Carbothane® 134 HG

Polyurethane Gloss Coating

Selection & Specification Data Substrates & Surface Preparation

Generic Type Aliphatic Acrylic Polyurethane
Description Thin film, high gloss finish with exceptional
weathering performance characteristics. Used
extensively in virtually all industrial markets
including marine exposure, Carbothane 134 HG
provides a smooth, durable finish that has
superior resistance to corrosion, abrasion and
chemical exposure.
General Surfaces must be clean and dry. Employ
adequate methods to remove dirt, dust, oil
and all other contaminants that could interfere
with adhesion of the coating. For all surfaces
prime with specific Carboline primer as
recommended by your Carboline sales
representative. Refer to the specific primer’s
Product Data Sheet for detailed requirements
of the specified primer.

Features  High solids, low VOC content Galvanized Prime with specific Carboline primer as
 Excellent weatherability Steel recommended by your Carboline Sales
 Conforms to the performance requirements Representative. Refer to the specific primer’s
of AS 3750.6:2009 Type 1 “Paints for Steel Product Data Sheet for substrate preparation
Structures – Full Gloss Polyurethane (2 requirements.
pack)”
 Approved for use in food & dairy processing Previously Lightly sand or abrade to roughen and
plants (see "Approvals" opposite) Painted degloss the surface. Existing paint must attain
 Exceeds SSPC Paint 36 specification for a Surfaces a minimum 3B rating in accordance with
Level 3 urethane ASTM D3359 “XScribe” adhesion test.
 Available in full lead-free colour range
 Excellent flow characteristics allow for Performance Data & Approvals
application by spray or roller
Test Method System Results Report #
 Superior impact and abrasion resistance Blasted Steel
 Indefinite recoatability ASTM D4541
1 ct Epoxy
18.3 MPa (2652 psi)
09360
Adhesion (Pneumatic)
 VOC compliant to current AIM regulations 1 ct 134 HG
ASTM D3359 Blasted Steel
Gloss Gloss Adhesion 1 ct Epoxy 5A 09360
1 ct 134 HG
ASTM D4060 Blasted Steel 70 mg loss after 1000
Colour NZ Standard: White, Black & Yellow LF cycles, CS17 wheel, 09360
Abrasion 1 ct 134 HG
AU Standard: White & Yellow LF 1000 gm load
AU / NZTinted: Full range of lead-free tinted No blistering, rusting or
AS, BS & RAL colours and ASTM G26 Blasted Steel cracking; gloss
custom colours Weatherometer 1 ct Epoxy retention of 85%; colour 09360
1 ct 134 HG change 1 McAdam unit
after 2000 hours
Primers Refer to Substrates & Surface Preparation ASTM G53 Blasted Steel No rusting, blistering or
ASTM D4587 1 ct Org. Zinc loss of adhesion; less 03390
® Accelerated 1 ct Epoxy than 5% gloss loss
Topcoats Carbothane 130 Clear Coat when required for
graffiti resistance or extreme weatherability Weathering 1 ct 134 HG after 3000 hours
Blasted Steel No rusting, blistering or
ASTM B117 1 ct Org. Zinc loss of adhesion or any
Dry Film 50-70 microns measurable creepage 03390
Salt Fog 1 ct Epoxy
Thickness 1 ct 134 HG from scribe after 3000
hours
ASTM D3363 Blasted Steel
Solids By Volume: 70% ± 2% 1 ct Epoxy H 09360
Hardness
Content 1 ct 134 HG
ASTM D2794 Blasted Steel 179 kg-cm (155 Inch-lb)
14 m2/l at 50 microns Impact no visible cracking. 03359
Theoretical Resistance
1 ct 134 HG
Gardner Impact Tester
Coverage Rate Allow for loss in mixing and application
No rusting in the scribe;
Blasted Steel no blistering, softening
Mix Ratio 4:1 by volume (Part A : Part B) ASTM D870 1 ct Org. Zinc or discolouration after
Immersion 1 ct Epoxy either 30 days 03390
Resistance 1 ct 134 HG freshwater immersion
VOC Values As supplied: 264 g/l or 30 days of slat water
Thinned 20% with #25: 366 g/l immersion at 24°C
These are nominal values and may vary slightly
with colour. Test reports and additional data available on written request.
Approvals:
Dry Temp. Continuous: 93°C NORSOK M-501, Revision 5, System 1: ISO 20340
Resistance Non-Continuous: 121°C Carbothane 134 HG 1 coat 60-75 microns DFT*
Discolouration and loss of gloss is observed *As finish coat over various approved priming & intermediate coats.
above 93°C. Reference N.I.T, Oslo, Norway;
Report Nos. 3410-05-0060 Mt01, Mt02, Mt03 & Mt08

