have
anywhere from 128 words up to 8192 words and some multichannel analyzers
have been built with much more for multiparameter analysis. The most
commonly used size for low-resolution spectrometry with scintillators is
1024 words, and most common sizes for high-resolution spectrometry with
solid-state detectors are either 4096 or 8192 words.
All analyzers are capable of storing at least 10 5 and usually 106 counts
per channel. If the memory is organized to count on a binary basis, 106 counts
require 20 bits, since 2 20 is approximately equal to 1 million. When counting
is done on a decimal basis, 4 bits are required to count to 10. This implies the
need for 24 bits to count to 106 ,4 for each decade.
Fig. 9-14. A logarithmic display of two identical spectra measured for different counting
intervals. Note that in a logarithmic display the difference in counts causes a vertical offset but
no shape change.
the flicker and letting the eye integrate the spectrum. Another approach is the
use of a long persistence or storage oscilloscope. With this the CRT phosphor
retains its glow long after the signal has gone away, thus eliminating flicker.
Some common, flexible display features available include horizontal
and vertical expansion of the spectrum for detailed examination, distinctive
marking of a memory subgroup (region of interest), intensification of every
eighth or tenth channel to ease channel identification, and overlap of
memory segments for spectral comparison.
A display feature available with many multichannel analyzers is a
logarithmic presentation (Figs. 9-14 and 7-24). This has two benefits. First,
it compresses the entire five or six decades of information into the displayable
range. Second, the spectral shape is independent of the number of counts so
that two spectra accumulated for different counting times can be compared
directly.
A multichannel-analyzer's input/output capabilities are best described
in terms of the number and variety of devices to which it is interfaced.
Almost all analyzers are interfaced to punched tape, typewriter, and parallel
printer. Many, in addition, can read in or out from magnetic tape. The
prospective multichannel-analyzer user should decide what type of input/
output medium is convenient for him and then choose an analyzer which has
that capability. He should also investigate the cost of adding an interface.
With some analyzers the input/output function is designed such that much
of the logic is built in. In these it is possible to interface to a new device
simply by the addition of some inexpensive circuit cards and cables. In others
each device may require an expensive dedicated driver. The redundancy in
that approach becomes an important cost factor when mUltiple devices are
interfaced.
Multichannel Analyzers 283
9.4.5.3. Pulse Pile-Up. As count rates get high and pulses occur closer
together, the probability increases that two pulses will overlap (Fig. 7-2).
This overlap will cause an erroneous measure of peak amplitude, thus
distorting the spectrum. To avoid this, a monitor oscilloscope should be
used to insure adequate pulse separation before the measurement. Addition-
ally, some ADCs include circuits, such as the baseline monitor in the 540lB,
which prevent the ADC from accepting a pulse until the tails of previous
pulses have returned to the baseline. When available, these monitors should
be used (see, e.g., Fig. 7-26).
9.6. REFERENCES
I. 1. Krugers and Q. Reifenschweiler, Practical Instrumental Analysis, pp. 117-129, Elsevier
Publishing Co., Amsterdam (1965).
2. D. Taylor, Neutron Irradiation and Activation Analysis, D. Van Nostrand, Princeton, N.J.
(1964).
3. R. Gould, The Mossbauer Effect and Its Application in Chemistry, American Chemical
Society, Washington, D.C. (1967).
4. S. Upshinsky, How to make a nuclear spectrum hold still, Hewlett-Packard Journal, 22,
No.8 (April 1971).
5. 1. Cross, 1. Doub, and 1. Stedman, On-line data reduction for nuclear analyzers, Hewlett-
Packard Journal, 22, No.7 (March 1971).
6. W. Ross, A multichannel pulse height analyzer with a very fast analog-digital convertor,
Hewlett-Packard Journal, 19, No.7 (March 1968).
7. G. Stanford, An Introduction to Multichannel Analyzers, Argonne National Laboratory,
ANL-6881 (April 1964).
8. D. H. Wilkinson, A stable ninety-nine channel pulse amplitude analyzer for slow counting,
Cambridge Phil. Soc., 46:508 (1950).
9. G. W. Hutchinson and G. G. Scarrot, A high precision pulse-height analyzer of moderately
high speed, Phil. Mag., 42:792 (1951).
10. R. Schumann and 1. McMahon, Argonne 256-channel pulse height analyzer, Rev. Sci.
Instr., 27 :675 (1956).
II. R. L. Chase, Nuclear Pulse Spectrometry, McGraw-Hill, New York (1961).
12. R. L. Chase, A servo stabilized analogue-to-digital converter for high resolution pulse-
height analysis, IRE Trans. Nuc!. Sci., NS-9:119 (1962).
13. D. Cronch and R. Heath, Routine Testing and Calibration Procedure for Multichannel
Analyzers, AEC R&D Report-Physics, IDO-16923 (Nov. 1963).