locus acdemy 23/07/20

01. Among the following , ‘X’ compounds are 05. Formula for Lindane is :
aromatic and ‘Y’ compounds are Anti-aromatic (1) C6Cl6 (2) C6H6Cl6
and ‘Z’ are Non - aromatic. (3) C6H5Cl (4) C6H4Cl2
Then calculate x + y – 3z :
06.

; ; ;
(1) (2)

; ; ; (3) Toluene (4) (1) & (3) Both

07. Which of the following reaction is known
as Friedel-Craft Alkylation reaction :
; ; ;
(1) CH3COOH + H2 - Ni → CH3CH2OH
(2) Ph-H + CH3CH2CH2Cl + Anhy. AlCl3 → Ph-CH(CH3)2
(3) CH3-C≡CH + NaNH2 → CH3C≡C-Na+ + NH3
; ; ;
(4)

; 08. Anhydrous AlCl3 is :

(1) 0 (2) 1 (1) Lewis Acid (2) Lone-pair acceptor
(3) 2 (4) 3 (3) Electrophilic (4) All of above
02. Anti aromatic compound(s) is/are :
09.(M)

(1) (2)
Then ‘R’ may be :
(1) CH3CH2CH2- (2) CH3CH2-
(3) (4) None (3) CH3CH2CH2CH2- (4)
03. Correct order of stability of the following :
(1) Aromatic < Anti-Aromatic < Non-Aromatic 10.
(2) Aromatic > Anti-Aromatic > Non-Aromatic
(3) Aromatic > Non-Aromatic > Anti-Aromatic Wheland intermediate of this reaction is/are :
(4) Aromatic < Non-Aromatic > Anti-Aromatic

(1) (2)
04.

(1) Lindane (2) B . H. C. (3) (4)

(3) Insecticide (4) A.O.T.
11. Total number of 𝝈 bond present in the above 17. Benzene + neo-pentyl chloride + AlCl3 → P is :
wheland intermediate :
(1) 18 (2) 17 (1) (2)
(3) 19 (4) 20
(3) (4) N.O.T.
12.

18. Benzene + Acetyl chloride + AlCl3 → P is :

(1) (2) Glyoxal
(1) Acetone (2) Acetophenone

(3) (4) (3) Benzoic acid (4) Phthallic acid

19. Phenol + Zn-Dust → (A)
(A) + CH3CH2Cl + Anhydrous AlCl3 → (B)
𝐊𝐌𝐧𝐎𝟒
13. (B) 𝐇𝐎−
(C) , then correct option is/are :

(1) A = Benzene (2) B = Ph-CH2-CH3

Total number of ‘sp3’ hybridized carbon atom (3) C = Benzoic acid (4) N.O.T.
in Wheland intermediate : 𝐊𝐌𝐧𝐎𝟒 𝐓𝐡𝐢𝐨𝐧𝐲𝐥
20. Cumene 𝐇𝐎−
(A) 𝐂𝐡𝐥𝐨𝐫𝐢𝐝𝐞 (B) + Gas (X + Y)
(1) 0 (2) 1
(1) (B) is Benzoic acid
(3) 2 (4) 3
(2) (B) is Benzoyl chloride
14. In Friedel craft alkylation rearrangement
(3) (A) is Benzoic acid
is possible due to :
(4) 2 & 3 both
(1) Attacking reagent is carbocation
21.
(2) Attacking reagent is carbanion
(3) Attacking reagent is nucleophile
(1)
(4) None
15.
(2)

(1) (2)
(3)

(4)
(3) (4)

22.
16.
𝐇𝐨𝐭
(A) 𝐊𝐌𝐧𝐎₄
Product is :

(1) (2)
(1) (2)

(3) (4) None

(3) (4) None
 𝑯𝑭
AROMATIC – 02 09. +
𝑩𝑭₃
Product is :

𝑯𝑭
01. + Product is : (1) (2)
𝑩𝑭₃

(1) (2)
(3) (4) None

(3) (4)
10. C6H6 + CH3Cl/AlCl3→ (A)

02. Benzene + CH3COOH + H3PO4 → (A) (A) + HOT KMnO4 → (B)

(A) + LiAlH4 → (B) (B) + SOCl2 → (C) + Gas X + Gas Y

(B) + Conc. H2SO4 →(C) If gas Y is a strong acid, then mark the correct options
(1) Gas X is SO3 (2) Gas X is HCl
(1) (A) = (2) (B) = (3) Gas X has suffocating odour (4) Gas X is H2S

(3) (C) = (4) (C) = Styrene

11. ? ‘?’ is :
𝑨𝒍𝑪𝒍𝟑
03. C6H6 + succinic anhydride 𝒂𝒏𝒉𝒚
(P)