Food Processing
NZ AsureQuality assessed & passed for food/beverage including
dairy farm & factory non-incidental contact. Ref: H3112

Issued August 2013 - Updating July 2012 - Users should check they are referencing the latest product and safety data by checking for updates or amendments at www.altexcoatings.com
Manufactured and / or distributed in Australia & New Zealand by Altex Coatings under license to Carboline Company. To the best of our knowledge the technical data contained herein is true and
accurate on the date of publication and is subject to change without prior notice. User must contact Altex Coatings to verify correctness before specifying or ordering. No guarantee of accuracy is
given or implied. We guarantee our products to conform to Carboline quality control. We assume no responsibility for coverage, performance or injuries resulting from use. Liability, if any, is limited
to replacement of products. NO OTHER WARRANTY OR GUARANTEE OF ANY KIND IS MADE BY ALTEX COATINGS OR CARBOLINE EXPRESS OR IMPLIED, STATUTORY, BY OPERATION
OF LAW, OR OTHERWISE, INCLUDING MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE. Carboline and Carbothane are registered trademarks of Carboline Company.
Carbothane® 134 HG

Application Equipment Application Conditions

Listed below are general equipment guidelines for the application of this product.
Job site conditions may require modifications to these guidelines to achieve the
Condition Material Surface Ambient Humidity
desired results. General Guidelines: Normal 16°-29°C 18°-29°C 18°-29°C 40-60%
Minimum 10°C 2°C 2°C 10%
Spray This is a high solids coating and may require Maximum 38°C 49°C 35°C 80%
Application adjustments in spray techniques. Wet film
(General) thickness is easily and quickly achieved. The
Industry standards are for substrate temperatures to be 3°C above
following spray equipment has been found
the dew point.
suitable and is available from manufacturers
Caution: This product is moisture sensitive in the liquid stage and
such as DeVilbiss and Graco.
until fully cured. Protect from high humidity, dew and direct moisture
contact until fully cured. Application and/or curing in humidities
Conventional Pressure pot equipped with dual regulators, 9mm above maximum, or exposure to moisture from rain or dew may
Spray (3/8”) I.D. minimum material hose, 1.8mm (.070”) result in a loss of gloss and/or micro-bubbling of the product.
I.D. fluid tip and appropriate air cap.

Airless Spray Pump Ratio: 30:1 (min.)* Curing Schedule

Output: 10 lt/min (min.)
Material Hose: 9mm (3/8”) I.D. (min.) Surface
Tip Size: .015-.017” Temp. & 50% Dry to Minimum Dry
Final Cure
Output PSI: 2100-2400 Relative Handle to Recoat*
Filter Size: 60 mesh Humidity
*Teflon packings are recommended and 2C 36 hours 36 hours 14 days
available from the pump manufacturer. 10C 16 hours 16 hours 10 days
24C 8 hours 8 hours 7 days
Brush & Multiple coats may be required to obtain desired 32C 4 hours 4 hours 5 days
Roller appearance, recommended dry film thickness
(General) and adequate hiding. Avoid excessive re- These times are based on a 50 micron dry film thickness. Higher film
brushing or re-rolling. For best results, tie-in thickness, insufficient ventilation or cooler temperatures will require
within 10 minutes at 24°C. longer cure times and could result in solvent entrapment and
premature failure.
Brush Recommended for touch-up only. Use a medium, *Maximum recoat times are indefinite. Surface must be clean and
natural bristle brush. dry. As part of good painting practice it is recommended to test for
adhesion by wiping the surface with Thinner 214 or 215. If the film
Roller Use a short-nap roller cover with a phenolic core shows a slight “tack” the surface is suitable for recoating without
extensive surface preparation such as abrading.
Mixing & Thinning
Packaging, Handling & Storage
Mixing Power mix Part A separately, then combine and
power mix. DO NOT MIX PARTIAL KITS. Pack Sizes Std Colours: 5 litre kits
Tinted Colours: 5 litre & 10 litre kits
Ratio 4:1 by volume (Part A : Part B)
Flash Point Carbothane 134 HG Part A: 10°C
Thinning Spray: Recommended 20% with #25 (Setaflash) Carbothane 134 HG Part B: 41°C
Brush: Up to 20% with #22
Roller: Up to 20% with #22
Use of thinners other than those supplied or Storage Store under cover. KEEP DRY
recommended by Carboline may adversely affect Temperature 4°-43°C
product performance and void product warranty, & Humidity 0-80% Relative Humidity
whether expressed or implied.

