2

Answer all questions.

Jawab semua soalan.

1. Diagram 1.1 and Diagram 1.2 shows the apparatus set up used in two experiment to determine heat
of displacement.
Rajah 1.1 dan Rajah 1.2 menunjukkan susunan radas yang digunakan dalam dua eksperimen untuk
menentukan haba penyesaran.

Experiment I
Eksperimen I

Excess magnesium powder is added into 50 cm3 of copper (II) nitrate 1.0 mol dm-3. The mixture is
stirred and the change of temperature is recorded.
Serbuk magnesium berlebihan ditambahkan kepada 50 cm3 larutan kuprum (II) nitrat 1.0 mol dm-3.
Campuran dikacau dan perubahan suhu dicatatkan.

Thermometer 60
30 Termometer
Thermometer Thermometer
Termometer Termometer
50
20
Magnesium powder
Serbuk magnesium
Polystyrene cup
Cawan polistirena

Stir
Kacau
copper(II) nitrate solution Colorless solution
larutan kuprum (II) nitrat Larutan tak berwarna

Beginning of experiment End of experiment

Awal eksperimen Akhir eksperimen

Diagram 1.1
Diagram 1.1

Initial temperature of the solution :

Suhu awal larutan …………………..

Highest temperature of the mixture :

Suhu tertinggi campuran …………………..

4541/3 @ 2018 MPSM Kedah [ Lihat halaman sebelah

SULIT
 3

Experiment II
Eksperimen II

Excess lead powder is added into 50 cm3 of copper(II) nitrate 1.0 moldm-3. The mixture is stirred
and the change of temperature is recorded.
Serbuk plumbum berlebihan ditambahkan kepada 50 cm3 larutan kuprum(II) nitrat 1.0 moldm-3.
Campuran dikacau dan perubahan suhu dicatatkan.

Thermometer 50
30 Termometer
Thermometer
Termometer
40
20
Lead powder
Serbuk plumbum

Polystyrene cup
Cawan polistirena
Lead powder
Serbuk plumbum Stir
Kacau
50 cm3 of 1.0 mol dm-3 copper(II) nitrate solution Colourless solution
50 cm3 larutan kuprum (II) nitrat 1.0 moldm-3 Larutan tak berwarna

Beginning of experiment End of experiment

Awal eksperimen Akhir eksperimen

Diagram 1.2
Diagram 1.2

Initial temperature of the solution :

Suhu awal larutan …………………..
Highest temperature of the mixture :
Suhu tertinggi campuran …………………..

(a) Record the initial and the highest temperature of the mixture and change in temperature for
Experiment I and II in the space provided.
Rekodkan suhu awal dan suhu tertinggi campuran serta perubahan suhu untuk Eksperimen I
dan II dalam ruangan yang disediakan.
[3 marks]

4541/3 @ 2018 MPSM kedah [ Lihat halaman sebelah

SULIT
 4

(b) Construct a table to record the initial thermometer reading, highest thermometer reading and
the temperature change.
Binakan satu jadual untuk merekod bacaan awal termometer, bacaan tertinggi termometer dan
perubahan suhu.

[3 marks]

(c) For this experiment, state:

Bagi eksperimen ini, nyatakan:

(i) the manipulated variable.

pemboleh ubah dimanipulasikan.

(ii) the responding variable.

pemboleh ubah bergerak balas.

(iii) the constant variable.

pemboleh ubah dimalarkan.

[3 marks]

(d) State the hypothesis for the experiment.

Nyatakan hipotesis bagi eksperimen tersebut.

[3 marks]

4541/3 @ 2018 MPSM kedah [ Lihat halaman sebelah

SULIT
 5

(e) (i) Based on the Experiment I, state two observation for this experiment other than
temperature changes.
Berdasarkan Eksperimen 1, nyatakan dua pemerhatian bagi eksperimen ini selain
daripada perubahan suhu.

