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Development of Stretch Flangeable Ferrite-Bainite Grades Through Thin Slab Casting and Rolling
Development of Stretch Flangeable Ferrite-Bainite Grades Through Thin Slab Casting and Rolling
Development of Stretch Flangeable Ferrite-Bainite Grades Through Thin Slab Casting and Rolling
To cite this article: M. Mukherjee, A.R. Chintha, S. Kundu, S. Misra, J. Singh, C. Bhanu & T.
Venugopalan (2016): Development of stretch flangeable ferrite–bainite grades through thin
slab casting and rolling, Materials Science and Technology
Article views: 69
Download by: [University of Saskatchewan Library] Date: 30 March 2016, At: 00:46
RESEARCH PAPER
Development of stretch flangeable ferrite –
bainite grades through thin slab casting and
rolling
M. Mukherjee*1, A.R. Chintha1, S. Kundu1, S. Misra2, J. Singh3, C. Bhanu3 and
T. Venugopalan4
The focus towards the design of light environment friendly fuel efficient vehicles has led to an
increase in the demand for high strength steels. As it is true for any developing country, the extra
challenge for Indian steel industries is to produce such high strength steels at minimum cost. The
aim of the present work was to develop two high strength steel grades with minimum tensile
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strengths of 540 and 590 MPa, in combination with good ductility and stretch flangeability,
through the thin slab casting and rolling route. The present paper describes the alloy and process
design methodology used for achieving the target properties. Several mill trials were taken to test
the proposed design, wherein the target microstructure and mechanical properties were
successfully achieved.
Keywords: Stretch flangeable, Ferrite, Bainite, Hole expansion ratio
Considering the factors mentioned above, it is necessary the presence of adequate amount of nitrogen (w0.008 wt-
that chemistry and processing parameters specifically %), enhanced precipitation of V(CN) takes place, which not
suited to TSCR conditions be developed, so that prop- only contributes to precipitation hardening but also retards
erties similar to those obtained by traditional routes can recovery and softening of the lower transformation pro-
be achieved. ducts like bainite during prolonged holding at relatively
The aim of the present work was therefore to design the higher temperatures after coiling.11 In view of the above,
chemistry and processing parameters required for produ- two microalloying strategies were adopted, one with only
cing two high strength steel grades, one with a minimum Nb for steel 1, and the other with Nb þ V for steel 2
tensile strength of 540 MPa for wheel rim applications (to account for its higher strength requirement). In order to
(steel 1) and another with a minimum tensile strength determine the maximum permissible amount of Nb which
of 590 MPa for wheel rim as well as structural applications would completely dissolve in austenite during the tem-
(steel 2), commercially through the TSCR mill at perature equalisation process, the dissolution temperatures
Tata Steel, Jamshedpur works. Additionally for both of carbonitrides of Nb and Nb þ V for various Nb and
steels, a minimum HER of 70% was aimed for. N contents were calculated using Thermo-Calc software
using the TCFE7 database.13 The base composition of the
steels used for the calculations was 0.06 wt-%C, 1.3 wt-
Alloy design: metallurgical aspects %Mn, 0.25 wt-%Si, 0.005 wt-%S, 0.012 wt-%P, 0.03 and
At the outset, the various possible strengthening mech- 0.05 wt-%V (for the Nb þ V steels). Considering that AlN
anisms were critically examined so that they could be has a close packed hexagonal structure and its nucleation
effectively utilised to identify the appropriate chemistry kinetics in austenite is very slow,14,15 it was not included in
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and processing parameters required for achieving the the calculations. Figure 1 shows the dissolution tempera-
target properties. The same are discussed below. tures thus calculated, with the average tunnel furnace tem-
perature of 1125uC indicated as a solid line. From the figure,
Solid solution strengthening it is evident that when N content is 0.0085 wt-% or more, the
The most effective solid solution strengthening elements Nb content has to be restricted to 0.025 wt-% to ensure
are Mn and Si. However, Mn levels beyond 1.5% enhance complete dissolution under tunnel furnace conditions. Even
centreline segregation during continuous casting and also when the N content is as low as 0.005 wt-%, Nb content
cause microstructural heterogeneities.9 On the other beyond 0.03 wt-% cannot be used. Since for Nb þ V steels,
hand, Si levels beyond 0.5 wt-% lead to formation of N has to be w0.008 wt-% to ensure enhanced precipitation
surface scales due to oxides of silicon.10 Hence, the Mn of V(CN), the Nb content of both steels was restricted to
level of the steel was fixed at 1.0–1.5 wt-%, whereas v0.025 wt-%.