(P) H₂-Ni Product is : (1) Zn-Hg/ conc. HCl. (2) B2H6 – H2O
(3)LiAlH4 (4)N2H4 – Base / Heat

(1) (2)

12.
(I) (II) (III) (IV) (V)
(3) (4) How many of the following will produce Benzoic acid
on reaction with hot alkaline KMnO4?
(1) I,II,III (2)I,II,IV,V

𝒁𝒏(𝑯𝒈) 𝒁𝒏(𝑯𝒈) (3) I,II,III,IV,V (4) I,II,IV

04. 05.
𝑪𝒐𝒏𝒄.𝑯𝑪𝒍 𝑪𝒐𝒏𝒄.𝑯𝑪𝒍

𝑯𝒐𝒕
13. Product is :
𝑲𝑴𝒏𝑶₄

𝒁𝒏(𝑯𝒈)
06.
𝑪𝒐𝒏𝒄.𝑯𝑪𝒍

𝒁𝒏(𝑯𝒈)
07. Acetophenone +
𝑪𝒐𝒏𝒄.𝑯𝑪𝒍 (1) (2)

08. + Conc. H₂SO₄ Product is :

(3) (4)
(1) (2)

(3) (4) None

 AROMATIC – 03
𝐑.𝐇.𝐓. 𝐂𝐇₃𝐎𝐇 𝐇𝐨𝐭
01. Acetylene (A) (B) (C)
𝐅𝐞 𝐇⁺ 𝐊𝐌𝐧𝐎₄
05. (I) , (II) , (III) ,
𝐙𝐧−𝐇𝐠 𝐒𝐮𝐜𝐜𝐢𝐧𝐢𝐜 𝐙𝐧−𝐇𝐠
(C) (D) 𝐀𝐧𝐡𝐲𝐝𝐫𝐢𝐝𝐞 𝐀𝐥𝐂𝐥₃ (E)𝐂𝐨𝐧𝐜.𝐇𝐂𝐥 (F)
𝐂𝐨𝐧𝐜.𝐇𝐂𝐥

𝐒𝐎𝐂𝐥₂ 𝐙𝐧−𝐇𝐠 𝐏𝐝−𝐂

(F) 𝐀𝐥𝐂𝐥₃
(G) 𝐂𝐨𝐧𝐜.𝐇𝐂𝐥 (H) 𝐎𝐫 𝐒𝐞 (I)
(IV) , (V) , (VI) ,
Then correct option is /are :

(VII) , (VIII) , (IX)

(1) E= (2) G=
How many of the above are ortho-para directing
towards electrophilic substitution reaction :
(3) H= (4) I= (1) 5 (2) 6
(3) 4 (4) 7

02.
06. Cu,Δ (A) 𝐙𝐧−𝐇𝐠 (B) 𝐇𝐨𝐭 (C)
𝐂𝐨𝐧𝐜.𝐇𝐂𝐥 𝐊𝐌𝐧𝐎₄
‘A’ and mechanism of reaction :
𝐍𝐚𝐎𝐇 𝐎₃
(C) 𝐂𝐚𝐎
(D) 𝐇₂𝐎 (E), then ‘E’ is :
(1) , SE 2 (2) , SE1
(1) Oxalic acid (2) Malomic acid
(3) Succinic acid (4) Glutanic acid
(3) , E1 (4) , SE2

07. ? ; ? is :
03. + CH3Cl/AlCl3 → Product is :

(1) Succinic anhydride/ AlCl3 , AlCl3 .

(2) Succinic anhydride/ AlCl3 , Zn-Hg conc. HCl , AlCl3
(1) (2)
(3) Succinic anhydride/ AlCl3, SOCl2, AlCl3 .
(4) Succinic anhydride/ AlCl3, Zn-Hg/conc.HCl , SOCl2
08. Which of the following will produce naphthalene :
(3) (4) None
𝑅.𝐻.𝑇. 𝑆𝑢𝑐𝑐𝑖𝑛𝑖𝑐
(1) CH≡CH (A) 𝐴𝑛ℎ𝑦𝑑𝑟𝑖𝑑𝑒 (B) Pd-C
𝐹𝑒

𝑅.𝐻.𝑇. 𝑍𝑛−𝐻𝑔 𝐴𝑛𝐴𝑙𝐶𝑙₃

(2) CH≡CH 𝐹𝑒
(A) An. AlCl₃ (B) 𝐶𝑜𝑛𝑐.𝐻𝐶𝑙 (C) 𝑃𝑑−𝐶
04. + Br2/Fe → Product is :