4 Hours at 24°C and less at higher temperatures. Shelf Life Part A: Min. 36 months at 24°C
Pot Life
Pot life ends when coating becomes too viscous Part B: Min. 24 months at 24°C
(Thinned) to use. *Shelf Life: (actual stated shelf life) when kept at recommended
MOISTURE CONTAMINATION WILL SHORTEN storage conditions and in original unopened containers.
POT LIFE AND CAUSE GELLATION.

Cleanup & Safety

Cleanup Use Thinner #2 or Acetone. In case of spillage,
absorb and dispose of in accordance with local
applicable regulations.

Safety Read and follow all caution statements on this

product data sheet and on the MSDS for this
product. Employ normal workmanlike safety
precautions. Hypersensitive persons should wear
protective clothing, gloves and use protective
cream on face, hands and all exposed areas.

Ventilation Contains isocyanate. When sprayed may be Manufactured / supplied by:-

harmful by inhalation - do not breath vapour or Altex Coatings Ltd, 91-111 Oropi Road,
Caution spray. Wear suitable clothing, gloves, eye and Tauranga 3112
face protection, including suitable breathing New Zealand
protection such as an air supplied respirator or Phone: +64 7 5411221
hood. Resene Paints Australia Ltd.
T/A Altex Coatings
7 Production Avenue
Queensland 4214
Australia
Phone: +61 7 55949522

Issued August 2013 - Updating July 2012 - Users should check they are referencing the latest product and safety data by checking for updates or amendments at www.altexcoatings.com
Manufactured and / or distributed in Australia & New Zealand by Altex Coatings under license to Carboline Company. To the best of our knowledge the technical data contained herein is true and
accurate on the date of publication and is subject to change without prior notice. User must contact Altex Coatings to verify correctness before specifying or ordering. No guarantee of accuracy is
given or implied. We guarantee our products to conform to Carboline quality control. We assume no responsibility for coverage, performance or injuries resulting from use. Liability, if any, is limited
to replacement of products. NO OTHER WARRANTY OR GUARANTEE OF ANY KIND IS MADE BY ALTEX COATINGS OR CARBOLINE, EXPRESS OR IMPLIED, STATUTORY, BY
OPERATION OF LAW, OR OTHERWISE, INCLUDING MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE. Carboline and Carbothane are registered trademarks of
Carboline Company.
Date Printed: 3/20/2013 Page 1 / 6

CHEMTREC Transportation Emergency Phone:

800-424-9300
Material Safety Pittsburgh Poison Control Center Health
Emergency No.: 412-681-6669

Data Sheet NOTE: The CHEMTREC Transportation Emergency

Phone is to be used only in the event of chemical
emergencies involving a spill, leak, fire, exposure, or
accident involving chemicals

1. Identification
Product Name: CARBOTHANE 134 HG PART A Revision Date: 3/20/2013

Identification Number: 0859A1NL Supercedes Date: 9/7/2011

Product Use/Class: Aliphatic Acrylic Polyurethane - FOR INDUSTRIAL USE ONLY

Manufacturer: Carboline Company Preparer: Regulatory Department

2150 Schuetz Road
St. Louis, MO 63146
800-848-4645

2. Hazard Identification
EMERGENCY OVERVIEW: Contains SILICA which can cause cancer. Risk of Cancer depends on duration and level of
exposure. This product may contain Titanium Dioxide, which is listed by IARC as possibly carcinogenic to humans (Group 2B). This
listing is based on inadequate evidence of carcinogenicity in humans and sufficient evidence in experimental animals. This
classification is relevant when exposed to titanium dioxide in dust or powder form only, including cured product that is subject to
sanding, grinding, cutting, or other surface preparation activities. Irritating to eyes and skin. WARNING! - FLAMMABLE LIQUID
AND VAPOUR. Keep away from heat and sources of ignition. Harmful if inhaled. Use with adequate ventilation. Vapours may
cause drowsiness and dizziness. Keep container closed. Avoid contact with skin, eyes and clothing. Wash thoroughly after
handling. Harmful if swallowed. Risk of serious damage to the lungs (by aspiration).
EFFECTS OF OVEREXPOSURE - EYE CONTACT: May cause eye irritation.
EFFECTS OF OVEREXPOSURE - SKIN CONTACT: May cause skin irritation.
EFFECTS OF OVEREXPOSURE - INHALATION: Harmful if inhaled. Symptoms of overexposure may be headache, dizziness,
tiredness, nausea and vomiting. Vapours may be irritating to eyes, nose, throat, and lungs.
EFFECTS OF OVEREXPOSURE - INGESTION: Harmful if swallowed.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: Crystalline silica is known to cause silicosis. Crystalline silica (Quartz)
is classified as a known human carcinogen (Group 1) by IARC. Exposure is by route of inhalation. If material is in a liquid matrix it
is unlikely to be inhaled. When sanding or grinding the finished product, there may be potential for crystalline silica to become
airborne. Repeated and prolonged exposure to solvents may cause brain and nervous system damage.
MEDICAL CONDITIONS PRONE TO AGGRAVATION: No information available.
PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Ingestion, Inhalation, Skin Absorption, Skin Contact