the Si level was fixed at 0.1–0.35 wt% for the current
development. The carbon level was restricted to Grain refinement
v0.07 wt-%, in order to ensure that the steel composition One of the most effective strengthening mechanisms is
was outside the peritectic range so as to guarantee grain refinement of ferrite.16 Grain refinement is gener-
adequate castability of the steel in the thin slab caster.11 ally brought about using the controlled rolling technol-
Lower carbon content also results in good weldability, ogy, which is possible with proper use of microalloying
which is necessary for automotive grades.11 elements. The minimum ferrite grain size achievable by
this method is 3–5 mm.17
The contribution of each of the mechanisms mentioned
Precipitation strengthening
above, to the yield strength of ferrite, was calculated using
Precipitation strengthening is brought about by the for- standard empirical equations applicable to microalloyed
mation of fine precipitates of microalloyed carbides, steels,18 and the same is illustrated in Fig. 2. The figure also
nitrides or carbonitrides. In order to form such fine pre- shows the maximum attainable yield strength of ferrite
cipitates, it is necessary that the microalloying elements calculated as the sum of the contributions from all the
remain in solid solution till the time rolling commences.
However, since the TSCR process involves very short dur-
ation soaking at relatively low temperatures before rolling,
the choice of the microalloying elements must be judiciously
made so as to ensure complete dissolution during tem-
perature equalisation. The most commonly used micro-
alloying elements are Ti, Nb and V. Among these, Ti is
generally avoided in TSCR grades because the dissolution
temperature of TiN precipitates (if formed during the prior
processing steps) is very high, and hence, these precipitates
are likely to remain undissolved even after temperature
equalisation. In fact, the tunnel furnace conditions may
only lead to coarsening of the TiN precipitates, rendering
them ineffective for precipitation strengthening.8 On the
other hand, the dissolution temperature of niobium is much
lower than titanium. Moreover, apart from precipitation
hardening, Nb retards recrystallisation of austenite and
lowers the austenite–ferrite transformation temperature, 1 Dissolution temperature of Nb(CN) or (Nb,V)(CN) in aus-
both factors leading to enhanced grain refinement of ferrite tenite for various Nb and N contents calculated using
in Nb microalloyed steels.8,12 The dissolution temperature Thermocalc;11 solid line represents average tunnel
of vanadium is even lower than both Nb and Ti. Further, in furnace temperature of 11258C
Process design
After hot rolling in a finishing mill, the steel undergoes two
stages of cooling; the first is laminar cooling on the runout
table (RoT), and the second is slow cooling during coiling
of the strip. In general, the total time spent in the RoT is
around 10–12 s. Hence, the challenge of producing a
ferrite þ bainite microstructure in the RoT is that, in this
short time, the austenite has to transform to ferrite and
bainite without any concomitant pearlite formation. At the
same time, martensite formation during cooling or coiling
also has to be prevented.
