Development of Stretch Flangeable Ferrite-Bainite Grades Through Thin Slab Casting and Rolling

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Materials Science and Technology

ISSN: 0267-0836 (Print) 1743-2847 (Online) Journal homepage: http://www.tandfonline.com/loi/ymst20

Development of stretch flangeable ferrite–bainite


grades through thin slab casting and rolling

M. Mukherjee, A.R. Chintha, S. Kundu, S. Misra, J. Singh, C. Bhanu & T.


Venugopalan

To cite this article: M. Mukherjee, A.R. Chintha, S. Kundu, S. Misra, J. Singh, C. Bhanu & T.
Venugopalan (2016): Development of stretch flangeable ferrite–bainite grades through thin
slab casting and rolling, Materials Science and Technology

To link to this article: http://dx.doi.org/10.1179/1743284715Y.0000000068

Published online: 19 Feb 2016.

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Download by: [University of Saskatchewan Library] Date: 30 March 2016, At: 00:46
RESEARCH PAPER
Development of stretch flangeable ferrite –
bainite grades through thin slab casting and
rolling
M. Mukherjee*1, A.R. Chintha1, S. Kundu1, S. Misra2, J. Singh3, C. Bhanu3 and
T. Venugopalan4
The focus towards the design of light environment friendly fuel efficient vehicles has led to an
increase in the demand for high strength steels. As it is true for any developing country, the extra
challenge for Indian steel industries is to produce such high strength steels at minimum cost. The
aim of the present work was to develop two high strength steel grades with minimum tensile
Downloaded by [University of Saskatchewan Library] at 00:46 30 March 2016

strengths of 540 and 590 MPa, in combination with good ductility and stretch flangeability,
through the thin slab casting and rolling route. The present paper describes the alloy and process
design methodology used for achieving the target properties. Several mill trials were taken to test
the proposed design, wherein the target microstructure and mechanical properties were
successfully achieved.
Keywords: Stretch flangeable, Ferrite, Bainite, Hole expansion ratio

Introduction and costly alloying elements like Cr/Ni/Mo/B and/or high


amounts of microalloying elements like Nb/Ti3,4 to achieve
During the past few decades, the automobile industry has the target properties. In order to minimise the cost, not only
shifted its focus towards the design of light weight should the alloy addition be optimised, but the processing
environment friendly, fuel efficient vehicles. This has cost also needs to be reduced. Of late, thin slab casting and
necessitated the replacement of conventional low strength rolling (TSCR) technology has become a major process for
steels with higher strength steels so that thinner gauges can hot strip production in the world due to its minimal energy
be used and reduction in the weight of the auto components consumption, higher productivity and reduced cost of
is possible without compromising on safety and functional production.5 However, there are certain unique features of
requirements. Among the various autocomponents, the this production route due to which the production of high
weight reduction achievable by substituting conventional strength grades of consistent quality through this route is
mild steel with high strength steels is found to be the largest not very straightforward. Some of these features are listed
for autowheels1 wherein the energy savings is estimated to below:
(i) austenitisation takes place through the dRc poly-
parts.2 Apart from this, there is also an increasing demand morphic transformation; hence, the austenitisation
for high strength steels for automotive structural parts temperature is quite high unlike in the conventional
like suspension and chassis components. The typical hot strip rolling process wherein austenite forms at
tensile strength requirement for such applications is the reheating temperature through phase trans-
540–590 MPa. Moreover, considering that these parts are formation; as a result, the primary austenite grains
quite complicated in shape and are manufactured mainly in this route are quite coarse (500–2000 mm)6,7
by press forming, apart from the high strength require- (ii) cast slabs are soaked in a tunnel furnace at 1100–
ments, it is also essential that such steels have good 1150uC for around 20–30 min primarily for tem-
formability and especially stretch flangeability [which is perature equalisation,8 unlike in conventional
measured as the hole expansion ratio (HER)]. mills where the slabs are reheated to temperatures
In general, high strength formable grades, such as those w1200uC for 2–3 h; therefore, the TSCR process
described above, are produced through the conventional requires judicious selection of microalloying el-
continuous casting hot strip rolling route. These alloys rely ements to ensure their complete dissolution during
on addition of very high amounts of Mn (1.7–2.0 wt-%) temperature equalisation, so that they can be
effectively utilised during the subsequent processing
steps
1
2
Research and Development, TATA Steel, Jamshedpur 831001, India (iii) there is no rough rolling stage as in the conven-
Product Technology – Flat Products, TATA Steel, Jamshedpur 831001,
India tional mill, and hence, the as cast dendritic
3
LD # 3 & TSCR, Tata Steel, Jamshedpur 831001, India microstructure has to be rolled and transformed
4
MD’s Office, Tata Steel, Jamshedpur 831001, India into a homogeneous microstructure in the
*Corresponding author, email: monideepa@tatasteel.com finishing train.8

