National Institute of Technology Calicut

Department of Chemistry
Interim Online Assessment - II
Semester III: B. Tech. Chemical Engineering & Engineering Physics
CY2001D: PHYSICAL CHEMISTRY
Date: 23 November 2020 Time: 4:05 PM-5:00 PM Maximum Marks: 10

Instructions:
a) Answer all questions
b) Write your Name and Registration Number on top of your answer sheet
c) Scan the answer sheet to a single .pdf file and upload by 5.15 PM
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1. At 25 °C, Kp for the given reaction is found to be 2.0 x 10-29. Calculate the standard Gibbs
free energy change for the reaction. [2 Marks]

2CO2(g) ⇌ 2CO(g) + O2(g)

2. For D2O, the normal freezing point is 3.82 °C and ΔfusH is 6305 J/mol.

(a) Calculate the cryoscopic constant for D2O.

(b) Find the freezing point of a solution of 0.954 g of CH3COCH3 in 68.40 g of D2O.

[2 Marks]

3. Draw a labelled phase diagram for tin-lead (Sn-Pb) system and explain the curves. How do
you calculate the eutectic point?

[2 Marks]

4. The solute Na2SO4 is 92% dissociated in 1/200 molal aqueous solution at 27 °C. What
would be the osmotic pressure of the solution? [2 Marks]

5. With a phase diagram for three component system, explain the acetic acid-chloroform-
water system at 1 atm. [2 Marks]