Annexure 3

Saturation Properties of Water

IAPWS 1992 supplementary release gives saturation properties of water by the following relations:

Reference constants for relations:

𝑇𝑐 = 647.096 𝐾 𝜌𝑐 = 322 kg/m3
𝑃𝑐 = 22.064 MPa 𝛼0 = 1000 J/K
Reference relations:
𝜃 = 𝑇/𝑇𝑐 , 𝑇 in 𝐾 𝜏 = 1−𝜃

Saturation pressure as function of temperature:

𝑃 𝑇𝑐
ln ( ) = [𝑎1 𝜏 + 𝑎2 𝜏 1.5 + 𝑎3 𝜏 3 + 𝑎4 𝜏 3.5 + 𝑎5 𝜏 4 + 𝑎6 𝜏 7.5 ]
𝑃𝑐 𝑇
Where,
𝑎1 = −7.85951783 𝑎4 = 22.6807411
𝑎2 = 1.84408259 𝑎5 = −15.9618719
𝑎3 = −11.7866497 𝑎6 = 1.80122502

Density of saturated liquid as function of temperature:

𝜌𝑓
= [1 + 𝑏1 𝜏 1/3 + 𝑏2 𝜏 2/3 + 𝑏3 𝜏 5/3 + 𝑏4 𝜏 16/3 + 𝑏5 𝜏 43/3 + 𝑏6 𝜏 110/3 ]
𝜌𝑐
Where,
𝑏1 = 1.99274064 𝑏4 = −1.75493479
𝑏 = 1.09965342 𝑏5 = −45.5170352
𝑏3 = −0.5100839303 𝑏6 = −6.74694450 × 105

Density of saturated vapor as function of temperature:

𝜌𝑔
ln ( ) = 𝑐1 𝜏 2/6 + 𝑐2 𝜏 4/6 + 𝑐3 𝜏 8/6 + 𝑐4 𝜏 18/6 + 𝑐5 𝜏 37/6 + 𝑐6 𝜏 71/6
𝜌𝑐
Where,
𝑐1 = −2.03150240 𝑐4 = −17.2991605
𝑐2 = −2.68302940 𝑐5 = −44.7586581
𝑐3 = −5.38626492 𝑐6 = −63.9201063

Specific enthalpy as function of temperature:

𝛼
= 𝑑𝛼 + 𝑑1 𝜃 −19 + 𝑑2 𝜃 + 𝑑3 𝜃 4.5 + 𝑑4 𝜃 5 + 𝑑5 𝜃 54.5
𝛼0
Where, 𝛼 = Auxiliary quantity for specific enthalpy
𝑑1 = −5.65134998 × 10−8 𝑑4 = −135.003439
 𝑑2 = 2690.6631 𝑑5 = 0.981825814
𝑑3 = 127.287297 𝑑𝛼 = −1135.905627715

Specific enthalpy of the saturated liquid:

𝑇 𝑑𝑃
ℎ𝑓 = 𝛼 +
𝜌𝑓 𝑑𝑇
Specific enthalpy of the saturated vapor:
𝑇 𝑑𝑃
ℎ𝑔 = 𝛼 +
𝜌𝑔 𝑑𝑇