3. Composition/Information On Ingredients

Hazardous Ingredients

Weight % ACGIH TLV- ACGIH TLV- OSHA PEL-

Chemical Name CAS-No. OSHA PEL-TWA
Less Than TWA STEL CEILING
TITANIUM DIOXIDE 13463-67-7 40.0 10 MGM3 N/E 10 MGM3 N/E
0.025 MG/M3 0.1 MG/M3
MICROCRYSTALLINE SILICA 14808-60-7 35.0 N/E N/E
(respirable) (respirable)
N-BUTYL ACETATE 123-86-4 10.0 150 PPM 200 PPM 710 MG/M3 N/E
TOLUENE 108-88-3 10.0 20 PPM N/E 375 MGM3 N/E
CARBON BLACK 1333-86-4 10.0 3.0 MG/M3 N/E 3.5 MG/M3 N/E
Date Printed: 3/20/2013 Page 2 / 6
META-XYLENE 108-38-3 5.0 100 PPM 150 PPM 435 MG/M3 N/E
TRADE
ALIPHATIC DIOL 5.0 25 PPM N/E 25 PPM N/E
SECRET
LIMESTONE 1317-65-3 5.0 10.00 MG/M3 N/E 5 MGM3 N/E
ETHOXYPROPIONATE 763-69-9 5.0 N/E N/E N/E N/E
ETHYL BENZENE 100-41-4 5.0 20 PPM N/E 435 MGM3 N/E
PARA-XYLENE 106-42-3 5.0 100 PPM 150 PPM 435 MGM3 N/E
STODDARD SOLVENT 8052-41-3 5.0 100 PPM N/E 500 PPM N/E
ORTHO-XYLENE 95-47-6 5.0 100 PPM 150 PPM 435 MG/M3 N/E
1-METHOXY-2-PROPANOL
108-65-6 5.0 100 ppm N/E N/E N/E
ACETATE

4. First-aid Measures
AFTER EYE CONTACT: Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
AFTER SKIN CONTACT: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing
contaminated clothing and shoes. If skin irritation persists, call a physician.

AFTER INHALATION: Give oxygen or artificial respiration if needed. Remove person to fresh air. If signs/symptoms continue, get
medical attention.

AFTER INGESTION: Do NOT induce vomiting. Never give anything by mouth to an unconscious person. If swallowed, call a
poison control centre or doctor immediately.

5. Fire-fighting Measures
Flash Point, °F: 50F (10C) Lower Explosive Limit, %: 0.6
(Setaflash) Upper Explosive Limit, %: 10.4
Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam, Water Fog

UNUSUAL FIRE AND EXPLOSION HAZARDS: Vapours are heavier than air and may spread along floors. Vapours may form
explosive mixtures with air. Vapors may travel to areas away from work site before igniting/flashing back to vapor source.* Provide
adequate ventilation. Prevent the creation of flammable or explosive concentrations of vapour in air and avoid vapour concentration
higher than the occupational exposure limits. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Electrical
installations / working materials must comply with the technological safety standards. Wear shoes with conductive soles. Flammable
liquid

SPECIAL FIREFIGHTING PROCEDURES: In the event of fire, wear self-contained breathing apparatus. Cool containers / tanks
with water spray. Flammable.

6. Accidental Release Measures

PERSONAL SAFETY MEASURES/ENVIRONMENTAL MEASURES/METHOD OF CLEANING/CONTAINMENT: Do not allow
material to contaminate ground water system. Prevent product from entering drains. Remove all sources of ignition. To avoid
ignition of vapours by static electricity discharge, all metal parts of the equipment must be grounded. Evacuate personnel to safe
areas. Wear personal protective equipment. For personal protection see section 8. Contain spillage, soak up with non-combustible
absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local /
national regulations (see section 13).

