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2012 Chemistry Pahang With Answer PDF
2012 Chemistry Pahang With Answer PDF
2012 Chemistry Pahang With Answer PDF
4541/1
CHEMISTRY
Kertas 1
OKT/NOV 2012
1 }{JAM
CHEMISTRY
Tingkatan 5
Kertas 1
Diagram 1
Rajah 1
A 7
8 6
c 5
-0 4
Element
Unsur
p Q R s
Proton number
11 14 16 19
Nombor proton
Table 1
Jadua/1
A P, Q,R,S
B P,S,Q,R
C S,R,Q,P
D R,Q,P,S
Table 2
Jadua/2
Which of the following substances has the highest kinetic energy at room temperature?
6. Which compound in the table below is correctly matched with its relative molecular
mass?
Sebatian yang manakah di dalam jadual di bawah dipadankan dengan betul dengan
jisim molekul relatif masing-masing?
(RAM: H,1; C,12 ; N,14; 0,16; Na, 23; P, 31; S, 32; Ca , 40; Fe, 56)
- - ---
Compound Relative molecular mass
Sebatian
II Jisim molekul relatif
I
I Ca3(P04)z I 310
II C,4H1aN20s 294
Ill FeS04.7H20 278
IV C,sH3,COONa 266
8. A compound with formula X 2S04 has a relative formula mass of 174. What is the
relative atomic mass of X?
(RAM: 0,16;8,32) .
Suatu sebatian dengan formula X 2 S04 mempunyai jisim formula relatif sebanyak 174.
Apakah jisim atom relatif bagi X?
(JAR :0 , 16; S,32)
A 39 c 78
B 52 D 104
XO + C02
A 0.08 g c 3.20 9
B 1.60 g D 6.20 g
10. Aluminium oxide has both acidic and basic properties, therefore it is
Aluminium oksida mempunyai kedua-dua sifat asid dam bes, oleh itu aluminium oksida
ialah
A. a base oxide
oksida bes
B. an acid oxide
oksida asid
C. a metalloid oxide
oksida metaloid
D. an amphoteric oxide
oksida amfoterik
11 . The diagram 2 shows the electron arrangement of a compound formed between atoms P
and Q.
Gambar rajah 2 menunjukkan susunan electron bagi sebatian yang terbentuk antara atom
.P dengan atom Q.
Diagram 2
Rajah 2
A. It is an ionic compound
Sebatian itu adalah sebatian ion
12. A restaurant owner wants to use colourful electric lamps to attract customers.
Which of the following substances A, B, C or D in the Periodic Table is suitable to be used
in the lamps?
Seorang pemilik restoran ingin menggunakan fampu efektrik yang berwama warni untuk
menarik perhatian pelanggan.
Antara unsur A, 8, C dan D dalam Jaduaf Berka/a berikut yang manakah sesuai
digunakan untuk lampu itu.
A D
B c
The diagram 3 shows the electron shells in the substance formed between atoms of
Diagram 3
Rajah 3
A 2.4
B. 2.8
C. 2.8.4
D. 2.8.8
Diagram 4
Rajah 4
Which of the following electron arrangement for the substances formed when the element
X and element Y react?
Antara berikut, yang manakah susunan elektron bagi sebatian yang terbentuk apabila
unsur X dan unsur Y bertindak balas?
A.
[0J~l
B.
C.
Dissolve in water
II Produced from the reaction between metal and non metal elements
Terbentuk daripada tindak balas antara unsur logam dengan unsur bukan /ogam
A I and II only
I dan II sahaja
Glucose
G/ukosa
II Acetamide
Asetamida
C. I and Ill
I dan Ill
D. Ill and IV
Ill dan IV
18. Which of the following voltaic cells has the lowest voltage?
Manakah antara sel kimia berikut mempunyai voltan yang paling rendah ?
19. Diagram 5 shows the set up of the apparatus of a simple chemical cell. The reading on
the voltmeter is 0.3 V .
Rajah 5 menunjukkan susunan radas bagi satu sel kimia ringkas. Bacaan voltmeter ialah
0.3 V.
lron(ll) sulphate
Larutan(/1) sulfat
Diagram 5
Rajah 5 ·
20. Amni are going to coat an iron key with silver by electrolysis. The anode should
Amni akan menyadur kunci besi dengan perak melalui elektrolisis. Anod adalah
22. Diagram 6 shows the set-up of apparatus used to investigate the ability of various
solutions to conduct electricity.
Bulb
Mento/
- ~ : .
Solution X
Larutan X
Diagram 6
Rajah 6
23 . The equation shows the reaction between sulphuric acid and potassium hydroxide.
Persamaan di bawah menunjukkan tindak balas di antara asid sulfurik dan kalium
hidroksida.
..
3
What is the volume of 0.2 mol dm- potassium hydroxide solution which can neutralize
20 .0 cm 3 of 0.1 mol dm- 3 sulphuric acid?
Berapakah isipadu /arutan kalium hidroksida 0.2 mol dm- 3 yang diperlukan untuk
meneutralkan 20. 0 cm 3 0. 1 mol dm- 3 asid sulfurik?
3
A. 10.0 cm C. 40.0 cm 3
B. 20 .0 cm 3 D. 80.0 cm 3
24. The equation shows the reaction between sodium chloride solution and silver nitrate
solution to produce silver chloride precipitate.
Persamaan menunjukkan tindak balas antara larutan natrium klorida dan larutan
argentum nitrat untuk menghasilkan mendakan argentum klorida.
20 cm3 of 1. 0 mol dm· 3 larutan natrium k/orida bertindak batas lengkap dengan larutan
argentum nitrat berlebihan. Hitungkan jisim mendakan yang terbentuk.
[Jisim atom relatif Ag=108; C/=35.5]
A 3.78 g c 2.78 g
8 3.87 g D 2.86 g
A Barium sulphate
Barium su/fat
B Potassium carbonate
Kalium karbonat
c Silver nitrate
Argentum nitrat
D Ammonium carbonate
Ammonium karbonat
26. Diagram 7 shows the set-up of apparatus to prepare a sulphate salt using the
precipitation reaction.