© 2016 Institute of Materials, Minerals and Mining


Received 24 February 2015; accepted 21 April 2015
DOI 10.1179/1743284715Y.0000000068 Materials Science and Technology 2016 1
Mukherjee et al. Stretch flangeable ferrite – bainite grades

Considering the factors mentioned above, it is necessary the presence of adequate amount of nitrogen (w0.008 wt-
that chemistry and processing parameters specifically %), enhanced precipitation of V(CN) takes place, which not
suited to TSCR conditions be developed, so that prop- only contributes to precipitation hardening but also retards
erties similar to those obtained by traditional routes can recovery and softening of the lower transformation pro-
be achieved. ducts like bainite during prolonged holding at relatively
The aim of the present work was therefore to design the higher temperatures after coiling.11 In view of the above,
chemistry and processing parameters required for produ- two microalloying strategies were adopted, one with only
cing two high strength steel grades, one with a minimum Nb for steel 1, and the other with Nb þ V for steel 2
tensile strength of 540 MPa for wheel rim applications (to account for its higher strength requirement). In order to
(steel 1) and another with a minimum tensile strength determine the maximum permissible amount of Nb which
of 590 MPa for wheel rim as well as structural applications would completely dissolve in austenite during the tem-
(steel 2), commercially through the TSCR mill at perature equalisation process, the dissolution temperatures
Tata Steel, Jamshedpur works. Additionally for both of carbonitrides of Nb and Nb þ V for various Nb and
steels, a minimum HER of 70% was aimed for. N contents were calculated using Thermo-Calc software
using the TCFE7 database.13 The base composition of the
steels used for the calculations was 0.06 wt-%C, 1.3 wt-
Alloy design: metallurgical aspects %Mn, 0.25 wt-%Si, 0.005 wt-%S, 0.012 wt-%P, 0.03 and
At the outset, the various possible strengthening mech- 0.05 wt-%V (for the Nb þ V steels). Considering that AlN
anisms were critically examined so that they could be has a close packed hexagonal structure and its nucleation
effectively utilised to identify the appropriate chemistry kinetics in austenite is very slow,14,15 it was not included in
Downloaded by [University of Saskatchewan Library] at 00:46 30 March 2016