(i) An.AlCl₃
𝐴𝑛𝐴𝑙𝐶𝑙₃ 𝑍𝑛−𝐻𝑔/𝐻𝐶𝑙
(3) Benzene (A) (C)
𝐴𝑛𝐴𝑙𝐶𝑙₃
(ii) R.T.H, Fe 𝑆𝑂𝐶𝑙₂
(𝑖)𝐴𝑛.𝐴𝑙𝐶𝑙₃
(1) (2) (C)(𝑖𝑖)𝑍𝑛−𝐻𝑔/𝐻𝐶𝑙,(𝑖𝑖𝑖)𝑆𝑒
𝑆𝑢𝑐𝑐𝑖𝑛𝑖𝑐
(i) An.AlCl₃ (𝑖)𝑆𝑂𝐶𝑙₂
(4) Acetylene (A)(𝑖𝑖)𝑃𝑑−𝐶
𝐴𝑛ℎ𝑦𝑑𝑟𝑖𝑑𝑒
(ii) R.T.H, Fe

(3) (4) (2) & (3)

 aromatic – 04 08. For which of the following molecule significant
µ ≠0?
01. compound is :
(1) Aromatic (2) Non-Aromatic (i) (ii) (iii) (iv)
(3) Anti- aromatic (4) heterocyclic
(1) Only (i) (2) (i) & (ii)
02. Heat (A) + (B) (3) Only (iii) (4) (iii) & (iv)

𝑯𝒐𝒕 09. is ?
(A) + NaOH → (C) ;(B) + H2-Ni → (D); (D) (E)
𝑲𝑴𝒏𝑶₄
(1) Ortho-Para directing and deactivating.
(2) Ortho-Para directing and activating.
(1) A= (2) B=
(3) Meta directing anddeactivating.
(4) Meta directing andactivating.
(3) C= (4) D=
10(M). An aromatic molecule will ?
(1) Have 4nπ- electrons (2) Be planar.
(5) E=
(3) Have (4n+2)π electrons (4) Be cyclic.

LiAlH₄ ;PCl₅ ;Alc. KOH 11. Which of the following molecules, in pure form,
03. CH3COOH (C)
is/are instable at room temperature ?
Product ‘C’ is :
(1) Acetaldehyde (2) Acetylene
(1) (2) (3) (4)
(3) Ethylene (4) Acetyl chloride
04. The compound that undergoes decarboxylation
𝑶₂/𝜟
most readily under mild condition is ? 12. + ClCH2CH2CH3 AlCl₃ (P) (Q)+Phenol
𝑯₃𝑶⁺

‘P’ & ‘Q’ are respectively :

(1) (2)
(1) + CH3CH2CHO (2) + CH3COCH3

(3) (4) (3) + CH3CH2CHO (4) + CH3COCH3

05. In the following sequence of reactions ;
𝑯𝒐𝒕 SOCl₂
𝑯₂−𝑷𝒅
Toluene 𝑲𝑴𝒏𝑶₄ (A) (B) 𝑩𝒂𝑺𝑶₄ (C)

The product ‘C’ is : 13.

(1) C6H5COOH (2) C6H5-CHO

(3) C6H5CH2OH (4) C6H5CH3 Product on monobromination of this compound :

06. ? STYRENE:
(1) (2)

07. ?
(3) (4)
 aromatic – 05 20.

01.The compound that is most reactive towards

electrophilic substitution is
(1)
(1) Toluene. (2)Benzene.
(3) Benzoic acid. (4) Nitrobenzene.
02. R—CH2OH Cu, Δ

03. R—CH(OH)—R’ Cu, Δ

(2)
𝑯𝑶𝑻
04. R—CH2OH 𝑲𝑴𝒏𝑶₄
𝑯𝑶𝑻
05. R—CH(OH) 𝑲𝑴𝒏𝑶₄
(3)

06.

(4)
07.
08. R—C≡C—R’ Na—Liq.NH₃ 21.
𝑯₂+𝑷𝒅
09. R—C≡C—R’ 𝑩𝒂𝑺𝑶₄
(1) (2)

10. HEAT
(3) (4)

𝑵𝒂𝑶𝑯/𝑪𝒂𝑶
11. R—COOH
𝑯𝒆𝒂𝒕 22. The compounds P, Q and S ,

12. ?