7. Handling and Storage

INSTRUCTIONS FOR SAFE HANDLING : Do not breathe vapours or spray mist. Do not get in eyes, on skin, or on clothing. Keep
containers dry and tightly closed to avoid moisture absorption and contamination. Use only with adequate ventilation/personal
protection. Wash thoroughly after handling. Ensure all equipment is electrically grounded before beginning transfer operations. Do
not use sparking tools. Prepare the working solution as given on the label(s) and/or the user instructions.

STORAGE CONDITIONS: Keep containers tightly closed in a dry, cool and well-ventilated place. Keep container closed when not
in use. Store in a dry, well ventilated place away from sources of heat, ignition and direct sunlight.
Date Printed: 3/20/2013 Page 3 / 6

8. Exposure Controls/Personal Protection

ENGINEERING CONTROLS: Avoid contact with skin, eyes and clothing. Ensure adequate ventilation, especially in confined
areas.

RESPIRATORY PROTECTION: Use only with ventilation to keep levels below exposure guidelines reported in this document. User
should test and monitor exposure levels to ensure all personnel are below guidelines. If not sure, or not able to monitor, use State or
federally approved supplied air respirator. For silica containing coatings in a liquid state, and/or if no exposure limits are established
above, air-supplied respirators are generally not required.

SKIN PROTECTION: Lightweight protective clothing Impervious gloves Gloves should be discarded and replaced if there is any
indication of degradation or chemical breakthrough. Request information on glove permeation properties from the glove supplier.

EYE PROTECTION: Safety glasses with side-shields

OTHER PROTECTIVE EQUIPMENT: Ensure that eyewash stations and safety showers are close to the workstation location.

PROTECTION AND HYGIENE MEASURES : When using, do not eat, drink or smoke. Handle in accordance with good industrial
hygiene and safety practice. Wash hands before breaks and at the end of workday.

9. Physical and Chemical Properties

Boiling Range: 232F (111C) - 284 F (140 C) Vapor Density: Heavier than Air
Odor: Solvent Odor Threshold: N/D
Appearance: Viscous Liquid, Various Colors Evaporation Rate: Slower Than Ether
Solubility in Water: N/D Specific Gravity: app. 1.28
Freeze Point: N/D pH: N/D
Physical State: Liquid Vapor Pressure: No Information

(See section 16 for abbreviation legend)

10. Stability and Reactivity

CONDITIONS TO AVOID: Heat, flames and sparks.

MATERIALS TO AVOID: Strong oxidizing agents

HAZARDOUS DECOMPOSITION PRODUCTS: Carbon dioxide (CO2), carbon monoxide (CO), oxides of nitrogen (NOx), dense
black smoke.

HAZARDOUS POLYMERIZATION: Hazardous polymerisation does not occur.

STABILITY: Stable under normal conditions.

11. Toxicological Information

Chemical Name CAS-No. LD50 LC50
TITANIUM DIOXIDE 13463-67-7 10000 mg/m3, oral (rat) 6.82 mg/L, Inh, rat 4H
MICROCRYSTALLINE SILICA 14808-60-7 Not Available Not Available
N-BUTYL ACETATE 123-86-4 10760 mg/kg, rat, oral 23.4 mg/l/4/h (rat)
5000 mg/kg rat oral, 14000 mg/
TOLUENE 108-88-3 8000 ppm/4 hrs, rat, inhalation
kg rabbit dermal
CARBON BLACK 1333-86-4 8000 mg/kg oral, rat Not Available
META-XYLENE 108-38-3 Not Available Not Available
Date Printed: 3/20/2013 Page 4 / 6
TRADE
ALIPHATIC DIOL Not Available Not Available
SECRET
LIMESTONE 1317-65-3 6450 mg/kg, oral, rat Not Available
ETHOXYPROPIONATE 763-69-9 Not Available Not Available
ETHYL BENZENE 100-41-4 3500 mg/kg rat, oral 17.2 mg/L Inh, Rat, 4Hr
PARA-XYLENE 106-42-3 Not Available Not Available
STODDARD SOLVENT 8052-41-3 6001 mg/kg, oral, rat 5500 mg/m3, 4h, inhalation
ORTHO-XYLENE 95-47-6 Not Available Not Available
1-METHOXY-2-PROPANOL ACETATE 108-65-6 8532 mg/kg, oral (rat) 1105 mg/m3/4H

12. Ecological Information

ECOLOGICAL INFORMATION: No information available.

13. Disposal Information

DISPOSAL INFORMATION: Dispose of in accordance with local regulations.

