Intercambio idnico lueves, 19 de noviembre de 2020 09:01p.m. EXAMPLE 15.2 Ion-Exchange Capacity. A commercial ion-exchange resin is made from 88 wt% styrene and 12 wt% divinylbenzene. Estimate the maximum ion-exchange ca- pacity in eq/kg resin (same as meq/g resin). Colcntor ln capacidad marr de int. Ifnic? aL sulfonav~ Solution a Basis: 100 g of resin before sulfonation. M g gmol Styrene 104.14 880.845 Divinylbenzene 130.18 2 0.092 100 0.937 ‘Sulfonation at one location on each benzene ring requires 0.937 mol of H2SO, to attach a sulfonic acid group (M = 81.07) and split out one water molecule. This is 0.937 equivalent, with a weight addition of 0.937(81.07) = 76 g. Total dry weight of sulfonated Eh Og hay By Ae estrera 4 12g de divinlbumuro APrndbisis: molar de la asina- Mesheano = 104.14 g/mol M Jiviailbenzeno > 130-18 9 /mol Bog2 2mol_ = 2. B45qmo) 2" ieig5 1294 gmol_ = 0,042 gmsl 130.12 5 em total = 6.845 40.092 = 0.937 Jmol CH=CH, CH=CH) CH —CH;—CH—CH,—CH—CH, —~ 5.532 oe oe oe +k J -_ J | | -estwero =CH, CH=CH, Siuiilte meno CH—CH,—CH —CH,- sihes pare A Witrembio J ch =| cH cH, CVn — 30,8) = Dy sifonacin, La rnigrra Canticdesl alt "Sia oy la maison comida de HeSOf qe oe alicionarin pL Custos grimes nucsito de e504 pova la sulforcusdn ? Dado at cs una sulfonacion, necesiva fmol o& H2sog. tn masa Sin embargo la subforocidn @ da con H'S037 (grupo aida sulfen io) 4 ant molbunta 503 se une con unm woldiula de la vesings #ts0,~ = Bl 9 /me Maser = 0.93% mol (* OF 2 \= 969 Masa de la résina Ya sulfonada Masa resin + Masa Sul foncda 894124 Jo = Mog para obbener esta masa expresuda en equiualentes SH. OBIS oa og