Solution
Larutan X
X~
, ·.- .· Stir
. I
Kacau
Precipitate
Mendakan
Diagram 7
Rajah 7
Solution X is
Larutan X adalah
C. Lead(ll) nitrate
Plumbum(//) nitrat
D. Lead(ll) carbonate
Plumbum(//) karbonat
l G
I
Added with dilute hydrochloric acid and
filtered
Tambah dengan asid hidroklorikdan
dituraskan
Precipitation Solution
Mendakan Larutan
White precipitate
dissolve
Mendakan putih
Ia rut
Diagram 8
Rajah 8
A Borosilicate glass
Kaca borosilikat
C Fused glass
Kaca silica terfakur
30 . Statues or monuments are made of bronze. What is the main metal in bronze?
Patung atau tugu dibuat daripada gangsa. Apakah logam utama dalam gangsa?
A Iron
Besi
B Aluminium
Aluminium
C Magnesium
Magnesium
D Copper
Kuprum
31. The following equation represents the reaction between calcium carbonate and
hydrochloric acid.
P. ~aan berikut mewakili tindak balas antara kasium karbonat dan asid hidroklorik.
Antara berikut, yang manakah adalah peranan yang dimainkan oleh mangkin dalam
meningkatkan kadar tindak balas?
33. Diagram 9 shows the apparatus for an experiment to determine the rate of reaction
between sodium thiosulphate solution and sulphuric acid.
Rajah 9 menunjukkan susunan radas bagi eksperimen untuk menentukan kadar tindak
balas antara larutan natrium tiosulfat dan asid sulfurik.
Sodium thiosulphate
solution + sulphuric acid
~J- ~·· Natrium tiosulfat + asid
~ ... . .~
i_{,··~x mark sulfurik
·,, TandaX
Diagram 9
Rajah 9
© 2012 Hak Cipta MPSM Pahang [ Lihat halaman sebelah
18 4541/1
Which of the following combination of conditions will make the mark X to disappear the
fastest?
Antara kombinasi keadaan berikut yang manakah mengambil masa yang paling singkat
untuk tanda X hilang daripada penglihatan?
Energy
Tenaga
Diagram 10
Rajah 10
c 130 kjmol· 1
D 830 kjmol" 1
35. Table 3 shows the total volume of gas collected at regular interval in a reaction.
Jadual 3 menunjukkan jumlah isipadu gas terkumpul pada seta masa tertentu.
Time,s
Masa,s
0 30 60 90 120 150 180 210
Volume of gas,cm 3
lsipadu gas,cm 3
0 2.0 3.7 5.2 6.4 7.3 8.6 8.6
Table 3
Jadua/3
A c
B D
36. Which of the following pairs of compounds are in the same homologous series?
Manakah antara pasangan sebatian berikut berada dalam siri homolog yang sama?
Compound 1 Compound 2
Sebatian 1 Sebatian 2
A c2 H4 c3 H s
B C2 Hs c3 H s
c C2 Hs OH CH3C02H
D C2HsOH C2 Hs COOH
37. The following equation represents a reaction for industrial preparation of Propanol.
.
~~ ''~aan
~ . ..
berikut mewakili tindak balas penyediaan etanol secara industri.
:.)~~'\.
~~~---------------------------------.
p Catalyst X
Mangk/nX
! A C2H4 Platinum
platinum
B C3Hs Nickel
nikel
c C2H4 Nickel
nikel
D C3Hs Phosphoric acid
Asid fosforik
38. Diagram 11 shows the formation of vulcanized rubber from natural rubber.
Diagram 11
Rajah 11
~f~~~_:l :.~~ tervulkan mudah menjadi lembut dan me/ekit dalam pe/arut organik.
·,<!:! ~ s~ bstance Y is hydrogen sulphide acid
· -~ · . Bahan Y adalah asid hidrogen su/fida.
0
It
CH3 - CH2- C - 0 -CH1
Diagram 12
Rajah 12
Antara yang berikut, manakah bahan tindak yang digunakan untuk menyediakan ester
seperti di atas.
41 . Diagram 13 shows the apparatus arrangement to investigate the oxidation and reduction
in terms of the transfer of electrons at a distance.
Acidified Potassium
Iron (II) sulphate Manganate (VII) solution
Ferum (II) sulfat Kalium mangganat(V/1)
berasid
Diagram 13
Rajah 13
Water droplet
Titisan air
Diagram 14
Rajah 14
A Fe ~Fe 2 + + 2e·
B 02 + 2H20 + 4e· ~ 40H-
C 40H- ~ 02 + 2H20 + 4e·
D Fe2+ + 2e· ~ Fe
43 . . Table 4 below shows the results of an experiment to investigate the effect of metals on
the rusting of iron.
X
' Iron nail is coiled Iron nail did not rust
_.,....... with metal P
. .'
'
[,..
Paku besi dililit Paku besi tidak berkarat
-uengan logam P
~ .
Table 4
Jadua/4
Based on the result above, arrange iron , P and Q in decreasing order of electropositivity.
44. Diagram 15 below shows the apparatus set up to measure the heat energy given out in
the reaction between magnesium and iron sulphate solution. The experiment is repeated
by using zinc and iron sulphate solution.
Rajah 15 di bawah menunjukkan susunan radas untuk mengukur tenaga haba yang
dibebaskan di dalam tindak balas antara magnesium dan larutan besi sulfat. Eksperimen
ini diulang dengan menggunakan zink dan larutan besi sulfat.
Magnesium powder~
Serbuk magnesium \ \, I Plastic cup
I • r-- Cawan plastik
l
Diagram 15
Rajah 15
Antara yang berikut, manakah yang perlu dikekalkan dalam tindak balas ini?
C 3H a + 50 2 ~ 4H20 + 3C02
l!.H= -2230 kJ mol- 1
A 0.02 g
B 0.44 g
c 0.88 9
D 1.00 g
46. The reaction between aqueous sodium hydroxide and dilute hydrochloric acid is an
exothermic reaction. Which of the following graphs shows the change in temperature
when sodium hydroxide solution is slowly added to dilute hydrochloric acid until it is very
much in excess?
Tindak balas eksotermik akan berlaku jika natrium hidroksida akueus berlindak balas
dengan asid hidroklorik cair. Graf yang manakah di bawah menunjukkan perubahan
suhu apabi/a natrium hidroksida dicampurkan perlahan-lahan sehingga berlebihan?