and processing parameters required for achieving the the calculations. Figure 1 shows the dissolution tempera-
target properties. The same are discussed below. tures thus calculated, with the average tunnel furnace tem-
perature of 1125uC indicated as a solid line. From the figure,
Solid solution strengthening it is evident that when N content is 0.0085 wt-% or more, the
The most effective solid solution strengthening elements Nb content has to be restricted to 0.025 wt-% to ensure
are Mn and Si. However, Mn levels beyond 1.5% enhance complete dissolution under tunnel furnace conditions. Even
centreline segregation during continuous casting and also when the N content is as low as 0.005 wt-%, Nb content
cause microstructural heterogeneities.9 On the other beyond 0.03 wt-% cannot be used. Since for Nb þ V steels,
hand, Si levels beyond 0.5 wt-% lead to formation of N has to be w0.008 wt-% to ensure enhanced precipitation
surface scales due to oxides of silicon.10 Hence, the Mn of V(CN), the Nb content of both steels was restricted to
level of the steel was fixed at 1.0–1.5 wt-%, whereas v0.025 wt-%.
the Si level was fixed at 0.1–0.35 wt% for the current
development. The carbon level was restricted to Grain refinement
v0.07 wt-%, in order to ensure that the steel composition One of the most effective strengthening mechanisms is
was outside the peritectic range so as to guarantee grain refinement of ferrite.16 Grain refinement is gener-
adequate castability of the steel in the thin slab caster.11 ally brought about using the controlled rolling technol-
Lower carbon content also results in good weldability, ogy, which is possible with proper use of microalloying
which is necessary for automotive grades.11 elements. The minimum ferrite grain size achievable by
this method is 3–5 mm.17
The contribution of each of the mechanisms mentioned
Precipitation strengthening
above, to the yield strength of ferrite, was calculated using
Precipitation strengthening is brought about by the for- standard empirical equations applicable to microalloyed
mation of fine precipitates of microalloyed carbides, steels,18 and the same is illustrated in Fig. 2. The figure also
nitrides or carbonitrides. In order to form such fine pre- shows the maximum attainable yield strength of ferrite
cipitates, it is necessary that the microalloying elements calculated as the sum of the contributions from all the
remain in solid solution till the time rolling commences.
However, since the TSCR process involves very short dur-
ation soaking at relatively low temperatures before rolling,
the choice of the microalloying elements must be judiciously
made so as to ensure complete dissolution during tem-
perature equalisation. The most commonly used micro-
alloying elements are Ti, Nb and V. Among these, Ti is
generally avoided in TSCR grades because the dissolution
temperature of TiN precipitates (if formed during the prior
processing steps) is very high, and hence, these precipitates
are likely to remain undissolved even after temperature
equalisation. In fact, the tunnel furnace conditions may
only lead to coarsening of the TiN precipitates, rendering
them ineffective for precipitation strengthening.8 On the
other hand, the dissolution temperature of niobium is much
lower than titanium. Moreover, apart from precipitation
hardening, Nb retards recrystallisation of austenite and
lowers the austenite–ferrite transformation temperature, 1 Dissolution temperature of Nb(CN) or (Nb,V)(CN) in aus-
both factors leading to enhanced grain refinement of ferrite tenite for various Nb and N contents calculated using
in Nb microalloyed steels.8,12 The dissolution temperature Thermocalc;11 solid line represents average tunnel
of vanadium is even lower than both Nb and Ti. Further, in furnace temperature of 11258C

2 Materials Science and Technology 2016


Mukherjee et al. Stretch flangeable ferrite – bainite grades

strengthening elements, namely, C, Mn and Si, were


considered. The effect of niobium was not considered
because it influences the CCT diagram in contrary ways
depending on its state of precipitation. When in solid
solution, niobium retards the austenite–ferrite trans-
formation kinetics, whereas when NbC exists as
precipitates, they act as nucleation sites for ferrite
resulting in an enhanced transformation kinetics.8
Vanadium, on the other hand, does not significantly
affect the ferrite transformation kinetics, but it retards
pearlite formation to some extent.23 However, vanadium
was also not included in the calculation, as it was not
added for steel 1. The CCT diagram shown in Fig. 3 was
constructed using steel 1 chemistry, but since the
compositions of both the steels with respect to the solid
2 Strengthening contribution of various mechanisms
solution strengthening elements were nearly equal, the
towards yield strength (YS) of ferrite in steels 1 and 2;
CCT diagram for Steel 2 was more or less identical to
dotted lines in figure represent target yield strengths of
the one shown in Fig. 3.
steels, i.e. 500 MPa for steel 1 and 550 MPa for steel 2
On the basis of the generated CCT diagram a single
stage RoT cooling strategy with rapid cooling (between
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30 and 100uC s21) from finish rolling temperature to an


