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Durability of Recycled Aggregate Concrete Using Pozzolanic Materials
Durability of Recycled Aggregate Concrete Using Pozzolanic Materials
com
a
School of Civil and Environmental Engineering, Yonsei University, Seoul, Republic of Korea
b
Department of Civil Engineering, Hanyang University, Seoul, Republic of Korea
Abstract
In this study, pulverized fuel ash (PFA) and ground granulated blast furnace slag (GGBS) were used to compensate for the loss of
strength and durability of concrete containing recycled aggregate. As a result, 30% PFA and 65% GGBS concretes increased the com-
pressive strength to the level of control specimens cast with natural granite gravel, but the tensile strength was still lowered at 28 days.
Replacement with PFA and GGBS was effective in raising the resistance to chloride ion penetrability into the concrete body, measured
by a rapid chloride ion penetration test based on ASTM C 1202-91. It was found that the corrosion rate of 30% PFA and 65% GGBS
concretes was kept at a lower level after corrosion initiation, compared to the control specimens, presumably due to the restriction of
oxygen and water access. However, it was less effective in increasing the chloride threshold level for steel corrosion. Hence, it is expected
that the corrosion time for 30% PFA and 65% GGBS concrete containing recycled aggregate mostly equates to the corrosion-free life of
control specimens.
2007 Elsevier Ltd. All rights reserved.
0956-053X/$ - see front matter 2007 Elsevier Ltd. All rights reserved.
doi:10.1016/j.wasman.2007.03.003
994 K.Y. Ann et al. / Waste Management 28 (2008) 993–999
Table 1
Oxide composition of binders (% w/w)
Binder Oxides Ignitiona
CaO SiO2 Al2O3 MgO Fe2O3 SO3 Na2O
OPC 61.4 20.5 6.4 3.0 2.9 2.1 1.2 0.8
PFA 4.22 55.0 21.1 1.2 10.9 0.06 1.0 5.0
GGBS 33.5 44.2 14.0 4.9 0.8 1.4 0.9 0.1
a
Loss on ignition.
K.Y. Ann et al. / Waste Management 28 (2008) 993–999 995
Fig. 2. Experimental set-up for testing the corrosion rate of steel in Results of the rapid chloride ion penetration test are
concrete containing recycled aggregate. given in Fig. 5, showing the total charge that passed
996 K.Y. Ann et al. / Waste Management 28 (2008) 993–999
40
30
Compressive strength (MPa) 1
20
Control
10 Recycled-OPC
Recycled-30% PFA
Recycled-65% GGBS
0
7 28 90 180
Time (days)
Fig. 3. Development of compressive strength of concrete containing granite (control) or recycled aggregate with PFA and GGBS.
2.00 0.20
1.50 0.10
1.25 0.05
Tensile strength
Ratio of tensile to compressive
1.00 0.00
Control Recycled-OPC Recycled-30% PFA Recycled-65% GGBS
Type of binder
Fig. 4. Tensile strengths and the ratio of tensile to compressive strengths of concrete containing granite (control) or recycled aggregate with PFA and
GGBS.
through the concrete specimens in 6 h. It was seen that 6587, 3521 and 3305 Coulombs for the control, OPC with
recycled aggregate in OPC concrete increased the total recycled aggregate only, 30% PFA and 65% GGBS con-
charge, as compared to the control specimen, but the cretes, respectively. It is evident that PFA and GGBS
charge that passed through 30% PFA and 65% GGBS con- enhanced the resistance to the chloride ion penetrability
cretes was slightly lower than that for control specimens. into the concrete containing recycled aggregate. According
The charge passed for all concrete specimens were 3875, to the standard (i.e., ASTM C 1202-91), the charge passed
K.Y. Ann et al. / Waste Management 28 (2008) 993–999 997
8000
6000
Total charge passed (Coulombs) 1
4000
2000
0
Co ntrol Recycled-OPC Recycled-30% PFA Recycled-65% GGBS
Type of binders
Fig. 5. Total charge passed through concrete specimens containing granite (control) or recycled aggregate with PFA and GGBS in rapid chloride ion
penetration test (ASTM C 1202-91).
for the control, as well as the 30% PFA and 65% GGBS m2 at corrosion initiation (Gonzalez and Andrade, 1982).
