Question 1

(1) Benzene (2) Toluene

ω = 0.210 ω = 0.262
Tc = 562.2K Tc = 591.8K
Pc = 48.98 bar Pc = 41.06 bar

ln Psat/kPa = A – [ B/(T/K + C)]

ln P1sat = 13.7819 – {2726.81/ [(100+273.15) + (-55.578)]}
P1sat = 180.45 kPa

ln P2sat = 13.9320 – {3056.96/ [(100+273.15) + (-55.525)]}

P2sat = 74.26 kPa

(a) Prepare a graph showing P vs x1 and P vs y1 for a temperature of 100 degC .

(use x1 range from 0 and 1 for every 0.1 interval )

Pbubble = x1P1sat + x2P2sat

x1 x2 Pbubble y1
0 1 74.260 0
0.1 0.9 84.879 0.213
0.2 0.8 95.498 0.378
0.3 0.7 106.117 0.510
0.4 0.6 116.736 0.618
0.5 0.5 127.355 0.708
0.6 0.4 137.974 0.785
0.7 0.3 148.593 0.850
0.8 0.2 159.212 0.907
0.9 0.1 169.831 0.956
1 0 180.450 1
(b) Prepare a graph showing T vs x1 and T vs y1 for a pressure of 70kPa.
(Guide: calculate x1 and y1 regarding on the estimated T from a range of T1sat to T2sat
for every 3ºC internal)

Tsat = [B / (A – ln Psat)] – C

T1sat = [ 2726.81 / (13.7819 – ln 70)] – 55.578

= 341.6049 K

T2sat = [ 3056.96 / (13.9320 – ln 70)] – 55.525

= 371.2124 K

T(K) P1sat P2sat x1 y1

341.60 70.0000 25.6954 1.0000 1.0000
344.15 76.1403 28.2344 0.8718 0.9483
347.15 83.9148 31.4845 0.7346 0.8806
350.15 92.3002 35.0310 0.6106 0.8051
353.15 101.3287 38.8932 0.4982 0.7212
356.15 111.0334 43.0912 0.3961 0.6282
359.15 121.4477 47.6456 0.3029 0.5255
362.15 132.6060 52.5780 0.2177 0.4124
365.15 144.5431 57.9103 0.1396 0.2882
368.15 157.2942 63.6653 0.0677 0.1520
371.21 171.1872 70.0000 0.0000 0.0000
 x1 P y1 P
1 341.60 1 341.60
0.8718 344.15 0.9483 344.15
0.7346 347.15 0.8806 347.15
0.6106 350.15 0.8051 350.15
0.4982 353.15 0.7212 353.15
0.3961 356.15 0.6282 356.15
0.3029 359.15 0.5255 359.15
0.2177 362.15 0.4124 362.15
0.1396 365.15 0.2882 365.15
0.0677 368.15 0.152 368.15
0 371.21 0 371.21

Graph of Temperature against x1, y2

375.00
370.00
365.00
360.00
Temperature (K)

355.00
350.00 Bubble Line
Dew Line
345.00
340.00
335.00
330.00
325.00
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
x1, y2
 x1 P y1 P
0 74.26 0 74.26
0.1 84.879 0.213 84.879
0.2 95.498 0.378 95.498
0.3 106.117 0.51 106.117
0.4 116.736 0.618 116.736
0.5 127.355 0.708 127.355
0.6 137.974 0.785 137.974
0.7 148.593 0.85 148.593
0.8 159.212 0.907 159.212
0.9 169.831 0.956 169.831
1 180.45 1 180.45

Graph of Pressure against x1, y2

180
160
140
120
Pressure (kPa)

Column P
100 Bubble Line
80 Dew Line
60
40
20
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
x1, y2