7 Resonence Educating for better tomorrow TARGET : JEE (Main + Advanced) 2017 Course : VIKAAS (JA) Date : 27-04-2015 TEST INFORMATION DATE : 24.05.2015 PART TEST-1 (PT-1) (ADVANCED) Syllabus : IUPAC Nomenclature (Alkane, Alkene, Alkyne, Cyclohexane and Non-chain terminating Functional groups). (All Cheminfos and Handouts till date) This DPP is to be discussed in the week (27-04-2015 to 02-05-2015) DPP No. # 01 (JEE-MAIN) Total Marks : 65 Max. Time : 40 min. Single choice Objective negative marking) Q.1 to. 0.15 (3 marks, 2 min.) [45,30] ChemINFO : § Questions ('-1" negative marking) 2.16 to @.20 (4 marks, 2 min.) (20, 10] 1. Stable valency of carbon is (Bivalency (@)Trivalency (C) Tetravalency (©)Monovalency corde wag stator & (A) fase (B) Presi (Cy ages (D) weenie 2, Which ofthe following is saturated hydrocarbon? fre & ater sige ereghorde 8 al] ans © OAN 3. Carbon has strong tendency to show catenation due to: (A) Its tetravalency (B) small size (C) Its high C -C bond energy (D*)Allof these cords A varies sper a YT UTET T a TET B (A) sera gaia © vr stoR (0) 8a) afta C-C aa Gat (0 wae we 4, Which of the following is the empirical formula of C,H, ? CH, ar ypTgaTAh ys Fr A a ats 8? (A*) CH (8)CH, OCH, (O) none of these wycH @cH, ocH, Ori a ag adi 5. AW and “~Z~ are (A) Identical (B*) Homologous (C) Alkane (0) Saturated hydrocarbon Aw VIAL , (A) areT (8°) ror (©) tet (O) aya eegrersT 6. What is the general formula of alkene ? feos ar aaa ya aa 8? AG Hoo @)CH,, OCH... OCH,,.. arpa Oc TS Tower AS BER ot Wa, avy Ro Raa RESONSNCE rene rmaresmmeonT Educating for better tomorrow carrraeTaGO ZOD ZIGT TOD 255 SESS] CH USSISERIEOOTPT COTO7. Howmany and. bonds are in the given compound ? HC =C—CH=CH, (A)3xand6cbonds — (B*)3nand7obonds (C)2rand7c bonds (D) 4x and 8 bonds feet Ta chit # ferent a TM o ae ei? Hc=C—CH=CH, (A) 3x 2 6c ae (B*) 3x aM 7a ae (©) 2n cH To det (0) 4x ee Body 8. Which ofthe following has 28 molecular mass ? fre 8 & Poway amy ae 26 & ? (A)CH, (CH, (CICH, OCH, 9. Which ofthe followings unsaturated hydrocarbon fre #8 ats ong eregrors & ? 0 a OS © CY OZZ 40. Which of the following is third member of C,H, 1, homologous series ? arch error Ava aor Stew aera ah CH, ? @CH, @cH, CCH, OCH, 44. Which of the following is molecular formula of =? SS a tae as aise 8? ACH, @cH, CCH, cH, 42, Which ofthe folowing nave same molecular formula ? Presta 9 Fos Sa | wT & ? WAS el] on (Oy Allofthese stan wh 13, Total number of bonds in HC = C-C = CH? HO=C-C=CH # ys aeh fh eieen 8? ays 9 ©10 on 14. How many hydrogen atoms are present in the given structure ? Boh deat 4 faery eregiory RAM wafer & (A)20 (B21 (22 (023 48. Howmany C-C o bonds are present in the given structure ? wh dea § fer C-C oa after #) a v a Nu at (B)2 3 Oa arpa Oi CS Tot SH BER War Ci Wa Tay Ro Rae ay Resonance} ducating for better tomorrow& ChemINFO- Oem etc) Daily Self-Study Dosage for mast ing Chemistry Hybridisation of 2 ay and halogen atoms ree of carbon, soos [Hybridisation of carbon in its compounds : [Carbon has three types of hybridisation inits compounds : (1) sp’ (2) sp* @sp Hybridisation No, of bonds formed by carbon Example 1 ES iy i noc 4 $F 1 sp 2 Ha@e=H Examples ee se ae ()HC-CH=CH-CH, —@) C=C = CH-CH, Degree of carbon, hydrogen and halogen atoms : Degree of Carbon | No. of Carbon attached Example 4° or Primary 1 He —CH, 2° or Secondary 2 CH,-CH,—CH, 3° or Tertiary 3 4° or Quaternary 4 INote: Hydrogen and halogen attached to 1°, 2° and 3° carbon atom are called 1°, 2° and 3° hydrogen and halogen atoms respectively. Ex. 1°,2°,3° and 4° carbon atoms and 1°, 2° and 3° hydrogen atoms are illustrated below. te é, “e &y,- oa CH, cH CH, [Memorize this theory as soon as you get the DP. Revize it regularly and master this concept by practice! 46. The state of hybridization of the asterisked carbon in CH,~CH = C*= CH, is (A) sp (8) sp? (©)sp" (D) none of these Resonance mete amet £68 To a8 «6, Pi Tn Gy Wa ei owt i TO47. Ketene CH, = C= Ohas (A) Only sp? carbon atom (© Only sp carbon atom (C*) sp? and sp carbon atoms (©) sp°, sp? and sp carbon atoms 18. Number of tertiary carbon in the following compound ans ee ©@7 os 19. Number of secondary halogen in the given compound are a ( cl (aye es ©3 os 20. Number of primary hydrogens the given compound are cH, CH, CH, cH, CH, a) 10 @ 18 14 0) 16 arpa Oi CS Tot SH BER War Ci Wa Tay Ro Rae ay Resonance} ducating for better tomorrowOem etc) ‘Hybridisation of carbon, degree of carbon, hydrogen and halogen atoms ChemINFO- ards a1 vad aiftel A dow: fords a te Hae at rer sre ere B) = (1) spe (2) sp* @)sp wae i a a) ao eae OY PT Tae i sp? 0 H—EoH H sp 1 sp 2 Benewol : wow oe ae (1) H.C CH = CH-CH, (@) H.C =C=CH-CH, fords, erggiort a ators ueamsit At one coda a aie ge gona At den saree 49 sora srerfra 1 6 — CH, 2e sera firm 2 H,-CH,- CH, GH, 3° spre qetaa 3 He. -& H 4 oem ay 4 Note: 1°, 2°4 3° wide weary & qua 4a ereshord da Reto HIM a HRI: 1°, 2° 4 3° elgghord a Belo weary wea 8 Ex, 1°, 2°, 3° 4° ards seem a 1°, 2° 3° erator say Aa ara wa | [Memorize this theory as soon as you get the DPP. Revize it regularly and master this concept by practicel 18. 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