? were separately subjected to nitration using

13.
HNO3/H2SO4 mixture. The major product formed
in each case respectively, is :
14. . ?

(1)
𝑪𝑯₃𝑪𝒍
15. 𝑨𝒏.𝑨𝑳𝑪𝒍₃

𝑩𝒓₂ (2)
16.
𝑭𝒆

𝑪𝑯₃𝑪𝑯₂𝑪𝑯₂𝑪𝒍
17.
𝑨𝒏.𝑨𝒍𝑪𝒍₃

(3)
𝑺𝒏𝑪𝒍𝟐 /𝑯𝑪𝒍
18.
𝑺𝒕𝒆𝒂𝒎

𝑺𝒏𝑪𝒍𝟐 /𝑯𝑪𝒍 (4)

19. R—CN
𝑺𝒕𝒆𝒂𝒎
23. Identify the correct order of reactivity in (1) is para-directing
electrophilic substitution reactions of the (2) is meta-directing
following compounds Benzene (I), Toluene (II), (3) activates the ring by hyperconjugation
Chlorobenzene (III) and Nitrobenzene (IV). (4) deactivates the ring
(1) I > II > IIII > IV (2) IV > III > II > I 32(M) A new carbon-carbon bond formation is
(3) II > I > III > IV (4) II > III > I > IV possible in :
24. Benzyl chloride (C6H5CH2Cl) can be prepared (1) Clemmensen reduction
from toluene by chlorination with 2) Rosenmund reduction
(1) SO2Cl2 (2) SOCl2 (3) Fridel-Craft’s alkylation
(3) Cl2/hv (4) NaOCl (4) Cannizaro’s reaction
25. The reaction of toluene with chlorine in the 33. What would be the major product in the
presence of ferric chloride gives predominantly : following reaction :
(1) Benzoyl chloride (2) m-chloro toluene
(3) Benzyl chloride (4) o,p-chlorotoluene
26. The compound that is most readily reactive
towards electrophilic substitution is :
34.
(1) Toluene (2). Benzene
(3) Chlorobenzene (1) Nitrobenzene
(1) (2)
27. Chlorination of toluene in the presence of
light and heat followed by treatment with
(3) (4)
aqueous NaOH gives :
(1). o-cresol (2) P-cresol
(3) 2,4-dihydroxytoluene (4) Benzoic acid
35.
28. Acylium ion is :
(1) R-CH2+ (2) R-C+= O
(1) (2)
(3) R-C≡O+ (4) Both “b” and “c”
29. Write increasing order of reactivity of
following compounds towards SE2 :
(3) (4)
(I)Ph-H, (II)Ph-CH3, (III)Ph-O-CH3, (IV)Ph-NO2
(1) I < II < III < IV (2) II < I < III < IV
36. + conc. H2SO4 P is :
(3) IV < I < II < III (4) IV < III < I < II
30. Predict the structures of the products in the
following reaction sequences :
37. Product is:

(1) (Ph)2CO (2)

31.(M) Toluene, when treated with Br2/Fe, gives

(3) (4)
p-bromotoluene as the major product because
the CH3 group :
 AROMATIC – 06 11.

12.
01.

13. + NO2BF4 → A ; A + Zn + HCl → ‘P’ is :

(1) Phthalic acid (2) Isophthalic acid

(1) (2) (3) (4)

(3) Terephthalic acid (4)

02. Arrange the following compound towards

reactivity for electrophilic substitution reaction :
14. ‘P’ is
(1) Benzene (2) C6D6
(3) PhCOCH3 (4) Toluene
(5) Ph-CH2CH3 (6) Cumene
(1) (2) (3) (4)

03. Attacking Reagent is :

15.
(1) Cl+ (2) Cl*
Correct is/are
(3) BOTH (4) NONE
04. Ph-H + NO2+BF4- / NO2+ClO4-→ ……..+…….: (1) (2)

𝐂.𝐇𝐍𝐎₃
05. Mechanism of C6H6 𝐂.𝐇₂𝐒𝐎₄
(3) (4)

𝑪.𝑯𝑵𝑶₃ 𝑪.𝑯𝑵𝑶₃ 𝑭𝒖𝒎𝒊𝒏𝒈 𝑯𝑵𝑶₃

06. C6H6𝑪.𝑯₂𝑺𝑶₄ (A) 𝑪.𝑯₂𝑺𝑶₄ (B)
𝑪.𝑯₂𝑺𝑶₄

Product is : 16. Cumene ? Phenol + Acetone .

(1) (2)

(3) (4)

07. C6H6 ? T.N.T.

08. T.N.T. ? T.N.B.

09.

10. C6H6 ? Aniline

 AROMATIC – 07 07.

