DELHI PUBLIC SCHOOL JODHPUR

HALF YEARLY EXAMINATION-2020-21

CLASS-11
CHEMISTRY (Theory)

Duration: 2 1/2 Hrs MM:50

General Instructions:
(1) All questions are compulsory.
(2) Marks against each question are indicated.
(3) Questions from one to 12 are MCQ type questions carrying one mark each
(4) In each of the questions from one to twelve ,only one option is correct. Write the
correct option
(5) Questions from 12 to20 are very short answer type questions carrying one mark
each.
(6) Questions from 21 to25 are short answer type questions carrying two marks each.
(7) Questions from 26 to 30 are short answer type questions carrying three marks each.
(8) Questions 31 is a long answer type questions carrying five mark .
1. The element with Z = 120 (not yet discovered) will be an/a

(a) Inner-transition metal (b) Transition metal

(c) Alkaline earth metal (d) Alkali metal

2.

3. Which of the following donot belong to d-block elements?

4. Number of angular nodes for 4d orbital is __________.

(a) 4 (b) 3

(c) 2 (d) 1

5. The probability density plots of 1s and 2s orbitals are given in

Fig. 2.1The density of dots in a region represents the
probability density of finding electrons in the region. On the
basis of above diagram which of the following statements is
incorrect?
 (a) 1s and 2s orbitals are (b) The probability density of electrons for 2s orbital
spherical in shape. decreases uniformly as distance from the nucleus increases.

(c) The probability of (d) The probability of finding the electron at a given distance
is equal in all directions
finding the electron is maximum
near the nucleus

6. In an atom maximum number of orbitals associated with n+l = 7 can be __________.

(a) 4 (b) 9

(c) 16 (d) 12

7. Which of the following is incorrect about Orbitals:

(a) angular momentum of (b) in H atom energy of electron in

electron in : 2S orbital is : 2s orbital is same as in 2p orbital
not equal to 3s orbital

(c) size of 2p orbital is (d) shape of 3p orbital is same as that of 4p orbital

not same as that of 3p
orbital

8. The pair of ions having same number of unpaired electrons

(a) Cr3+, Fe3+ (b) Cr3+, Mn2+

(c) Fe2+, Mn2+ (d) Cr3+, Co2+

9. What will be the molality of the solution containing 0.5 mole glucose is dissolved 0.49kg of its
aqueous solution ?

(a) 1.02molal (b) 1.25

(c) 1m (d)1.5

10. The types of hybrid orbitals of nitrogen in NO2+, NO3– and NO2- respectively are expected
to be

(a) sp, sp3 and sp2 (b) sp, sp2 and sp2

(c) sp2, sp2 and sp3 (d) sp2, sp3 and sp2

11. In which of the following pairs I molecule is more polar than ii molecule

(a) SO2 or SO3 (b) CO2 Or CO

(c) BF3 , BCl3 (d) SiF4, XeF4

12. Which of the following species has tetrahedral geometry

 (a) BH4– (b) CO32–

(c) SF4 (d) HNO3

13. The empirical formula and molecular mass of a compound are CH2O and 120 g
respectively. What will be the molecular formula of the compound?

14. What do you mean by term limiting reagent in a chemical reaction ?

15. If travelling at same speeds, arrange the following matter waves in increasing order of
wavelength? (i) Electron (ii) Alpha particle (He2+) (iii) Neutron (iv) Proton

16. Write the electronic configuration of As (Z=33)

17. Write the IUPAC symbol for an element having atomic number 109.

18. Arrange the following in increasing order of electronegativity O, S, Cl, F.

19. What is the type of hybridisation of carbon atoms marked with star.

20. Draw the lewis structure of carbon monoxoide

OR
Draw the lewis structure of NO2

21. In three moles of ethane (C2H6), calculate the following :

(i) mass of ethane . (ii) Number of hydrogen atoms.

22. Define the following (i) molarity (ii) mole fraction

23. The first ionization enthalpy (Δi H ) values of the second period elements, Li, Be and C are
respectively 520, 900 and 1090 kJ mol-1. Predict whether the first Δi H value for B will be more
close to 800 or 1000 kJ mol-1 ? Justify your answer.
24. . Match the species in Column I with the geometry/shape in Column II.

Column I Column II

(i) H3O+ (a) Linear

(ii) HC ≡ CH (b) See saw

(iii) SF4 (c) Tetrahedral

(iv) NH4+ (d) Trigonal bipyramidal

(e) Pyramidal
25. Define the following :- (i) bond order (ii) bond angle (iii) bond enthalpy

OR

Draw canonical structure and resonance hybrid of ozone, also find bond order and explain
why both the O-O bond length are identical in O3 molecule ?

26. Sulphuric acid reacts with sodium hydroxide as follows :H2SO4 + 2NaOH —> Na2SO4 + 2H2O
When 1L of 0.1M sulphuric acid solution is allowed to react with 1L of 0.1M sodium hydroxide
solution, the mass of sodium sulphate formed and its molarity in the solution obtained is
(atomic mass Na=23,S=32,O=16)

27. (i) An atomic orbital has n = 3. What are the possible values of l and ml ?
(ii) List the quantum numbers (ml and l ) of electrons for 3d orbital.
(iii) Which of the following orbitals are possible? 1p, 2s, 2p and 3p

28. Considering the atomic number and position in the periodic table, arrange the following
elements in the increasing order of property mentioned
(i)Si, Be, Mg, Na, P. (metallic character )
(ii) Mg, Mg2+, Al, Al3+ . (size of atoms and ions)
(iii) P, S, Cl, F (electron gain enthalpy)

29. Describe hybridisation in the case of PCl5 also explain The length of axial bonds and
equatorial bonds in PCl5

OR
Describe hybridisation in the case of SF6 also explain The length of axial bonds and
equatorial bonds in SF6

30. Briefly describe the valence bond theory of covalent bond formation by taking an example of
hydrogen.

OR

Write the difference between sigma and pie bond

31. (i) Explain the Line Spectrum of Hydrogen

(ii) What are the frequency and wavelength of a photon emitted during a transition
from n = 5 state to the n = 2 state in the hydrogen atom?
OR

(i) Write the statement of Heisenberg’s Uncertainty Principle and its mathematical
form
(ii) Calculate the energy associated with the first orbit of He+ . What is the radius of this orbit?