PVT Separator Samples Study

Well: HBNEP-3 DST#2

Field: Hassi Berkine Est

Sample Type : Separator

Sampling Date: 07 June 2016

Certificate No. 22824

Certificate No. 22824

28 December
Reported: 06 May 2009 2016 Reference: HML 1980
Reference: HML 1500
HML 1493
 HML 1980
Hassi Berkine Est / HBNEP-3 DST#2
CONTENTS

Description of Experiments

Tables

1. Data Summary
2. Sample Validation

Sample Numbers: 2-3 & 2-4, Cylinder Numbers: 1390-C1-F & 2448-M1-F
3. Separator Gas Composition
4. Separator Liquid Composition
5. Properties of Single Stage Flash at 24.0°C and Data For Recombination
6. Calculated Recombined Fluid Composition

Sample Numbers: 2-5 & 2-6, Cylinder Numbers: 3786-C1-F & 0747-M1-F
7. Separator Gas Composition
8. Separator Liquid Composition
9. Properties of Single Stage Flash at 24.0°Cand Data For Recombination
10. Calculated Recombined Fluid Composition
11. Constant Composition Expansion at 137.0°C - PV Relationship

Figures

Sample Numbers: 2-5 & 2-6, Cylinder Numbers: 3786-C1-F & 0747-M1-F
CONSTANT COMPOSITION EXPANSION AT 137.0°C
1. Relative Volume as a Function of Pressure

Appendix

A. Molecular Weights and Densities Used in PVT Report

B. Glossary
C. Hoffmann Crump - Sample Numbers: 2-3 & 2-4, Cylinder Numbers: 1390-C1-F & 2448-M1-F
D. Hoffmann Crump - Sample Numbers: 2-5 & 2-6, Cylinder Numbers: 3786-C1-F & 0747-M1-F

DRAFT REPORT
HML 1980
Hassi Berkine Est / HBNEP-3 DST#2
DESCRIPTION OF EXPERIMENTS

On the 07 June 2016, three separator pairs were taken on the HBNEP-3 DST#2 well on Hassi Berkine Est field and sent to the
Expro Hassi Messaoud laboratory for analysis.

Validation
The separator gases were heated to above separator temperature, the opening pressures of each cylinder was measured and the
sample was checked for the presence of free liquid. A portion of each gas was sub-sampled for compositional analysis by gas
chromatography.

The saturation pressure of each of the liquids was measured by performing a limited pressure volume relationship in the cylinder
at ambient temperature. The samples were checked for the presence of free water, no free water was detected in any of the
samples.

Separator Liquid Flash

The selected separator oils were restored for several hours at separator temperature and above separator pressure, then agitated
in order to homogenise the fluid in single phase. The samples were then charged into the PVT "blind" cell to determine the
saturation pressure at separator temperature. The fluid was flashed from above separator conditions down to atmospheric
conditions for GOR, Bo and stock tank density measurements with the collection of the evolved gas and residual liquid for
compositional analysis by gas chromatography.

Calculated Recombined Fluid Composition

The field Condensate Gas Ratio (CGR) was corrected by applying laboratory measured separator gas SG and compressibility factor
values to the flow meter calculation. This provided a field corrected CGR which was then used to mathematically recombine the
separator gas and liquid composition to provide the calculated reservoir fluid composition.

Hoffman Crump plots are provided as an appendix to this report.

Physical Recombination (Gas Condensate)

A sub-sample of the required gas was charged to a calibrated recombination cell. The volume of gas at STP (Standard
Temperature and Pressure) was determined. Using the CGR the required quantity of separator liquid at separator conditions was
calculated. The liquid was then injected into the gas at a pressure above separator pressure using a volumetric correction. This
correction was determined during the limited Pressure-Volume relationship conducted on the separator liquid. The recombined
fluid was then stabilised in single phase for use in further experiments.

Constant Composition Expansion (CCE)

The selected gas condensate sample was charged to a visual PVT cell above reservoir conditions. The CCE was conducted by
expanding the sample to a series of suitable pressure stages and stabilising by agitation. The sample was then left until
equilibrium of phases within the cell was achieved. At each stable pressure, the pressure and volume were recorded. Below the
dew point, once a liquid phase was observed, measurements of the volume of retrograde condensation were also made. The dew
point of the fluid was measured by slowly dropping the pressure in the cell until misting was observed in the gas phase. This was
repeated in a series of expansions to provide confirmation of the value.

The fluid was displaced at the end of the CCE and the recovered volume measured, this was used with the CCE volumetric data
to provide the gas deviation values.