In order to establish the appropriate RoT cooling
strategy, the continuous cooling transformation (CCT)
diagrams for the selected alloy chemistries were gener- 3 Continuous cooling transformation diagram for selected
ated using a neural network based CCT prediction chemistries generated using neural network based CCT
model.23 For these calculations, only the solid solution prediction model21
Grade C Mn Si S P Nb V N
Results
Microstructure
Figures 5 and 6 show the typical optical and scanning
electron micrographs obtained from the hot rolled steel
samples of steels 1 and 2 respectively. In both steels, the
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5 a optical and b scanning electron micrographs of hot rolled steel 1 grade (a B: bainite; a: ferrite)
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6 a optical and b scanning electron micrographs of hot rolled steel 2 grade (a B: bainite; a: ferrite)
7 a transmission electron micrograph of carbon extraction replica showing precipitation state in steel 1, b size distribution
of precipitates and EDS spectrum of precipitates marked c A and d B
8 a transmission electron micrograph of carbon extraction replica showing precipitation state in steel 2, b size distribution
of precipitates and EDS spectrum of precipitates marked c A and d B
Table 2 Mechanical properties* cooling rate at this stage not only prevents any pearlite
formation but also results in lowering the ferrite start
Steel grade YS/MPa UTS/MPa TEL/% HER/%
temperature, which leads to refinement of the ferrite grain
Steel 1 508¡4 570¡2 29¡4 78¡6 size.25 However, if the cooling rate is too high, it will
Steel 2 566¡3 618¡2 22¡2 77¡2 prevent ferrite formation also, which is not desirable.
The first stage of cooling continues till an intermediate
* YS: yield strength; UTS: ultimate tensile strength; TEL: total
elongation; HER: hole expansion ratio.
temperature (which is below the bainite start temperature
Bs) is reached. The air cooling step beyond this stage results
in the transformation of the remaining austenite to bainite.
conventional continuous casting, i.e. hot strip mill route, The intermediate temperature is, therefore, a very
which, due to their high alloy addition, are not only crucial parameter because if the correct intermediate tem-
expensive but also very difficult to produce through the perature is not attained, apart from insufficient bainite
TSCR route. This work successfully demonstrates that the formation, undesired microstructural components like
same grades can be produced through the TSCR route pearlite and/or degenerate pearlite may form, which not
using much leaner chemistries by appropriately tailoring only affects the tensile properties but also lowers the
the microstructure to achieve the target properties. How- HER.26 A few examples of the above conditions
ever, there are some critical factors pertaining to the design are described here to highlight the significance of attaining
philosophy, which are described in this section. the correct cooling profile.
Figure 9 shows the optical and scanning electron
micrographs of steel 1 produced with a slower than
Microstructure evolution and importance of prescribed cooling rate and a higher than prescribed coiling
cooling profile temperature. The mechanical properties and the ferrite
Continuous cooling lowers the austenite–ferrite trans- grain size thus obtained are listed in Table 3. From the
formation temperature, whereas, when austenite is optical micrograph (Fig. 9a), the microstructure seems to
deformed, the transformation temperature increases. contain only ferrite and pearlite. However, a few bainite
Hence, the finish rolling temperature was set at Ae3+ 50uC islands could be detected at much higher magnifications
to ensure that there is no rolling in the intercritical region. using SEM. The ferrite grain size (Table 3) was also much
This was confirmed by the absence of elongated ferrite higher than the targeted value. Failure to achieve the
grains, typical of intercritical rolling, in the final micro- proper cooling rate led to the inappropriate microstructure
structure. After finish rolling, the deformed austenite was as a result of which the targeted tensile properties could not
cooled on the RoT according to the prescribed cooling be achieved.
strategy. On the basis of several mill trials taken for both Figure 10 shows the scanning electron micrographs of
steel grades, the cooling profile was identified to be one of steel 2 grade produced with the correct initial cooling
the most critical parameters for achieving the desired rate but a high intermediate temperature. The micro-
microstructure and mechanical properties. In the first graphs reveal that the second phase consists of a mixture
stage of cooling, austenite transforms to ferrite. The high of bainitic regions, pearlitic regions and what appears
9 a optical and scanning electron micrographs of steel 1 produced using improper cooling profile (a: ferrite; P: pearlite;
a B: bainite)
Table 3 Mechanical properties and grain size of steel 1 rolling) of Nb and/or V leading to reduction in their
grade produced using improper cooling profile
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10 Scanning electron micrograph of steel 2 produced using high intermediate temperature (1: bainitic region; 2: pearlitic
region; 3: bainite and/or non-lamellar pearlite)
Table 4 Mechanical properties and grain size of steel 2 grade produced using high intermediate temperature
useful, as determination of volume fraction and radius of 6. F. Siciliano, L. A. L. Lezama, C. Klinkenberg and K. E. Hensger:
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