01. (1)

(1) (2) (3) (4)NONE

(2)

02. Attacking reagent in above reaction :

(1) N2+ (2) NO+ (3)
(3) N2+ (4) N.O.T.
03. Ph—N2+Cl- heat (A) + Gas X
Heat (4)
NH4NO2 (B) + Gas X
Correct option is
(1) A = C6H6 , B = H2O , X = N2O 𝐊𝐂𝐍/𝐂𝐮
08. PhN2+Cl- A
𝚫
(2) A = C6H5Cl , B = H2O , X = N2O
𝐒𝐧/𝐇𝐂𝐥
(3) A = C6H5Cl , B = H2O , X = N2 A B
𝐒𝐭𝐞𝐚𝐦

(4) A = C6H6 , B = H2O2 , X = N2 product ‘B’ is:

[NOTE : In place of Zn-HCl , Fe/HCl; and
(1) Benzoic acid (2) Benzoyl chloride
TiCl3/Conc. HCl can be used.]
𝐍𝐚𝐍𝐎₂/𝐇𝐂𝐥 (3) Benzaldehyde (4) Benzamide
04. ANILINE (A) KI (B)
𝟐𝟕𝟑−𝟐𝟕𝟖 𝐊

(A) and (B) is : 09. CONVERSIONS :–

(1) benzene diazonium chloride , Iodo-benzene (i) Aniline ? Cyano Benzene

(2) benzene diazonium chloride , chloro -benzene (ii) Nitro Benzene ? Benzaldehyde
(3) nitro benzene , ido - benzene ?
(iii) Benzene Diazonium chloride
(4) chloro benzene , ido – benzene
(iv) Benzene ? Aniline

(v) Benzene Diazonium Chloride ? Phenol

05.
(vi) Benzene ? Flourobenzene

(1) C6H6 (2) C6H5-Cl

(3) (4)

10
06. PhN2+Cl- HBF₄ (A) Δ (B) ; B is
.
(1) C6H5-Cl

(2) C6H5-F

(3) C6H6
NOTE :- Copper Favours the Liberation of N2
(4) 1-fluoro, 4-chloro benzene
aromatic – 08 08. Which of the following process is known
as Gattermann- Koch aldehyde synthesis :

01.

(1)

(1) (2) (2)

(3) (4)
(3)

02. Which of the following shows dipole

moment ? (4)
(1) SO2Cl2 (2) Benzene 𝐂𝐎−𝐇𝐂𝐥 O₂ 𝐂𝐇₃𝐂𝐥
09. Benzene 𝐀𝐧.𝐀𝐥𝐂𝐥₃ (A) (B) 𝐀𝐧.𝐀𝐥𝐂𝐥₃ (C)
(3) Azulene (4) Both (1) and (3)
Then “C” is :
𝐎₂,𝐕₂𝐎₅
03. Benzene Product is :
𝟓𝟎𝟎 ͦ 𝐂

𝐍𝐚𝐎𝐇
04. Benzene conc. H₂SO₄ (A) NaOH (B) 𝐇+,𝐇𝐞𝐚𝐭 (C)
(1) (2)
Product ‘C’ is :

(1) (2) (3) (4) None (3) (4)

05. Attacking electrophile in Gatterman - Koch 10. Which of the following reagent is used
aldehyde synthesis is : in Etard reaction :
(1) CO+ (2) SO3 (1) HCN/HCl + An. HCl3/H2O (2) O2 / H+, Δ
(3) HCO+ (4) CO2 (3) CrO2Cl2/H2O (4) CO─HCl/An. AlCl3

06. Attacking reagent in, 11. Match column “ I ” with “ II “

“I“ “ II “
Benzene Conc. H₂SO₄
(I) Gattermann aldehyde (a) CrO2Cl2/H2O
(1) HSO3─
synthesis
(2) SO32─
(II) Gattermann KOH (b) CO-HCl/An.AlCl3
(3) SO2 aldehyde Synthesis
(4) SO3 (III) Etard reaction (c) HCN-HCl/An.Cl3
07. In Gattermann ─ Koch aldehyde (IV) Stephen reduction (d) Sn-HCl/Steam
Synthesis reagent is : Correct option is :
(1) CO + HCl /An. AlCl3 (1) (I)→(c) , (II) →(b) , (III) →(a) , (IV) →(d)
(2) HBr + CO2 / An. AlCl3 (2) (I)→(b) , (II) →(c) , (III) →(d) , (IV) →(a)
(3) CO + HBr / An. AlBr3 (3) (I)→(c) , (II) →(a) , (III) →(b) , (IV) →(d)
(4) CO2 + HCl / An. AlCl3 (4) (I)→(b) , (II) →(c) , (III) →(a) , (IV) →(d)
 (𝒊)𝑪𝑯₃𝑪𝒍
12. In the following sequence of reaction
𝑨𝒍𝑪𝒍₃
𝐇𝟐 /𝐏𝐝 (𝒊𝒊)𝑪𝒓𝑶₂𝑪𝒍₂
Toluene KMnO₄ (A) SOCl₂ (B) (C) 20. Benzene (A) Air (B)
𝐁𝐚𝐒𝐎₄ 𝑯₂𝑶

the product ‛C ’ is : (B) H₂—Ni (C) Product “C” is :