Gas Chromatography of Gases

Gases containing nitrogen, oxygen, argon, carbon dioxide and C1 to C12 hydrocarbons are routinely analysed by gas
chromatography (GC). The inorganic components and C1 to C5 hydrocarbons are separated on multiple packed columns linked by
valves, and detected by a thermal conductivity detector. C1 to C12 hydrocarbons are separated on a non-polar capillary column
and detected by a flame ionisation detector. The system is calibrated with a certified gas mixture. A second certified gas standard
is analysed daily and the results must be within specification before analysing any unknown samples. Samples are heated to
80.0°C before analysis and are loaded onto the columns via evacuated sample loops. The transfer line and valves are heated to
110.0°C and 130.0°C, respectively.

Gas Chromatography of Liquids

Black oils and condensates are analysed by gas chromatography (GC). The instrument is equipped with a split/splitless injector, a
non-polar capillary column and a flame ionisation detector. A quantitative blend of normal alkanes is analysed daily to ensure that
there is no discrimination up to at least C40. A solvent blank is run to allow a correction to be applied for the rise in the baseline
that occurs as the oven temperature is ramped. An ASTM reference gas oil or a reference crude oil is analysed daily, the results
must be within specification before any unknown samples are analysed. Samples are diluted and require the gravimetric addition
of internal standard if they are not fully recovered at C40. Components up to about C9 may be individually resolved and
quantified but species beyond nC9 are usually reported as pseudo-components, based on the retention times of the normal
alkanes.

Destruction des Echantillons

Les échantillons référencés dans ce rapport seront conservés au laboratoire d’Expro en Algerie pour une période de 30 jours à
partir de la soumission du rapport finale. A la fin de cette période les échantillons seront détruits. Dans le cas où la Sonatrach
souhaiterait conserver certains de ces échantillons au-delà de cette période, une demande devra être effectué et des frais de
location par cylindre conservé s’appliqueront pour la période au-delà des 30 jours initiaux.

DRAFT REPORT
HML 1980 TABLE 1
Hassi Berkine Est / HBNEP-3 DST#2

Data Summary

Sampling Details

Field Hassi Berkine Est

Well Number HBNEP-3
Test Number DSt#2
Sampling Date 07 June 2016
Sample Type Separator Samples
Reservoir Pressure Information Not Available
Reservoir Temperature Information Not Available
Separator Pressure 20.3 bara
Separator Temperature 24.0°C

Liquids Gases

Cylinder Numbers 5642-M1-F 2338-C1-F

2448-M1-F 1390-C1-F
0747-M1-F 3786-C1-F

DRAFT REPORT
HML 1980 TABLE 2
Hassi Berkine Est / HBNEP-3 DST#2

Sample Validation

Separator Liquids

Sample Cylinder Separator Saturation Water

Number Number Pressure Temperature Pressure Temperature Content(1)
bara °C bara °C cm3

2-2 5642-M1-F 20.3 24.0 - - -

2-4 2448-M1-F 20.3 24.0 19.7 21.0 0
2-6 0747-M1-F 20.3 24.0 19.3 21.0 0

Separator Gases

Sample Cylinder Sampling Opening Water

Number Number Pressure Temperature Pressure Temperature Content(1)
bara °C bara °C cm3

2-1 2338-C1-F 20.3 24.0 - - -

2-3 1390-C1-F 20.3 24.0 19.3 32.0 0
2-5 3786-C1-F 20.3 24.0 19.0 32.0 0

Notes:
1. Quantity of free water drained from sample.

DRAFT REPORT
HML 1980 TABLE 3
Hassi Berkine Est / HBNEP-3 DST#2

Separator Gas Composition

Sample Number: 2-3

Cylinder Number: 1390-C1-F

Component mol%

N2 0.405
CO2 3.154
nC1 86.625
nC2 6.520
nC3 1.863
iC4 0.478
nC4 0.406
neo-C5 0.018
iC5 0.234
nC5 0.091
C6 0.120
Benzene 0.003
C7 0.055
Toluene 0.002
C8 0.014
Ethylbenzene <0.001
M- and P- Xylenes 0.002
O- Xylene <0.001
C9 0.005
C10 0.004
C11 0.001
C12+ <0.001
Total 100.000

Molecular Weight / (g/mol) : 19.1

Gas Gravity, (air=1.000) : 0.661

DRAFT REPORT
HML 1980 TABLE 4
Hassi Berkine Est / HBNEP-3 DST#2

Separator Liquid Composition

Sample Number: 2-4

Cylinder Number: 2448-M1-F

Component Plus Fraction Estimated Molecular

Evolved Gas Stabilised Oil Separator Liquid Composition Density¹ Weight
wt% mol% wt% mol% wt% mol% wt% mol% g/cm³ g/mol