A temperature/suhu
temperature/suhu c oc
oc .:t.·:.~~~t:~~5~::,~q~::r~-~;,:~
47 . An acid HX and an alkali YOH, both with the same concentration, are mixed in different
volume ratios as shown in the table below. Which of the following sets of mixture will
produce the highest rise in temperature?
Satu asid HX dan satu alkali YOH yang mempunyai kepekatan yang sama dicampurkan
pada nisbah isipadu seperti yang ditunjukkan pada jadual di bawah. Antara larutan set
berikut yang manakah akan menghasilkan kenaikan suhu yang paling besar?
,_ : ·- '.,
A 90 10
B 70 30
c 50 50
D 40 60
48. The diagram 16 below shows the structure of a soap molecule. Which of the following
statements is not true?
Diagram 16
Rajah 16
A I and II c II and IV
I dan II II dan IV
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END OF QUESTION
SOALAN TAMAT
4541/2 Nama: ..... ... .... ............ ........ ... ............... ............ ....... ...... ... .... ..
Chemistry
Kertas 2 Kelas : .. ... .. ..... ..... .. ........... .... ............ ... .. ...... ........................... .
Okt/Nov
2% jam
MPSM PAHANG
PEPERIKSAAN PERCUBAAN SPM 2012
TINGKATAN 5
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CHEMISTRY
Kertas 2
Section A
Sahagian A
(60 Marks)
(60 Markah)
1.
Esterification
Hydrogenation Dehydration · Pengesteran
Propene
y X z
Propena
Penghidrogenan Pendehidratan Ethanoic acid
As1d etano1k
Diagram 1
Rajah 1
Diagram 1 shows the flow chart of a series of changes that occur between some
members of the homologous series.
Rajah 1 menunjukkan carta alir bagi suatu perubahan yang berlaku antara ahli-ahli siri
homolog.
[1 mark]
[1 markah]
b) (i) Write the general formula homologous series of compound X.
(1 mark]
[1 markah]
c) Draw the structural formula for one of the isomers of compound X. Name the isomer.
Lukis formula struktur bagi salah satu isomer sebatian X. Namakan isomer tersebut.
[2 marks]
[2 markah]
d) {i) Name compound Y.
Namakan bahan Y.
[1 mark]
[1 markah]
(ii) Write the chemical equation for the hydrogenation of propene to produce
compound Y.
[2 marks]
[2 markah]
e) X will change to Z through esterification reaction .
Name product Z.
Namakan bahan Z.
~~~"; ;_
· :· · · ·· .. · · · · · · · " ' ' ' ' " '"'""''""''' ' '"'"'"'"''""'"''''""' ' '''"'" ' "'''"''""'' '''" '"""'
[1 mark)
[1 markah]
.\ -~
2. Diagram 2 shows the chemical symbols which represent three elements P, Q and R.
The letters used are not the actual symbols of the elements.
Rajah 2 menunjukkan simbol kimia yang mewaki/i tiga unsur P, Q dan R. Huruf yang
digunakan adalah bukan simbol sebenar unsur itu.
32
15
p 35
17 Q
37
17 R
Diagram 2
Rajah 2
[1 mark]
{1 markah]
(ii) State the proton number for atom P.
[1 mark]
[1 markah]
b) What is represented by the number 35 for the element Q?
[1 mark]
{1 markah]
[1 mark]
[1 markah]
[1 mark]
[1 markah]
[1 mark]
[1 markah}
(2 marks]
[2 markah]
Group
,- Kump u/an ~
Period p Q
Kala
T y z
Figure 3
Rajah 3
a) Using the letters in the Periodic Table of the Elements in Figure 3, answer the
following questions.
Dengan menggunakan huruf-huruf yang terdapat da/am Jadual Berkala Unsur pada
Rajah 3, jawab soalan berikut.
[1 mark]
[1 markah]
(1 mark]
[1 markah]
[1 mark]
{1 markah]
[1 mark]
{1 markah]
[2 marks]
{2 markah]
e) Write the formula for the ion formed from an atom of element Y.
[1 mark]
{1 markah]
(1 mark]
{1 markah]
[1 mark]
[1 markah]
Seorang pelajar telah menjalankan satu eksperimen elektrolisis larutan kuprum(/1) sulfat
dengan menggunakan elektrod karbon P dan elektrod karbon Q seperti ditunjukkan pada
Rajah 4 di bawah.
Copper(ll) sulphate
solution
Switch
Ammeter suis
Diagram 4
Rajah 4
[1 mark]
[1 markah]
(ii) The intensity of blue colour of copper(ll) sulphate solution decreases. Why?
[1 mark]
[1 markah]
c) Write the half equation for the reaction that takes place at electrode P.
Tuliskan setengah persamaan bagi tindak balas yang berlaku di elektrod karbon P.
[1 mark]
[1 markah]
d) If the experiment is repeated using copper electrode, state the observation at:
(i) anode.
anod.
[1 mark]
{1 markah]
e) If the student wants to electroplate an iron spoon with copper metal by electrolysis,
draw a labelled diagram to show the apparatus arrangement used by the student.
Jika pe/ajar tersebut ingin menyadurkan sebatang sudu besi dengan /ogam kuprum
secara elektrolisis, lukiskan gambar rajah berlabel untuk menunjukkan susunan radas
yang digunakan oleh pe/ajar itu.
[2 marks]
{2 markah]
f) The experiment is repeated by using 0.0001 mol dm-3 sodium chloride solution. The
table below shows the ions which gather at electrode P.
Eksperimen ini diulangi dengan menggunakan larutan natrium klorida 0.0001 mol
dm-3 . Jadual di bawah menunjukkan ion-ion terkumpu/ di elektrod P.
Chloride ions
ion klorida
Hydroxide ion
ion hidroksida
Table 1
Jadua/1
,~·--t{):..:_~~~C! tick (I') in the table 1 to select the ion which will be selectively discharged
7:;._~1 ~·
) ' 0 a(e1e&trode P.
Q ·. . .
~~, ')~--
·~)': .
~ Q&
"'Tlr,·'
._..- ;.,. A
. .: . : (/') da/amJ·adua/1 untuk memilih ion yang akan dinyahcas secara pilihan
,,, Cjc : <;_S:"af'elektrod P.
