Porosidad de particula, moléculas en monocapa y Jnares, 17 de noviembre de 2020 08:08 p.m Eyumpio IS] Seaders pagina 572 ‘Table 152 _Represcatative Properties of Commercial Porous Adsorb Capacity for HO Pore Vapor Diameter | Ads Naure aa A (Day Bais ‘evading 1075 7 Site ge: Sal po 750-850 uy Las pee 11 om) om 300380, Activated carom Sima pre w2s 0406 05.09 400-1200 1 Lage pore 330 a geas — 2m.6m - Moclarsve carbon Hydrophobic 210 08 “00 Molcuarsiceealies Polaydrphic,eyalie 31002084700 202s Pilyoat atsabeatt 025 0403s 700 = EXAMPLE 15.1 Particle Porosity. Bole se de on, pot tiles Using data from Table 15.2, determine the volume fraction of pores can pores poses in silica gel (small-pore type) iled with adsorbed water vapor when Le’ fos dtl its partial pressure is 4.6 mmilg and the temperature is 25°C. At adseviealt these conditions, the patial pressure is considerably below the ¢3rkn. Heras vapor pressure of 23.75 mmHg. In addition, determine whether the A ¥ Por amount of water adsorbed is equivalent wo more than 3 monolayer, — & Kas IF the rca of an adsorbed water molecule is given by (15-8) andthe spocitie surface area ofthe silica gel i $30 mV. ‘Solution [Take I g of silica get particles sa basis, From (15-3) and data in Table 15.2, Vp = 0.47/1.09 = 04M em"/g. Thus, for I g, pore vol- ume is 0.431 em rom the expacity vale in Table 15.2, amount of adored water = 0.11 +011) = 00581. Assume desis of Pye A ray fukorbed water is 1 glam? volume of adsorbed water = (0991 0991/0431 Si LaDy os sumed nolecule tm pica sul, EReeSiirtanteNL ne way, ad soiasn, Number of H:0 molecules asorbed = OPPD (G0 10") 31 x 108 Number of HO molecules in monolayer fr 830 n? == 5041007 Tost x 19 = 790% 1 | Therefore, only 3.31/7.90 oF 426 of one monolayer is adsorbed, Cal = paste la adsordisn en hula este caso 1 Feascein 3 pores DS cuntided dL igus ad Sorbiga ES ehaivelbeet 6 uA muescafa,OQ) DSA cuantided dL Oyu Ad Sorbiga C6 Cgaivelbsee 6 uae onsescaf Eo: 18.3, 16-4,18.5 )Is.6,15.4,18.4. Neha cantidad SHLOmiNida AL vilica apl, pee SL puede pmrpante. C wo cobeutar velamtn at porw espec'fico? \Ipe Povesided - £5 densidad Pp Ex porasidad de portieulo. P= densidod deta prrKeuim para Shia gel, (ove pequetto Epr 0 420d Poe 109 [em Vpr ow = 943) end Pe it? a pF cada gramo, hay 0-43! cmSdisponipies en volumen de Poe Capatidad de wpur del agua pare »ilice gol pom gequrio as 11% este M7 deven afactar ol voluman dipo ibie capatidad de vapor Para adserter grams de silica + copacidad de w por Cantidad de agua absorbic = 0.09415 asumiede ge UP te ag cain ype Valent Se Sapone gt D-094/5 = 9-04[ con? —> 6/ Volumen del agua Blowt adsorgide ts 48 0.094] om? G6 fraccién de foros lens ? fraseidn Volumen valine Fe de pores = “aims hoperible eweO0sl em? = 9.23 = 237 1 dee de superficie (proytctocle) es decade. por la ee (= ——_Shroe Ue rnokem 800, M= peso nvoltcalar NA = num, aitgadro LPassorbaty> densidad J ad sorbate OfF dren a Siperficib en ete tx80 seria of dita dol molb cule Adsorbida, #1 ahorbats | moldcula adserida an este caso eyus.) *h d= fon ee b05e0" 5 emt fans el Numero de moldcules adsorbidas recsite saber cabins emloulas hay en les 5 dt agua it tthe adeorbides. GJ edsotbides 2 0.0451 g= 0.014! ond Hmoldeaig= 9 ads NA = gs rollin me! moléenla M OF Frolfeda = 0.04719 4 Gu23«0%S ie B.S 4107 plseala, moléanlas en la monoce pa LS hesesarie Sale priveso e kta esper Piva siperfieal (de la sitica gel 68 530 ut/q) lease Célido > 1g stmaldalas ta la monecapa. = Grea espee'tice (b.c) Grea. de sup. dl adsorbato Hrveléeulusen = 830 of ty la monecepa 2 = 29x10 nolélesalas fletens