AL/2020/02/T

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mwpTWj;jy;fs; :
 ,t;tpdhj;jhs;fs; 7 gf;fq;fspy; 10 gy;Nju;T> 1 mikg;Gf;fl;Liu> 1 fl;Liu
tpdhf;fis nfhz;lJ.
 vy;yh tpdhf;fSf;Fk; tpil jUf.
 jug;gl;Ls;s ,lj;jpy; ckJ Rl;nlz;iz vOJf.
 gFjp-I 1 njhlf;fk; 10 tiuahd tpdhf;fs; xt;nthd;wpYk; (1),(2),(3),(4),(5) vd
,yf;fkplg;gl;l tpilfspy; rupahd my;yJ kpfg; nghUj;jkhd tpilia njupT nra;f.
mfpy thA khwpyp R = 8.314 J K-1mol-1
mtfhjNuh khwpyp NA = 6.022×1023 mol-1
gpshq;fpd; khwpyp h = 6.626×10-34 Js
xspapd; Ntfk; c = 3×108 ms-1

gFjp-I
1. gpd;tUk; Nru;itfspy; vJ mjp$ba mad; jd;ikia nfhz;bUf;Fk;.
(1) MgS (2) SrSe (3) CaS (4) MgSe (5) SrS
2. gpd;tUtdtw;Ws; vij iej;jpNuw;wk; nra;tJ kpf fbdkhdjhf ,Uf;Fk;
OH NH2 CH3 Cl F

(1) (2) (3) (4) (5)

3. Mg, Al vd;gtw;iw khj;jpuk; nfhz;l fyit xd;wpy; ,Ue;J ,U rk jpzpTfs;

vLf;fg;gl;L ,it xt;nthd;Wk; jdpj;jdpNa NaOH, H2SO4 ,y; fiuf;fg;gl;l NghJ
Ma;Tf;$lntg;g mKf;f epge;jidapy; tpLtpf;fg;gLk; H2 thAtpd; fdtsT tpfpjk;
2:3 Mf fhzg;gl;lJ. fyitapy; Mg : Al jpzpT tpfpjk; ahJ?
(1) 4:9
(2) 9:4
(3) 4:3
(4) 2:3
(5) 3:4

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4. HBr ,ypUe;J Br2 I tpLtpf;f KbahjJ vJ?

(1) MnO2 (2) H2O2 (3) ConHNO3 (4) I2 (5) F2
5. gpd;tUk; Nru;itapd; IUPAC ngau; ahJ?
(1) 4 – methylhept – 2– yn– 5– enal CH3−CH=CH−CH−C≡C−CHO
(2) 4 – formyl – 3 – methylhex – 4 – en– 1– yne │
CH3
(3) 4 – methyl– 1– oxohept – 5– en – 2 – yne
(4) 4 – methylhept – 5– en – 2 – ynal
(5) 4 – methyl– 1– oxohept – 2– yne– 5– one

6. NaOH ,d; ePu;ff ; iurypDs; gpd;tUk; vg;gjhu;j;jj;ij Nru;f;Fk; NghJ mjd; pH ,y;
tPo;rr
; p Vw;glhJ?
(1)Sn(s) (2)HCl(aq) (3)CuSO4(aq) (4)H2O(l) (5)K(s)
7. gpd;tUk; vJ jFe;j epge;jidfspd; fPo; AgNO3 cld; jhf;Fk;?

COOH Cl C≡C-H O-CHO

(a) (b) (c) (d)

8. gpd;tUtdtw;Ws; kpf vspjhf ePu;g;gFg;G mila $baJ vJ?

(a) C6H5Cl (b) CH3CH=CHCl (c) CH3CH2COCl (d)(CH3)3CBr

9. $w;W 01 – gPypq;fpd; fiurYld; benzaldehyde itf;Fk; NghJ nrq;fl;b rptg;G epw

tPo;gbT Njhd;Wk;
$w;W 02 – benzaldehyde xU mNwhkw;wpf; my;bifl;lhFk;.
10. $w;W 01 – CH3−C≡C−H IAk; C6H5-NH3Cl IAk; NtWgLj;j njhydpd; Nrhjidg;
nghUis gad;gLj;j KbahJ
$w;W 02 – CH3−C≡C−H , C6H5-NH3Cl ,uz;Lk; NH3 Nru; AgNO3 cld; ntz;
tPo;gbit jUk;.