-~-·
[1 mark]
{1 markah]
5. Question 5 is about the titration between sulphuric acid and sodium hydroxide
solution .
Soalan 5 berkaitan dengan pentitratan antara asid sulfurik dan larutan natrium
hidroksida.
Several drops of phenolphthalein indicator are added into 25 cm 3 of 0.5 mol dm·3
sodium hydroxide solution in a beaker.
a) State the change on the colour of the phenolphthalein in the sodium hydroxide
solution at the end point.
Nyatakan perubahan warna feno/ftalein dalam larutan natrium hidroksida pada takat
akhir.
[1 mark]
[1 markah]
[1 mark)
[1 markah)
c) Write a chemical equation to represent the reaction between sulphuric acid and
~ • ~9itt€!;1_ .hydroxide solution.
~~--"" ~~ ~~ ~
~r ·':·· ,.,. . . ., "
7-"'"i · ~- Tu/isk~h;~ ersamaan kimia mewakili tindak balas antara asid sulfurik dan larutan
c - i'' .'
~·<;:-',
.·, .
;: ' #(ltnum_. t.d roks1da.
'{l-\ '\.1} ,~
' ~A
~ :...;.,...... -
".. r. '''Vl
~ .~ A
, .;_,~~ Qo ~ t~~-2?
~ ..;;;-..;....... ....... ... ..... .. .. ......... .... ........... ...... ....... ... .. ... ..... .... .... ....... .. ........ ...... .. .
[2 marks]
[2 markah}
[1 mark]
[1 markah]
e) 0.25 mol dm"3 of sulphuric acid is needed to completely neutralize the sodium
hydroxide solution . Calculate the volume of sulphuric acid.
0.25 mol dm·3 asid sulfurik diperlukan untuk meneutralkan sepenuhnya /arutan
natrium hidroksida. Kirakan isipadu asid sulfurik .
[3 marks]
[3 markah]
f) Predict the volume of acid used if the experiment is repeated using 0.25 mol dm·3
hydrochloric acid.
[1 mark]
{1 markah]
[2 markah]
f) Predict the volume of acid used if the experiment is repeated using 0.25 mol dm-3
hydrochloric acid.
[1 mark]
[1 markah1
6.
Rusting of iron is a corrosive reaction which happen naturally.
Pengaratan besi ada/ah suatu tindak ba/as kimia yang bo/eh
berlaku secara semulajadi
[ 1 mark 1
[1 markah 1
[ 1 mark 1
[1 markah 1
c) Iron undergoes oxidation reaction during rusting. Write half equation for the oxidation
of iron.
d) Draw a labeled diagram for rusting of iron to show the condition of rusting of iron ,
the flow of electron, anode and cathode.
[3 mark]
(3 markah]
e) Describe the transfer of electron and the reaction that take place at the cathode after
iron is oxidized .
Huraikan pemindahan elektron dan tindak balas yang berlaku pada katod selepas
besi dioksidakan.
[ 3 marks]
(3 markah]
' " '; : - ' ' . '. 0 . ' . ' , ' ' : • . •• 0 •••••••••••• •• •••• • •••• •• • •• •• •••••• 0 ••• • • •• • ••••••••••••••••••• 0 • • • • •• • •••••••••••••• '.' • • ' ••••
\.;)
Section 8
Sahagian B
(20 Marks)
(20 Markah)
7 . A student has carried out an experiment to construct an ionic equation for the formation
of lead (II) iodide. Seven test tubes of the same size were labelled 1 to 7. A fixed volume
3 3
of 5. 0 cm of 1.0 mol dm· potassium iodide solution was placed in each test tube . 0.5 cm 3
3
of 1.0 mol dm· lead (II) nitrate solution was added into test tube 1. 1.0 ct:n 3 into test tube 2
3
and so on until 3.5 cm was added into test tube 7. The heights of the precipitate formed
in each test tube were measured.
Seorang pelajar te/ah menjalankan satu eksperimen untuk membina persamaan ion bagi
pembentukan plumbum (II) iodida . Tujuh buah tabung yang sama saiz dilabelkan
3
dengan 1 hingga 7. lsipadu tetap 5.0 cm larutan kalium iodida 1.0 mol dm· 3 diletakkan
3
da/am setiap tabung uji 0.5 cm larutan plumbum (II) nitrat 1.0 mol dm· 3 ditambah ke
dalam tabung uji 1, 1.0 cm 3 ke dalam tabung uji 2, dan seterusnya sehingga 3.5 cm 3
ditambah ke dalam tabung uji 7. Tinggi mendakan yang terbentuk da/am setiap tabung
uji diukur.
Test tube
1 2 3 ~--r 5 6 7
Tabung uji
Volume of 1.0 moldm·3 lead (II) nitrate
solution I cm 3
1:
f;t· ,-. r~an plumbum (II) nitra/1.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5
.{!if(~~-
~\rf·"". . \"'
a) Based on table 7, plot a graph of the height of the precipitate against volume of lead
(II) nitrate solution on the graph paper.
b) (i) Write the chemical equation for the formation of lead (II) iodide.
Tuliskan persamaan kimia bagi pembentukan plumbum(//) iodida.
[2 marks]
[2 markah)
(ii) Determine the volume of lead (II) nitrate solution that had reacted completely with
5.0 cm 3 of 1.0 mol dm-3 potassium iodide.
Tentukan isipadu larutan plumbum (II) nitrat yang telah bertindak balas lengkap
dengan 5. 0 cm 3 larutan kalium iodida 1.0 mol dm- 3 .
[3 mark]
[3 markah}
(iii) Using the volume obtained in (b)(ii), calculate the number of moles of lead (II) ions
and iodide ions that are required for the formation of lead (II) iodide.
c) The following flow chart in diagram 7 shows the formation of copper (II) salt solution
•
~: ~u~B.a~es
'~I 'r. -,-"\'\,1'
•
of its reactions .
~
r;·~ ~rta a/.;/~)am rajah 7 menunjukkan p~nghasilan sejenis larutan garam kuprum (II)
~\
• ~'
·;;;_~
' 0·
-
dan'-'satut e..'hi tmdak balas larutan garam Jtu .
tl (l~~
·-· r · ·{l./,1
- ·~ .. t.~ ~
. ~1 tier ;·:c:..;;*'
~~~~\..,._.