strengthening mechanisms. Considering that the target intermediate temperature in the bainitic bay followed by
yield strength for steel 1 was *500 MPa and that for steel 2 air cooling to the coiling temperature was proposed so
was *550 MPa (as indicated by dotted lines in the figure), that the desired microstructure consisting of ferrite þ -
it is evident that the above mentioned strengthening bainite could be produced.
mechanisms are not sufficient to achieve the targeted yield
strength, hence indicating that a single phase precipitation
strengthened ferritic microstructure would not be ade- Mill trials
quate. Therefore, the only way forward was to tailor the Mill trials were carried out using the proposed chemistries
microstructure so as to include lower temperature trans- as given in Table 1. The finish rolling temperature TFRT was
formation products like bainite (or acicular ferrite) and/or selected such that Ae3250uC<TFRT<Ae3 þ 50uC, where
martensite to get the desired strength. Ae3 is the temperature at which the transformation of
Dual phase steels with ferrite–martensite microstruc- austenite to ferrite starts at equilibrium. After finishing, the
ture have found wide applications in the automotive strip was fast cooled at the proposed cooling rate
sector due to their superior strength formability combi- until an intermediate temperature TINT, given by
nation.19,20 However, these steels have relatively low Ae32320uC<TINT<Ae32300uC was reached. This was
yield strength and low stretch flangeability.21 Addition- followed by natural cooling till the coiling temperature
ally, these steels soften in the heat affected zone.21 given by 450uCvTCTv500uC was attained, and then the
On the other hand, steels with ferrite þ bainite strip was coiled at TCT. Figure 4 shows a schematic diagram
microstructure have much better strength–stretch of the proposed cooling profile.
flangeability balance and fracture toughness.22 Tensile test specimens of 50 mm gage length and
Additionally, problems associated with welding are not 12.5 mm gage width (ASTM E8) were machined parallel
encountered in these steels.21 Hence, bainite was chosen to the transverse direction of the rolled strips. For each
as the second phase microstructure for both steels. steel, a minimum of three samples were prepared from
Taking into consideration all the factors mentioned the tail end of the strips. Tensile tests were carried out
above, a microstructure consisting of precipitation
strengthened ferrite as matrix and bainite as the second
phase was targeted for both grades.

Process design
After hot rolling in a finishing mill, the steel undergoes two
stages of cooling; the first is laminar cooling on the runout
table (RoT), and the second is slow cooling during coiling
of the strip. In general, the total time spent in the RoT is
around 10–12 s. Hence, the challenge of producing a
ferrite þ bainite microstructure in the RoT is that, in this
short time, the austenite has to transform to ferrite and
bainite without any concomitant pearlite formation. At the
same time, martensite formation during cooling or coiling
also has to be prevented.
In order to establish the appropriate RoT cooling
strategy, the continuous cooling transformation (CCT)
diagrams for the selected alloy chemistries were gener- 3 Continuous cooling transformation diagram for selected
ated using a neural network based CCT prediction chemistries generated using neural network based CCT
model.23 For these calculations, only the solid solution prediction model21

Materials Science and Technology 2016 3


Mukherjee et al. Stretch flangeable ferrite – bainite grades

Table 1 Chemical compositions of trial grades with Fe to balance/wt-%

Grade C Mn Si S P Nb V N

Steel 1 ... ,0.005


Steel 2 ,0.07 1.0–1.5 0.1–0.35 ,0.005 ,0.03 ,0.025 0.05–0.06 0.007–0.012

carbon film/extraction replicas started peeling off. The


replicas were then floated in distilled water from where they
were collected on copper grids. The replicas were observed
using a JEOL JEM2200F transmission electron micro-
scope operated at 200 kV. The composition of the
precipitates was determined using energy dispersive X-ray
spectrometry (EDS).

Results
Microstructure
Figures 5 and 6 show the typical optical and scanning
electron micrographs obtained from the hot rolled steel
samples of steels 1 and 2 respectively. In both steels, the
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microstructures were found to have a ferritic matrix and