[3 marks]

(ii) Give the corresponding inference base on your answer in 1(e)(i)

Beri inferens yang sepadan, berdasarkan kepada jawapan anda di 1(e)(i)

[3 marks]

(f) State the operational definition of heat of displacement for the experiment.
Nyatakan definisi secara operasi bagi haba penyesaran dalam eksperimen ini.

[3 marks]

(g) Based on Experiment I, calculate

Berdasarkan kepada Eksperimen I, hitung

(i) the heat release when copper displaced by magnesium.

(Heat capacity of the solution is 4.2 J g-1 oC-1, density of solution is 1.0 g cm-3.)
haba yang terbebas apabila kuprum disesarkan oleh magnesium.
(Muatan haba tentu larutan ialah 4.2 J g-1o C-1, ketumpatan larutan ialah 1.0 g cm-3.)

Heat energy Heat capacity of Temperature

Mass of
release solution change
= solution X X
Tenaga haba Muatan haba tentu Perubahan
Jisim larutan
yang terbebas larutan suhu
=
……………… X ………………….. X ……………
=
…………… J

(ii) The number of mole of copper ion displaced.

Bilangan mol ion kuprum yang disesarkan.

Molarity X (volume )
Number of mole of copper ion 1000
=
Bilangan mol ion kuprum Molariti X (isipadu)
1000
=
…..…….. mol

4541/3 @ 2018 MPSM kedah [ Lihat halaman sebelah

SULIT
 6

Heat energy release

The heat of displacement Tenaga haba yang terbebas
(iii) =
Haba penyesaran Number of mol of copper ion
Bilangan mol ion kuprum

=
…..……….. kJ mol-1

[3 marks]

(h) By calculate the heat of displacement, draw energy level diagram for Experiment II.
Dengan menghitung haba penyesaran, lukiskan gambar rajah aras tenaga untuk Eksperimen
II

[3 marks]
(i) Based on this experiment, predict the heat of displacement for copper by zinc.
Berdasarkan eksperimen ini, ramal haba penyesaran kuprum oleh zink.

[3 marks]

(j) A list of chemicals is dissolved in distilled water as follows:

Satu senarai bahan kimia dilarutkan di dalam air suling seperti berikut:

Sodium hydroxide Anhydrous copper(II) sulphate

Natrium hidroksida Kuprum(II) sulfat kontang

Ammonium nitrate Ammonium chloride

Ammonium nitrat Ammonium klorida

Classify these substances that produce exothermic reactions and endothermic reactions when
dissolved in water.
Kelaskan bahan-bahan ini kepada bahan yang menghasilkan tindak balas eksotermik dan
tindak balas endotermik apabila dilarutkan di dalam air.

[3 marks]

4541/3 @ 2018 MPSM kedah [ Lihat halaman sebelah

SULIT
 7

2 Diagram 2 show the products that can be made from rubber. Tyre and rubber band are widely
used in our life. However tyre is more elastic than rubber band.
Rajah 2 menunjukkan produk yang dapat dihasilkan dari getah. Tayar dan gelang getah
digunakan dengan meluas dalam kehidupan kita. Walaubagaimanapun tayar adalah lebih
elastic daripada gelang getah.

Rubber trees
Pokok getah

Diagram 2
Rajah 2

Referring to the diagram, plan a laboratory experiment to investigate the elasticity of vulcanise
and unvulcanised rubber.
Merujuk kepada rajah di atas, rancang satu eksperimen makmal untuk mengkaji kekenyalan
bagi getah tervulkan dan getah tidak tervulkan.

Your planning should include the following aspects:

Perancangan anda hendaklah mengandungi aspek-aspek berikut:

(a) Statement of problem

Pernyataan masalah
(b) All the variables
Semua pembolehubah
(c) Statement of the hypothesis
Pernyataan hipotesis
(d) List of materials and apparatus
Senarai bahan dan radas
(e) Procedure of the experiment
Prosedur eksperimen
(f) Tabulation of data
Penjadualan data [ 17 marks ]
[ 17 markah ]

END OF QUESTION PAPER

KERTAS SOALAN TAMAT

4541/3 @ 2018 MPSM kedah [ Lihat halaman sebelah

SULIT