Pass through
+ sulphuric acid
lime water
+ asid sulfurik
Alir ke dalam
air kapur
Copper (II) salt solution + water+ gas Z
Larutan garam kuprum (II) + air + gas Z
Lime water turns cloudy
Air kapur keruh
+ Barium nitrate solution
+ Larutan Barium nitrat
Y precipitate
Mendakan Y
Diagram 7
Rajah 7
Based on Diagram 7:
~ : •__Jtl __~? per (II) salt solution is a soluble salt. Describe chemical test to verify the
8. Diagram 8 shows the set-up of the apparatus to study the heat of displacement .
Rajah 8 menunjukkan susunan radas bagi mengkaji haba penyesaran.
I
' Polystyrene cup
Cawan polistren
Table 8
Jadua/8
[3 marks]
[3 markah)
(ii) Calculate the heat of displacement for this experiment if excess zink powder
is added to 50cm 3 copper(ll) sulphate solution 0.1 mol dm-3 .
[Specific heat capacity of solution= 4.2 Jg-1°C ., Density of solution=1.0 gcm-3]
Hitungkan haba penyesaran bagi eksperimen ini jika serbuk zink ditambah
3
secara berlebihan kepada 50 cm larutan kuprum(/1) sulfat 0. 1 mol dm- 3 .
{Muatan haba tentu larutan =4.2 Jg- °C. Ketumpatan /arutan =1.0gcm-
1 3
)
[4 marks]
[4 markah]
(iv) Why is the value of heat of displacement obtained in the experiment is less than
the theorical value?
State two precautions that should be taken during the experiment.
Mengapakah nilai haba penyesaran yang diperoleh dalam eksperimen ini adalah
kurang daripada nilai teori?
Nyatakan dua langkah berjaga-jaga yang perlu diambil ketika menjalankan
eksperimen ini.
[3 marks]
[3 markah]
(v) Predict the value of temperature change when 0.2 mol dm-3 of copper (II)
sulphate solution is used to replace 0.1 mol dm-3 of copper (II) sulphate solution.
Explain your answer.
Rama/kan nilai perubahan suhu apabi/a larutan kuprum (II) sulfat 0.2 mol
dm-3 digunakan bagi menggantikan larutan kuprum (II) sulfat 0. 1 mol dm-3.
~~~ ...
[2 marks]
{ 2 markah)
[3 marks]
[3 markah}
• Type of reaction.
Kandungan tenaga bagi bahan tindak balas dan hasi/ tindak balas.
Section C
Sahagian C
[20 marks]
{20 markah]
Diagram 9.1
Rajah 9.1
.. r;,.~.
~ ~ ~ · ··-= "~~ ).,. ~ -5!'"
-~ ,..... ..
-"\ ;..
.
Stat~:..:t;wo types of food additive found on the label and state the function for
"·~ "';,\'
12 '~0
eac!lrtype of food additives.
~~~-' ~j-~ ~1-fJJkan dua jenis bahan tambah makanan yang terdapat pada label itu dan
~(.r'Do;,iC::.""V/akan fungsi bagi setiap
~~.Y.,··'
bahan tambah makanan tersebut.
[4 marks)
[4 markah]
(ii) What are the advantage and disadvantage of using food additives?
Apakah kebaikan dan keburukan menggunakan bahan tambah makanan?.
[ 2 marks)
[ 2 markah)
Ly--J
Part A Part B
Sahagian Sahagian S
Diagram 9.2
Rajah 9.2
~ ·c ·ifYta@,;...~ 9.3 shows the apparatus set-up to investigate how to remove oily stain from
r;~-r "'~- a cloti{~~e observation is made before and after the experiment.
r:.r c.c "" '"
~· \ ~tf!aJahl~~i3 menujukkan susunan radas yang digunakan untuk mengkaji bagaimana
~~--'if!Or.. -~~-: ~
- ihkan kesan minyak daripada sehelai kain. Pemerhatian dibuat sebelum dan
7
s~fepas eksperimen.
~ Hard water
~
Soap Air fiat Detergent
Sabun Detergen
Cloth
Kain
Oily stain
Kesan minyak
Experiment I Experiment II
Eksperimen I Ekperimen II
Before experiment
Sebelum eksperimen
Cloth
Cloth
Kain
Kain
Oily stain remain Oily stain remove
Experiment II
Experiment I Kesan minyak kekal Kesan minyak
Eksperimen II
Eksperimen I hifang
After experiment
Se/epas eksperimen
Diagram 9.3
Rajah 9.3
«:J."": !"'·s.i1~~ the observation, compare and explain the effectiveness of the cleansing
7::.-..:;' ,.taction 6~~\E!en detergent and soap in hard water
~~-
~9:'
r:roasqt./!"f,i.t;~:
' f
pemerhatian,banding dan terangkan keberkesanan tindakan pencucian
~R:_<& lfif!.ta:;.Ef:tJetergen dan sabun dalam air fiat.
. 0~;;-..,.,;:.:<~
[ 10 marks]
{10 markah]
(2 marks]
[2 markah]
b) Aisyah is preparing her father's favorite drink, coffee. She heat the water
which is used to dissolve the coffee powder and sugar.
Base on the above statement, what is the purpose for Aisyah to heat the water which
is used to dissolve the coffee powder and sugar. Your explanation should include the
collision theory.
Based on the statement above, name the precipitate formed and describe an
experiment to investigate the effect of temperature on the rate of reaction between
sodium thiosulphate, Na2S203 solution and sulphuric acid, H2S0 4 .
• A list of material
Senarai bahan
• A list of apparatus
Senarai radas
.. Conclusion
Kesimpu/an
[12 marks]
{12 markah}
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END OF THE QUESTION PAPER
KERTAS SOALAN TAMAT
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4541/2
MAKLUMATUNTUKCALON
1. This question paper consists of three sections: Section A, Section S and Section C.
2. Answe r all questions in Section A. Write your answers for Section A in the spaces
provided in the question paper.
3. Answer one question from Section B and one question from Section C. Write your
answers for Section B and Section C in the lined pages at the end of the question
paper. Answer questions in Section Band Section C in detail. You may use equations,
diagrams, tables, graphs and any other suitable method to explain your answer.