bainite as second phase. Le Pera24 etching and SEM
confirmed that no measurable martensite was present in
the microstructures. In steel 2, slight banding was
4 Schematic diagram of cooling profile observed, which could be due to the moderately higher
level of manganese used in this steel. In both steels,
the average area fraction of bainite was determined to be
using an electromechanical tensile testing machine
0.25 from standard point counting method. The average
(Instron 5582) at a crosshead speed of 1.67 mm s21.
grain size of ferrite was found to vary between 3.5 and
From the stress–strain data, yield strength (0.2% offset),
3.7 mm in both steels.
tensile strength and total elongation were determined.
Hole expansion tests were carried out according to Precipitation state
ISO 16630 standards on a 60 tonne hydraulic press. For
The precipitation state in steels 1 and 2 are shown in
this, 100| 100 mm square samples with a 10 mm
Figs. 7 and 8 respectively. From EDS analysis, the
diameter hole punched at the centre of the specimens
precipitates were found to consist of either only Nb, or
were used. For each steel, a minimum of four samples
Nb þ Ti in steel 1, whereas in steel 2, the precipitates
were prepared from the tail end of the strips. The pun-
were found to consist of either Nb þ V or Nb þ V þ Ti.
ched hole was expanded using a 50 mm diameter conical
Precipitates containing only Ti were not detected in
punch with a 60u apex angle. All tests were conducted in
either steel. Furthermore, in steel 2, precipitates con-
the burr up position, and no lubricant was applied to the
taining either only Nb, or only V or V þ Ti were not
specimen. The test was stopped as soon as a through
detected. The average atomic per cent of Nb in the
thickness crack was detected. The HER (in %) was cal-
Nb þ Ti containing precipitates in steel 1 was found to
culated according to equation (1), where do and df are
be 54%, indicating that they were only slightly richer in
the initial and final diameters of the punched hole, which
Nb. In steel 2, on the other hand, the average atomic per
were determined by taking the mean of three measure-
cent of Nb in the Ti containing precipitates was found to
ments made roughly at 60u to each other
be 63%, with the average atomic per cent of vanadium
  and titanium being 19 and 22% respectively. In the non-
df 2 do
HER ¼ 100 ð1Þ Ti precipitates, also the average atomic per cent of Nb
do
was 61%, clearly indicating that, in all precipitates of
For the microstructural study, through thickness speci- steel 2, Nb was the dominant component. In both steels,
mens were sectioned, ground and polished according to the Ti containing precipitates were found to be larger
standard metallographic techniques. The samples were with an average size of *30 nm, while the size of the
then etched with 2% nital and examined using light non-Ti precipitates was found to be *17 nm.
optical microscopy as well as scanning electron
Mechanical properties
microscopy (SEM). Some samples were also etched with
the Le Pera24 reagent to detect the presence of marten- The mechanical properties (yield strength, ultimate ten-
site, if any. Ferrite grain size was determined using the sile strength and total elongation) of the hot rolled steels
planimetric method according to ASTM E112 stan- are listed in Table 2. In both steels, the mechanical
dards, using the Leica Q grain software package. properties with respect to ultimate tensile strength and
Transmission electron microscopy (TEM) of carbon HER were achieved.
extraction replicas was carried out to determine the nature
of the precipitates. For preparing the extraction replicas,
polished samples were first etched with 2% nital. The etched
Discussion
samples were then coated with a carbon film following Traditional high strength steels for wheel rim and
which they were immersed in concentrated HCl till the structural applications are produced through the

4 Materials Science and Technology 2016


Mukherjee et al. Stretch flangeable ferrite – bainite grades

5 a optical and b scanning electron micrographs of hot rolled steel 1 grade (a B: bainite; a: ferrite)
Downloaded by [University of Saskatchewan Library] at 00:46 30 March 2016

6 a optical and b scanning electron micrographs of hot rolled steel 2 grade (a B: bainite; a: ferrite)

7 a transmission electron micrograph of carbon extraction replica showing precipitation state in steel 1, b size distribution
of precipitates and EDS spectrum of precipitates marked c A and d B

Materials Science and Technology 2016 5


Mukherjee et al. Stretch flangeable ferrite – bainite grades
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8 a transmission electron micrograph of carbon extraction replica showing precipitation state in steel 2, b size distribution
of precipitates and EDS spectrum of precipitates marked c A and d B