14. Transport Information

DOT Proper Shipping Name: Paint Packing Group: II
DOT Technical Name: N/A Hazard Subclass: N/A
DOT Hazard Class: 3 Resp. Guide Page: 128
DOT UN/NA Number: UN 1263
Additional Notes: No Information

15. Regulatory Information

U.S. Federal Regulations:
CERCLA - SARA Hazard Category

This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the
Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to
meet the following categories:

Fire Hazard, Acute Health Hazard, Chronic Health Hazard

Sara Section 313:

This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
Chemical Name CAS-No.
TOLUENE 108-88-3
META-XYLENE 108-38-3
ETHYL BENZENE 100-41-4
PARA-XYLENE 106-42-3
ORTHO-XYLENE 95-47-6
Toxic Substances Control Act:
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported
from the United States:

No TSCA 12(b) components exist in this product.

Date Printed: 3/20/2013 Page 5 / 6

U.S. State Regulations:

New Jersey Right-to-Know:
The following materials are non-hazardous, but are among the top five components in this product.
Chemical Name CAS-No.
ACRYLIC COPOLYMER TRADE SECRET
YELLOW PIGMENT 14059-33-7
COLOR PIGMENT 5567-15-7
Pennsylvania Right-To-Know:
The following non-hazardous ingredients are present in the product at greater than 3%.
Chemical Name CAS-No.
ACRYLIC COPOLYMER TRADE SECRET
YELLOW PIGMENT 14059-33-7
COLOR PIGMENT 5567-15-7
YELLOW PIGMENT 31837-42-0
AZO PIGMENT 82199-12-0
YELLOW IRON OXIDE 51274-00-1
IRON OXIDE 1309-37-1
POLYMER NON HAZARDOUS TRADE SECRET
AZO PIGMENT 2786-76-7
RED PIGMENT 84632-65-5
COLOR PIGMENT 15793-73-4
QUINACRIDONE PIGMENT 1047-16-1
COLOR PIGMENT 1328-53-6
IRON OXIDE 1332-37-2
CALIFORNIA PROPOSITION 65:
Warning: The following ingredients present in the product are known to the state of California to cause Cancer:
Chemical Name CAS-No.
TITANIUM DIOXIDE 13463-67-7
MICROCRYSTALLINE SILICA 14808-60-7
CARBON BLACK 1333-86-4
ETHYL BENZENE 100-41-4
BENZENE 71-43-2
Warning: The following ingredients present in the product are known to the state of California to cause birth defects, or other
reproductive hazards.

Chemical Name CAS-No.

TOLUENE 108-88-3
METHYL ALCOHOL 67-56-1
BENZENE 71-43-2

International Regulations:
CANADIAN WHMIS:

This MSDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16 headings.

Canadian WHMIS Class: B2 D2A D2B

Date Printed: 3/20/2013 Page 6 / 6

16. Other Information

HMIS Ratings:
Health: 2 Flammability: 3 Reactivity: 1 Personal Protection: X

VOLATILE ORGANIC COMPOUNDS, GR/LTR MIXED (UNTHINNED): 264

Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined

The information contained herein is, to the best of our knowledge and belief accurate. However, since the conditions of handling
and use are beyond our control, we make no guarantee of results, and assume no liability for damages incurred by use of this
material. It is the responsibility of the user to comply with all applicable federal, state, and local laws and regulations.
Date Printed: 4/24/2013 Page 1 / 5

CHEMTREC Transportation Emergency Phone:

800-424-9300
Material Safety Pittsburgh Poison Control Center Health
Emergency No.: 412-681-6669

Data Sheet NOTE: The CHEMTREC Transportation Emergency

Phone is to be used only in the event of chemical
emergencies involving a spill, leak, fire, exposure, or
accident involving chemicals