4. Show your working in calculations , it may help you to get marks .
5. If you Wish to cancel any answer, neatly cross out the answer.
6. The diagrams in the questions are not drawn to scale unless stated.
7. Marks allocated for each question or parts there of are shown in brackets.
8. % ~~suggested to complete Section A is 90 minutes, Section S is 30 minutes and
~ ·~eeti .~ ~~ 30 minutes .
43/
... A:!,~ ,-4• ,..,........ '
NAMA
4541/3
CHEMISTRY KELAS
Kertas 3
OKT 2012 GURU
1 1/2 JAM
http://cikguadura.wordpress.com/
CHEMISTRY
Paper 3
1 hour 30 minutes
2. Jawapan kepada Soalan 1 dan soalan 2 hendaklah ditulis dalam ruangan yang
disediakan dalam kertas soalan.
3. Jawapan kepada Soalan 3 hendaklah ditulis pada he/aian tambahan. Anda bo/eh
menggunakan persamaan, gambar rajah, jadua/, graf dan cara lain yang sesuai untuk
menjelaskan jawapan anda .
5. Sekiranya anda hendak membatalkan sesuatu jawapan, buat garisan di atas jawapan itu.
7. Markah yang diperuntukkan bagi setiap soalan atau ceraian soalan ditunjukkan di dalam
kurungan.
8. Mas a yang dicadangkan menjawab Soa/an 1dan soa/an 2 ialah 45 min it dan Soa/an 3
ia/ah 45 minit.
Pemberian markah :
Markah Penerangan
3 Cemerlang : Respons yal}_g paling baik
2 Memuaskan: Respons yal}_g sederhana
1 Lemah: Respons yang kural}_g tejl_at
0 Tiada respons atau res_Q_ons salah
2. Write your answer for Question 1 and Question 2 in the spaces provided in the question
paper.
3. Write your answers for Question 3 on the extra sheet. You may use equations, diagrams,
tables, graphs and other suitable methods to explain your answer.
5. If you wish to cancel any answer, neatly cross out the answer.
6. The diagrams in the questions provided are not drawn to scale unless stated.
7. Marks allocated for each question or part question are shown in brackets.
8. The time suggested to answer Question 1and Question 2 is 45 minutes and Question 3 is
45 minutes.
10. This question paper must be handed in at the end of the examination.
Marks awarded:
Mark Description
3 Excellent: The best re~onse provided
2 Satisfactory: An average response provided
1 Weak: An inaccurate response provided
0 No response or wrong response provided
1. Table 1 shows the observations in three test tubes used to investigate the effect of other Untuk
Kegunaan
metals on rusting. A mixture of jelly solution, potassium hexacyanoferrate (Ill), Pemeriksa
K3Fe(CN)e solution and phenolphthalein were used as medium in each test tube. The
observations were recorded after one week.
Jadual 1 menunjukkan pemerhatian dalam tiga buah tabung uji yang digunakan untuk
menyiasat kesan logam lain ke atas pengaratan. Medium yang digunakan di dalam
setiap tabung uji adalah campuran larutan agar-agar. Larutan kalium
heksasianoferat(/11), K3Fe(CN)s dan fenolftalein. Pemerhatian direkod selepas satu
minggu.
Test Set-up of apparatus Observation
tube
Susunan radas Pemerhatian
Tabung
uji
Jelly solution +
potassium
hexacyanoferrate (Ill),
K3Fe(CN)s solution +
Iron nail phenolphthalein
Paku besi
Copper strip Larutan agar-agar,
Kepingan _ _.........,:1\'l'>o_ larutan kalium
kuprum heksasianoferat (Ill),
K3Fe(CN)6 dan
feno/ftalein
Jelly solution +
potassium
hexacyanoferrate (Ill),
K3Fe(CN)s solution +
phenolphthalein
Larutan agar-agar,
larutan kalium
heksasianoferat (Ill),
K3Fe(CN)6 dan
fenolftalein
Jelly solution +
...-:-::-:-
potassium
Ill :=:~r- hexacyanoferrate (Ill),
::_:~=~ K3Fe(CN)B solution +
Iron nail ---....1;-ioii::l[:-:.: phenolphthalein
Paku besi ~ -
Larutan agar-agar,
-
::-
~= larutan kalium
0 heksasianoferat (Ill),
K3Fe(CN)6 dan
fenolftalein
Table 1
Jadua/1
Test tube 1:
Tabung uji 1:
··· ···· ···· ···· ······ ·· ········· ········· ··· · ··· ···· ·· ··········· ·· ·· ···· ··· ·· ·· · ··· ······ ··· ············ ········
····· ·········· ·· · ··· ·· ···· ·········· ··· ···················· ·· ······ ······························ ··· ··· ··· ····
···· ··· ····· ···· ·· ·· ··· ·········· ··· ···· ···· ··· ······ ····· ·· ··· ······ ··· ··· ··· ····· · ··· ···· ···· · ·················
§t_tube Ill :
· ·_..:IQ~~fl uji Ill:
,..,_. :,.""~v·
.~~ ...... .~~·#::{·.... ...... ... ... ................ 0 • •• 0 •• 0 •• • •• 0 •• • • •••• •• • • •••• •• ••••••••••• • • • • • • • ••••• • ••• • •• •• •
c.O ,-; ·
[ 3 marks]
{ 3 markah]
I:=J
l___l2j
@ 2012 Hak Cipta MPSM Pahang [ Lihat halaman sebelah
6 4541/3
Untuk
c) State the hypothesis for the experiment. Kegunaan
Pemeriksa
Nyatakan hipotesis bagi eksperimen tersebut.
···· ···· ·· ···· ············· ··········· ····· ········ ··· ·· ··· ······ ··· ·· ·· ······ ······· ···· ···· ·· ······ ········ ··
······· ······ ··· ·· ··········· ····· ·· ·· ···· ··· ·· ··· ··· ·· ·· ·· ···· ···· ········ ·· ······ ········ ··· ·· ···· ·· ·· ·· ·· ···
..... ..... ....... .... .. ...... ......... ... ...... ... ... ... .. .... .... ..... ..... ......... .. .. ..... ........... ......
