LOCUSACDEMY chemistry for iit jee & neet

AROMATIC - 01
01. Among the following , ‘X’ compounds are 05. Formula for Lindane is :
aromatic and ‘Y’ compounds are Anti-aromatic (1) C6Cl6 (2) C6H6Cl6
and ‘Z’ are Non - aromatic. (3) C6H5Cl (4) C6H4Cl2
Then calculate x + y – 3z :
06.

; ; ;
(1) (2)

; ; ; (3) Toluene (4) (1) & (3) Both

07. Which of the following reaction is known
as Friedel-Craft Alkylation reaction :
; ; ;
(1) CH3COOH + H2 - Ni → CH3CH2OH
(2) Ph-H + CH3CH2CH2Cl + Anhy. AlCl3 → Ph-CH(CH3)2
(3) CH3-C≡CH + NaNH2 → CH3C≡C-Na+ + NH3
; ; ;
(4)

; 08. Anhydrous AlCl3 is :

(1) 0 (2) 1 (1) Lewis Acid (2) Lone-pair acceptor
(3) 2 (4) 3 (3) Electrophilic (4) All of above
02. Anti aromatic compound(s) is/are :
09.

(1) (2)
Then ‘R’ may be :
(1) CH3CH2CH2- (2) CH3CH2-
(3) (4) None (3) CH3CH2CH2CH2- (4)
03. Correct order of stability of the following :
(1) Aromatic < Anti-Aromatic < Non-Aromatic 10.
(2) Aromatic > Anti-Aromatic > Non-Aromatic
(3) Aromatic > Non-Aromatic > Anti-Aromatic Wheland intermediate of this reaction is :
(4) Aromatic < Non-Aromatic > Anti-Aromatic

(1) (2)
04.

(1) Lindane (2) B . H. C. (3) (4)

(3) Insecticide (4) A.O.T.
11. Total number of 𝝈 bond present in the above 17.
wheland intermediate :
(1) 18 (2) 17 (1) (2)
(3) 19 (4) 20
(3) (4) N.O.T.
12.

18.
(1) (2) Glyoxal
(1) Acetone (2) Acetophenone

(3) (4) (3) Benzoic acid (4) Phthallic acid

19. Phenol + Zn-Dust → (A)
(A) + CH3CH2Cl + Anhydrous AlCl3 → (B)
𝑯𝒐𝒕
13. (B) 𝑲𝑴𝒏𝑶₄ (C) , then correct option is/are :

(1) A = Benzene (2) B = Ph-CH2-CH3

Total number of ‘sp3’ hybridized carbon atom (3) C = Benzoic acid (4) N.O.T.
in Wheland intermediate : 𝑯𝒐𝒕 𝑻𝒉𝒊𝒐𝒏𝒚𝒍
20. Cumene 𝑲𝑴𝒏𝑶₄ (A) (B) + Gas (X + Y)
𝑪𝒉𝒍𝒐𝒓𝒊𝒅𝒆
(1) 0 (2) 1
(1) (B) is Benzoic acid
(3) 2 (4) 3
(2) (B) is Benzoyl chloride
14. In Friedel craft alkylation rearrangement
(3) (A) is Benzoic acid
is possible due to :
(4) 2 & 3 both
(1) Attacking reagent is carbocation
21.
(2) Attacking reagent is carbanion
(3) Attacking reagent is nucleophile
(1)
(4) None
15.
(2)

(1) (2)
(3)

(4)
(3) (4)

22.
16.
𝑯𝒐𝒕
(A) 𝑲𝑴𝒏𝑶₄ Product is :

(1) (2)
(1) (2)

(3) (4) None

(3) (4) None
 [AROMATIC – 02] 08. + Conc.H₂SO₄ Product is :

𝑯𝑭 (1) (2)
01. + Product is :
𝑩𝑭₃

(3) (4) None

(1) (2)

𝑯𝑭
09. + Product is :
(3) (4) 𝑩𝑭₃

H₃PO₄ (1) (2)

02. Benzene + CH3COOH (A)
(A) + LiAlH4→(B) + Conc. H2SO4 →(C)

(3) (4) None

(1) (A) = (2) (B) =
10. Ph-H + CH3Cl/anhy. AlCl3→ (A)
(A) + HOT KMnO4 → (B)
(B) + SOCl2 → (C) + Gas X + Gas Y
(3) (C) = (4) (C) = Styrene
If gas Y is a strong acid, then mark the correct options :
(1) Gas Xis SO3 (2)Gas XisHCl
(3) Gas X has suffocating odour (4)Gas X is H2S
𝑨𝒏𝒉𝒚
03. + Product (P)
𝑨𝒍𝑪𝒍₃

11. ? ‘?’ is :
(P) H₂-Ni Product is :

(1) (2) (1) Zn-Hg/ conc. HCl. (2)H2-Ni.

(3)LiAlH4 (4)N2H4 – BASE / Heat

(3) (4)
12.
(I) (II) (III) (IV) (V)
How many of the following will produce Benzoic acid on
reaction with hot alkaline KMnO4?
𝒁𝒏(𝑯𝒈)
04. (1) I,II,III (2)I,II,IV,V
𝑪𝒐𝒏𝒄.𝑯𝑪𝒍
(3) I,II,III,IV,V (4) I,II,IV
𝑯𝒐𝒕
13. Product is :
𝑲𝑴𝒏𝑶₄

𝒁𝒏(𝑯𝒈)
05.
𝑪𝒐𝒏𝒄.𝑯𝑪𝒍

(1) (2)

𝒁𝒏(𝑯𝒈)
06.
𝑪𝒐𝒏𝒄.𝑯𝑪𝒍
(3) (4)
07. Acetophenone + Clemmensen Reduction →
 [AROMATIC – 03]
𝑹.𝑯.𝑻. 𝑪𝑯₃𝑶𝑯 𝑯𝒐𝒕
01. Acetylene (A) (B) (C)
𝑭𝒆 𝑯⁺ 𝑲𝑴𝒏𝑶₄
05. (I) , (II) , (III) ,
𝒁𝒏−𝑯𝒈 𝑺𝒖𝒄𝒄𝒊𝒏𝒊𝒄 𝒁𝒏−𝑯𝒈
(C) (D) 𝑨𝒏𝒉𝒚𝒅𝒓𝒊𝒅𝒆 𝑨𝒍𝑪𝒍₃ (E)𝑪𝒐𝒏𝒄.𝑯𝑪𝒍 (F)
𝑪𝒐𝒏𝒄.𝑯𝑪𝒍

𝑺𝑶𝑪𝒍₂ 𝒁𝒏−𝑯𝒈 𝑷𝒅−𝑪

(F) 𝑨𝒍𝑪𝒍₃
(G) 𝑪𝒐𝒏𝒄.𝑯𝑪𝒍 (H) 𝑶𝒓 𝑺𝒆 (I)
(IV) , (V) , (VI) ,
Then correct option is /are :

(VII) , (VIII) , (IX)

(1) E= (2) G=
How many of the above are ortho-para directing
towards electrophilic substitution reaction :
(3) H= (4) I= (1) 5 (2) 6
(3) 4 (4) 7

02.
06. Cu,Δ (A) 𝒁𝒏−𝑯𝒈 (B) 𝑯𝒐𝒕 (C)
𝑪𝒐𝒏𝒄.𝑯𝑪𝒍 𝑲𝑴𝒏𝑶₄
‘A’ and mechanism of reaction :
𝑵𝒂𝑶𝑯 𝑶₃
(C) 𝑪𝒂𝑶
(D) 𝑯₂𝑶 (E), then ‘E’ is :

(1) Oxalic acid (2) Malomic acid

(1) , SE 2 (2) , SE1
(3) Succinic acid (4) Glutanic acid

(3) , E1 (4) , SE2 ?