concretes, equated to the level of ‘Moderate’’ and ‘High’ The order of chloride threshold level is 30% PFA > con-
for OPC with recycled aggregate (see Table 3). The temper- trol = 65% GGBS > OPC with recycled aggregate only,
ature in the chambers of each cell was well sustained, rang- ranging from 0.20% to 0.73% by weight of cement, depend-
ing from 40 to 43 C for 6 h, which implies that it is not ing on binders and aggregate.
likely to have affected the mobility of chloride ions (i.e.,
Joule’s effect). 4. Discussion
The results for corrosion test of concrete containing Recycled aggregates are by-products of crushed con-
recycled aggregate are given in Fig. 6, which shows the cor- crete, usually deteriorated by a chemical or/and physical
rosion rate for various levels of chlorides. It was seen that attack, such as carbonation, sulphate attack, chloride-
an increase in the chloride content resulted in an increase in induced corrosion or a loss of strength. Hence, the benefits
the corrosion rate, irrespective of binders and aggregate from cement paste in recycled aggregate, such as chloride
type. The corrosion rate does not seem to depend on the binding, an inhibitive nature to steel corrosion and a resis-
binder and aggregate for a lower level of chlorides, ranging tance to aggressive ions, are less likely to be expected.
between less than 0.2% and 0.3% by weight of cement, but Moreover, recycled aggregate is more porous, compared
with a ratio of more than 0.5% of chlorides, the binders to natural aggregate, which is considered as being impervi-
and the aggregate significantly changed the corrosion rate. ous inert filler. Increased porosity of recycled aggregate
It is evident that 30% PFA and 65% GGBS concretes were may lower the bond strength between the cement paste
more effective in mitigating corrosion reaction at a higher and the aggregate (i.e., interfacial transition zone), thereby
level of chlorides, as compared to the control specimens. leading to a loss of concrete strengths (Figs. 3 and 4), an
For example, the corrosion rate at the chloride content of increase in ion penetrability (Fig. 5) and presumably a
2% was 18.63, 33.14, 12.34 and 6.32 mA/m2 for the control reduction of the corrosion resistance.
specimen, OPC with recycled aggregate, 30% PFA and 65% Apart from the capillary pores in cement matrix, the
GGBS concretes, respectively. continuous porosity at the interfacial transition zone
Table 4 gives the chloride threshold level for corrosion, between cement paste and recycled aggregate provides a
calculated by fitting the relationship in the quadratic equa- well-networked path for ions (Oh et al., 2002), which
tion between the corrosion rate and chloride contents for may be held responsible for increased accessibility of
each mix, assuming that the corrosion exceeds 1–2 mA/ aggressive ions into the concrete body. Moreover, the high
998 K.Y. Ann et al. / Waste Management 28 (2008) 993–999
100
Control
Recycled-OPC
Recycled-30% PFA
Recycled-65% GGBS
Corrosion rate (mA/m2)1
10
0.1
0.0 0.5 1.0 1.5 2.0 2.5
rides and mitigates further development of corrosion after reduced by PFA and GGBS, due to the restriction
the onset. A reduction of ion penetrability for 30% PFA of cathodic reaction, which needs a sufficient supply
and 65% GGBS concretes containing recycled aggregate of oxygen and water.
may imply that it will take longer for the corrosion critical
chloride content to reach the depth of the steel and thus the
time to corrosion initiation will be increased (Bamforth, References
1999). Also, it was seen in Fig. 6 that 30% PFA and 65%
GGBS concretes containing recycled aggregate were not ASTM C 1202-91, 1991. Standard test method for electrical indication of
effective in increasing the chloride threshold level, which concrete’s ability to resist chloride ion penetration.
Bamforth, P.B., 1999. The derivation of input data for modelling chloride
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This study used recycled aggregate from crushed con-
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Poon, C.S., Shui, Z.H., Shui, Lam, L., 2004. Effect of microstructure of
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(2) The rapid chloride ion test indicated that the concrete aggregates. Construction and Building Materials 18, 461–468.
containing recycled aggregate forms a more open pore Sagoe-Crentsil, K.K., Brown, T., Taylor, A.H., 2001. Performance of
structure, compared to the control specimens. The use concrete made with commercially produced coarse recycled concrete
of 30% PFA and 65% GGBS in binder resulted in a aggregate. Cement and Concrete Research 31, 707–712.
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decrease in the charge passed through concrete speci- mechanical behaviour of concrete manufactured with recycled aggre-
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