... .. .... ..... .... .. .... ... ... ... ..... .. ...... ....... ... .. .... ......... ... ..... .. ........ ......... ... .. ... ......
[ 3 marks]
[ 3 markah]
... .. ... ..... .. ...... ... ... ...... .... ..... ... ....... ...... .. ...... ... ... ....... ....... ......... .... .... .. ...
.... ..... ................... .... ...... ... .. ..... ... ..... ..... .. ............ ............ .. .. ... ..... ... ......
·· ·· ····· ····· ········ ······· ···· ······· ········· ···· ···· ···· ···· ··· ····· ···· ·· ··· ·· ········ ···· ···· ······· ·
[ 3 marks 1
[ 3 markah]
r--=J
Ll2J
Untuk
e) State the operational definition for the rusting of iron nail. Kegunaan
Nyatakan definisi secara operasi bagi pengaratan paku besi. Pemeriksa
[ 3 marks 1
{ 3 markah]
f) Diagram 1 shows the apparatus set-up of an experiment.
Rajah 1 menunjukkan susunan radas bagi satu eksperimen.
Phenolphthalein lfenolftalein
Diagram 1
Rajah 1
[ 3 marks 1
[ 3 markah] [Ej
Total1
2. Diagram 2 shows the set-up of apparatus to determine the heat of combustion for
alcohols.
Copper can
Thermometer
Tin kuprum
Termometer
Alcohols
Alkohol
Wooden block
Blok kayu
Diagram 2
Rajah 2
Three sets of experiments are carried out to determine the heat of combustion of
different types of alcohols.
50 60
40
so
30 40
10
II 30
10
20
60
50
40
30
111
20
Diagram 2.1
Rajah 2.1
(a) Record the initial thermometer readings and highest thermometer readings in Set I, Untuk
Keg una an
Set II and Set Ill at space provided in Diagram 2.1 Pemeriksa
Rekodkan bacaan awal termometer dan bacaan tertinggi termometer dalam Set /,
Set II dan Set J/1 pada ruang yang disediakan pada Rajah 2. 1
[ 3 marks]
[ 3 markah]
(b) Construct a table to record the initial temperature of water, highest temperature of
water and increase in temperature in Set I, Set II and Set Ill.
Bina satu jadual untuk merekodkan suhu awal air, suhu tertinggi dan kenaikan suhu
dalam Set/, Set II dan Set Ill.
( 3 marks]
[ 3 markah]
Methanol
Ethanol
Propanol
Butanol
Table 2
Jadua/2
(c) Sketch a graph to show heat of combustion of alcohols in Table 2 against number of
carbon atoms per molecule.
Lakar graf untuk menunjukkan haba pembakaran bagi alkohol dalam Jadual 2
. me/a wan atom karbon per molekul.
[ 3 marks ]
{ 3 markah]
r--=J
lJ2J
Diagram 2.2 shows the energy level for combustion of ethanol. Untuk
Kegunaan
Rajah 2. 2 menunjukkan aras tenaga untuk pembakaran eta no/. Pemeriksa
Energy
Tenaga
Diagram 2.2
Rajah 2.2
1. ····· · ····· · ··· ··· ······ ····· ···· .......................... ... ...... . .. . .... .... ... ...... ... . ..... . ... ..... .......... .. ... ..
2 . ..... . : .... . ..................... .. . ....... ....... .. .. ........ ............ .... ......... ... ............ .. ............ .... .. ..
3....... ...... .......................... ...... ... .... .................. .. . ................. ............. ... .. .... .. ... ....... .
[ 3 marks ] \.=J
{ 3 markah] L.l.:J
Untuk
(e) Alcohol is one example of carbon compounds. Kegunaan
Pam eriksa
Classify the following carbon compounds into hydrocarbons and non-hydrocarbons.
Alkoho/ ada/ah satu contoh sebatian karbon .
Kelaskan sebatian karbon berikut kepada hidrokarbon dan bukan hidrokarbon.
[ 3 marks]
{3 markah]
Tota12
3.
Snail body covered by a cone-shaped shell. What is the chemical compound found in the shells
so hard and waterproof? Actually, the above mentioned shell consists of calcium carbonate,
CaC03 which is insoluble salt.
Badan siput dilindungi oleh cengkerang yang berbentuk kon. Apakah sebatian kimia yang
terdapat pada cengkerang itu supaya keras dan kalis air? Sebenarnya, cengkerang terdiri
daripada ka/sium karbonat, CaC0 3 iaitu garam yang tidak larut.
Referring to the situation above, plan a labarotary experiment to compare the solubility of nitrate
salt, sulphate salt, carbonate salt and chloride salt in water.
a) Problem statement
Pernyataan masalah
c) Hypothesis
Hipotesis
[ 17 marks]
{17 markah]
SULIT 4541/1
1 A 14 C 27 C 40 B
2 C 15 C 28 B 41 B
3 D 16 C 29 B 42 A
4 D 17 D 30 D 43 A
5 C 18 C 31 C 44 C
6 C 19 C 32 B 45 C
7 C 20 C 33 C 46 D
8 A 21 B 34 A 47 C
9 D 22 B 35 B 48 D
10 D 23 B 36 A 49 C
11 B 24 D 37 B 50 C
12 D 25 A 38 A
13 A 26 C 39 A
© 2012 Hak Cipta MPSM Pahang [ Lihat halaman sebelah
SULIT
SULIT 1 4541/2/PP
4541/2/PP
Peraturan Permarkahan
Chemistry
Kertas 2
Okt/Nov 2012
MPSM PAHANG
TINGKATAN 5
http://cikguadura.wordpress.com/
CHEMISTRY
Kertas 2
PERATURAN PEMARKAHAN
Amaran
_____________________________________________________________________
1.a) C3H6 1
b)(i) CnH2n+1 OH 1
(ii) C3H7OH C3H6 + H20 1
c) H H H H H H
H- C –C- C - H
H – C – C – C -O H 1+1
H H H H OH H
Propan-1-ol Propan-2-ol
(any one)
d)(i) Propane 1
(ii) C3 H6 + H 2 C3H8
-Formula reactant correct 1
-Formula product correct 1
e)(i) Propyl ethanoate 1
2.a)
(i) Number of proton in nucleus of its atom 1
(ii) 15 1
b) Nucleon number 1
c)(i) Q and R have different number of neutron/nucleon number 1
(ii) Carbon 14 - to estimate the age of fossils and artifacts 1
Cobalt 60 - kill cancer cells,sterilised medical instruments
Sodium 24-detect leakage of underground pipes
(any one)
d (i) 2.8.7 1
(ii) 7 1
iii) Draw diagram:
R
9
3.a)
( i) Z 1
(ii) Q 1
(iii) Y 1
b) Q, P, Z, Y, T 1
c) 4 1
d) Z has higher number of protons than T. Hence it has stronger 1+1
nuclei attraction on the electrons.
e) Y3+ 1
f) Transition Elements 1
g) Their ions or compounds are colored//They form complex 1
ions or compounds/they are good catalysts//They can have
variable oxidation.