07. ; ? is :

03. + CH3Cl/Anhydrous AlCl3 → Product is :

(1) Succinic anhydride/ An.AlCl3 , anhydrous AlCl3 .
(2) Succinic anhydride/ An.AlCl3 , Zn-Hg conc. HCl ,
An.AlCl3
(1) (2)
(3) Succinic Anhydride/ An. AlCl3, SOCl2, An. AlCl3 .
(4) Succinic Anhydride/ An. AlCl3, Zn-Hg/conc.HCl , SOCl2
08. Which of the following will produce naphthalene :
(3) (4) None 𝑅.𝐻.𝑇. 𝑆𝑢𝑐𝑐𝑖𝑛𝑖𝑐
(1) CH≡CH 𝐹𝑒
(A) 𝐴𝑛ℎ𝑦𝑑𝑟𝑖𝑑𝑒 (B) Pd-C

𝑅.𝐻.𝑇. 𝑍𝑛−𝐻𝑔 𝐴𝑛𝐴𝑙𝐶𝑙₃

(2) CH≡CH (A) An. AlCl₃ (B) 𝐶𝑜𝑛𝑐.𝐻𝐶𝑙 (C)
𝐹𝑒 𝑃𝑑−𝐶
04. + Br2/Anhydrous AlCl3 → Product is :
(i) An.AlCl₃ 𝐶𝑙𝑒𝑚𝑚𝑒𝑛𝑠𝑒𝑛
(3) Acetylene (ii) R.T.H, Fe (A) (C)
𝑆𝑂𝐶𝑙₂
(𝑖)𝐴𝑛.𝐴𝑙𝐶𝑙₃
(C) 𝐻𝑔
(1) (2) (𝑖𝑖)𝑍𝑛−
𝐶𝑜𝑛𝑐
.𝐻𝐶𝑙,(𝑖𝑖𝑖)𝑆𝑒
(i) An.AlCl₃ (𝑖)𝑆𝑂𝐶𝑙₂
(4) Acetylene (ii) R.T.H, Fe (A)(𝑖𝑖)𝑃𝑑−𝐶

(3) (4) (2) & (3)

 [AROMATIC – 04] 08. For which of the following molecule significant
µ ≠0?

01. compound is :
(1) Aromatic (2) Non- Aromatic (i) (ii) (iii) (iv)

(3) Anti- Cromatic (4) Inorganic

(1) Only (i) (2) (i) & (ii)

02. Heat (A) + (B) (3) Only (iii) (4) (iii) & (iv)

𝑯𝒐𝒕
(A) + NaOH → (C) ;(B) + H2-Ni → (D); (D) 𝑲𝑴𝒏𝑶₄ (E)
09. is ?
(1) Ortho-Para directing and deactivating.
(1) A= (2) B= (2) Ortho-Para directing and activating.
(3) Meta directing anddeactivating.
(3) C= (4) D= (4) Meta directing andactivating.
10. AnAromatic molecule will ?
(5) E= (1) Have 4nπ- electrons (2) Be planar.
(3) Have (4n+2)π electrons (4) Be cyclic.
03. In the reaction, CH3COOH LiAlH₄ ;PCl₅ ;Alc. KOH (C)
11. Which of the following molecules, in pure form,
Product ‘C’ is : is/are instable at room temperature ?
(1) Acetaldehyde (2) Acetylene
(3) Ethylene (4) Acetyl chloride (1) (2) (3) (4)
04. The compound that undergoes decarboxylation
most readily under mild condition is ? 𝑶₂/𝜟
12. + ClCH2CH2CH3 AlCl₃ (P) 𝑯₃𝑶⁺
(Q)+Phenol

‘P’ & ‘Q’ are respectively :

(1) (2)

(1) + CH3CH2CHO (2) + CH3COCH3

(3) (4)
(3) + CH3CH2CHO (4) + CH3COCH3
05. In the following sequence of reactions ;
𝑯𝒐𝒕 SOCl₂
𝑯₂−𝑷𝒅
Toluene 𝑲𝑴𝒏𝑶₄ (A) (B) 𝑩𝒂𝑺𝑶₄ (C)

The product ‘C’ is : 13.

Product on monobromination of this compound :

(1) C6H5COOH (2)
(3)C6H5CH2OH (4) C6H5CH3

(1) (2)
06. ? STYRNE:

(3) (4)
07. ?