Odule 4: Acids & Bases Objectives:: Water

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MTChem1: Inorganic and Organic Chemistry for MLS

A.Y.: 2020-2021

Module 4:  Every Bronsted–Lowry acid has a


ACIDS & BASES conjugate base, and every Bronsted–
Objectives: Lowry base has a conjugate acid.
 Understand the importance and
properties of acids and bases. 
 Identify the role of a specie in an acid-
base reaction.
Module Outline  Conjugate acid: formed when a [H+] is
1. Arrhenius and Bronsted Lowry Acid-Base added to a Bronsted-Lowry base.
Theory  Conjugate base: remains when a [H+]
2. Mono-, di-, triprotic Acids is removed from a Bronsted-Lowry acid.
3. Properties of Acids and Bases
4. Strength of Acids and Bases  Amphiprotic Substances: They can
5. The pH Concept function as either Bronsted-Lowry acids
6. Acid Base Neutralizations or bases.
o Ex: Water
ARRHENIUS ACID-BASE THEORY
 Proposed by Swedish chemist, Svante
August Arrhenius in 1884.
 That acids and bases be defined in
terms of the chemical species they
form when they dissolve in water.
 Arrhenius acid: produces [H+] ions MONO, DI, - TRIPORTIC ACIDS
though ionization.  Classification of acids based on the
 Arrhenius base: produces [OH-] ions number of [H+] they can transfer per
through dissociation. molecule in an acid-base reaction.
o Monoprotic Acid: supplies 1 [H+]
BRONSTED-LOWRY ACID-BASE o Diprotic Acid: supplies 2 [H+]
THEORY o Triprotic Acid: supplies 3 [H+]
 Johannes Nicolaus Bronsted, a
Danish chemist, and Thomas Martin General Properties of Acids and
Lowry, a British chemist Bases
independently and almost ACIDS
simultaneously proposed a theory for  pH <7
both aqueous and nonaqueous acids  tastes sour
and bases.  affect indicators
 Bronsted-Lowry acid: proton donor  reacts with active metals and produce H2
 Bronsted-Lowry base: proton acceptor  reacts with carbonates
 neutralize bases
NOTE:
[H+] hydrogen ions are hydrogen
atoms that lost its only electron
thus hydrogen ions and protons
are used interchangeably used in
this theory BASES
 pH >7
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MTChem1: Inorganic and Organic Chemistry for MLS
A.Y.: 2020-2021

 taste bitter  The pH is the negative logarithm of an


 have slippery feel aqueous solution’s molar hydronium
 affect indicators giving colors opposite to ion concentration
that of the acids
 neutralize acids
pH= -log[H3O+]

STRENGTH OF ACIDS AND BASES


Bronsted–Lowry acids vary in their ability to NEUTRALIZATION
transfer protons and produce hydronium ions in Neutralization is a chemical reaction wherein
aqueous solution. Acids can be classified as the addition of an acid and a base will result
strong or weak on the basis of the extent to which in a solution with no excess [H+] or [OH-] thus
proton transfer occurs in aqueous solution. yielding a neutral pH.
 [H3O+] and [OH-] ion concentrations  In an acid–base neutralization
determine the acidity/alkalinity of
reaction with an acid and a hydroxide
solutions.
base results in the production of SALT
 Acidic [H3O+] > [OH-] and WATER

Neutra [H3O+] = [OH-] Acid + Hydroxide Base  Salt + H2O


l
 Hydroxide bases are compounds that
Basic [H3O+] < [OH-] have an alkaline pH but does not
contain a [OH-] group.

 Examples
The pH Concept Hydroxide Non-hydroxide bases
 Power of Hydrogen/Potential of
bases
Hydrogen
NaOH PO4
 The pH scale is a scale of small
KOH NH3
numbers that is used to specify molar
LiOH Na2CO3
hydronium ion concentration in an
aqueous solution.

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MTChem1: Inorganic and Organic Chemistry for MLS
A.Y.: 2020-2021

.
pH
14 Strong It reacts completely or almost completely
13 Base with water to form hydroxide ions.
12
11 Moderate
10 Base
9 Weak base It dissociates only partially in water to
8 produce hydronium ions.
7 Neutral
6 Weak Acid It dissociates only partially in water to
5 produce hydronium ions.
4 Moderate
3 Acid
2 Strong It reacts completely or almost completely
1 Acid with water to form hydronium ions.
0

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