10
4.a) H+ , Cu 2+ , 1
SO42- , OH - 1
b.(i) Bubbles of gas released 1
(ii) Concentration of Cu2+ decrease // Cu 2+ 1
discharge to form Cu atom
(c) Cu2+ + 2e Cu 1
d)(i) Anode become thinner / smaller / mass 1
decrease
(ii) Cathode become thicker / bigger / mass 1
increase
e) Correct diagram 1
Copper electrode at anode
Steel spoon at cathode
Copper (II) sulphate as electrolyte
Correct label 1
10
e) M1V1 = 1 1
M2V2 2
0.25 × V1 = 1 1
0.5 × 25 2
V1 = 1 × 0.5 × 25
2 × 0.25
= 25cm3 1
f) 50 cm3
1
g) i) Vinegar is used to cure wasp sting that alkaline in nature
1+1
ii) Toothpaste contain bases to neutralize acid produce by
bacteria
11
6.
a) Redox reaction is a reaction in which oxidation and reduction 1
occur at the same time
b) Oxygen and water 1
c) Fe → Fe2+ + 2e 1
d) Label of water droplet, oxygen and iron 1
Label of anode and cathode 1
Draw arrow from negative to positive pole iron 1
11
7
a)
6
height of precipitate/ cm
0
1 2 3 4 5 6 7
1
Correct axis with unit
1
Correct and Smooth line
1
Correct scale
b.
(i) Pb(NO3)2 + 2KI PbI2 + 2KNO3 1+1
Volume of Pb(NO3)2 = 2.5 cm3 1
20
8.
a) 1. the mixture becomes hot
2. the thermometer reading increase
3. zinc powder dissolves
4. brown solid/precipitate formed
5. the blue solution turn colourless
1+1+1
(Any three)
2 precautions
1. use polysterene cup//use two layers of polysterene cup
Instead of one.
2. add zink powder quickly into the solution
3. stir the mixture continuously until highest temperature
obtained.
Zn + Cu2+
H= - 210 kJ mol-1
Energy
Zn2+ + Cu
20
9
1. Tomato puree is used as a colouring agent to restore the
a.(i)
colour of the food.
2. Sugar // spice is used as a flavouring agent to enhance
the taste of food
3. Permitted modified starch is used as thickener to thicken
2+2
food.
(Any two)
(ii) Advantage :
i) to prevent food from spoilage 1
ii) to improve appearance, texture or taste
Disadvantage:
i) Lead to serious diseases like asthma, and cancer 1
20
10.
a.(i) The speed at which reactant are converted into product in a 1
chemical reaction// change in selected quantity of reactant or
produrt per unit of time taken.
The heat given to the water will give more kinetic energy to 1
the particles.
c) Precipitate : Sulphur
1
Materials:
0.2 mol dm-3 sodium thiosulphate, 1.0 mol dm-3 sulphuric 1
acid, a piece of white paper marked ‘X’ at the centre.
Apparatus:
150 cm3 conical flask, stopwatch, 50 cm3 measuring cylinder, 1
10 cm3 measuring cylinder, thermometer, Bunsen burner,
wire gauze.
Procedure:
Using a measuring cylinder, 50 cm3 of 0.2 mol dm-3 sodium 1
thiosulphate solution is measured and poured into a conical
flask.
The ‘X’ mark is observed vertically from the top of the conical 1
flask through the solution.
The stopwatch is stopped once the ‘X’ mark disappears from 1
view.
20
4541/3/PP
Peraturan Permarkahan
Kimia
Kertas 3
OKT/NOV 2012
MPSM PAHANG
MARKING SCHEME
TINGKATAN 5
http://cikguadura.wordpress.com/
CHEMISTRY
Paper 3
Amaran
Kertas skema permarkahan ini mengandungi 14 muka surat bercetak.
@ 2012 Hak Cipta MPSM Pahang 1 [ Lihat halaman sebelah
SULIT
SULIT 4541/3/PP
Rusting occurs.
OR
1.correct titles
Set I II III
1. Titles
2. Readings
Sample answer:
I II III 2
Sample answer :
I II III 1
Increase in temperature
2. Correct unit
3. Correct curve
Sample answer:
3
Heat of combustion, KJmol‐1
1 2 3 4
Number of C atom per molecule
sample answer:
2
Heat of combustion
1 2 3 4
Number of carbon atom
Sample answer:
1
@ 2012 Hak Cipta MPSM Pahang 8 [ Lihat halaman sebelah
SULIT
SULIT 4541/3/PP
Or
Number of C atom
No response or wrong response 0
Sample answer:
Sample answer:
Hydrocarbon Non-hydrocarbon
Prophyl ethanoate,
CH3COOC3H7
Sample answer:
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salt/temperature
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Material:
1. Test tube
2. Spatula
Able to list incompletely materials and apparatus. 2
Sample answer:
Materials:
1. Incomplete salt :
List only 3 type of salt Eg zinc nitrate, lead (II) sulphate,
calcium carbonate
2. Distilled water
Apparatus:
1. Test tube
2. Spatula
Able to give an idea of materials and apparatus. 1
Sample answer:
Materials:
1. Incomplete salt :
List only 2 type of salt Eg zinc nitrate, plumbum (II)
sulphate, calcium carbonate
2. No distilled water
Apparatus:
1. Test tube
2. Spatula
Sample answer:
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Zinc nitrate
Magnesium chloride
Sodium chloride
Potassium carbonate
Sample answer: