AVKI

NTERNATI
ONALRESI
DENTIALSR.SEC.SCHOOL,
(CBSE)
SANKARANKOVIL
WORKSHEET
CHEMISTRY
STD :XII
CHAPTER :10.ALCOHOLS,PHENOLS&ETHERS

1)
Classi
fyt
hef
oll ngas10,
owi 20&30al
cohol
s:

2)Namet
heabov
ecompoundsaccor
dingt
oIUPACsy
stem.

3)Wr
it
est
ruct
uresoft
hef
oll
owi
ngcompounds.

(
i)4-
Bromo-
3-et
hyl
but
an-
1-ol (
ii
)2,
3-Di
met
hyl
phenol

(
ii
i)3,
5-Di
met
hyl
hexane-
1,3,
5-t
ri
ol (
iv)1-
Pheny
lpr
opan-
2-ol

(
v)Cy
clohex-
3-en-
1-ol (
vi)3-
Cycl
ohexy
lpent
an-
3-ol

(
vii
)Et
hoxy
-3-
met
hyl
pent
ane (
vii
i
)Cy
clohexy
lmet
hanol

(
ix)2-
Met
hyl
propan-
2-ol (
x)1,
2-Di
met
hoxyet
hane

4)Drawthestr
uct
uresofal
lisomer
sofmol
ecul
arf
ormul
aC5H12Oandgi
vet
hei
rIUPACnamesandcl
assi
fy
0 0 0
thecompoundsas1, 2 &3.

5)Drawthestr
uct
uresofal
lisomer
sofmol
ecul
arf
ormul
aC6H14Oandgi
vet
hei
rIUPACnamesandcl
assi
fy
0 0 0
thecompoundsas1, 2 &3.

6)Drawthestr
uct
uresofal
lisomer
sofmol
ecul
arf
ormul
aC4H10Oandgi
vet
hei
rIUPACnamesandcl
assi
fy
0 0 0
thecompoundsas1, 2 &3.
7)Whyal
cohol
shav
ehi
gherboi
l
ingpoi
ntst
hanhy
drocar
bonsofcompar
abl
emol
ecul
armasses.

8)Whyal
cohol
sar
emor
esol
ubl
einwat
ert
hanhy
drocar
bonsofcompar
abl
emol
ecul
armasses.

9)Gi
veI
UPACnamesoft
hef
oll
owi
ngcompounds.

10)Wr
it
ethemechani
sm ofhy
drat
ionofet
henet
oet
hanol
.

11)Expl
aint
hef
oll
owi
ngwi
thanexampl
e.

(
i)Rei
mer
-Ti
emannr
eact
ion (
ii
)Wi
l
li
amsonet
hersy
nthesi
s

(
ii
i)Kol
be’
sreact
ion (
iv)Est
eri
fi
cat
ion (
v)Unsy
mmet
ri
cal
ether

12)Expl
aint
hemechani
sm ofdehy
drat
ionofet
hanol
toet
hene.

13)Namet
her
eagent
susedi
nthef
oll
owi
ngr
eact
ion.

(
i)Oxi
dat
ionof10al
cohol
tocar
boxy
li
caci
d(i
i
)Reduct
ionofcar
boxy
li
caci
dto10al
cohol

(
ii
i)Oxi
dat
ionof10al
cohol
toal
dehy
de (
ii
i)Reduct
ionofal
dehy o10al
det cohol

(
iv)Oxi
dat
ionof20al
cohol
toket
one (
v)Reduct
ionofket o20al
onet cohol

(
vi)Benzy
lal
cohol
toBenzoi
caci
d (
vi)Benzy
lal
cohol
toBenzal
dehy
de
 (
vii
)But
-1-
enet
oBut
an-
2-ol (
vii
i
)But
-1-
enet
oBut
an-
1-ol

(
ix)Phenol
tomono-
nit
rophenol (
x)Phenol
tot
ri
-ni
tr
ophenol

(
xi)Phenol
toBenzene (
xii
)Benzenet
oPhenol

(
xii
i
)Phenol
toBenzoqui
none

14)Showhowwoul
dyousy
nthesi
sthef
oll
owi
ngal
cohol
sfr
om appr
opr
iat
eal
kenes?

15)Ar
ranget
hesetoff
oll
owi
ngcompoundsi
nincr
easi
ngor
deroft
hei
raci
dst
rengt
h.

(
i)2,
4,
6-Tr
ini
tr
ophenol
;3-
Nit
rophenol
;3,
5-Di
nit
rophenol
;Phenol
.

(
ii
)Pr
opan-
1-ol
;3-
Nit
rophenol
;3-
Met
hyl
phenol
;Phenol
.

(
ii
i)But
an-
2-ol
;2-
Met
hyl
but
an-
2-ol
;But
an-
1-ol
.

16)Ar
ranget
hesetoff
oll
owi
ngcompoundsi
nincr
easi
ngor
derofboi
l
ingpoi
nts.

(
i)Met
hanol
;Pent
anol
;Et
hanol
;Hexanol
;But
anol
.

(
ii
)Et
hoxy
ethane;
But
anol
;n-
Pent
ane.

(
ii
i)3-
Met
hyl
Pent
an-
2-ol
;Hex
an-
1-ol
;2,
3-Di
met
hyl
But
an-
2-ol
;Hexan-
2-ol
.

17)Ar
ranget
hesetoff
oll
owi
ngcompoundsi
ndecr
easi
ngor
derofsol
ubi
l
ityi
nwat
er.

(
i)Met
hanol
;Pent
anol
;Et
hanol
;Hexanol
;But
anol
.

(
ii
)Et
hoxy
ethane;
But
anol
;n-
Pent
ane.

(
ii
i)3-
Met
hyl
Pent
an-
2-ol
;Hex
an-
1-ol
;2,
3-Di
met
hyl
But
an-
2-ol
;Hexan-
2-ol
.

18)Dot
heconv
ersi
ons.

(
i)Pr
openet
oPr
opan-
2-ol

(
ii
)Et
hanol
toPr
opan-
2-ol

(
ii
i)Met
hyl
magnesi
um br
omi
det
o2-
Met
hyl
propan-
2-ol
 (
iv)Chl
orobenzenet
oPhenol

(
v)Ani
l
inet
oPhenol

(
vi)Acet
onet
o2-
Met
hyl
but
an-
2-ol

(
vii
)But
anol
toPent
an-
2-ol

19)Wr
it
etheequat
ionoft
hef
oll
owi
ng

(
i)r
eact
ionofHIwi
th1-
Propoxypr
opane (
ii
)react
ionofHIwi
thbenzy
let
hyl
ether

(
ii
i)r
eact
ionofHIwi
tht
ert
-but
ylpr
opy
let
her (
iv)r
eact
ionofHBrwi
thbenzy
lpheny
let
her

(
v)r
eact
ionofHBrwi
thet
hyl
but
ylet
her (
vi)r
eact
ionofHBrwi
thAni
sol
e

(
vii
)Fr
iedel
-Cr
aft
sal
kyl
ati
onofani
sol
e (
vii
i
)Br
omi
nat
ionofani
sol
e

(
ix)Fr
iedel
-Cr
aft
sacet
ylat
ionofani
sol
e (
x)Ni
tr
ati
onofani
sol
e

20)Wr
it
egoodequat
ionf
ort
hepr
epar
ati
onoft
hef
oll
owi
nget
her
sbywi
l
li
amson’
ssy
nthesi
s.

(
i)1-
Propoxypr
opane (
ii
)1-
Met
hoxyet
hane

(
ii
i)2-
Met
hoxy
-2-
met
hyl
propane (
iv)Et
hoxybenzene

(
v)t
ert
-but
ylmet
hyl
ether (
vi)Benzy
let
hyl
ether
29)Howshal
lwedi
sti
ngui ween10,
shbet 20&30al
cohol
swi
thsui
tabl
echemi
cal
equat
ions?

30)Just
if
ytheaci
dit
yofal
cohol
andphenol
.