N2 0.026 0.033 0.000 0.000 0.002 0.007

CO2 4.373 3.584 0.000 0.000 0.290 0.771
nC1 17.428 39.189 0.000 0.000 1.157 8.427
nC2 15.650 18.772 0.042 0.193 1.078 4.188
nC3 18.186 14.874 0.286 0.903 1.474 3.907
iC4 10.181 6.318 0.503 1.203 1.146 2.303
nC4 10.184 6.320 0.834 1.995 1.455 2.925
neo-C5 0.581 0.290 0.063 0.122 0.098 0.158
iC5 9.216 4.607 2.267 4.368 2.728 4.419
nC5 3.811 1.905 1.347 2.595 1.511 2.447
C6 6.774 2.835 6.210 10.015 6.247 8.471
Benzene 0.143 0.066 0.244 0.433 0.237 0.354 C7+ 82.814 61.977 0.796 156
C7 2.550 0.918 9.827 13.631 9.344 10.897
Toluene 0.118 0.046 1.279 1.929 1.202 1.524
C8 0.668 0.211 11.429 13.908 10.713 10.962
Ethylbenzene 0.002 0.001 0.166 0.217 0.155 0.171
M- and P- Xylenes 0.022 0.007 1.189 1.557 1.112 1.223
O- Xylene 0.002 0.001 0.378 0.495 0.353 0.388
C9 0.064 0.018 8.260 8.951 7.716 7.030
C10 0.008 0.002 8.012 7.826 7.481 6.144
C11 0.004 0.001 6.465 5.748 6.036 4.512
C12 0.004 0.001 5.198 4.241 4.853 3.329 C12+ 38.465 18.772 0.847 239
C13 0.003 0.001 4.520 3.407 4.220 2.675
C14 0.002 <0.001 3.853 2.699 3.597 2.119
C15 0.000 0.000 3.350 2.192 3.128 1.721
C16 0.000 0.000 2.907 1.784 2.714 1.401
C17 0.000 0.000 2.919 1.687 2.725 1.324
C18 0.000 0.000 2.444 1.335 2.282 1.048
C19 0.000 0.000 1.876 0.971 1.752 0.762
C20 0.000 0.000 1.813 0.892 1.693 0.700 C20+ 13.194 4.393 0.887 351
C21 0.000 0.000 1.592 0.746 1.486 0.586
C22 0.000 0.000 1.420 0.635 1.326 0.499
C23 0.000 0.000 1.239 0.531 1.157 0.417
C24 0.000 0.000 1.091 0.448 1.018 0.351
C25 0.000 0.000 0.960 0.378 0.896 0.297
C26 0.000 0.000 0.858 0.325 0.801 0.255
C27 0.000 0.000 0.752 0.274 0.702 0.215
C28 0.000 0.000 0.660 0.232 0.616 0.182
C29 0.000 0.000 0.583 0.198 0.545 0.156
C30 0.000 0.000 0.520 0.171 0.486 0.134
C31 0.000 0.000 0.440 0.140 0.411 0.110
C32 0.000 0.000 0.394 0.121 0.368 0.095
C33 0.000 0.000 0.342 0.102 0.319 0.080
C34 0.000 0.000 0.294 0.085 0.274 0.067
C35 0.000 0.000 0.252 0.071 0.236 0.056
C36+ 0.000 0.000 0.922 0.246 0.860 0.193 C36+ 0.860 0.193 0.923 520
Total 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 - 117

Notes:
¹ Density: Taken from Katz and Firoozabadi, Journal of Petroleum Tech., Nov. 1978.

DRAFT REPORT
HML 1980 TABLE 5
Hassi Berkine Est / HBNEP-3 DST#2

Properties of Single Stage Flash at 24.0°C

Sample Number: 2-4

Cylinder Number: 2448-M1-F

Single Stage Flash to Stock Tank Conditions

Gas Liquid Ratio 34.9 sm³/sm³

Gas Gravity, (air = 1.000) 1.245

Stabilised Oil Gravity at STP 0.7487 [57.49°API]

(1)
Fluid Volume Factor 1.113
Saturation Pressure 19.7 bara

Fluid Density at Saturation Pressure 0.720 g/cm³

Data for Recombination

Sample Numbers: 2-3 & 2-4

Cylinder Numbers: 1390-C1-F

Separator Gas Field Laboratory

Data Data

Gas Gravity, sg, (air=1.000) 0.732 0.661

Fg, (sg-½) 1.169 1.230
Fpv, (Z-½) 1.039 1.026
(2)
CGR (sm³/MMsm³) 46.5 44.7
Correction Factor 1.039

Notes:

1. Fluid volume factor: Fluid volume at saturation pressure per volume of stock tank oil at STP.

2. Corrected CGR=Field CGR ÷ Fg (lab) x Fpv (lab)

Fg (field) x Fpv (field)

DRAFT REPORT
HML 1980 TABLE 6
Hassi Berkine Est / HBNEP-3 DST#2

Calculated Recombined Fluid Composition

Sample Numbers: 2-3 & 2-4

Cylinder Numbers: 1390-C1-F & 2448-M1-F

CGR 44.7 sm³/MMsm³

Component Calculated Fluid Plus Fraction Estimated Molecular

Composition Density¹ Weight
wt% mol% wt% mol% g/cm³ g/mol

N2 0.568 0.402
CO2 6.958 3.137
nC1 69.571 86.061
nC2 9.856 6.503
nC3 4.175 1.878
iC4 1.440 0.492
nC4 1.241 0.424
neo-C5 0.070 0.019
iC5 0.960 0.264
nC5 0.391 0.108
C6 0.782 0.180
Benzene 0.022 0.005 C7+ 3.988 0.532 0.790 148
C7 0.674 0.133
Toluene 0.061 0.013
C8 0.533 0.092
Ethylbenzene 0.007 0.001
M- and P- Xylenes 0.060 0.011
O- Xylene 0.017 0.003
C9 0.362 0.056
C10 0.348 0.049
C11 0.267 0.034
C12 0.208 0.024 C12+ 1.637 0.135 0.847 239
C13 0.180 0.019
C14 0.153 0.015
C15 0.133 0.012
C16 0.115 0.010
C17 0.116 0.010
C18 0.097 0.008
C19 0.074 0.005
C20 0.072 0.005 C20+ 0.561 0.032 0.887 351
C21 0.063 0.004
C22 0.056 0.004
C23 0.049 0.003
C24 0.043 0.003
C25 0.038 0.002
C26 0.034 0.002
C27 0.030 0.002
C28 0.026 0.001
C29 0.023 0.001
C30 0.021 0.001
C31 0.017 0.001
C32 0.016 0.001
C33 0.014 0.001
C34 0.012 <0.001
C35 0.010 <0.001
C36+ 0.037 0.001 C36+ 0.037 0.001 0.923 520
Total 100.000 100.000 100.000 100.000 - 19.8

Notes:
¹ Density: Taken from Katz and Firoozabadi, Journal of Petroleum Tech., Nov. 1978.

DRAFT REPORT
HML 1980 TABLE 7
Hassi Berkine Est / HBNEP-3 DST#2

Separator Gas Composition

Sample Number: 2-5

Cylinder Number: 3786-C1-F

Component mol%

N2 0.400
CO2 3.140
nC1 86.240
nC2 6.502
nC3 1.882
iC4 0.505
nC4 0.441
neo-C5 0.021
iC5 0.296
nC5 0.124
C6 0.235
Benzene 0.006
C7 0.130
Toluene 0.011
C8 0.052
Ethylbenzene <0.001
M- and P- Xylenes 0.004
O- Xylene <0.001
C9 0.008
C10 0.001
C11 0.001
C12+ 0.001
Total 100.000

Molecular Weight / (g/mol) : 19.4

Gas Gravity, (air=1.000) : 0.670

DRAFT REPORT
HML 1980 TABLE 8
Hassi Berkine Est / HBNEP-3 DST#2

Separator Liquid Composition

Sample Number: 2-6

Cylinder Number: 0747-M1-F

Component Plus Fraction Estimated Molecular

Evolved Gas Stabilised Oil Separator Liquid Composition Density¹ Weight
wt% mol% wt% mol% wt% mol% wt% mol% g/cm³ g/mol