1. Identification
Product Name: URETHANE CONVERTER 811 Revision Date: 4/24/2013

Identification Number: 0856B1NL Supercedes Date: 3/28/2011

Product Use/Class: Catalyst for Polyurethane Products - FOR INDUSTRIAL USE ONLY

Manufacturer: Carboline Company Preparer: Regulatory Department

2150 Schuetz Road
St. Louis, MO 63146
800-848-4645

2. Hazard Identification
EMERGENCY OVERVIEW: Harmful if inhaled. Violent chemical reaction; water reactive Keep away from oxidising agents,
strongly acid or alkaline materials, as well as of amines, alcohols and water. Causes eye, skin, and respiratory tract irritation. May
cause sensitization of susceptible persons. Combustible liquid and vapour. Keep away from heat and sources of ignition. Use with
adequate ventilation. May be harmful if swallowed.
EFFECTS OF OVEREXPOSURE - EYE CONTACT: May cause eye irritation.
EFFECTS OF OVEREXPOSURE - SKIN CONTACT: May cause allergic skin reaction. May cause skin irritation.
EFFECTS OF OVEREXPOSURE - INHALATION: Vapours may be irritating to eyes, nose, throat, and lungs. May cause allergic
respiratory reaction. Harmful if inhaled. Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting.
Liver and kidney injuries may occur.
EFFECTS OF OVEREXPOSURE - INGESTION: Harmful if swallowed.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: Repeated and prolonged exposure to solvents may cause brain and
nervous system damage. Prolonged exposure can be harmful for certain organs, e.g. liver, kidneys, blood, nervous system and
skin.
MEDICAL CONDITIONS PRONE TO AGGRAVATION: Persons allergic to isocyanates, and particularly those suffering from
asthma or other respiratory conditions, should not work with isocyanates.
PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Ingestion, Skin Absorption, Skin Contact

3. Composition/Information On Ingredients

Hazardous Ingredients

Weight % ACGIH TLV- ACGIH TLV- OSHA PEL-

Chemical Name CAS-No. OSHA PEL-TWA
Less Than TWA STEL CEILING
HOMOPOLYMER OF HDI 28182-81-2 90.0 N/E N/E N/E N/E
N-BUTYL ACETATE 123-86-4 5.0 150 PPM 200 PPM 710 MG/M3 N/E
AROMATIC HYDROCARBON 64742-95-6 5.0 N/E N/E N/E N/E
HEXAMETHYLENE
822-06-0 1.0 0.005 PPM N/E N/E N/E
DIISOCYANATE
Date Printed: 4/24/2013 Page 2 / 5

4. First-aid Measures
AFTER EYE CONTACT: Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

AFTER SKIN CONTACT: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing
contaminated clothing and shoes. If skin irritation persists, call a physician.

AFTER INHALATION: Give oxygen or artificial respiration if needed. Remove person to fresh air. If signs/symptoms continue, get
medical attention.

AFTER INGESTION: Do NOT induce vomiting. Never give anything by mouth to an unconscious person. If swallowed, call a
poison control centre or doctor immediately.

5. Fire-fighting Measures
Flash Point, °F: 127F (53C) Lower Explosive Limit, %: 0.9
(Setaflash) Upper Explosive Limit, %: 7.6
Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam

UNUSUAL FIRE AND EXPLOSION HAZARDS: Combustible Liquid Provide adequate ventilation. Keep away from
heat/sparks/open flames/hot surfaces. - No smoking.

SPECIAL FIREFIGHTING PROCEDURES: Combustible material Cool containers / tanks with water spray. In the event of fire,
wear self-contained breathing apparatus.

6. Accidental Release Measures

PERSONAL SAFETY MEASURES/ENVIRONMENTAL MEASURES/METHOD OF CLEANING/CONTAINMENT: Remove all
sources of ignition. To avoid ignition of vapours by static electricity discharge, all metal parts of the equipment must be grounded.
Evacuate personnel to safe areas. Wear personal protective equipment. For personal protection see section 8. Contain spillage,
soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for
disposal according to local / national regulations (see section 13). Do not allow material to contaminate ground water system.
Prevent product from entering drains.

7. Handling and Storage

INSTRUCTIONS FOR SAFE HANDLING : Do not breathe vapours or spray mist. Do not get in eyes, on skin, or on clothing. Keep
containers dry and tightly closed to avoid moisture absorption and contamination. Use only with adequate ventilation/personal
protection. Wash thoroughly after handling. Ensure all equipment is electrically grounded before beginning transfer operations. Do
not use sparking tools. Prepare the working solution as given on the label(s) and/or the user instructions.

STORAGE CONDITIONS: Keep container closed when not in use. Store in a dry, well ventilated place away from sources of heat,
ignition and direct sunlight.

8. Exposure Controls/Personal Protection

ENGINEERING CONTROLS: Avoid contact with skin, eyes and clothing. Ensure adequate ventilation, especially in confined
areas.

RESPIRATORY PROTECTION: In order to avoid inhalation of spray-mist and sanding dust, all spraying and sanding must be done
wearing adequate respirator. Use only with ventilation to keep levels below exposure guidelines reported in this document. User
should test and monitor exposure levels to ensure all personnel are below guidelines. If not sure, or not able to monitor, use State or
federally approved supplied air respirator. For silica containing coatings in a liquid state, and/or if no exposure limits are established
above, air-supplied respirators are generally not required.