Table 2 Mechanical properties* cooling rate at this stage not only prevents any pearlite
formation but also results in lowering the ferrite start
Steel grade YS/MPa UTS/MPa TEL/% HER/%
temperature, which leads to refinement of the ferrite grain
Steel 1 508¡4 570¡2 29¡4 78¡6 size.25 However, if the cooling rate is too high, it will
Steel 2 566¡3 618¡2 22¡2 77¡2 prevent ferrite formation also, which is not desirable.
The first stage of cooling continues till an intermediate
* YS: yield strength; UTS: ultimate tensile strength; TEL: total
elongation; HER: hole expansion ratio.
temperature (which is below the bainite start temperature
Bs) is reached. The air cooling step beyond this stage results
in the transformation of the remaining austenite to bainite.
conventional continuous casting, i.e. hot strip mill route, The intermediate temperature is, therefore, a very
which, due to their high alloy addition, are not only crucial parameter because if the correct intermediate tem-
expensive but also very difficult to produce through the perature is not attained, apart from insufficient bainite
TSCR route. This work successfully demonstrates that the formation, undesired microstructural components like
same grades can be produced through the TSCR route pearlite and/or degenerate pearlite may form, which not
using much leaner chemistries by appropriately tailoring only affects the tensile properties but also lowers the
the microstructure to achieve the target properties. How- HER.26 A few examples of the above conditions
ever, there are some critical factors pertaining to the design are described here to highlight the significance of attaining
philosophy, which are described in this section. the correct cooling profile.
Figure 9 shows the optical and scanning electron
micrographs of steel 1 produced with a slower than
Microstructure evolution and importance of prescribed cooling rate and a higher than prescribed coiling
cooling profile temperature. The mechanical properties and the ferrite
Continuous cooling lowers the austenite–ferrite trans- grain size thus obtained are listed in Table 3. From the
formation temperature, whereas, when austenite is optical micrograph (Fig. 9a), the microstructure seems to
deformed, the transformation temperature increases. contain only ferrite and pearlite. However, a few bainite
Hence, the finish rolling temperature was set at Ae3+ 50uC islands could be detected at much higher magnifications
to ensure that there is no rolling in the intercritical region. using SEM. The ferrite grain size (Table 3) was also much
This was confirmed by the absence of elongated ferrite higher than the targeted value. Failure to achieve the
grains, typical of intercritical rolling, in the final micro- proper cooling rate led to the inappropriate microstructure
structure. After finish rolling, the deformed austenite was as a result of which the targeted tensile properties could not
cooled on the RoT according to the prescribed cooling be achieved.
strategy. On the basis of several mill trials taken for both Figure 10 shows the scanning electron micrographs of
steel grades, the cooling profile was identified to be one of steel 2 grade produced with the correct initial cooling
the most critical parameters for achieving the desired rate but a high intermediate temperature. The micro-
microstructure and mechanical properties. In the first graphs reveal that the second phase consists of a mixture
stage of cooling, austenite transforms to ferrite. The high of bainitic regions, pearlitic regions and what appears

6 Materials Science and Technology 2016


Mukherjee et al. Stretch flangeable ferrite – bainite grades

9 a optical and scanning electron micrographs of steel 1 produced using improper cooling profile (a: ferrite; P: pearlite;
a B: bainite)

Table 3 Mechanical properties and grain size of steel 1 rolling) of Nb and/or V leading to reduction in their
grade produced using improper cooling profile
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overall effectiveness and hence reduction in the yield


Steel grade YS/MPa UTS/MPa TEL/% Grain size/mm strength.27 Since, in the present work, titanium was not
intentionally added, the detection of titanium containing
Steel 1 465¡7 524¡5 23¡2 6 precipitates in both steels suggests that the scrap used to
make the steel contained traces of titanium. However,
to be ferrite/cementite aggregates that could be bainite and/ the fact that no significant effect on the yield strength
or non-lamellar pearlite or degenerate pearlite. The corre- was recorded implies that the extent of premature pre-
sponding mechanical properties and grain size obtained are cipitation was quite low.
listed in Table 4. Failure to attain the correct intermediate In steel 2, all precipitates had Nb as the dominant com-
temperature might have led to the formation of the non- ponent, which is expected as Nb has a higher dissolution
bainitic components in the microstructure, which not only temperature and hence starts precipitating earlier compared
led to inferior tensile properties but also low HER.26 to V, and the extent of precipitation is also higher. Although
However, due to the correct initial cooling rate, the target the existence of precipitates was confirmed in these steels,
ferrite grain size could be achieved. a detailed TEM study after various processing stages is
required for accurately determining the exact mechanism of
Precipitation behaviour precipitation.
As mentioned earlier, addition of titanium is not pre- In general, the contribution of precipitation strengthening
ferred in TSCR grades because of the high dissolution is determined as a function of the volume fraction and radius
temperature of TiN precipitates. Moreover, the presence of precipitates using the Ashby–Orowan relationsip.16
of titanium also leads to premature precipitation (before However, for design purposes, this relationship is not very

10 Scanning electron micrograph of steel 2 produced using high intermediate temperature (1: bainitic region; 2: pearlitic
region; 3: bainite and/or non-lamellar pearlite)

Table 4 Mechanical properties and grain size of steel 2 grade produced using high intermediate temperature

Steel grade YS/MPa UTS/MPa TEL/% HER/% Grain size/mm

Steel 2 495¡2 556¡1 26¡1 70¡1 3?5

Materials Science and Technology 2016 7


Mukherjee et al. Stretch flangeable ferrite – bainite grades

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