N2 0.040 0.052 0.000 0.000 0.003 0.011

CO2 4.081 3.439 0.000 0.000 0.260 0.693
nC1 16.601 38.385 0.000 0.000 1.059 7.737
nC2 14.682 18.108 0.054 0.248 0.987 3.848
nC3 17.437 14.665 0.328 1.023 1.419 3.773
iC4 10.016 6.392 0.552 1.306 1.156 2.331
nC4 10.189 6.502 0.908 2.146 1.499 3.024
neo-C5 0.589 0.303 0.068 0.130 0.101 0.164
iC5 9.655 4.963 2.426 4.621 2.887 4.690
nC5 4.063 2.088 1.437 2.737 1.604 2.606
C6 7.665 3.299 6.501 10.369 6.575 8.944
Benzene 0.175 0.083 0.250 0.440 0.245 0.368 C7+ 82.450 62.179 0.795 155
C7 3.305 1.223 10.041 13.774 9.611 11.245
Toluene 0.194 0.078 1.284 1.916 1.215 1.545
C8 1.071 0.348 11.450 13.781 10.788 11.071
Ethylbenzene 0.005 0.002 0.164 0.212 0.154 0.170
M- and P- Xylenes 0.058 0.020 1.173 1.518 1.102 1.217
O- Xylene 0.006 0.002 0.369 0.477 0.345 0.381
C9 0.151 0.044 8.186 8.774 7.674 7.014
C10 0.014 0.004 7.895 7.628 7.393 6.091
C11 <0.001 <0.001 6.367 5.600 5.961 4.471
C12 0.001 <0.001 5.117 4.129 4.791 3.297 C12+ 37.962 18.606 0.847 239
C13 0.001 <0.001 4.454 3.321 4.170 2.652
C14 0.001 <0.001 3.799 2.632 3.557 2.102
C15 <0.001 <0.001 3.305 2.138 3.094 1.707
C16 0.000 0.000 2.871 1.743 2.688 1.392
C17 0.000 0.000 2.880 1.646 2.696 1.314
C18 0.000 0.000 2.414 1.304 2.260 1.041
C19 0.000 0.000 1.852 0.948 1.734 0.757
C20 0.000 0.000 1.790 0.871 1.676 0.695 C20+ 12.972 4.344 0.887 350
C21 0.000 0.000 1.578 0.731 1.477 0.584
C22 0.000 0.000 1.402 0.621 1.313 0.495
C23 0.000 0.000 1.227 0.520 1.149 0.415
C24 0.000 0.000 1.077 0.437 1.008 0.349
C25 0.000 0.000 0.952 0.371 0.891 0.296
C26 0.000 0.000 0.848 0.318 0.794 0.254
C27 0.000 0.000 0.742 0.268 0.694 0.214
C28 0.000 0.000 0.647 0.225 0.605 0.180
C29 0.000 0.000 0.569 0.191 0.533 0.153
C30 0.000 0.000 0.502 0.163 0.470 0.130
C31 0.000 0.000 0.430 0.135 0.403 0.108
C32 0.000 0.000 0.381 0.116 0.357 0.093
C33 0.000 0.000 0.329 0.097 0.308 0.078
C34 0.000 0.000 0.282 0.081 0.264 0.065
C35 0.000 0.000 0.240 0.067 0.225 0.054
C36+ 0.000 0.000 0.859 0.227 0.805 0.181 C36+ 0.805 0.181 0.923 520
Total 100.000 100.000 100.000 100.000 100.000 100.000 100.000 100.000 - 117

Notes:
¹ Density: Taken from Katz and Firoozabadi, Journal of Petroleum Tech., Nov. 1978.

DRAFT REPORT
HML 1980 TABLE 9
Hassi Berkine Est / HBNEP-3 DST#2

Properties of Single Stage Flash at 24.0°C

Sample Number: 2-6

Cylinder Number: 0747-M1-F

Single Stage Flash to Stock Tank Conditions

Gas Liquid Ratio 32.6 sm³/sm³

Gas Gravity, (air = 1.000) 1.280

Stabilised Oil Gravity at STP 0.7493 [57.34°API]

(1)
Fluid Volume Factor 1.108
Saturation Pressure 19.3 bara

Fluid Density at Saturation Pressure 0.722 g/cm³

Data for Recombination

Sample Numbers: 2-5 & 2-6

Cylinder Numbers: 3786-C1-F & 0747-M1-F

Separator Gas Field Laboratory

Data Data

Gas Gravity, sg, (air=1.000) 0.732 0.670

Fg, (sg-½) 1.169 1.222
Fpv, (Z-½) 1.039 1.025
(2)
CGR (sm³/MMsm³) 46.5 45.1
Correction Factor 1.031

Notes:

1. Fluid volume factor: Fluid volume at saturation pressure per volume of stock tank oil at STP.

2. Corrected GOR=Field GOR x Fg (lab) x Fpv (lab)

Fg (field) x Fpv (field)

DRAFT REPORT
HML 1980 TABLE 10
Hassi Berkine Est / HBNEP-3 DST#2

Calculated Recombined Fluid Composition

Sample Numbers: 2-5 & 2-6

Cylinder Numbers: 3786-C1-F & 0747-M1-F

CGR 45.1 sm³/MMsm³

Component Calculated Fluid Plus Fraction Estimated Molecular

Composition Density¹ Weight
wt% mol% wt% mol% g/cm³ g/mol

N2 0.553 0.397
CO2 6.831 3.122
nC1 68.320 85.671
nC2 9.691 6.482
nC3 4.155 1.895
iC4 1.498 0.518
nC4 1.327 0.459
neo-C5 0.078 0.022
iC5 1.176 0.328
nC5 0.510 0.142
C6 1.278 0.298
Benzene 0.034 0.009 C7+ 4.583 0.666 0.783 139
C7 1.047 0.210
Toluene 0.100 0.022
C8 0.747 0.132
Ethylbenzene 0.008 0.002
M- and P- Xylenes 0.067 0.013
O- Xylene 0.017 0.003
C9 0.376 0.059
C10 0.322 0.046
C11 0.260 0.034
C12 0.206 0.024 C12+ 1.605 0.136 0.847 239
C13 0.177 0.019
C14 0.150 0.015
C15 0.132 0.013
C16 0.113 0.010
C17 0.114 0.010
C18 0.095 0.008
C19 0.073 0.005
C20 0.071 0.005 C20+ 0.545 0.032 0.887 350
C21 0.062 0.004
C22 0.055 0.004
C23 0.048 0.003
C24 0.042 0.003
C25 0.038 0.002
C26 0.033 0.002
C27 0.029 0.002
C28 0.026 0.001
C29 0.022 0.001
C30 0.020 0.001
C31 0.017 0.001
C32 0.015 0.001
C33 0.013 0.001
C34 0.011 <0.001
C35 0.009 <0.001
C36+ 0.034 0.001 C36+ 0.034 0.001 0.923 520
Total 100.000 100.000 100.000 100.000 - 20.1

Notes:
¹ Density: Taken from Katz and Firoozabadi, Journal of Petroleum Tech., Nov. 1978.

DRAFT REPORT
HML 1980 TABLE 11
Hassi Berkine Est / HBNEP-3 DST#2

Constant Composition Expansion at 137.0°C

PV Relationship

Sample Numbers: 2-5 & 2-6

Cylinder Numbers: 3786-C1-F & 0747-M1-F

Pressure Coefficient Relative Gas Calculated Volume Percent

of Volume Compressibility Gas of
Compressibility Factor Viscosity(1) Liquid
C0 Z
bara 10-6 (vol/vol) bar-1 (VSp=1.000) cP %VSp

551.6 924.8 0.727 1.236 0.0324

Rp 523.9 980.9 0.747 1.206 0.0315
482.6 1103.6 0.780 1.159 0.0302
448.2 1251.5 0.812 1.121 0.0290
413.7 1454.5 0.850 1.084 0.0278
379.2 1731.1 0.898 1.050 0.0266
344.7 2108.1 0.959 1.019 0.0252
Sp 326.1 2366.6 1.000 1.005 0.0245 0.0
310.3 1.037 < 0.1
293.0 1.083 < 0.1
275.8 1.137 < 0.1
241.3 1.273 < 0.1
206.8 1.464 < 0.1
172.4 1.743 < 0.1
137.9 2.178 < 0.1
103.4 2.928 < 0.1
68.9 4.472 < 0.1
34.5 9.209 < 0.1

Specific volume at saturation pressure 5.227 cm3/g

Notes:
Rp: Reservoir pressure
Sp: Saturation pressure
1. Calculated from Gonzalez, Lee and Eakin : "The viscosity of natural gases", J.P.T. August 1966

DRAFT REPORT
HML 1980 FIGURE 1
Hassi Berkine Est / HBNEP-3 DST#2

CONSTANT COMPOSITION EXPANSION AT 137.0°C

Relative Volume as a Function of Pressure
Sample Numbers: 2-6 & 2-6, Cylinder Numbers: 3786-C1-F & 0747-M1-F
10.000

9.000

8.000

7.000
Relative Volume / (VSp=1.000)

6.000

5.000

4.000

3.000

2.000

1.000

0.000
0.0 100.0 200.0 300.0 400.0 500.0 600.0

Pressure, (bara)
HML 1980 APPENDIX A
Hassi Berkine Est / HBNEP-3 DST#2

Molecular Weights and Densities Used in PVT Report

Component Molecular Density

Weight
g/mol g/cm3

N2 28.01
CO2 44.01
nC1 16.04
nC2 30.07
nC3 44.10
iC4 58.12
nC4 58.12
neo-C5 72.15
iC5 72.15
nC5 72.15
C6 86.18 0.685
Benzene 78.11 0.722
C7 100.20 0.722
Toluene 92.14 0.745
C8 114.23 0.745
Ethylbenzene 106.17 0.764
M- and P- Xylenes 106.17 0.764
O- Xylene 106.17 0.764
C9 128.26 0.764
C10 142.28 0.778
C11 156.31 0.789
C12 170.34 0.800
C13 184.36 0.811
C14 198.39 0.822
C15 212.42 0.832
C16 226.44 0.839
C17 240.47 0.847
C18 254.50 0.852
C19 268.53 0.857
C20 282.55 0.862
C21 296.58 0.867
C22 310.61 0.872
C23 324.63 0.877
C24 338.66 0.881
C25 352.69 0.885
C26 366.71 0.889
C27 380.74 0.893
C28 394.77 0.896
C29 408.79 0.899
C30 422.82 0.902
C31 436.84 0.906
C32 450.87 0.909
C33 464.89 0.912
C34 478.92 0.914
C35 492.94 0.917
C36+ As reported

Notes:
Molecular weight data obtained from the following reference :
CRC Handbook of Chemistry and Physics, 77th Edition, 1996-97.

DRAFT REPORT
HML 1980 APPENDIX B
Hassi Berkine Est / HBNEP-3 DST#2

Glossary

Terminology

Residual Liquid
The dead oil remaining from a depletion-type experiment

Stabilised Liquid
The dead oil from any single-stage flash of a live fluid (separator or reservoir).

Stock Tank Oil

Specifically the oil generated from a separator test.

Notation
STP Standard conditions of temperature and pressure. For this report the standard
1.013 bara.

Sp Saturation pressure.
Rp Reservoir pressure.
Bo The oil volume factor is defined as the fluid volume at the reservoir temperature
tank oil at STP.
FVF The fluid volume at specified conditions per volume of residual liquid at STP.
SVF The fluid volume at separator conditions per volume of stock tank oil at STP.
GOR Gas-oil ratio.
Z Gas compressibility factor.

Pstp x Vstp = PT&P x V T&P

Zstp x Tstp ZT&P x TT&P
Rs Solution GOR.
Bg Gas formation volume factor.

Y-function p sat p  1
Y 
V V sat  1

where psat is the saturation pressure and Vsat is the sample volume at
saturation.

ki y
k i  i
x i

where yi is the mole fraction of component i in the gas and xi is the mole
fraction of component i in the liquid.
b The Boyle temperature of the component.
Tb The true boiling temperature of the component.
%VSp Percentage volume of condensate at specified conditions to sample volume at
saturation point.
VSp=1 The volume at saturation is taken arbitrarily to be equal to one.

Relative Deviation Defined as:

measured value  expected
relative deviation 
expected value

% Initial Wellstream The cumulative percentage of the initial wellstream produced.

Two-phase Z-Factor
Stage Pr essure
Sp ZSp 1  Pr oduced Volume Fraction 
Coefficient of Compressibility
Co1,2 = 1 x ( V 2 - V1 )
V1 ( P2 - P1 )

DRAFT REPORT
HML 1980 APPENDIX B
Hassi Berkine Est / HBNEP-3 DST#2

The Orifice Equation is given by

C' =Fb Fpb Ftb Fg Ftf Fr YFpv Fm Fl Fa

where the value C' is known as the orifice constant and is the product of the factors defined below.

Fb The basic orifice flow factor.

Fpb The pressure-base factor.
Ftb The temperature-base factor.
Fg The specific gravity factor, used when the specific gravity of the gas is other
than 1.00.
Ftf The flowing-temperature factor.
Fr The Reynold's number factor.
Y The expansion factor.
Fpv The supercompressibility factor, the function is dependent on the variation
of the gas from the ideal-gas laws.
Fm The manometer factor.
Fl The gauge location factor.
Fa The thermal expansion factor.

References
Calculated Density
Katz and Firoozabadi, Journal of Petroleum Tech., Nov. 1978

Gas Viscosity
Calculated from Gonzalez, Lee and Eakin: "The viscosity of natural gases", J.P.T. August 1996.

Hoffmann Crump
SPE Reprint Series No. 15, Phase Behaviour, 1981, pp 270-280. Reprint of 'Equilibrium Constants of a
Gas-Condensate System', A. E. Hoffman, J. S. Crump, C. R. Hocott, AIME (1953), 198, 1-10.

Molecular Weight
CRC Handbook of Chemistry and Physics, 77th Edition, 1996-97.

Orifice Equation
Petroleum Engineering Handbook, SPE, 1992, H. Bradley.

DRAFT REPORT
 HML 1980 APPENDIX B
Hassi Berkine Est / HBNEP-3 DST#2

standard conditions used are 15.6°C and

temperature and pressure per volume of stock

per volume of residual liquid at STP.

per volume of stock tank oil at STP.

is the mole

Percentage volume of condensate at specified conditions to sample volume at

value
 100 %

DRAFT REPORT
 HML 1980 APPENDIX B
Hassi Berkine Est / HBNEP-3 DST#2

The specific gravity factor, used when the specific gravity of the gas is other

The supercompressibility factor, the function is dependent on the variation

hase Behaviour, 1981, pp 270-280. Reprint of 'Equilibrium Constants of a

DRAFT REPORT
HML 1980 APPENDIX C
Hassi Berkine Est / HBNEP-3 DST#2

Hoffmann Crump

Sample Numbers: 2-3 & 2-4

Cylinder Numbers: 1390-C1-F & 2448-M1-F

Separator Temperature: 24.0 °C

Separator Pressure: 20.3 bara

Component Tb 1/Tb b b[1/Tb-1/T] yi xi Ki K ip ln[Kip]

Rankine mol% mol%

C1 201.01 0.00497 805 2.50 86.623 8.427 10.279 3032.44 2.33

C2 332.16 0.00301 1412 1.61 6.520 4.188 1.557 459.25 0.44
C3 415.96 0.00240 1799 0.96 1.863 3.907 0.477 140.70 -0.74
I-C4 470.58 0.00213 2037 0.52 0.478 2.303 0.208 61.28 -1.57
C4 490.79 0.00204 2153 0.36 0.406 2.925 0.139 40.90 -1.98
I-C5 541.82 0.00185 2368 -0.05 0.252 4.577 0.055 16.23 -2.90
C5 556.62 0.00180 2480 -0.18 0.091 2.447 0.037 10.92 -3.30
C6 615.42 0.00162 2780 -0.68 0.120 8.471 0.014 4.17 -4.26
C7 668.86 0.00150 3068 -1.15 0.058 11.251 0.005 1.53 -5.26
C8 717.89 0.00139 3335 -1.59 0.016 12.485 0.001 0.37 -6.67
C9 763.12 0.00131 3590 -2.00 0.008 8.813 0.001 0.27 -6.99
C10 805.11 0.00124 3828 -2.40 0.004 6.144 0.001 0.21 -7.27

Notes:
SPE Reprint Series No. 15, Phase Behaviour, 1981, pp 270-280. Reprint of 'Equilibrium Constants of a
Gas-Condensate System', A. E. Hoffman, J. S. Crump, C. R. Hocott, AIME (1953), 198, 1-10.

4.00

C1
2.00

C2
0.00
C3
-2.00 C4
ln[Kip]

C5
-4.00
C6
C7
-6.00
C8
C10 C9
-8.00

-10.00
-3.00 -2.00 -1.00 0.00 1.00 2.00 3.00
b[1/Tb-1/T]

DRAFT REPORT
HML 1980 APPENDIX D
Hassi Berkine Est / HBNEP-3 DST#2

Hoffmann Crump

Sample Numbers: 2-5 & 2-6

Cylinder Numbers: 3786-C1-F & 0747-M1-F

Separator Temperature: 24.0 °C

Separator Pressure: 19.3 bara

Component Tb 1/Tb b b[1/Tb-1/T] yi xi Ki K ip ln[Kip]

Rankine mol% mol%

C1 201.01 0.00497 805 2.50 86.239 7.737 11.146 3120.92 2.41

C2 332.16 0.00301 1412 1.61 6.502 3.848 1.690 473.12 0.52
C3 415.96 0.00240 1799 0.96 1.882 3.773 0.499 139.65 -0.70
I-C4 470.58 0.00213 2037 0.52 0.505 2.331 0.217 60.69 -1.53
C4 490.79 0.00204 2153 0.36 0.441 3.024 0.146 40.78 -1.93
I-C5 541.82 0.00185 2368 -0.05 0.317 4.855 0.065 18.28 -2.73
C5 556.62 0.00180 2480 -0.18 0.124 2.606 0.048 13.35 -3.04
C6 615.42 0.00162 2780 -0.68 0.235 8.944 0.026 7.37 -3.64
C7 668.86 0.00150 3068 -1.15 0.136 11.612 0.012 3.28 -4.45
C8 717.89 0.00139 3335 -1.59 0.063 12.616 0.005 1.39 -5.31
C9 763.12 0.00131 3590 -2.00 0.013 8.782 0.001 0.42 -6.51
C10 805.11 0.00124 3828 -2.40 0.001 6.091 0.000 0.07 -8.33

Notes:
SPE Reprint Series No. 15, Phase Behaviour, 1981, pp 270-280. Reprint of 'Equilibrium Constants of a
Gas-Condensate System', A. E. Hoffman, J. S. Crump, C. R. Hocott, AIME (1953), 198, 1-10.

4.00

C1
2.00

C2
0.00
C3
-2.00 C4
ln[Kip]

C5
-4.00 C6
C7
C8
-6.00
C9

-8.00
C10

-10.00
-3.00 -2.00 -1.00 0.00 1.00 2.00 3.00
b[1/Tb-1/T]

DRAFT REPORT