SKIN PROTECTION: Lightweight protective clothing Impervious gloves Gloves should be discarded and replaced if there is any
indication of degradation or chemical breakthrough. Request information on glove permeation properties from the glove supplier.
Date Printed: 4/24/2013 Page 3 / 5
EYE PROTECTION: Safety glasses with side-shields

OTHER PROTECTIVE EQUIPMENT: Ensure that eyewash stations and safety showers are close to the workstation location.

PROTECTION AND HYGIENE MEASURES : Handle in accordance with good industrial hygiene and safety practice. Wash hands
before breaks and at the end of workday. When using, do not eat, drink or smoke.

9. Physical and Chemical Properties

Boiling Range: 262 F (128 C) - 262F (128C) Vapor Density: Heavier than Air
Odor: Slight Odor Odor Threshold: N/D
Appearance: Colorless, Mobil Liquid Evaporation Rate: Slower Than Ether
Solubility in Water: Reacts Specific Gravity: 1.12
Freeze Point: N/D pH: N/D
Physical State: Liquid Vapor Pressure: No Information

(See section 16 for abbreviation legend)

10. Stability and Reactivity

CONDITIONS TO AVOID: Heat, flames and sparks.

MATERIALS TO AVOID: Strong oxidizing agents

HAZARDOUS DECOMPOSITION PRODUCTS: Carbon dioxide (CO2), carbon monoxide (CO), oxides of nitrogen (NOx), dense
black smoke.

HAZARDOUS POLYMERIZATION: Hazardous polymerisation does not occur.

STABILITY: Stable under normal conditions.

11. Toxicological Information

Chemical Name CAS-No. LD50 LC50
HOMOPOLYMER OF HDI 28182-81-2 5000 mg/kg, oral, rat 390 mg/m3, inhalation, rat
N-BUTYL ACETATE 123-86-4 10760 mg/kg, rat, oral 23.4 mg/l/4/h (rat)
AROMATIC HYDROCARBON 64742-95-6 4700 mg/kg, oral, rat 3670 ppm/8 hours, rat, inhalation
HEXAMETHYLENE DIISOCYANATE 822-06-0 710 mg/kg, oral rat 23 ppm / 4 hrs

12. Ecological Information

ECOLOGICAL INFORMATION: No information available.

13. Disposal Information

DISPOSAL INFORMATION: Dispose of in accordance with local regulations.
Date Printed: 4/24/2013 Page 4 / 5

14. Transport Information

DOT Proper Shipping Name: Paint Packing Group: III
DOT Technical Name: N/A Hazard Subclass: N/A
DOT Hazard Class: 3 Resp. Guide Page: 128
DOT UN/NA Number: UN 1263
Additional Notes: No Information

15. Regulatory Information

U.S. Federal Regulations:
CERCLA - SARA Hazard Category

This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the
Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to
meet the following categories:

Fire Hazard, Acute Health Hazard

Sara Section 313:

This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
Chemical Name CAS-No.
HEXAMETHYLENE DIISOCYANATE 822-06-0
Toxic Substances Control Act:
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported
from the United States:

No TSCA 12(b) components exist in this product.

U.S. State Regulations:

New Jersey Right-to-Know:
The following materials are non-hazardous, but are among the top five components in this product.

No NJ Right-To-Know components exist in this product.

Pennsylvania Right-To-Know:
The following non-hazardous ingredients are present in the product at greater than 3%.

No PA Right-To-Know components exist in this product.

CALIFORNIA PROPOSITION 65:
Warning: The following ingredients present in the product are known to the state of California to cause Cancer:
Chemical Name CAS-No.
ETHYL BENZENE 100-41-4
CUMENE 98-82-8
Warning: The following ingredients present in the product are known to the state of California to cause birth defects, or other
reproductive hazards.

Chemical Name CAS-No.

TOLUENE 108-88-3
Date Printed: 4/24/2013 Page 5 / 5

International Regulations:
CANADIAN WHMIS:

This MSDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16 headings.
Canadian WHMIS Class: B3 D2A D2B

16. Other Information

HMIS Ratings:
Health: 2 Flammability: 3 Reactivity: 1 Personal Protection: X

VOLATILE ORGANIC COMPOUNDS, GR/LTR MIXED (UNTHINNED): Refer to Part A MSDS

Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined

The information contained herein is, to the best of our knowledge and belief accurate. However, since the conditions of handling
and use are beyond our control, we make no guarantee of results, and assume no liability for damages incurred by use of this
material. It is the responsibility of the user to comply with all applicable federal, state, and local laws and regulations.