CHM 524-TUTORIAL-CHAPTER 2-A

1. The resistance of 0.01 M NaCl solution in a conductivity cell was found to be 210Ω.
The specific conductance of this solution is 4.5 x 10​–3​ S cm​–1​. What is the cell
constant of the cell? ​0.945 cm​–1
2. Calculate ​⋀​° m NH​4​OH from the following values. ⋀
​ °​ m for Ba(OH)​2​ , BaCl​2​, NH​4​Cl
​
are 257.6, 240.6, 129.8 Scm​2​ mol​-1 respectively. ​238.3 Scm2​ ​ mol-1
​
3. Calculate the molar conductivity at infinite dilution for CH​3​COOH if the molar
conductivities at infinite dilution for NaCl, HCl and CH​3​COONa are 126.45, 426.16
​ ​ cm2​ ​ mol–1
and 91.0 ohm​–1​ cm​2​ mol​–1​ respectively.​390.71 ohm–1 ​
4. At 25°C, the molar conductance of propanoic acid at infinite dilution is 386.6 S cm​2
mol​-1​. If its ionization constant is 1.4 x 10​-5​, Calculate molar conductance of 0.05 M
propanoic acid solution at 25°C? ​6.47 S cm2​ ​mol​-1
5. Molar conductivities at infinite dilution at 25°C of NH​4​Cl, NaOH and NaCl are 129.8,
217.4 & 108.9 S cm​2 ​mol​-1​. For 0.01 M NH​4​OH molar conductance is 9.33 S cm​2
mol​-1​. Calculate ionization constant of NH​4​OH. ​1.6 x 10-5
​
6. The molar conductivity of a weak monobasic acid at infinite dilution is 387 ohm​–1
cm​2​ mol​–1​. The 0.02M solution of the same acid has a specific conductivity of
3.3 x 10​–4​ ohm​–1​ cm​2​ mol​–1​. Calculate the degree of dissociation of the acid at the
given concentration.​0.0426
7. Find the ionic strength of a 0.020 M Na​2​SO​4​ solution?​ 0.060 M
8. Calculate the ionic strength of a 0.060 M solution of KCl.​0.060 M