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gFjp-II
mikg;Gf;fl;Liu tpdh
1. (a) C5H12O %yf;$w;Wr;#j;jpuKila A, B, C, D, E vd;w rkgFjpaq;fspy; A, B vd;gd epiyf;fl;likg;Gr;
rkgFjpa tbtpy; fhzg;gLfpd;wd. E MdJ A, B, C, D vd;gtw;wpd; njhopw;ghl;Lf; fl;likg;Gr; rkgFjpa
tbtpy; fhzg;gLfpd;wJ. A, B, E vd;gd xspapay; rkgFjpa tbtpy; fhzg;glf;$bad. ePuw;w ZnCl2/
Con HCl cld; A MdJ B ,Yk; tpiuthff; fyq;fy; jd;ikiaj; Njhw;Wtpf;ff; $baJ. C ahdJ
Ijhd H2SO4/K2Cr2O7 ePu;f;fiurYld; vt;tpj mtjhdj;ijAk; juhJ.

(i) A, B, C, D, E ,id ,dq;fhz;f.

A B C

D E
(ii) H2SO4 ,id kl;Lk; gad;gLj;jp DC khw;wl
P ;bid jUf.
…………………………………………………………………………………………………………….
…………………………………………………………………………………………………………….
…………………………………………………………………………………………………………….
…………………………………………………………………………………………………………….
…………………………………………………………………………………………………………….
…………………………………………………………………………………………………………….
…………………………………………………………………………………………………………….
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(b) C7H14 %yf;$w;Wr;#j;jpuKila A vd;w rkgFjpar; Nru;itahdJ ehd;F jpz;k rkgFjpa

tbtpy; fhzg;glf;$baJ.
1. A ,d; fl;likg;Gr; #j;jpuj;ijj; jUf.

…………………………………………………………………………………………………………….

2. A apd; IUPAC ngauPli

; lj; jUf.

…………………………………………………………………………………………………………….

3. A 
dilH 2 SO4
B B apd; IUPAC ngauPli
; lj; jUf.

…………………………………………………………………………………………………………….

4. A 
HBr / H 2 SO4
C C ,d; fl;likg;Gr;#j;jpuj;ijj; jUf.

…………………………………………………………………………………………………………….

5. B 
PBr3
D ,j;jhf;fj;jpw;fhd jhf;ftifiaj; jUf.

…………………………………………………………………………………………………………….
6. C, D vr;rkgFjpa tifiar; rhu;e;jd.

…………………………………………………………………………………………………………….

7. B 
ConH 2 SO4

 F 
dryHBr
 G F, G ,d; fl;likg;Gr; #j;jpuq;fisj; jUf

F G
8. C, G ,id ,dq;fhZk; Kiwnahd;iwj; jUf.
…………………………………………………………………………………………………………….……
……………………………………………………………………………………………………….…………
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gFjp-II
fl;Liu tpdh
1) (a)
(i) VfdtsTila tpiwj;j nfhs;fynkhd;wpDs; 0.5 mol PCl5 MdJ mKf;fk; P1> ntg;gepiy
T1 K ,y; fhzg;gLfpwJ
ghj;jpuj;jpd; ntg;gepiy T2 K Mf cau;e;jNghJ PCl5(g) MdJ gpd;tUkhW $l;lw;
gpuptile;jJ.
PCl5 (g) PCl3(g) +Cl2(g)

NkYk; ntg;gepiy T2 K mKf;fk; P2 ,Yk; rkepiy milfpd;wJ PCl5 ,d;

$l;lw;gpuptpisT 𝛼 MdJ gpd;tUk; Nfhitahy; jug;gLk; vd epWTf
𝑇1 𝑃2 − 𝑇2 𝑃1
𝛼=
𝑇2 𝑃1
(ii) gpd;tUk; jhf;fj;ij fUJf.
PCl5(g) PCl3(g) +Cl2(g)
gpd;tUk; tiuglq;fSs; Nkw;jug;gl;l rkepiyia Fwpj;Jf;fhl;lf;$baJ vJ?
rkepiyahdJ ,Ugf;fq;fspYkpUe;J eilngwf;$baJ kw;Wk; Muk;gj;jpy; VjhtJ xd;W
my;yJ gy $Wfs; vLf;fg;gLk; vdTk; fUJf. Nkw;jug;gl;l jhf;fj;jpd; KC MdJ
0.3moldm-3 tplf; FiwthdJ {KC<0.3moldm-3} NkNy jug;gl;l rkepiyia Fwpg;gjw;F
Vida tiuGfis njupT nra;ahjjw;fhd fhuzq;fis tpsf;Ff.

nrwpT nrwpT
moldm-3 moldm-3 tiuG - II

-
tiuG - I
1.2 - 1.2
-
- -
- 0.9 -
0.9 - Cl2
- -
- -
0.6 -
0.6 - PCl3 PCl5
- - PCl3
- -
0.3 -
0.3 - PCl5
- -
- - Cl2
0 Neuk; 0 Neuk;

nrwpT nrwpT
moldm-3 moldm-3
tiuG - IV
1.2 -
tiuG - III
1.2 -
- -
- -
0.9 - PCl5 0.9 - PCl5
- -
- -
0.6 -
0.6 - PCl3 Cl2
- -
- -
0.3 -
0.3 - PCl3
-
Cl2
- -
- Neuk;
0 Neuk; 0

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(b) gpd;tUk; kPSk; jhf;fj;ij fUJf.

X(g) Y(g) +Z(g)
127oC apy; fdtsT khwf;$ba nfhs;fynkhd;wpDs; Fwpg;gpl;lsT X(g) ,lg;gl;L
rkepiyia mila tplg;gl;lJ.
rkepiyr;nrwpTfs; [X(g)]=0.2moldm-3, [Y(g)]=[Z(g)]=0.4moldm-3
(i) 127oC apy; jhf;fj;jpd; Kc If; fzpf;Ff.
(ii) 127oC apy; ghj;jpuj;jpd; mKf;fk; rLjpahf miug;gq;fhdJ ,e;epge;jidfspd; fPo;
[Y(g)][Z(g)]
127oC apy; jhf;fj;jpd; <T 𝑄𝐶 = If;fhz;f.
[X(g)]
(iii) Nkw;jug;gl;l gFjp (ii) y; fzpj;j QC ,d; mbg;gilapy; jhf;fj;jpd; jpiria
vjpu;T $Wf. (Kw;jhf;fkh my;yJ gpw;jhf;fkh)
(iv) ,jd; NghJ cUthFk; rkepiyapYs;s xt;nthU thAf;fspd; nrwpTfisf;
fzpf;Ff.
(v) 127oC ,y; rkepiyj;njhFjpapy; mKf;fk; ,U klq;fhFk; NghJ rkepiyapd; QC
If; fzpf;Ff.
(vi) gFjp (v) ,y; njhFjpapYs;s xt;nthU $wpdJk; rkepiyr;nrwpit fzpf;Ff.
(vii) gFjp(vi)y; rkepiyj;njhFjpapd; KP If; fzpf;Ff.

−𝑏 ± √𝑏 2 − 4𝑎𝑐
𝑎𝑥 2 + 𝑏𝑥 + 𝑐 = 0 𝑥 = )
2𝑎

(c) mt;ntg;gepiyapy; A(g) gpd;tUk; rkepiy milfpwJ.

A(g) B(g) +2C(g)
mNj ntg;gepiyapy; C Ak; $l;lw;gpuptile;J kw;Nwhu; rkepiy mikfpd;wJ.

C(g) 2D(g) +3B(g)

o
227 C ,y; Nkw;jug;gl;l rkepiyfspd; KC ngWkhdq;fs; fPNo jug;gl;Ls;sd.
A(g) B(g) +2C(g) 𝐾𝐶1
C(g) 2D(g) +3B(g) 𝐾𝐶2
13
(i) rkepiy mKf;fk; Muk;g mKf;fj;jpd; klq;fhtJld; (Akl;Lk; fhzg;gLk;NghJ)
6
4
C(g)d; rkepiyr;nrwpT A(g)d; rkepiyr;nrwptpd; klq;fhFk;)
9

𝐾𝐶1 , 𝐾𝐶2 Mfpatw;iw fzpf;Ff.

(ii) 227oC ,y; C(g) 2D(g) +3B(g) vDk; jhf;fj;jpd; KP If; fzpf;Ff.

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(d) 25oC ,y; tpiwj;;j ghj;jpuj;jpDs; 5mol N2O4 ck; 5mol NO2 fyf;fg;gl;lJ mt;
ntg;gepiyapy; ghj;jpuj;jpDs; gpd;tUk; jhf;fk; epfoKbAk;
N2O4 (g) 2NO2(g)

mjd; gpd;G ghj;jpuj;jpDs; nkj;j mKf;fk; 2×105pa MFk;. gpd;tUk; ml;ltizapy; NO2
kw;Wk; N2O4 Mfpatw;wpd; epak fpg;]pd; RahjPd rf;jpfs; jug;gl;Ls;sJ

ΔGof kJ mol-1
N2O4(g) 100

NO2(g) 50

(i) 25oC ,y; NO2, N2O4 Mfpatw;wpd; gFjpaKf;fq;fis fhz;f.

(ii) 25oC ,y; jhf;fj;jpd; jhf;f <T [Q] If; fhz;f.
(iii) Kw;jhf;fj;jpd; ΔG If; fzpf;Ff. [rkepiyj; jhf;fj;jpd; vf;fzj;jpYk;
(rkepiyapd; NghJ my;yJ rkepiy mila Kd;G)]

G G

A
.
.
.
B
C

N2O4(g) NO2(g)
jhf;fp tpisT

(iv) fzpf;fg;gl;l ΔG ngWkhdkhdJ NkNy jug;gl;l tiugpd; Gs;sp xd;wpy;

fhzg;gLk;. mg;ngWkhdk; fhzg;gLk; Gs;spia A, B, C Mfpatw;wpypUe;J njupT
nra;J tpsf;Ff