(1) C6H5COOH (2) C6H5CH3
(3) C6H5CH2OH (4) C6H5CHO
13. In the reaction (1) (2) (3) (4)
𝑵𝒂𝑵𝑶𝟐 −𝑯𝑪𝒍 21. Product is Fittig reaction :
p-methyl-aniline (D)
𝟎−𝟓 ͦ 𝑪
𝑪𝒖𝑪𝑵/𝑲𝑪𝑵
(1) Benzene (2) Toluene
(D) (E) + (N2)
𝜟 (3) Biphenyl (4) mesitylene
the product “ E “ is : 𝑵𝒂
22. Chlorobenzene Product is:
𝑫𝒓𝒚 𝒆𝒕𝒉𝒆𝒓
(1) p-methyl-benzoic acid
(2) Toluene
23.
(3) p-methyl-benzonitrile
(4) cyano benzene
Which product is used in Stephen reaction :
14. Acetylene does not react with :
(1) 1 (2) 2
(1) Ammonical AgNO3 (2) Na
(3) 3 (4) NONE
(3) HCl (4) NaOH
𝑵−𝒃𝒓𝒐𝒎𝒐 𝒔𝒖𝒄𝒄𝒊𝒏𝒊𝒎𝒊𝒅𝒆 𝒂𝒒. 24. C—C Bond order in Benzene ?
15. Toluene A Product is
(𝑵.𝑩.𝑺) 𝑲𝑶𝑯 (1) 1.5 (2) 1.2
(3) 2.5 (4) 3
25. Phenol PCl₅ Product is ?
(1) (2) (3) (4)
26. Reagent used in Reimer Tiemann Reaction is :
16. Benzene Conc. H₂SO₄ Product (A) ,
(1) CrO2Cl2 / H2O (2) SnCl2 / HCl
Attacking reagent is R , and product A is :
(3) (i) CH3Cl/KOH,(ii) H+ (4) (i) CHCl₃/KOH,(ii) H+
(1) SO3+ , PhSO3H
27. Attacking reagent in Reimer Tiemann
(2) SO3 , PhSO3H
reaction is :
(3) SO3+ , PhSO2H
(1) CCl3+ (2) CHCl2+
(4) SO3 , PhSO2H
(3)+CHO (4) CCl2
17. O.N. of metal “M” present in intermediate of
28. Correct acidic order of PhOH , H2O , ROH is :
Etard reaction is :
(1) PhOH > H2O > ROH
(1) +4 (2) +5
(2) PhOH < H2O < ROH
(3) +6 (4) +7
(3) H2O > PhOH > ROH
18. Intermediate in etard reaction is :
(4) ROH > PhOH > H2O
(1) Ph-CH(OCrCl2OH)2
(2) Ph-CH(OCOCH3)2
(3) Ph-CH(CrCl2OH)2 𝐂𝐇𝐂𝐥𝟑 /𝐍𝐚𝐎𝐇
29. Product is :
𝐇⁺
(4) Ph-CH(COCH3)2
19. Product obtain in Etard Reaction : (1) Benzaldehyde
(1) Aldehyde (2) Ketone (2) Salicylaldehyde
(3) Ether (4) Imine (3) Acetaldehyde
(4) Formaldehyde
 aromatic – 09 09. Reagent used in perkin reaction is :

01. In which of the following intra-molecular (1) CH3COONa , CH3CH2OCH3

hydrogen bonding is present.. (2) CH3COONa , ((CH3)2CHCO)2O

(3) (CH3)2CHCOONa , ((CH3)2CHCO)2O

(1) (2) (4) CH3CH2COONa , (CH3CH2CO)2O

10. Product and reactant in Perkin reaction is :

(3) (4) (1) Benzaldehyde , Cinnamic acid

(2) Cinnamic acid , Salicylaldehyde
(3) Cinnamic acid , Benzaldehyde
(𝐢)𝐇𝐂𝐍/𝐇𝐂𝐥 (4) Benzaldehyde , Salicylaldehyde
02. 𝐀𝐧.𝐀𝐥𝐂𝐥₃(𝐢𝐢)𝐇₂𝐎
……….?
11. Cinnamic acid is :
(1) Ph-CH=CH-COOH (2)
(𝐢)𝐂𝐇𝐂𝐥₃/𝐊𝐎𝐇
03. ……….?
𝐇⁺

𝑪𝑶−𝑯𝑪𝒍
04.
𝑨𝒏.𝑨𝒍𝑪𝒍₃
………..? (3) (4)

𝐂𝐎−𝐇𝐂𝐥 𝐂𝐇₃𝐂𝐎𝐎𝐍𝐚
12. Benzene 𝐀𝐧.𝐀𝐥𝐂𝐥₃ (A) (𝐂𝐇 (B) ; B is ?
05. Toluene CrO₂Cl₂ (I) H₂O (J) ; (I) & (J) are ? 𝟑 𝐂𝐎)₂𝐎

06. Match the column [I] with column [II] (1) Cinnamic acid (2) Salicylic acid
COLUMN-[I] COLUMN-[I] (3) Picric acid (4) Benzoic acid
𝐂𝐎−𝐇𝐂𝐥
(P) Benzene 𝐀𝐧.𝐀𝐥𝐂𝐥₃
(a) Formyl cation
13.
(Q) Benzene C.H₂SO₄ (b) Methyl cation
𝐍𝐚𝐍𝐎₂−𝐇𝐂𝐥
(R) Aniline (c) NO+
𝟎−𝟓 ͦ𝐂
𝐂𝐇₃𝐂𝐥 (1) (2)
(S) Toluene (d) SO3
𝐀𝐧.𝐀𝐥𝐂𝐥₃

(1) P→b, Q→d, R→c, S→a

(2) P→a, Q→c, R→d, S→b
(3) (4)
(3) P→b, Q→d, R→c, S→a
(4) P→a, Q→d, R→c, S→b
14. Which of the following will produce
07. Toluene ? p–Methylbenzaldehyde.
violet colour with FeCl3 :
(1) HCN – HCl/An. AlCl3
(2) CrO2Cl2/H3O+
(3) CO-HCl/An. AlCl3 (1) (2) (3) (4)
(4) Cl2/hv, Aq.KOH , Cu, Δ
08. Which of the following is σ ,β-unsatured 𝐂𝐎₂−𝐍𝐚𝐎𝐇
15. Ph—OH 𝐇⁺
Product is :
acid is :
(1) Salicylic acid
(2) Cinamic acid
(1) (2)
(3) Salicylaldehyde
(4) Picric acid
(3) (4)
16. (A) + Conc. HNO3 → Picric acid : 23. Toluene Hot KMnO₄ (A) SOCl₂ (B)
Then correct option is:
(1) (2) (1) (A) is more acidic then Phenol
(2) (B) on reaction with H2-Ni gives toluene
H₂−Pd
(3) (B) BaSO₄ Benzaldehyde

(4) Both (1) & (3)

(3) (4)
𝐂𝐎₂−𝐍𝐚𝐎𝐇
24. Ph—OH (A) PhOH Product is :
𝐇₃𝐎⁺

Conc. H₂SO₄ 𝐅𝐮𝐦𝐢𝐧𝐠 𝐍𝐢𝐭𝐫𝐚𝐭𝐢𝐧𝐠 (1) (2)

17. (A) (B)
𝐌𝐢𝐱𝐭𝐮𝐫𝐞

(3) (4)
(1) (2)

25. Arrange the following compounds in order

of decreasing acidity :

(3) (4)

18.
(1) B > D > A > C
(2) A > B > C > D
(3) C > A > B > D
19.
(4) D > C > A > B

𝐂𝐥₂/𝐡𝐯 26. The order of stability of the following

20. Al4C3 Water (A) 𝐄𝐱𝐜𝐞𝐬𝐬
(B)
carbocations :
𝐍𝐚𝐎𝐇
Ph—OH + (B) 𝐇⁺
(C) (A) CH2=CH-CH2+, (B) CH3-CH2+ , (C) Ph-CH2+
𝒁𝒏−𝑯𝑪𝒍 𝑵𝒂𝑵𝑶₂−𝑯𝑪𝒍 𝑯₃𝑷𝑶₂−𝑪𝒖 (1) C > B > C (2) B > C > A
21. Ph-NO2 B C D
𝑶𝒓 𝑻𝒊𝑪𝒍₃−𝑯𝑪𝒍 𝟐𝟕𝟑−𝟐𝟕𝟖 ͦ𝑲 𝜟
(3) A > B > C (4) C > A > B
22. Compound (A) , C8H9Br gives a white ppt
27. A solution of 1-chloro-1-phenylethane in
When warmed with alcoholic AgNO3. Oxidation
Toluene racemises slowly in the presence of a
of (A) gives an acid (B) C8H6O4. (B) easily
small amount of SbCl5 due to the formation of :
forms anhydride on heating. Identity the
(1) Carbanian
compound (A) .
(2) Carbene
(3) Carbocation
(1) (2)
(4) free radical
28.(M) The carbonyl functional group (-COOH) is
present in :
(3) (4)
(1) Picric acid (2) Barbituric acid
(3) Ascorbic acid (4) Aspirin
 AROMATIC – 10 05. In the reaction shown below, the major
product (s) formed is/are :
01. Which of the following molecules, in
pure form, is unstable at room temperature :

(1) (2) (3) (4)

02. The major product “U” in the following
reaction is : (1)
𝑪𝑯₂=𝑪𝑯−𝑪𝑯₃ 𝑹𝒆𝒅𝒊𝒄𝒂𝒍
Ph
𝑯⁺/𝑯𝒆𝒂𝒕
“T” “U”
𝒊𝒏𝒊𝒕𝒊𝒂𝒕𝒐𝒓,𝑶₂

(1) (2) (2)

(3) (4) (3)

03. In the following reactions,

𝐏𝐝−𝐁𝐚𝐒𝐎₄ (𝐢) 𝐁₂𝐇₆
C8H6 C8H8 (𝐢𝐢)𝐇₂𝐎₂−𝐍𝐚𝐎𝐇
“X”
𝐇₂ (4)
Compound “X” is :
𝐇𝐠𝐒𝐎₄−𝐇₂𝐒𝐎₄
06. C8H6 𝐇₂𝐎
Product is :

(1) (2)

(1) (2)
(3) (4)
04.(M) Among the following , benzaldehyde (3) (4)
will be formed in is/are :
𝐂𝐎−𝐇𝐂𝐥 07. Sodium phenoxide when heated with CO2
(1)
𝐀𝐧.𝐀𝐥𝐂𝐥₃
under pressure at 125ᵒC yields a product which on
acetylation produces C :
𝐇₂𝐎
(2) 𝟏𝟐𝟓 ͦ 𝑪 𝑯⁺
𝟏𝟎𝟎 ͦ𝐂 Ph-ONa + CO2 (B) (C)
𝟓 𝑨𝒕𝒎 𝑨𝒄₂𝑶

The major product “C” would be :

𝐇₂
(3)
𝐏𝐝−𝐁𝐚𝐒𝐎₄
(1) (2)
𝐃𝐈𝐁𝐀𝐋−𝐇
(4)
𝐓𝐨𝐥𝐮𝐞𝐧𝐞,−𝟕𝟖 ͦ𝐂 𝐇₂𝐎

(3) (4)
08. Benzene diazonium chloride on reaction with (3) (4)
aniline in the presence of dilute hydrochloric acid
gives:
(1)

(2)
11. The major product of the following reaction is:

(3)

(4)

(1)
09. Aniline dissolved in dil. HCl is reacted with
sodium nitrite at 0oC. This solution was added
dropwise to a solution containing equimolar
mixture of aniline and phenol in dil.HCl. The
structure of the major product is: (2)

(1)

(2)
(3)
(3)

(4)
(4)
10. Coupling of benzene diazonium chloride with
1-napthol in alkaline medium will give:
𝐍𝐚 𝐎𝟑
12. Toluene Product is:
𝐋𝐢𝐪.𝐍𝐇𝟑 𝐌𝐞𝟐 𝐒

(1) (2)
(1) (2)

(3) (4)
 Ans key Aromatic - 09
Aromatic - 07 Q.N Ans Q.N Ans
Q.N Ans 01 2 02
01 03
02 02
03 03
04 01 03 04
05 01
06 02
07 04
08 03
09 (i) NaNO2-HCl/0-5ͦC , CuCN|KCN 05 06 4

(ii) TiCl3-HCl, NaNO2-HCl/0-5ͦC , H3PO2 ,

COHCl/AlCl3
(iii) Cu2Br2|HBr
(iv) Conc.HNO3/Conc.H2SO4 , Sn-HCl | NaOH 07 3 08 3
(v) steam 09 4 10 3
(vi) Conc.HNO3/Conc.H2SO4 , Sn-HCl, 11 1 12 1
NaNO3-HBF4 , Δ
13 2 14 1
15 1 16 1
17 4 18
Aromatic - 08
Q.N Ans Q.N Ans Q.N Ans
01 2 11 4 21 3
02 3 12 4 22 Biphenyl
03 13 3 23 2

19 20 A= CH4
04 3 14 4 24 1 B=CCl4
05 3 15 3 25 Ph3PO4
06 4 16 2 26 4
07 1 17 1 27 4
08 4 18 1 28 1
09 2 19 1 29 2
10 3 20 4
21 B= PhNH2 , 22 4
C = PhN2+Cl- ,
D = C6H6
23 4 24 2
25 3 26 4
27 3 28 4

Aromatic - 10
Q.N Ans Q.N Ans
01 2, 3 02 2
03 3 04 1, 2, 3, 4
05 3 06 2
07 1 08 3
09 1 10 3
11 1 12 2